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    • 2. 发明授权
    • Polyamide supported metallocene catalysts
    • 聚酰胺负载金属茂催化剂
    • US07309678B2
    • 2007-12-18
    • US11094681
    • 2005-03-29
    • David John RauscherWilliam John GauthierShady Nader HenryKai Hortmann
    • David John RauscherWilliam John GauthierShady Nader HenryKai Hortmann
    • B01J31/16
    • C08F10/00C08F4/65912C08F4/65927C08F110/06Y02P20/52Y10S526/904Y10S526/943C08F4/65916C08F2500/16C08F2500/15C08F2500/12C08F2500/18
    • Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers such as the polymerization of propylene to produce syndiotactic polypropylene or isotactic polypropylene. The supported catalyst comprises a stereospecific metallocene catalyst component and a co-catalyst component comprising an alkylalumoxane. Both the metallocene catalyst component and the co-catalyst component are supported on a particulate polyamide support comprising spheroidical particles of a polyamide having an average diameter with the range of 5-60 microns, and a porosity permitting distribution of a portion of the co-catalyst within the pore volume of the polyamide particles while retaining a substantial portion on the surface of the particles. The polyamide support is characterized by relatively low surface area, specifically a surface area less than 20 square meters per gram. The metallocene component can take the form of a single metallocene or two or more co-supported metallocenes.
    • 支持的立体定向催化剂和用于衍生自烯属不饱和单体的聚合物链的立体定向扩散的方法,例如丙烯聚合以产生间同立构聚丙烯或全同立构聚丙烯。 载体催化剂包括立体特异性茂金属催化剂组分和包含烷基铝氧烷的助催化剂组分。 金属茂催化剂组分和助催化剂组分均负载在包含平均直径为5-60微米范围的聚酰胺的球形颗粒的颗粒聚酰胺载体上,并且允许一部分助催化剂分布的孔隙率 在聚酰胺颗粒的孔体积内,同时保留颗粒表面上的实质部分。 聚酰胺载体的特征在于相对较低的表面积,特别是小于20平方米/克的表面积。 金属茂组分可以采用单一茂金属或两种或多种共支撑金属茂的形式。