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    • 10. 发明授权
    • Preparing copolymers of carboxylic acid, aromatic vinyl compound and hydrophobic polyalkylene oxide
    • 制备疏水改性的低阻燃共聚物的方法,疏水改性的低阻燃共聚物及其作为水泥添加剂的用途
    • US06528593B1
    • 2003-03-04
    • US09762853
    • 2001-02-14
    • Juergen EifflerChristoph FroehlichKerstin Stranimaier
    • Juergen EifflerChristoph FroehlichKerstin Stranimaier
    • C04B702
    • C04B24/2641C04B24/32C08G65/332C08L71/02
    • A process for the preparation of a copolymer comprises reacting in an aqueous medium at a temperature of from 25° C. to 100° C. in the presence of from 1.0-25 weight percent based on the total weight of a), b) and c) of a free-radical initiator, a) at least one monomer selected from the group consisting of &agr;,&bgr;-unsaturated monocarboxylic acids and their salts, &agr;,&bgr;-unsaturated dicarboxylic acids, their half-esters free of polyoxyalkylene side chains and their salts, b) at least on olefinic monomer selected from the group consisting of aromatic vinyl compounds, vinyl ethers, vinyl esters, nitrogen-containing vinyl compounds and aliphatic olefins, and c) from 0.01 to 30 weight percent based on the total amount of a), b) and c) of at least one hydrophobic compound free of olefinic unsaturation containing units of the formula: wherein R1 is independently at each occurrence selected from the group consisting of hydrogen and C1-C4 alkyl, with the proviso that at least one R1 is selected from the group consisting of C1-C4 alkyl.
    • 制备共聚物的方法包括在水介质中在25℃至100℃的温度下,以1.0-25%(重量)a),b)和 c)自由基引发剂,a)至少一种选自α,β-不饱和一元羧酸及其盐的单体,α,β-不饱和二羧酸,它们不含聚氧化烯侧链的半酯和 其盐,b)至少在选自芳族乙烯基化合物,乙烯基醚,乙烯基酯,含氮乙烯基化合物和脂族烯烃的烯烃单体,和c)基于总量的0.01至30重量% ),b)和c)至少一种不含烯属不饱和键的含有下式的单元的疏水性化合物:其中R 1在每次出现时独立地选自氢和C 1 -C 4烷基,条件是至少一个 R1是sel 由C1-C4烷基组成的组。