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    • 4. 发明授权
    • Stabilized modifier and impact modified thermoplastics
    • 稳定改性剂和冲击改性热塑性塑料
    • US5451624A
    • 1995-09-19
    • US196742
    • 1994-02-15
    • Nazir A. MemonRichard H. Weese
    • Nazir A. MemonRichard H. Weese
    • C08K3/32C08K3/28C08K5/13C08K5/37C08K5/52C08K5/524C08L51/04C08L101/00C08K5/526C08K5/36
    • C08L51/04C08L101/00Y10S525/902
    • The invention relates to improved thermoplastic compositions composed of one or more thermoplastics (component A), and a stabilized MBS core shell graft copolymer (component B) formed from a rubber-elastic core based on polybutadiene, and a hard graft shell.The stabilized MBS core shell graft copolymer (component B) contains a special stabilization formulation of at least one hindered phenol, a phosphite, an organic sulfide, and optionally a pH buffer system. The stabilized MBS core shell graft copolymer improves the impact strength and heat aging properties of thermoplastic compositions and polyacetal compositions.The shaped articles produced from the improved thermoplastic compositions are particularly distinguished by an excellent high-temperature impact strength and a good heat aging performance.
    • 本发明涉及由一种或多种热塑性塑料(组分A)组成的改进的热塑性组合物和由基于聚丁二烯的橡胶弹性芯形成的稳定的MBS核壳接枝共聚物(组分B)和硬质接枝壳。 稳定的MBS核壳接枝共聚物(组分B)含有至少一种受阻酚,亚磷酸盐,有机硫化物和任选的pH缓冲体系的特殊的稳定化配方。 稳定的MBS芯壳接枝共聚物改善了热塑性组合物和聚缩醛组合物的冲击强度和热老化性能。 由改进的热塑性组合物制成的成形制品特别地具有优异的高温冲击强度和良好的热老化性能。
    • 6. 发明授权
    • Modifier for polypropylene imparting improved melt strength
    • 聚丙烯改性剂提高熔体强度
    • US5506307A
    • 1996-04-09
    • US428284
    • 1995-04-25
    • Nazir A. Memon
    • Nazir A. Memon
    • C08L23/10C08L29/00C08L33/04C08L33/06C08L23/16C08L33/12
    • C08L23/10C08L33/06
    • Polymer melt blends of a homopolymer of propylene or a copolymer of propylene with up to 40 weight percent of another monoolefin, with a homopolymer of one or more of a C.sub.10 to C.sub.30 alkyl (meth)acrylate or a copolymer containing at least 70 weight percent of the one or more C.sub.10 to C.sub.30 ester of an alkyl (meth)acrylate with up to 30 weight percent of one or more of a C.sub.1 to C.sub.9 alkyl (meth)acrylate, the homopolymer or copolymer having a weight-average molecular weight of at least 670,000, exhibit a relative characteristic time, as herein described, at least five (5) times that for the unmodified homo- or copolymer of polypropylene, and a melt strength ratio (as judged by relative sag resistance) at least 5 times that of the unmodified homo- or copolymer of polypropylene. Such blends are useful in thermoforming operations wherein sheet is thermoformed into cartons, containers, appliance housings, and the like.
    • 丙烯均聚物或丙烯与至多40重量%的另一种单烯烃的共聚物与(甲基)丙烯酸C 10〜C 30烷基酯的一种或多种的均聚物或含有至少70重量% 一种或多种(甲基)丙烯酸烷基酯的一种或多种C 10至C 30酯与至多30重量%的一种或多种(甲基)丙烯酸C1至C9烷基酯的均聚物或共聚物的重均分子量至少为 表现出相对特征时间,如本文所述,至少五(5)倍于未改性的聚丙烯均聚物或共聚物,以及熔体强度比(通过相对抗流挂性测定)至少为5倍 未改性的聚丙烯均聚物或共聚物。 这样的共混物可用于热成型操作,其中片材被热成型为纸箱,容器,电器外壳等。