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1. 发明授权

US09791603B2 Optical stack comprising adhesive 有权
公开(公告)号：US09791603B2
公开(公告)日：2017-10-17
申请号：US14005912
申请日：2012-03-26
申请人： William F. Edmonds , Brandt K. Carter , Jason S. Petaja
发明人： William F. Edmonds , Brandt K. Carter , Jason S. Petaja
IPC分类号： G02B27/10 , G02B27/12 , B64D47/06 , G02F1/1335 , G02B5/04 , C09J133/08 , C09J7/02 , C09J151/06
CPC分类号： G02B5/045 , C08L2205/04 , C09J7/38 , C09J133/08 , C09J151/06
摘要： Presently described are optical stacks comprising a first optical film comprising a plurality of structures comprising an optically active portion designed primarily to provide optical gain and optionally an optically in-active bonding portion disposed on a first surface bonded to a second optical film with a light-transmissive adhesive layer such that a portion of the structures penetrate the adhesive layer and a separation is provided between the adhesive layer and the first surface. In one embodiment, the optical stacks exhibit a combination of high peel strength and high retained brightness, particularly after aging. The adhesive layer preferably comprises an interpenetrating network of the reaction product of a polyacrylate component and a polymerizable monomer and the adhesive layer has an elastic modulus ranging from 100 to 2000 MPa at 25° C.

2. 发明申请

US20140016208A1 OPTICAL STACK COMPRISING ADHESIVE 有权
标题翻译：包含粘合剂的光学堆叠
公开(公告)号：US20140016208A1
公开(公告)日：2014-01-16
申请号：US14005912
申请日：2012-03-26
申请人： William F. Edmonds , Brandt K. Carter , Jason S. Petaja
发明人： William F. Edmonds , Brandt K. Carter , Jason S. Petaja
IPC分类号： G02B5/04
CPC分类号： G02B5/045 , C08L2205/04 , C09J7/38 , C09J133/08 , C09J151/06
摘要： Presently described are optical stacks comprising a first optical film comprising a plurality of structures comprising an optically active portion designed primarily to provide optical gain and optionally an optically in-active bonding portion disposed on a first surface bonded to a second optical film with a light-transmissive adhesive layer such that a portion of the structures penetrate the adhesive layer and a separation is provided between the adhesive layer and the first surface. In one embodiment, the optical stacks exhibit a combination of high peel strength and high retained brightness, particularly after aging. The adhesive layer preferably comprises an interpenetrating network of the reaction product of a polyacrylate component and a polymerizable monomer and the adhesive layer has an elastic modulus ranging from 100 to 2000 MPa at 25° C.
摘要翻译：目前描述的是包括第一光学膜的光学堆叠，该第一光学膜包括多个结构，该多个结构包括主要用于提供光学增益的光学活性部分和可选地设置在与第二光学膜结合的第一表面上的光学活性粘合部分，透明粘合剂层，使得一部分结构穿透粘合剂层，并且在粘合剂层和第一表面之间提供分离。在一个实施例中，光学堆叠表现出高剥离强度和高保留亮度的组合，特别是在老化之后。粘合剂层优选包括聚丙烯酸酯组分和可聚合单体的反应产物的互穿网络，并且粘合剂层在25℃下具有100至2000MPa的弹性模量。

3. 发明授权

US10293370B2 Process for gradient nanovoided article 有权
公开(公告)号：US10293370B2
公开(公告)日：2019-05-21
申请号：US13501304
申请日：2010-10-22
申请人： Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
发明人： Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
IPC分类号： B05D3/10 , B05D5/00 , B82Y20/00 , B05D7/04 , B05D3/02 , B05D3/06
摘要： A process and apparatus for producing a gradient nanovoided article, a gradient nanovoided coating, and a gradient low refractive index coating is described. The process includes providing a first solution of a polymerizable material in a solvent, and providing a first environment proximate a first region of the coating and a different second environment proximate an adjacent region of the coating. The process further includes at least partially polymerizing the polymerizable material to form a composition that includes an insoluble polymer matrix and a second solution. The insoluble polymer matrix includes a plurality of nanovoids that are filled with the second solution, and a major portion of the solvent from the second solution is removed. A first volume fraction of the plurality of nanovoids proximate the first region of the coating is less than a second volume fraction of the plurality of nanovoids proximate an adjacent of the coating. An apparatus for the process is also described, and includes a web line, a coating section, a partial polymerization section, and a solvent removal section.

4. 发明申请

US20120201977A1 PROCESS FOR GRADIENT NANOVOIDED ARTICLE 审中-公开
标题翻译：梯度纳米制品的工艺
公开(公告)号：US20120201977A1
公开(公告)日：2012-08-09
申请号：US13501304
申请日：2010-10-22
申请人： Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
发明人： Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
IPC分类号： C23C14/28 , C08J9/28 , B82Y40/00
CPC分类号： B05D3/101 , B05D3/0209 , B05D3/0254 , B05D3/067 , B05D3/10 , B05D3/107 , B05D5/00 , B05D7/04 , B82Y20/00 , G02B2207/101 , G02B2207/107
摘要： A process and apparatus for producing a gradient nanovoided article, a gradient nanovoided coating, and a gradient low refractive index coating is described. The process includes providing a first solution of a polymerizable material in a solvent, and providing a first environment proximate a first region of the coating and a different second environment proximate an adjacent region of the coating. The process further includes at least partially polymerizing the polymerizable material to form a composition that includes an insoluble polymer matrix and a second solution. The insoluble polymer matrix includes a plurality of nanovoids that are filled with the second solution, and a major portion of the solvent from the second solution is removed. A first volume fraction of the plurality of nanovoids proximate the first region of the coating is less than a second volume fraction of the plurality of nanovoids proximate an adjacent of the coating. An apparatus for the process is also described, and includes a web line, a coating section, a partial polymerization section, and a solvent removal section.
摘要翻译：描述了用于生产梯度纳米组分制品，梯度纳米复合涂层和梯度低折射率涂层的方法和设备。该方法包括在溶剂中提供可聚合材料的第一溶液，以及在涂层的第一区域附近提供第一环境以及邻近涂层的相邻区域的不同的第二环境。该方法还包括至少部分聚合可聚合材料以形成包含不溶性聚合物基质和第二溶液的组合物。不溶性聚合物基质包括填充有第二溶液的多个纳米泡，并且除去来自第二溶液的大部分溶剂。靠近涂层的第一区域的多个纳米空心的第一体积分数小于邻近涂层的多个纳米空间的第二体积分数。还描述了一种用于该方法的装置，并且包括幅材线，涂布部分，部分聚合部分和溶剂去除部分。

5. 发明申请

US20120200919A1 VOIDED DIFFUSER 有权
标题翻译：无声差示器
公开(公告)号：US20120200919A1
公开(公告)日：2012-08-09
申请号：US13501310
申请日：2010-10-22
申请人： Jason S. Petaja , William F. Edmonds , Adam D. Haag , Eric W. Nelson , Encai Hao , William Blake Kolb , Fei Lu , Richard J. Pokorny
发明人： Jason S. Petaja , William F. Edmonds , Adam D. Haag , Eric W. Nelson , Encai Hao , William Blake Kolb , Fei Lu , Richard J. Pokorny
IPC分类号： G02B5/30 , B32B5/22
CPC分类号： G02B5/0247 , G02B5/0242 , Y10T428/249986
摘要： A voided diffuser and an optical construction incorporating the voided diffuser are provided. The voided diffuser includes a plurality of beads and a binder composition in contact with the plurality of beads. The binder composition includes a binder and a plurality of interconnected voids. The optical construction includes the voided diffuser disposed on a substrate.
摘要翻译：提供了一种排空的扩散器和结合有空隙扩散器的光学结构。空隙扩散器包括多个珠粒和与多个珠粒接触的粘合剂组合物。粘合剂组合物包括粘合剂和多个相互连接的空隙。光学结构包括设置在基板上的空隙扩散器。

6. 发明授权

US09279918B2 Gradient low index article and method 有权
标题翻译：梯度低指数的文章和方法
公开(公告)号：US09279918B2
公开(公告)日：2016-03-08
申请号：US13501295
申请日：2010-10-22
申请人： Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
发明人： Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
IPC分类号： G02B5/02
CPC分类号： G02B5/0242 , G02B5/0231 , G02B5/0247 , G02B5/0263 , G02B5/0278 , G02B2207/107 , Y10T428/249961
摘要： A gradient optical film and an optical construction including the gradient optical film are described. The gradient optical film includes a binder, a plurality of particles, and a plurality of interconnected voids having a local volume fraction. The local volume fraction of the plurality of interconnected voids varies along a thickness direction of the gradient optical film. The refractive index of the gradient optical film can also varies along a thickness direction of the gradient optical film, as the refractive index can also depend upon the local volume fraction of the plurality of interconnected voids.
摘要翻译：描述了包括梯度光学膜的梯度光学膜和光学结构。梯度光学膜包括粘合剂，多个颗粒和具有局部体积分数的多个互连的空隙。多个相互连接的空隙的局部体积分数沿梯度光学膜的厚度方向变化。梯度光学膜的折射率也可以沿着梯度光学膜的厚度方向变化，因为折射率也可以取决于多个互连空隙的局部体积分数。

7. 发明授权

US08982468B2 Voided diffuser 有权
标题翻译：空洞扩散器
公开(公告)号：US08982468B2
公开(公告)日：2015-03-17
申请号：US13501310
申请日：2010-10-22
申请人： Jason S. Petaja , William F. Edmonds , Adam D. Haag , Eric W. Nelson , Encai Hao , William Blake Kolb , Fei Lu , Richard J. Pokorny
发明人： Jason S. Petaja , William F. Edmonds , Adam D. Haag , Eric W. Nelson , Encai Hao , William Blake Kolb , Fei Lu , Richard J. Pokorny
IPC分类号： G02B5/02
CPC分类号： G02B5/0247 , G02B5/0242 , Y10T428/249986
摘要： A voided diffuser and an optical construction incorporating the voided diffuser are provided. The voided diffuser includes a plurality of beads and a binder composition in contact with the plurality of beads. The binder composition includes a binder and a plurality of interconnected voids. The optical construction includes the voided diffuser disposed on a substrate.
摘要翻译：提供了一种排空的扩散器和结合有空隙扩散器的光学结构。空隙扩散器包括多个珠粒和与多个珠粒接触的粘合剂组合物。粘合剂组合物包括粘合剂和多个相互连接的空隙。光学结构包括设置在基板上的空隙扩散器。

8. 发明申请

US20120200931A1 GRADIENT LOW INDEX ARTICLE AND METHOD 有权
标题翻译：梯度低指数文章和方法
公开(公告)号：US20120200931A1
公开(公告)日：2012-08-09
申请号：US13501295
申请日：2010-10-22
申请人： Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
发明人： Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
IPC分类号： G02B5/02 , B32B5/14 , C08J9/35
CPC分类号： G02B5/0242 , G02B5/0231 , G02B5/0247 , G02B5/0263 , G02B5/0278 , G02B2207/107 , Y10T428/249961
摘要： A gradient optical film and an optical construction including the gradient optical film are described. The gradient optical film includes a binder, a plurality of particles, and a plurality of interconnected voids having a local volume fraction. The local volume fraction of the plurality of interconnected voids varies along a thickness direction of the gradient optical film. The refractive index of the gradient optical film can also varies along a thickness direction of the gradient optical film, as the refractive index can also depend upon the local volume fraction of the plurality of interconnected voids.
摘要翻译：描述了包括梯度光学膜的梯度光学膜和光学结构。梯度光学膜包括粘合剂，多个颗粒和具有局部体积分数的多个互连的空隙。多个相互连接的空隙的局部体积分数沿梯度光学膜的厚度方向变化。梯度光学膜的折射率也可以沿着梯度光学膜的厚度方向变化，因为折射率也可以取决于多个互连空隙的局部体积分数。

9. 发明申请

US20130022315A1 OPTICAL STACK AND LIGHTGUIDES 有权
标题翻译：光学堆叠和光源
公开(公告)号：US20130022315A1
公开(公告)日：2013-01-24
申请号：US13634583
申请日：2011-04-11
申请人： William F. Edmonds , Tao Liu , John F. Van Deriofske III , John A. Wheatley
发明人： William F. Edmonds , Tao Liu , John F. Van Deriofske III , John A. Wheatley
IPC分类号： G02B5/30 , G02B6/26
CPC分类号： G02B5/045 , F21V11/00 , G02B6/0053 , G02F1/133606 , G02F2001/133607 , Y10T428/24612
摘要： Optical stack is disclosed. The optical stack includes a first optical stack that includes, a first optical adhesive layer, and a reflective polarizer layer that is disposed on the first optical adhesive layer. The reflective polarizer layer substantially reflects light of a first polarization state and substantially transmits light of a second polarization state orthogonal to the first polarization state. The optical stack also includes a second optical stack that includes a second optical adhesive layer, a low index layer that is disposed on the second optical adhesive layer and includes a plurality of voids dispersed in a binder, and a light directing film that is disposed on the low index layer and includes a plurality of unitary discrete structures. Portions of each unitary discrete structure penetrate into the first optical adhesive layer. Portions of each unitary discrete structure do not penetrate into the first optical adhesive layer. Each unitary discrete structure defines a penetration depth and a penetration base at the interface between the penetrating and non-penetrating portions of the unitary discrete structure. The penetration base has a minimum penetration base dimension. The plurality of unitary discrete structures has an average penetration depth and an average minimum penetration base dimension. The ratio of the average penetration depth to the average minimum penetration base dimension is at least 1.5. The peel strength between the first and second optical stacks is greater than about 30 grams/inch.
摘要翻译：公开了光堆叠。光学堆叠包括第一光学堆叠，其包括第一光学粘合剂层和设置在第一光学粘合剂层上的反射偏振器层。反射型偏振层基本上反射第一偏振态的光，并且基本上透射与第一偏振状态正交的第二偏振状态的光。光学堆叠还包括第二光学堆叠，其包括第二光学粘合剂层，设置在第二光学粘合剂层上并包括分散在粘合剂中的多个空隙的低折射率层，以及设置在低折射率层并且包括多个单一离散结构。每个单一离散结构的部分渗入第一光学粘合剂层。每个单一离散结构的部分不会渗透到第一光学粘合剂层中。每个单一离散结构在整体离散结构的穿透部分和非穿透部分之间的界面处限定穿透深度和穿透基部。穿透底座具有最小穿透基座尺寸。多个单一离散结构具有平均穿透深度和平均最小穿透基础尺寸。平均渗透深度与平均最小穿透基础尺寸之比至少为1.5。第一和第二光学叠层之间的剥离强度大于约30克/英寸。

10. 发明授权

US09588262B2 Optically diffuse low refractive index element 有权
$Optically diffuse low refractive index element$
标题翻译：光学扩散低折射率元件
公开(公告)号：US09588262B2
公开(公告)日：2017-03-07
申请号：US13879839
申请日：2011-10-14
申请人： William D. Coggio , Michael L. Steiner , William F. Edmonds , Robert F. Kamrath , Lan H. Liu , Encai Hao
发明人： William D. Coggio , Michael L. Steiner , William F. Edmonds , Robert F. Kamrath , Lan H. Liu , Encai Hao
IPC分类号： G02B5/02
CPC分类号： G02B5/02 , G02B5/0242 , G02B5/0247 , G02B2207/107
摘要： An optical article includes an optical element and a low refractive index layer disposed on the optical element. The low refractive index layer having an effective refractive index of 1.3 or less and including a binder, a plurality of metal oxide particles dispersed in the binder and a plurality of interconnected voids. The low refractive index layer has a haze value of at least 30%.
摘要翻译：光学制品包括设置在光学元件上的光学元件和低折射率层。低折射率层具有1.3以下的有效折射率，并且包括粘合剂，分散在粘合剂中的多个金属氧化物颗粒和多个互连的空隙。低折射率层的雾度值至少为30％。

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