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1. 发明授权

US4186112A Catalyst for reducing carbon monoxide with hydrogen 失效
标题翻译：用氢还原一氧化碳的催化剂
公开(公告)号：US4186112A
公开(公告)日：1980-01-29
申请号：US854466
申请日：1977-11-23
申请人： Wilhelm Vogt , Jurgen Koch , Hermann Glaser
发明人： Wilhelm Vogt , Jurgen Koch , Hermann Glaser
IPC分类号： B01J23/83 , B01J23/00 , B01J23/10 , B01J23/32 , B01J23/34 , B01J23/66 , B01J23/74 , B01J23/76 , B01J23/889 , B01J23/89 , B01J27/26 , B01J37/03 , C07B61/00 , C07C1/00 , C07C1/04 , C07C9/00 , C07C11/02 , C07C67/00 , B01J23/72 , B01J23/78 , B01J23/84
CPC分类号： B01J23/8933 , B01J23/007 , B01J23/10 , B01J23/32 , B01J23/66 , B01J23/74 , B01J23/76 , B01J37/03 , C07C1/0445 , B01J27/26 , C07C2527/26
摘要： Catalyst for reducing carbon monoxide by means of hydrogen so as to obtain a mixture consisting substantially of C.sub.1 -C.sub.4 -hydrocarbons. The catalyst is made by precipitating a salt of a hydrocyanic acid of the general formula Me.sub.I Me.sub.II (CN).sub.x, separating and drying the salt so precipitated and forming it. In the formula, the cationic component Me I stands for at least one of the elements Ce, Cu, Co, Ni, Fe, Mn, Zn, Ag and K or a mixture of these elements, or for Ca or Mg in admixture with (NH).sub.4 ; the anionic component Me.sub.II stands for at least one of the elements Cu, Co, Ni, Fe, Mn, Zn and Ag or a mixture of these elements; and x stands for the sum of the metal valencies; Me.sub.I and Me.sub.II are not permitted to stand for iron alone, or for a mixture of iron with copper.
摘要翻译：通过氢气还原一氧化碳以获得基本上由C1-C4烃组成的混合物的催化剂。通过使通式MeIMeII（CN）x的氢氰酸盐沉淀，分离和干燥沉淀并形成其的盐来制备催化剂。在该配方中，阳离子组分Me I代表Ce，Cu，Co，Ni，Fe，Mn，Zn，Ag和K中的至少一种元素或这些元素的混合物，或者与Ca（或Mg） NH）4; 阴离子组分MeII代表元素Cu，Co，Ni，Fe，Mn，Zn和Ag中的至少一种或这些元素的混合物; x代表金属价值之和; MeI和MeII不允许单独使用铁，也不允许铁与铜混合使用。

2. 发明授权

US4172053A Catalyst for reducing carbon monoxide 失效
标题翻译：用于还原一氧化碳的催化剂
公开(公告)号：US4172053A
公开(公告)日：1979-10-23
申请号：US917856
申请日：1978-06-22
申请人： Wilhelm Vogt , Hermann Glaser , Jurgen Koch
发明人： Wilhelm Vogt , Hermann Glaser , Jurgen Koch
IPC分类号： B01J23/745 , C07C1/04 , B01J21/04 , B01J21/08 , B01J23/72 , B01J23/74
CPC分类号： B01J23/745 , C07C1/0445 , C07C2521/04 , C07C2521/08 , C07C2521/16 , C07C2521/18 , C07C2523/72 , C07C2523/745
摘要： Reduction of carbon monoxide by means of hydrogen with the resultant formation of a mixture of hydrocarbons having substantially from 1 to 4 carbon atoms in contact with a catalyst containing iron or a mixture of iron and copper as its catalytically active ingredient, the catalyst being made by contacting one or more complex salts of the following general formula:Me.sub.x [Fe(CN).sub.6 ].sub.yin which Me stands for an iron and/or copper-ion, x stands for a number of 1 to 4, and y stands for a number of 1 to 3, with hydrogen or a hydrogen/carbon monoxide-mixture at about 200.degree. to 500.degree. C., under 1 to 100 atmospheres absolute and over a period of about 2 to 20 hours and thereby reducing the complex salts substantially to elementary iron or copper.
摘要翻译：通过氢还原一氧化碳，从而形成与含有铁或铁和铜的混合物的催化剂接触的具有1-4个碳原子的烃的混合物作为其催化活性成分，催化剂由使一种或多种下列通式的复盐接触：

3. 发明授权

US4387263A Process for mixing olefins 失效
标题翻译：烯烃混合方法
公开(公告)号：US4387263A
公开(公告)日：1983-06-07
申请号：US378425
申请日：1982-05-14
申请人： Wilhelm Vogt , Hermann Glaser , Jurgen Koch
发明人： Wilhelm Vogt , Hermann Glaser , Jurgen Koch
IPC分类号： C07C1/20 , C07C1/24
CPC分类号： C07C1/20 , C07C2529/40 , Y02P30/42
摘要： The disclosure relates to a process for making C.sub.2 to C.sub.4 -olefins from gas mixtures containing methanol, dimethylether and optionally steam in the presence of catalysts at temperatures of 250.degree. to 500.degree. C. under pressure of 0.1 to 6 bars, unreacted feed material being recycled. To this end, the disclosure provides for a mixture containing methanol and water in a ratio by volume of 1:(0 up to 2) to be evaporated and reacted in a reactor having the catalyst placed therein; for the reaction gases to be partially condensed by cooling them and separated, in a separator, into three phases; for the oil phase consisting of higher aliphates and aromates to be removed and for the remaining aqueous phase and gas phase to be water-scrubbed in a scrubbing column under pressures of 1 to 40 bars; for a gaseous hydrocarbon mixture containing predominantly C.sub.2 to C.sub.4 -olefins to be removed overhead and separated into its components; for an aqueous phase containing unreacted methanol and intermediarily formed dimethylether to be removed from the base portion of the scrubbing column; for the methanol and dimethylether to be distilled off in a stripping column and recycled into the reactor; and for the water to be removed from the base portion of the stripping column.
摘要翻译：本公开涉及一种在0.005至500℃的温度下，在0.1至6巴的压力下，在催化剂存在下，在甲醇，二甲醚和任选蒸汽的气体混合物中制备C 2至C 4烯烃的方法，未反应的原料为回收。为此，本公开内容提供了以1：（0至2）的体积比的甲醇和水的混合物进行蒸发并在其中放置有催化剂的反应器中反应; 反应气体通过冷却而被部分冷凝，并在分离器中分离成三相; 用于由更高的脂肪族和芳烃被除去的油相和剩余的水相和气相在1至40巴的压力下在洗涤塔中进行水洗; 对于主要含有C2至C4-烯烃的气态烃混合物，其顶部除去并分离成其组分; 对于含有未反应的甲醇和中间形成的二甲醚的水相从洗涤塔的基部除去; 甲醇和二甲基醚在汽提塔中蒸馏除去，再循环到反应器中; 并且用于从汽提塔的基部除去水。

4. 发明授权

US4146503A Process for preparing a catalyst for reducing carbon monoxide 失效
标题翻译：制备用于还原一氧化碳的催化剂的方法
公开(公告)号：US4146503A
公开(公告)日：1979-03-27
申请号：US854147
申请日：1977-11-23
申请人： Wilhelm Vogt , Jurgen Koch , Hermann Glaser
发明人： Wilhelm Vogt , Jurgen Koch , Hermann Glaser
IPC分类号： B01J23/74 , B01J23/745 , B01J37/00 , C07B61/00 , C07C1/00 , C07C1/04 , C07C9/00 , C07C11/02 , C07C67/00 , B01J21/12 , B01J23/72
CPC分类号： B01J37/0009 , B01J23/745 , C07C1/0445 , C07C2521/12 , C07C2523/72 , C07C2523/745
摘要： A catalyst containing iron or a mixture of iron with copper as its active ingredient, made by precipitating a complex salt of the general formula:Me.sub.x [Fe(CN).sub.6 ].sub.yin which Me stands for an iron and/or copper ion, X stands for 1, 2, 3 or 4, and y stands for 1, 2 or 3; separating and drying the precipitated salt, and reducing the salt by contacting it with at least stoichiometric proportions of hydrogen or a mixture of hydrogen and carbon monoxide, for use in the reduction of carbon monoxide by means of hydrogen with the resultant formation of a mixture consisting substantially of C.sub.1 -C.sub.4 hydrocarbons is modified. The modified catalyst is formed(a) by subjecting the precipitated and dried salt to thermal decomposition at a temperature of 200.degree. to 500.degree. C. in the absence of hydrogen or a mixture of hydrogen and carbon monoxide, or(b) mixing the precipitated and dry salt with a carrier, tabletting, pelletizing or extruding the resulting mixture and reducing it by means of hydrogen or a mixture of hydrogen and carbon monoxide, or(c) mixing the precipitated and dry salt with a carrier, tabletting, pelletizing or extruding the resulting mixture and thermally decomposing it at 200.degree. to 500.degree. C. in the absence of hydrogen or a mixture of hydrogen and carbon monoxide.
摘要翻译：含有铁或铁与铜的混合物作为其活性成分的催化剂，通过沉淀下列通式的络合盐制备：

5. 发明授权

US4753915A Process for making a carrier-supported catalyst 失效
标题翻译：制备载体载体催化剂的方法
公开(公告)号：US4753915A
公开(公告)日：1988-06-28
申请号：US921945
申请日：1986-10-22
申请人： Wilhelm Vogt , Hermann Glaser , Eitel Goedicke
发明人： Wilhelm Vogt , Hermann Glaser , Eitel Goedicke
IPC分类号： B01D53/94 , B01J23/89 , B01J21/04 , B01J21/06 , B01J23/10 , B01J23/74
CPC分类号： B01D53/945 , B01J23/8906 , B01J23/8953 , Y02T10/22
摘要： A carrier-supported catalyst is made by applying one or more non-noble metal and noble metal components on to a ceramic honeycomb structure coated with a layer of a heat-resistant metal oxide. To this end, the ceramic honeycomb structure is dipped at least once into an aqueous suspension of pseudoboehmite and zirconium oxide hydrate, the honeycomb structure so treated is dried at temperatures of up to 250.degree. C. and calcined at temperatures of up to 1000.degree. C.; next, the honeycomb structure is impregnated with an aqueous solution of at least one iron salt, and, if desired, nickel and cerium salts, dried at temperatures of up to 250.degree. C. and annealed at temperatures of up to 600.degree. C.; next, the honeycomb structure is impregnated with an aqueous solution containing at least one soluble compound of platinum, rhodium or palladium, and, if desired cerium, one of the solutions under (b) or (c) being required to contain cerium; the honeycomb structure so treated is ultimately dried at temperatures of up to 250.degree. C. and annealed at temperatures of up to 600.degree. C.
摘要翻译：通过将一种或多种非贵金属和贵金属组分施加到涂覆有耐热金属氧化物层的陶瓷蜂窝结构上制成载体负载型催化剂。为此，陶瓷蜂窝结构体至少浸入一次假勃姆石和氧化锆水合物的水悬浮液中，将处理的蜂窝结构体在高达250℃的温度下干燥并在高达1000℃的温度下煅烧。接下来，用至少一种铁盐的水溶液和如果需要的话，将镍盐和铈盐浸渍在蜂窝结构体中，在高达250℃的温度下干燥并在高达600℃的温度下进行退火。接下来，用含有铂，铑或钯的至少一种可溶性化合物的水溶液浸渍蜂窝结构体，如果需要，铈，（b）或（c）中的溶液之一需要含有铈; 如此处理的蜂窝结构体最终在高达250℃的温度下干燥，并在高达600℃的温度下退火

6. 发明授权

US4497747A Process for making acetic anhydride 失效
标题翻译：制备乙酸酐的方法
公开(公告)号：US4497747A
公开(公告)日：1985-02-05
申请号：US515283
申请日：1983-07-19
申请人： Wilhelm Vogt , Hermann Glaser , Erhard Jagers
发明人： Wilhelm Vogt , Hermann Glaser , Erhard Jagers
IPC分类号： C07C53/12 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/54 , C07C51/56 , C07C67/00
CPC分类号： C07C51/54 , C07C51/56
摘要： The disclosure relates to a process for making acetic anhydride by reacting methyl acetate and/or dimethylether with carbon monoxide, if desired in admixture with up to 20 volume % hydrogen, under practically anhydrous conditions at temperatures of 120.degree. to 270.degree. C., under pressures of 1 to 500 bars in the presence of a catalyst system containing nickel or a nickel compound, an organic iodine or bromine compound as well as a tertiary or quaternary organic phosphorus compound. More particularly, a catalyst system containing a titanium or zirconium compound as an additional constituent is used.
摘要翻译：本公开内容涉及通过使乙酸酐和/或二甲醚与一氧化碳反应制备乙酸酐的方法，如果需要，在实际无水条件下，在120〜270℃的温度下，在约20体积％的氢气的混合下，在含镍或镍化合物，有机碘或溴化合物以及叔或季有机磷化合物的催化剂体系存在下，压力为1至500巴。更具体地，使用含有钛或锆化合物作为附加成分的催化剂体系。

7. 发明授权

US4062810A Carrier-supported catalyst 失效
标题翻译：载体催化剂
公开(公告)号：US4062810A
公开(公告)日：1977-12-13
申请号：US718331
申请日：1976-08-27
申请人： Wilhelm Vogt , Hermann Glaser , Helmut Dyrschka
发明人： Wilhelm Vogt , Hermann Glaser , Helmut Dyrschka
IPC分类号： B01D53/94 , B01J23/10 , B01J37/00
CPC分类号： B01J23/10 , B01D53/944 , B01J37/0018
摘要： The invention provides a carrier-supported catalyst, wherein alumina partially converted to .alpha.-Al.sub.2 O.sub.3 is the carrier having between 0.2 and 10 weight % of cerium in oxide form deposited thereon as the catalytically active ingredient.The carrier supported catalyst is made by compressing hydrous alumina or unstable anhydrous alumina into shapes. The shapes are annealed for 10-20 hours at 1000.degree.-1250.degree. C. The annealed shapes are impregnated with an aqueous solution of a cerium salt of a readily decomposable acid and dried at 130.degree.-150.degree. C. The dry cerium salt is decomposed by gradually heating the shapes at 20.degree.-300.degree. C and 450.degree.-550.degree. C, respectively, and the resulting cerium oxide-containing shapes are annealed at 700.degree.-900.degree. C.
摘要翻译：本发明提供一种载体负载催化剂，其中部分转化为α-Al 2 O 3的氧化铝是其中沉积有氧化物形式的铈的0.2至10重量％的载体作为催化活性成分。

8. 发明授权

US4529560A Process for making acetic anhydride 失效
标题翻译：制备乙酸酐的方法
公开(公告)号：US4529560A
公开(公告)日：1985-07-16
申请号：US515284
申请日：1983-07-19
申请人： Wilhelm Vogt , Erhard Jagers , Hermann Glaser
发明人： Wilhelm Vogt , Erhard Jagers , Hermann Glaser
IPC分类号： C07C53/12 , B01J31/00 , C07B61/00 , C07C51/00 , C07C51/56 , C07C67/00 , C07C51/54
CPC分类号： C07C51/56
摘要： The disclosure relates to a process for making acetic anhydride by reacting methyl acetate and/or dimethylether with carbon monoxide, which may be used in admixture with up to 30 volume % hydrogen, under practically anhydrous conditions at temperatures of 390.degree. to 540.degree. K., under pressures of 1 to 300 bars in the presence of a catalyst system containing nickel or nickel compounds, iodine and/or its compounds as well as a tertiary or quaternary organic nitrogen, phosphorus, arsenic or antimony compound. More particularly a catalyst system is used which contains vanadium or niobium or a compound thereof as an additional constituent.
摘要翻译：本公开涉及通过使乙酸甲酯和/或二甲醚与一氧化碳反应制备乙酸酐的方法，其可以在几乎无水条件下在390°至540°K的温度下与最多30体积％的氢混合使用。在含有镍或镍化合物的催化剂体系，碘和/或其化合物以及叔或季有机氮，磷，砷或锑化合物的存在下，在1至300巴的压力下进行。更具体地，使用含有钒或铌或其化合物作为附加成分的催化剂体系。

9. 发明授权

US4471148A Process for making catalytically active aluminosilicates and their uses 失效
标题翻译：制备催化活性硅铝酸盐的方法及其用途
公开(公告)号：US4471148A
公开(公告)日：1984-09-11
申请号：US455279
申请日：1983-01-03
申请人： Wilhelm Vogt , Hermann Glaser , J/u/ rgen Koch , G/u/ nter Lenz
发明人： Wilhelm Vogt , Hermann Glaser , J/u/ rgen Koch , G/u/ nter Lenz
IPC分类号： B01J21/00 , B01J29/06 , C01B33/26 , C01B39/02 , C01B39/06 , C07C1/00 , C07C1/20 , C07C2/86 , C07C5/22 , C07C5/27 , C07C11/02 , C07C67/00
CPC分类号： C07C2/864 , B01J29/06 , C01B39/02 , C07C1/20 , C07C5/222 , C07C5/2737 , C07C2521/12 , Y02P20/52
摘要： The disclosure relates to a process for making catalytically active aluminosilicates from glasses by hydrothermal cristallization. The hydrothermal cristallization is more particularly effected in the presence of an aqueous solution of an inorganic alkali metal compound producing an alkaline reaction but in the absence of an amine. Useful alkali metal compounds comprise alkali metal carbonate, water glass, alkali metal hydroxide or alkali metal phosphate.The catalytically active aluminosilicates can be used for dehydrating alcohols, ethers and other oxygen-containing organic compounds with formation of hydrocarbons, or for isomerizing or alkylating hydrocarbons.
摘要翻译：本公开涉及通过水热结晶从玻璃制备催化活性铝硅酸盐的方法。在产生碱反应的无机碱金属化合物的水溶液的存在下，但不存在胺时，更特别地实现了水热团聚。有用的碱金属化合物包括碱金属碳酸盐，水玻璃，碱金属氢氧化物或碱金属磷酸盐。催化活性的铝硅酸盐可用于使醇，醚和其它含氧有机化合物脱氢形成烃，或用于烃的异构化或烷基化。

10. 发明授权

US4719196A Process for making a carrier-supported catalyst 失效
标题翻译：制备载体载体催化剂的方法
公开(公告)号：US4719196A
公开(公告)日：1988-01-12
申请号：US903666
申请日：1986-09-04
申请人： Wilhelm Vogt , Hermann Glaser , Eitel Goedicke
发明人： Wilhelm Vogt , Hermann Glaser , Eitel Goedicke
IPC分类号： B01J23/40 , B01J23/56 , B01J23/63 , B01J23/89 , B01J37/02 , B01J21/04 , B01J23/10
CPC分类号： B01J37/0203 , B01J23/40 , B01J23/63 , B01J23/8906 , B01J23/894 , B01J37/0242
摘要： A carrier-supported catalyst is prepared by applying a noble metal on to a ceramic honeycomb structure coated with an aluminum oxide layer. To this end, the ceramic honeycomb structure is impregnated with an aqueous solution containing nitrilotriacetic acid or ethylenediaminotetraacetic acid, ammonia and at least one noble metal compound.
摘要翻译：通过将贵金属涂覆在涂覆有氧化铝层的陶瓷蜂窝结构体上来制备载体负载的催化剂。为此，陶瓷蜂窝结构体用含有次氮基三乙酸或乙二胺四乙酸的水溶液，氨和至少一种贵金属化合物浸渍。

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