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1. 发明授权

US4507220A Aqueous suspensions of peroxydisulfates and their use as oxidative desizing agents for textile goods sized with starch 失效
标题翻译：过氧化二硫酸盐的水性悬浮液及其作为用淀粉大小的纺织品的氧化脱浆剂的用途
公开(公告)号：US4507220A
公开(公告)日：1985-03-26
申请号：US452491
申请日：1982-12-23
申请人： Werner Streit , Linda Witt , Heinz-Dieter Angstmann
发明人： Werner Streit , Linda Witt , Heinz-Dieter Angstmann
IPC分类号： C08L33/00 , B01F17/52 , C01B15/08 , C08L33/02 , D06L1/14 , D06L3/02
CPC分类号： D06L1/14
摘要： Water-containing peroxydisulfate suspensions containing potassium peroxydisulfate, a water-soluble polymer or copolymer of acrylic acid and/or maleic acid, with or without an anionic surfactant, where appropriate mixed with a non-ionic surfactant, and water, in which the aqueous phase contains from 12 to 65% by weight of not less than one other dissolved compound which keeps the system at a pH of not less than 5 and is a source of potassium ions.
摘要翻译：含有过二硫酸钾的水，含有或不含有阴离子表面活性剂的水溶性聚合物或丙烯酸和/或马来酸的共聚物的过二硫酸氢盐悬浮液，其中适当地与非离子表面活性剂混合，以及水，其中水相含有12至65重量％的不少于一种其它溶解的化合物，其保持体系不低于5的pH并且是钾离子的来源。

2. 发明授权

US4654043A Desizing cotton and cotton-containing fabrics 失效
标题翻译：脱棉棉和含棉面料
公开(公告)号：US4654043A
公开(公告)日：1987-03-31
申请号：US690522
申请日：1985-01-11
申请人： Werner Streit , Linda Witt , Heinz-Dieter Angstmann , Rolf Blanckenhorn , Rolf Fikentscher
发明人： Werner Streit , Linda Witt , Heinz-Dieter Angstmann , Rolf Blanckenhorn , Rolf Fikentscher
IPC分类号： D06L1/14 , D06M13/34 , A01N3/00
CPC分类号： D06L1/14
摘要： Cotton and cotton-containing fabrics are desized in strongly alkaline aqueous solution with an alkali metal hypochlorite by a process in which from 0.5 to 8.0 g/l of a tertiary hydroxyalkylamine which is soluble in aqueous alkaline solution, of an oxyethylated and/or oxypropylated ethylenediamine, of an oxyethylated polyethyleneimine, of malonic acid, of cyanuric acid, of a cyanuric acid derivative, of a urea derivative, of cyanoguanidine, of oxazolidone, of pyrrolidone, of N-methylpyrrolidone, of N-methylimidazole or of a mixture of these is added to the aqueous bath, as an activator for the hypochlorite. Activators for hypochlorite are used in the desizing of cotton and cotton-containing fabrics in strongly alkaline aqueous solutions.
摘要翻译：棉和含棉织物在碱金属次氯酸盐的强碱性水溶液中通过其中可溶于碱性水溶液的0.5-8.0g / l的三羟基烷基胺，氧乙基化和/或氧丙基化的乙二胺的丙二酸，氰尿酸，氰尿酸衍生物，脲衍生物，氰基胍，恶唑烷酮，吡咯烷酮，N-甲基吡咯烷酮，N-甲基咪唑或它们的混合物的氧乙基化聚乙烯亚胺，加入到水浴中，作为次氯酸盐的活化剂。用于次氯酸盐的活化剂用于在强碱性水溶液中脱棉和含棉织物。

3. 发明授权

US5820636A Continuous pretreatment of cellulosic textile material 失效
标题翻译：纤维素纺织材料的连续预处理
公开(公告)号：US5820636A
公开(公告)日：1998-10-13
申请号：US537750
申请日：1995-11-15
申请人： Heinz-Dieter Angstmann , Dieter Bassing , Peter Freyberg
发明人： Heinz-Dieter Angstmann , Dieter Bassing , Peter Freyberg
IPC分类号： D06L1/14 , D06L3/02
CPC分类号： D06L3/02 , D06L1/14 , D06L3/023
摘要： A process for the continuous pretreatment of cellulosic textile material comprises a) a precleaning step wherein the treatment bath used comprises customary surfactants and other customary auxiliaries with or without customary enzymes as desizing agents and has a pH of from 5 to 11, and, after washoff and rinse, b) a bleaching step with hydrogen peroxide in an alkaline-aqueous liquor which comprises customary surfactants and other customary auxiliaries, wherefor the treatment bath of (a) additionally comprises from 1 to 10% by weight, based on the weight of the textile material, (i) either of an aminopolycarboxylic acid, of a hydroxyalkyl- or amino-phosphonic acid, of a polycarboxylic acid, of a polyhydroxycarboxylic acid or of an inorganic polymetaphosphate, or a mixture thereof, as complexing agent for polyvalent metal ions, or (ii) of a water-soluble polymer derived from 40 to 100% by weight of monoethylenically unsaturated mono- or dicarboxylic acids or anhydrides, or a mixture thereof, and has a K value of from 8 to 80, as dispersant, or(iii) a mixture of components (i) and (ii) in a weight ratio of from 10:1 to 1:10.
摘要翻译： PCT No.PCT / EP94 / 01507 Sec。 371日期：1995年11月15日 102（e）1995年11月15日日期PCT PCT 1994年5月10日PCT公布。公开号WO94 / 28228 PCT 日期1994年12月8日一种用于纤维素纺织材料的连续预处理的方法包括a）预清洗步骤，其中使用的处理浴包括常规表面活性剂和具有或不具有常规酶作为脱浆剂的其它常规助剂，并且具有5至11的pH ，并且在洗涤和冲洗之后，b）在含有常规表面活性剂和其它常规助剂的碱性水溶液中用过氧化氢进行漂白步骤，其中（a）的处理浴另外包含1至10重量％的基于关于纺织材料的重量，（i）多羧酸，多羟基羧酸或无机聚偏磷酸盐或其混合物的氨基多羧酸，羟基烷基或氨基膦酸中的任一种作为络合剂对于多价金属离子，或（ii）衍生自40至100重量％的单烯属不饱和单羧酸或二羧酸或酸酐的水溶性聚合物，或其混合物，并且具有8至80的K值作为分散剂，或（iii）组分（i）和（ii）的混合物，其重量比为10:1至1:10。

4. 发明授权

US4344764A Desizing of textiles consisting of or containing cellulose 失效
标题翻译：纺织品的脱浆或由纤维素组成
公开(公告)号：US4344764A
公开(公告)日：1982-08-17
申请号：US23357
申请日：1979-03-23
申请人： Wilfried Kothe , Heinz-Dieter Angstmann
发明人： Wilfried Kothe , Heinz-Dieter Angstmann
IPC分类号： D06L1/14 , D06L1/06 , D06M11/04 , D06M15/38
CPC分类号： D06L1/14
摘要： In addition to the very time-consuming enzymatic and hydrolytic desizing processes, oxidative degradation of starch size by means of persulfate, to render the starch water-soluble, is conventionally practised. Because of the chemical similarity between starch and cellulose, oxidative degradation of the cellulose is unavoidable in this desizing process. The invention overcomes this problem by breaking up the macromolecules of the starch into dispersible fragments by means of such small amounts of persulfate that neither is the starch made water-soluble nor is the cellulose significantly damaged, the dispersants employed for the fragments being relatively oxidation-stable polymers of unsaturated carboxylic acids.
摘要翻译：除了非常耗时的酶促和水解退浆方法之外，常规地进行通过过硫酸盐的淀粉尺寸的氧化降解以使淀粉成为水溶性的。由于淀粉和纤维素之间的化学相似性，在该退浆过程中纤维素的氧化降解是不可避免的。本发明克服了这个问题，即通过少量的过硫酸盐将淀粉的大分子分解成可分散的片段，淀粉也不溶于水，也不是纤维素显着损坏，用于片段相对氧化的分散剂，稳定的不饱和羧酸的聚合物。

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