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1. 发明授权

US5789621A Preparation of amines and aminonitriles 失效
标题翻译：胺和氨基腈的制备
公开(公告)号：US5789621A
公开(公告)日：1998-08-04
申请号：US693983
申请日：1996-08-08
申请人： Werner Schnurr , Guido Voit , Klemens Flick , Rolf-Hartmuth Fischer
发明人： Werner Schnurr , Guido Voit , Klemens Flick , Rolf-Hartmuth Fischer
IPC分类号： B01J23/78 , B01J23/94 , B01J27/187 , B01J27/28 , B01J38/10 , C07B43/04 , C07B61/00 , C07C20060101 , C07C209/48 , C07C209/52 , C07C211/12 , C07C211/35 , C07C253/30 , C07C255/24 , C07C209/02
CPC分类号： C07C209/48 , C07C209/52
摘要： A process for preparing an NH.sub.2 -containing compound by hydrogenating a compound containing at least one unsaturated carbon-nitrogen bond with hydrogen in the presence of a catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent which process includes the following steps: a) using a catalyst comprising a cobalt- and/or iron-containing catalyst, and b) after the conversion based on the compound to be hydrogenated and/or the selectivity based on the desired product has or have dropped below a defined value or the amount of an unwanted by-product has risen beyond a defined value, interrupting the hydrogenation by stopping the feed of the compound to be hydrogenated and of the solvent, if used, c) treating the catalyst at from 150.degree. to 400.degree. C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and d) subsequently continuing the hydrogenation of the compound containing at least one unsaturated carbon-nitrogen bond.
摘要翻译：在催化剂存在下，在不低于室温和升高的氢分压的情况下，在存在或不存在溶剂的情况下，通过氢化含有至少一个不饱和碳 - 氮键的化合物与氢气来制备含NH 2的化合物的方法，方法包括以下步骤：a）使用包含含钴和/或含铁催化剂的催化剂，和b）基于待氢化的化合物转化后，和/或基于所需产物的选择性具有或已经下降低于定义的值或不想要的副产物的量已经超过定义的值，如果使用，则通过停止待氢化化合物的进料和溶剂的中断氢化，c）在150℃下处理催化剂在氢气压力为0.1〜30MPa，处理时间为2〜48h的范围内，使氢气变为400℃，d）随后继续进行水压该化合物含有至少一个不饱和碳 - 氮键。

2. 发明授权

US5874607A Coproduction of 6-aminocapronitrile and hexamethylenediamine 失效
标题翻译：共聚6-氨基己腈和六亚甲基二胺
公开(公告)号：US5874607A
公开(公告)日：1999-02-23
申请号：US635653
申请日：1996-04-22
申请人： Werner Schnurr , Guido Voit , Klemens Flick , Rolf-Hartmuth Fischer
发明人： Werner Schnurr , Guido Voit , Klemens Flick , Rolf-Hartmuth Fischer
IPC分类号： B01J23/78 , B01J23/94 , B01J27/187 , B01J27/28 , B01J38/10 , C07B61/00 , C07C209/48 , C07C211/12 , C07C253/30 , C07C255/24 , C07C255/03
CPC分类号： C07C209/48 , C07C253/30 , Y02P20/584
摘要： A process for the coproduction of 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) by treatment of adiponitrile (ADN) with hydrogen in the presence of a nickel-containing catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent comprises, after the conversion based on ADN and/or the selectivity based on ACN has or have dropped below a defined value(a) interrupting the treatment of ADN with hydrogen by stopping the feed of ADN and of the solvent, if used,(b) treating the catalyst at from 150.degree. to 400.degree. C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and(c) then continuing the hydrogenation of ADN with the treated catalyst of stage (b).
摘要翻译：在含镍催化剂存在下，在不低于室温的温度和氢分压升高的情况下，通过用氢气处理己二腈（ADN），共同生产6-氨基己腈（ACN）和六亚甲基二胺（HMD）的方法，没有溶剂包括在基于ADN的转化和/或基于ACN的选择性之后，或者已经降低到低于定义的值（a）通过停止ADN和溶剂的进料而中止用氢处理ADN，如果使用，（b）使用氢气压力为0.1〜30MPa，处理时间为2〜48小时，用氢气在150〜400℃下处理催化剂，（c）然后继续用（b）阶段处理的催化剂氢化ADN。

3. 发明授权

US5827938A Preparation of amines and aminonitriles 失效
标题翻译：共同生产6-氨基己腈和6-六亚甲基二胺的方法
公开(公告)号：US5827938A
公开(公告)日：1998-10-27
申请号：US635684
申请日：1996-04-22
申请人： Werner Schnurr , Guido Voit , Klemens Flick , Johann-Peter Melder , Rolf-Hartmuth Fischer , Wolfgang Harder
发明人： Werner Schnurr , Guido Voit , Klemens Flick , Johann-Peter Melder , Rolf-Hartmuth Fischer , Wolfgang Harder
IPC分类号： B01J25/02 , C07B61/00 , C07C209/48 , C07C211/12 , C07C253/30 , C07C255/24 , C07C255/00
CPC分类号： C07C209/48 , C07C253/30 , Y02P20/584
摘要： A process for the coproduction of 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) by treatment of adiponitrile (ADN) with hydrogen in the presence of a nickel-containing catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent comprises, after the conversion based on ADN and/or the selectivity based on ACN has or have dropped below a defined value (a) interrupting the treatment of ADN with hydrogen by stopping the feed of ADN and of the solvent, if used, (b) treating the catalyst at from 150.degree. to 400.degree. C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and (c) then continuing the hydrogenation of ADN with the treated catalyst of stage (b).
摘要翻译：在含镍催化剂存在下，在不低于室温的温度和氢分压升高的情况下，通过用氢气处理己二腈（ADN），共同生产6-氨基己腈（ACN）和六亚甲基二胺（HMD）的方法，没有溶剂包括在基于ADN的转化和/或基于ACN的选择性之后，或者已经降低到低于定义的值（a）通过停止ADN和溶剂的进料而中止用氢处理ADN，如果使用，（b）使用氢气压力为0.1〜30MPa，处理时间为2〜48小时，用氢气在150〜400℃下处理催化剂，（c）然后继续用（b）阶段处理的催化剂氢化ADN。

4. 发明授权

US08383866B2 Process for preparing diols by hydrogenating a carboxylic acid-comprising mixture by means of cobalt-comprising catalysts 失效
标题翻译：通过使含钴催化剂氢化含羧酸的混合物来制备二醇的方法
公开(公告)号：US08383866B2
公开(公告)日：2013-02-26
申请号：US12953004
申请日：2010-11-23
申请人： Rolf Pinkos , Axel Paul , Rolf-Hartmuth Fischer , Roman Dostalek
发明人： Rolf Pinkos , Axel Paul , Rolf-Hartmuth Fischer , Roman Dostalek
IPC分类号： C07C29/156
CPC分类号： C07C29/149 , C07C31/20
摘要： The present invention relates to a process for preparing diols by hydrogenating a mixture comprising carboxylic acid, carboxylic anhydrides and/or carboxylic esters/lactones by means of a cobalt-comprising catalyst, wherein alkali metal and/or alkaline earth metal ions are added to the hydrogenation feed, excluding alkali metal and/or alkaline earth metal ions of mineral acids.
摘要翻译：本发明涉及通过使含钴催化剂氢化包含羧酸，羧酸酐和/或羧酸酯/内酯的混合物来制备二醇的方法，其中将碱金属和/或碱土金属离子加入到氢化进料，不含碱金属和/或无机酸的碱土金属离子。

5. 发明申请

US20110224401A1 APPARATUS FOR SEPARATION BY DISTILLATION 审中-公开
标题翻译：通过蒸馏分离的装置
公开(公告)号：US20110224401A1
公开(公告)日：2011-09-15
申请号：US13131790
申请日：2009-11-29
申请人： Stefan Käshammer , Rolf Pinkos , Tobias Wabnitz , Rolf-Hartmuth Fischer
发明人： Stefan Käshammer , Rolf Pinkos , Tobias Wabnitz , Rolf-Hartmuth Fischer
IPC分类号： B01D3/14 , C08G65/20 , C08G63/00
CPC分类号： B01D1/065 , B01D1/22 , B01D3/06 , C08G65/20 , C08G65/30
摘要： The invention relates to an apparatus for separating a liquid substance mixture by distillation, a method for producing a tetrahydrofuran homopolymer and copolymer in which the oligomers in a liquid starting mixture containing oligomers are separated by distillation in such an apparatus, tetrahydrofuran homopolymers and copolymers which can be obtained using said method and have a narrow distribution of the relative molar mass, and the use thereof.
摘要翻译：本发明涉及一种通过蒸馏分离液体物质混合物的装置，四氢呋喃均聚物和共聚物的制备方法，其中含有低聚物的液体起始混合物中的低聚物在这种装置中通过蒸馏分离，四氢呋喃均聚物和共聚物可以使用所述方法获得并且具有相对摩尔质量的窄分布及其用途。

6. 发明授权

US07875740B2 Iron-containing material suitable for use as hydrogenation catalyst 有权
标题翻译：适用于氢化催化剂的含铁材料
公开(公告)号：US07875740B2
公开(公告)日：2011-01-25
申请号：US10493419
申请日：2002-10-18
申请人： Andreas Ansmann , Christoph Benisch , Peter Baβler , Rolf-Hartmuth Fischer , Stefan Maixner , Johann-Peter Melder , Hermann Luyken
发明人： Andreas Ansmann , Christoph Benisch , Peter Baβler , Rolf-Hartmuth Fischer , Stefan Maixner , Johann-Peter Melder , Hermann Luyken
IPC分类号： C07C255/03 , C07C209/04
CPC分类号： C07C253/30 , B01J23/745 , B01J23/8892 , C07C209/48 , C07C211/12 , C07C255/24
摘要： The iron-containing catalyst suitable for use as a catalyst contains a) iron or a mixture containing iron and an iron-based compound. The iron has an average crystallite size ranging from 1-35 nm measured by X-ray diffraction.
摘要翻译：适合用作催化剂的含铁催化剂含有a）铁或含有铁和铁基化合物的混合物。铁通过X射线衍射测得的平均微晶尺寸为1-35nm。

7. 发明授权

US07385073B2 Method for reducing the content of an unsaturated amine in a mixture containing an amino nitrile, a diamine, a dinitrile or mixtures thereof 有权
标题翻译：降低含氨基腈，二胺，二腈或其混合物的混合物中不饱和胺含量的方法
公开(公告)号：US07385073B2
公开(公告)日：2008-06-10
申请号：US10515281
申请日：2003-05-21
申请人： Stefan Maixner , Christoph Benisch , Hermann Luyken , Peter Baβler , Rolf-Hartmuth Fischer , Johann-Peter Melder , Andreas Ansmann
发明人： Stefan Maixner , Christoph Benisch , Hermann Luyken , Peter Baβler , Rolf-Hartmuth Fischer , Johann-Peter Melder , Andreas Ansmann
IPC分类号： C07C253/34
CPC分类号： C07C253/34 , C07C255/24
摘要： A process for reducing the level of an aliphatic monounsaturated amine (IV) in a mixture (V) containing an aminonitrile (I) or a diamine (II) or a dinitrile (III) or mixtures thereof as well as said mine (IV) by a) reacting said mixture (V) with an anionic nucleophile (VI) which contains a nucleophilic atom selected from the group consisting of oxygen, nitrogen and sulfur, which is capable of taking up an H+ ion to form an acid having a pKa value in the range from 7 to 11, as measured in water at 25° C., and which has a relative nucleophilicity, as measured in methyl perchlorate/methanol at 25° C., in the range from 3.4 to 4.7 when said nucleophilic atom is oxygen, in the range from 4.5 to 5.8 when said nucleophilic atom is nitrogen, and in the range from 5.5 to 6.8 when said nucleophilic atom is sulfur, in an amount in the range from 0.01 to 10 mol per mole of said amine (IV) in said mixture (V) at a temperature in the range from 50 to 200° C. to obtain a mixture (VII), b) distilling said aminonitrile (I) or said diamine (II) or said dinitrile (III) or mixtures thereof from said mixture (VII) at a temperature in the range from 50 to 200° C. and at a pressure in the range from 0.1 to 100 kPa to obtain a bottom product (VIII), which comprises c) distilling an aminonitrile (I) or diamine (II) or dinitrile (III) or mixtures thereof from said bottom product (VIII) at a temperature which is lower than that chosen in step b).
摘要翻译：在含有氨基腈（I）或二胺（II）或二腈（III）或其混合物以及所述矿（IV）的混合物（V）中降低脂族单不饱和胺（IV）的水平的方法， a）使所述混合物（V）与阴离子亲核试剂（VI）反应，所述阴离子亲核试剂（VI）含有选自氧，氮和硫的亲核原子，其能够吸收H + 形成在25℃下在水中测量的具有7至11的pK值的酸，其在25℃下在高氯酸甲酯/甲醇中测得的具有相对亲核性当所述亲核原子为氧时，在3.4至4.7的范围内，当所述亲核原子为氮时，在4.5至5.8的范围内，当所述亲核原子为硫时在5.5至6.8的范围内，其量为在所述混合物（V）中在50至200℃的温度范围内每摩尔所述胺（IV）为0.01至10摩尔的范围，以获得混合物（VII）中，b）在50至200℃的温度下，从所述混合物（VII）中蒸馏所述氨基腈（I）或所述二胺（II）或所述二腈（III）或其混合物，压力为0.1至100kPa，以获得底部产物（VIII），其包括c）在所述底部产物（VIII）中蒸馏氨基腈（I）或二胺（II）或二腈（III）或其混合物，温度低于步骤b）中选择的温度。

8. 发明授权

US07351311B2 Method for purifying tetrahydrofuran by distillation 有权
标题翻译：通过蒸馏提纯四氢呋喃的方法
公开(公告)号：US07351311B2
公开(公告)日：2008-04-01
申请号：US10505774
申请日：2003-02-28
申请人： Gunther Windecker , Alexander Weck , Rolf-Hartmuth Fischer , Markus Rösch , Nils Bottke , Michael Hesse , Stephan Schlitter , Holger Borchert
发明人： Gunther Windecker , Alexander Weck , Rolf-Hartmuth Fischer , Markus Rösch , Nils Bottke , Michael Hesse , Stephan Schlitter , Holger Borchert
IPC分类号： B01D3/14 , C07D307/08
CPC分类号： B01D3/146 , C07D307/08 , Y10S203/20
摘要： Crude water-containing tetrahydrofuran is purified by passing the crude tetrahydrofuran through three distillation columns, withdrawing water from the bottom of the first column, recycling water-containing tetrahydrofuran from the top of the second column into the first column, passing a sidestream of the first column into the second column, recycling the bottom product of the third column into the first column, and withdrawing a distillate at the top of the first column. Additionally, a sidestream of the second column is passed into the third column and the purified tetrahydrofuran is recovered as the top product of the third column.
摘要翻译：通过将粗四氢呋喃通过三个蒸馏塔，从第一塔的底部排出水，将含水四氢呋喃从第二塔的顶部再循环到第一塔中，将第一个塔塔进入第二列，将第三塔的底部产物回收到第一塔中，并且抽出第一塔顶部的馏出物。此外，将第二塔的侧流送入第三塔，回收纯化的四氢呋喃作为第三塔的顶部产物。

9. 发明授权

US07271299B2 Two-stage method for producing butanediol with intermediated separation of succinic anhydride 失效
标题翻译：用丁二酸中间分离制备丁二醇的两阶段方法
公开(公告)号：US07271299B2
公开(公告)日：2007-09-18
申请号：US10516922
申请日：2003-06-11
申请人： Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rösch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
发明人： Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rösch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
IPC分类号： C07C31/18
CPC分类号： C07C29/149 , C07C31/207
摘要： Optionally alkyl-substituted 1,4-butanediol is prepared from C4-dicarboxylic acids and/or of derivatives thereof by: a) a gas stream of the C4-dicarboxylic acid or the derivative thereof in a first reactor in the gas phase to obtain a product which contains mainly optionally alkyl-substituted γ-butyro-lactone; b) removing succinic anhydride from the product of step a); c) catalytically hydrogenating the product of step b) in a second reactor in the gas phase to obtain optionally alkyl-substituted 1,4-butanediol; d) removing the desired product from intermediates, by-products and any unconverted reactants; and e) optionally recycling unconverted intermediates into one or both hydrogenation stages. The catalysts employed in each of the hydrogenation stages comprise ≦95% by weight of CuO, and ≦5% by weight of an oxidic support, and the second reactor has a higher pressure than the first reactor.
摘要翻译：任选地，烷基取代的1,4-丁二醇由C 4-14二羧酸和/或其衍生物通过以下方法制备：a）引入C 4 - 二羧酸或其衍生物在气相中的第一反应器中，以获得主要含有烷基取代的γ-丁内酯的产物; b）从步骤a）的产物中除去琥珀酸酐; c）在气相中的第二反应器中催化氢化步骤b）的产物以获得任选的烷基取代的1,4-丁二醇; d）从中间体，副产物和任何未转化的反应物中除去所需的产物; 和e）任选地将未转化的中间体再循环到一个或两个氢化阶段。在每个氢化阶段中使用的催化剂包含<95重量％的CuO和<= 5重量％的氧化载体，并且第二反应器具有比第一反应器更高的压力。

10. 发明授权

US07169958B2 Method for the production of 1,4- butane-diol by combined gas-phase and liquid-phase hydrogenation 失效
标题翻译：通过组合气相和液相氢化生产1,4-丁二醇的方法
公开(公告)号：US07169958B2
公开(公告)日：2007-01-30
申请号：US10516923
申请日：2003-06-10
申请人： Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rösch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
发明人： Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rösch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
IPC分类号： C07C29/132 , C07C29/149 , C07C29/136 , C07C29/147
CPC分类号： C07C29/149 , C07C31/207
摘要： The present invention relates to a process for preparing optionally alkyl-substituted 1,4-butanediol by two-stage catalytic hydrogenation in the gas phase of C4-dicarboxylic acids and/or of derivatives thereof having the following steps: a) introducing a gas stream of a C4-dicarboxylic acid or of a derivative thereof at from 200 to 300° C. and from 2 to 60 bar into a first reactor and catalytically hydrogenating it to a product which contains mainly optionally alkyl-substituted γ-butyrolactone; b) converting the product stream into the liquid phase; c) introducing the product stream obtained in this way into a second reactor at a temperature of from 100° C. to 240° C. and a pressure of from 20 to 250 bar and catalytically hydrogenating it in the liquid phase to optionally alkyl-substituted 1,4-butanediol; d) removing the desired product from by-products and any unconverted reactants; e) optionally recycling unconverted intermediates into one or both hydrogenation stages, said hydrogenation stages both using a catalyst which comprises ≦95% by weight, preferably from 5 to 95% by weight, in particular from 10 to 80% by weight, of CuO, and ≧5% by weight, preferably from 5 to 95% by weight, in particular from 20 to 90% by weight, of a support, said second reactor having a higher pressure than said first reactor, and the product mixture removed from said first reactor being introduced without further purification into said second reactor.
摘要翻译：本发明涉及通过在具有下列物质的C 4 - 二羧酸和/或其衍生物的气相中通过两阶段催化氢化制备任选的烷基取代的1,4-丁二醇的方法步骤：a）将200-300℃和2-60巴的C 4-14二羧酸或其衍生物的气流引入第一反应器，并将其催化氢化至主要含烷基取代的γ-丁内酯的产品; b）将产物流转化成液相; c）将以这种方式获得的产物流在100℃至240℃的温度和20至250巴的压力下引入第二反应器，并将其在液相中催化氢化为任选的烷基取代的 1,4-丁二醇 d）从副产物和任何未转化的反应物中除去所需的产物; e）任选地将未转化的中间体再循环到一个或两个氢化阶段中，所述氢化步骤均使用包含<= 95重量％，优选5至95重量％，特别是10至80重量％的CuO ，和> = 5重量％，优选5至95重量％，特别是20至90重量％的载体，所述第二反应器具有比所述第一反应器更高的压力，并将产物混合物从所述第一反应器不经进一步纯化地引入所述第二反应器。

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