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    • 1. 发明授权
    • Process for producing molten pig iron of liquid steel preproducts and
plant for carrying out the process
    • 用于生产液态钢前产品和生产工厂的生铁生产工艺
    • US5961690A
    • 1999-10-05
    • US860241
    • 1997-06-10
    • Werner Leopold KepplingerFelix WallnerJohannes-Leopold Schenk
    • Werner Leopold KepplingerFelix WallnerJohannes-Leopold Schenk
    • C21B11/00C21B13/00C21B13/14C22B5/14
    • C21B13/14C21B13/002Y02P10/122Y02P10/126Y02P10/128Y02P10/136
    • In a process for producing molten pig iron or liquid steel pre-products, from particulate iron-oxide-containing material by fluidization, the iron-oxide-containing material is prereduced in at least one prereduction stage (7) by aid of a reducing gas and subsequently is reduced to sponge iron in a final reduction stage (8), the sponge iron is melted in a meltdown-gasifying zone (11) under the supply of carbon carriers and an oxygen-containing gas, and a CO- and H.sub.2 -containing reducing gas is produced which is introduced into the final reduction stage (8), is reacted there, is drawn off, subsequently is introduced into a prereduction stage (7), is reacted there, is drawn off, subjected to scrubbing and subsequently is carried off as an export gas and wherein at least a portion of the reacted reducing gas is purified from CO.sub.2, is heated and is used as a recycle-reducing gas for the reduction of the iron-oxide-containing material. To ensure reduction while avoiding the occurrence of "sticking", while also minimizing the amount of carbon carriers charged, a portion of the reducing gas flowing from the final reduction stage (8) into the prereduction stage (7) is branched off, washed, purified from CO.sub.2 and heated and subsequently is recycled to the final reduction stage (8) (FIG. 1).
    • PCT No.PCT / AT96 / 00191 Sec。 371日期:1997年6月10日 102(e)日期1997年6月10日PCT提交1996年10月8日PCT公布。 公开号WO97 / 13880 PCT 日期1997年04月17日在通过流化从含有氧化锰的物质生产熔融生铁或液钢预制品的方法中,含氧化铁材料在至少一个预还原阶段(7)中被预还原 还原气体的帮助,随后在最终还原阶段(8)中还原成海绵铁,海绵铁在碳载体和含氧气体的供应下在熔化气化区(11)中熔化,并且 产生含有CO和H 2的还原气体,其被引入到最终还原阶段(8)中,在其中反应,被排出,随后被引入预还原阶段(7),在那里被反应,被排出 进行洗涤,随后作为出口气体运送,并且其中至少一部分反应的还原气体从CO 2中净化,被加热并用作还原还原气体以还原含氧化铁的材料。 为了确保减少,同时避免“粘附”的发生,同时最小化装载的碳载体的量,一部分从最终还原段(8)流入预还原阶段(7)的还原气体被分支,洗涤, 从CO 2中纯化并加热,随后再循环至最终还原阶段(8)(图1)。
    • 3. 发明授权
    • Process for producing liquid pig iron or semifinished steel products from iron-containing materials
    • 从含铁材料生产液态生铁或半成品钢产品的工艺
    • US06454833B1
    • 2002-09-24
    • US09101176
    • 1998-08-13
    • Michael NaglJohannes-Leopold SchenkWerner Leopold Kepplinger
    • Michael NaglJohannes-Leopold SchenkWerner Leopold Kepplinger
    • C21B1300
    • C21B13/14C21B13/002C21B2100/44
    • In a method for producing liquid pig iron (9) or steel pre-products from fine-particulate iron-containing material (4) in a melter gasifier (1), the iron-containing material (4) is melted in a bed of solid carbon carriers (2) under supply of carbon-containing material (2) and oxygen-containing gas, at the simultaneous formation of a reducing gas, wherein the fine-particulate reduced material (4) and oxygen are introduced into the bed (20, 21) from the side. To be able to charge the fine-particulate iron-containing material to the melter gasifier (1) without a need for briquetting and, in doing so, avoid discharging of the fine-particulate iron-containing material (4) by the reducing gas formed in the melter gasifier (1), a fluidized bed (21) of fine-particulate solid carbon carriers (2) and fine-particulate iron-containing reduced material (4) is maintained above a fixed bed (20) formed of solid carbon carriers (2) and the fine-particulate reduced material (4) is charged into the fluidized bed (21) directly, in immediate contact with oxygen, preferably in the form of a strand having a ring-shaped cross-section and peripherally surrounding an oxygen jet and enclosing the oxygen, such that the oxygen is enclosed by the supplied fine-particulate reduced material (4), and the fine-particulate reduced material (4) is melted in the fluidized bed (FIG. 1).
    • 在熔融气化炉(1)中由含细粒铁的材料(4)生产液体生铁(9)或钢制预制品的方法中,含铁材料(4)在固体床 碳载体(2)在含碳材料(2)和含氧气体的供给下同时形成还原气体,其中将细颗粒还原材料(4)和氧气引入床(20, 21)从一边。 为了能够将微细含铁材料装入熔化炉气化器(1)而不需要压块,并且在这样做时,避免由形成的还原气体排出细粒状含铁材料(4) 在熔化器气化器(1)中,在固体碳载体(20)形成的固定床(20)上方保持有细颗粒固体碳载体(2)和细颗粒含铁还原材料(4)的流化床(21) (2)和细颗粒还原材料(4)直接与氧气直接接触到流化床(21)中,优选以具有环形横截面并且周围环绕氧的线形式 喷射并包围氧气,使得氧被所提供的细颗粒还原材料(4)包围,并且细颗粒还原材料(4)在流化床(图1)中熔化。
    • 4. 发明授权
    • Process for producing liquid metal and facilities for carrying out the process
    • 生产液态金属的工艺和进行工艺的设备
    • US06235082B1
    • 2001-05-22
    • US09029786
    • 1998-05-24
    • Werner Leopold KepplingerJohann WurmJohannes-Leopold Schenk
    • Werner Leopold KepplingerJohann WurmJohannes-Leopold Schenk
    • C21B1100
    • C21B13/002C21B13/14C21B2100/44C21B2100/66Y02P10/136
    • With a method for producing liquid metal from charging substances containing ore and of fluxes, the ore is directly reduced to sponge metal in at least one reduction zone (5, 7, 8), the sponge metal is melted along with fluxes in a melt-down gasifying zone (11) under the supply of carbon carriers and an oxygen-containing gas. A CO- and H2-containing process gas serving as a reducing gas is produced, fed into the reduction zone (5, 7, 8), reacted there, and subsequently withdrawn, wherein slagforming fluxes, in particular calcium carbonate, dolomite etc., gas are calcined by the process gas in a calcining zone (26′) that is separate from the reduction zone (5, 7, 8) and melt-down zone (11). To be able to employ slagforming fluxes of any desired grain and without disturbances of the reduction process, the calcining zone (26′) is connected in parallel to the reduction zone (5, 7, 8) with respect to the material flow and the calcined fluxes are fed into the melter gasifier (10) directly.
    • 通过从含有矿石和助熔剂的物质中提取液态金属的方法,矿石在至少一个还原区(5,7,8)中直接还原成海绵状金属,海绵金属与助熔剂一起熔化, 在碳载体和含氧气体的供应下向下气化区(11)。 产生用作还原气体的含CO和H 2的工艺气体,进料到还原区(5,7,8)中,在那里反应,随后取出,其中成型熔渣,特别是碳酸钙,白云石等, 在与还原区(5,7,8)和熔化区(11)分离的煅烧区(26')中,工艺气体煅烧气体。 为了能够使用任何所需颗粒的成渣助熔剂,并且没有干燥的还原过程,煅烧区(26')相对于材料流与还原区(5,7,8)平行连接,并且煅烧 助熔剂直接进入熔化炉气化器(10)。
    • 5. 发明授权
    • Method of charging metal carriers to a melt-down gasifying zone
    • 将金属载体装入熔化气化区的方法
    • US06277172B1
    • 2001-08-21
    • US09205425
    • 1998-12-04
    • Leopold Werner KepplingerFelix WallnerJohannes-Leopold Schenk
    • Leopold Werner KepplingerFelix WallnerJohannes-Leopold Schenk
    • C21B1100
    • C21B13/002C21B13/0026C21B13/14C21B2100/44C21B2100/66Y02P10/136
    • In a method of charging metal carriers which contain a portion of fines and are at least partially reduced and carbon carriers to a melter gasifier (10) in which a melt-down gasifying zone (11) is maintained, the metal carriers and the carbon carriers are fed into the melter gasifier (10) above the level of the melt-down gasifying zone (11) and descend to the melt-down gasifying zone (11) and travel through the same forming a metal melt and producing a reducing gas by coal gasification. In order to prevent a partial discharge of the metal carriers from the melter gasifier (10) during the charging of the same and to be able to achieve uniform distribution of the carbon carriers and the metal carriers, both the carbon carriers and the metal carriers are introduced into the melter gasifier centrally above the melt-down gasifying zone (11), preferably gravitationally, with a central strand (32) of metal carriers being formed which is peripherally surrounded by a jacket strand (37) formed by the carbon carriers.
    • 在将含有一部分细粉并且至少部分还原的金属载体和碳载体装入其中保持熔化气化区(11)的熔化气化器(10)的方法中,金属载体和碳载体 被送入熔融气化炉(10)的高于熔化气化区(11)的水平面并下降到熔化气化区(11)并通过其形成金属熔体并由煤生产还原气体 气化。 为了防止金属载体在其充电期间从熔融气化器(10)中部分放电,并且能够实现碳载体和金属载体的均匀分布,碳载体和金属载体都是 优选重力地在熔融气化区(11)的上方引入到熔融气化器中,形成金属载体的中心线(32),周边地被由碳载体形成的护套线(37)围绕。
    • 6. 发明授权
    • Process for producing liquid pig iron or semifinished steel products from ore
    • 从矿石生产液态生铁或半成品钢产品的工艺
    • US06179896B2
    • 2001-01-30
    • US09101150
    • 1998-07-01
    • Leopold Werner KepplingerFelix WallnerJohannes-Leopold Schenk
    • Leopold Werner KepplingerFelix WallnerJohannes-Leopold Schenk
    • C21B1100
    • C21B13/002
    • In a method of producing molten pig iron (9) or steel pre-products from lump ore which in at least one reduction zone is reduced to partially and/or completely reduced sponge iron (4) in a shaft furnace, the sponge iron (4) is melted down in a melt-down gasifying zone (8) of a melter gasifier (1) under supply of carbon-containing material (2) and oxygen and while simultaneously forming a reducing gas. To ensure that there will be a specific gap volume in the bed (13) of solid carbon carriers (2) even when charging fine-particle sponge iron (14) and hence that the bed (13) of solid carbon carriers (2) will be thoroughly flown through by gas, at least the sponge iron (4) is charged to the melt-down gasifying zone (8) discontinually, under formation of areas (14) of piled-up sponge iron which are embedded in the bed (13) of carbon carriers (2) and which are superposed and which are separated by solid carbon carriers (2), wherein each of the areas (14) of piled-up sponge iron while sparing a cross section zone (15) of the melt-down gasifying zone (8) extends over the cross section of the same and wherein the reducing gas forming the melt-down gasifying zone (8) flows past the areas (14) of piled-up sponge iron under melting of the same and upwards through the cross section zones (15) that are free from sponge iron and formed from carbon carriers (2), and flows through these zones.
    • 在生产熔融生铁(9)或块矿的钢制前产品的方法中,在竖炉中至少一个还原区被还原成部分和/或完全还原海绵铁(4)的方法中,海绵铁 )在含碳材料(2)和氧的供应下同时形成还原气体的同时在熔化气化器(1)的熔化气化区(8)中熔化。 为了确保在固体碳载体(2)的床(13)中将具有特定的间隙体积,即使在加入细颗粒海绵铁(14)时,因此固体碳载体(2)的床(13)将会 通过气体彻底地流通,至少将海绵铁(4)不连续地装入熔化气化区(8)中,形成嵌入床(13)中的堆积海绵铁的区域(14) )的碳载体(2)并且它们被重叠并且被固体碳载体(2)分离,其中堆积的海绵铁的每个区域(14)同时保持熔融物的横截面区域(15) 向下气化区(8)在其横截面上延伸,并且其中形成熔化气化区(8)的还原气体流过堆积的海绵铁的区域(14),熔融的同时向上通过 横截面区域(15),其不含海绵铁并由碳载体(2)形成并且流过这些区域。
    • 7. 发明授权
    • Plant for charging metal carriers to melt-down gasifying zone
    • 用于对金属载体进行充电以熔化气化区的装置
    • US06491864B2
    • 2002-12-10
    • US09883176
    • 2001-06-19
    • Udo GennariJohannes-Leopold Schenk
    • Udo GennariJohannes-Leopold Schenk
    • C21B1300
    • C21B13/002C21B13/0026C21B13/14C21B2100/44Y02P10/136
    • Plant for charging metal carriers which contain a portion of fines and are at least partially reduced to a melter gasifier in which a melt-down gasifying zone formed by a bed is maintained, the metal carriers and carbon carriers are fed into the melter gasifier above the level of the melt-down gasifying zone. The metal carriers descend to the melt-down gasifying zone and travel through the same forming a metal melt and producing a reducing gas by coal gasification. In order to prevent a partial discharge from the melter gasifier of the metal carriers, in particular of the fine particles thereof, when charging the same, feeding of the metal carriers into the interior of the melter gasifier is effected at a vertical distance below a dome (30) terminating the melter gasifier toward the top, gravitationally and under the formation of a strand (44), and the strand (44) is surrounded by a gas jacket (45) enclosing and accompanying the freely falling strand (44) from its level of origin (at 40) onwards over a section (46) of the fall, and in this section (46) the strand (44) is supported against expansion by the gas jacket (45).
    • 用于对含有一部分细粉的金属载体进行充电并且至少部分地还原成其中保持由床形成的熔化气化区的熔化器气化器,将金属载体和碳载体进料到熔融气化器中, 熔化气化区的水平。 金属载体下降到熔化气化区,并通过其形成金属熔体并通过煤气化产生还原气体。 为了防止金属载体,特别是其微细颗粒的熔融气化器的局部放电,当充电时,金属载体进入熔化器气化器的内部在垂直距离的圆顶下方进行 (30)在重力作用下和在股线(44)的形成下终止熔融气化器朝向顶部终止熔融气化器,并且该股线(44)由围绕其自由落下的股线(44)的气套(45)包围, 起始点(40°)在秋天的一部分(46)之后,在该部分(46)中,股线(44)被气套(45)支撑而不被膨胀。
    • 8. 发明授权
    • Method of charging metal carriers to a melt-down gasifying zone
    • 将金属载体装入熔化气化区的方法
    • US06258148B1
    • 2001-07-10
    • US09223372
    • 1998-12-30
    • Udo GennariJohannes-Leopold Schenk
    • Udo GennariJohannes-Leopold Schenk
    • C21B1100
    • C21B13/002C21B13/0026C21B13/14C21B2100/44Y02P10/136
    • In a method of charging metal carriers which contain a portion of fines and are at least partially reduced to a melter gasifier in which a melt-down gasifying zone formed by a bed is maintained, the metal carriers and carbon carriers are fed into the melter gasifier above the level of the melt-down gasifying zone. The metal carriers descend to the melt-down gasifying zone and travel through the same forming a metal melt and producing a reducing gas by coal gasification. In order to prevent a partial discharge from the melter gasifier of the metal carriers, in particular of the fine particles thereof, when charging the same, feeding of the metal carriers into the interior of the melter gasifier is effected at a vertical distance below a dome (30) terminating the melter gasifier toward the top, gravitationally and under the formation of a strand (44), and the strand (44) is surrounded by a gas jacket (45) enclosing and accompanying the freely falling strand (44) from its level of origin (at 40) onwards over a section (46) of the fall, and in this section (46) the stand (44) is supported against expansion by the gas jacket (45).
    • 在包含一部分细粉的金属载体的方法中,至少部分地还原成保持由床形成的熔化气化区的熔化气化器,将金属载体和碳载体进料到熔炉气化器 高于熔化气化区的水平面。 金属载体下降到熔化气化区,并通过其形成金属熔体并通过煤气化产生还原气体。 为了防止金属载体,特别是其微细颗粒的熔融气化器的局部放电,当充电时,金属载体进入熔化器气化器的内部在垂直距离的圆顶下方进行 (30)在重力作用下和在股线(44)的形成下终止熔融气化器朝向顶部终止熔融气化器,并且该股线(44)由围绕其自由落下的股线(44)的气套(45)包围, 起始点(40°)在秋天的一部分(46)之后,在该部分(46)中,支架(44)被气套(45)支撑而不会膨胀。