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1. 发明授权

US5871650A Supported zeolite membranes with controlled crystal width and preferred orientation grown on a growth enhancing layer 失效
标题翻译：在生长增强层上生长的具有受控晶体宽度和优选取向的支撑沸石膜
公开(公告)号：US5871650A
公开(公告)日：1999-02-16
申请号：US272361
申请日：1994-07-08
申请人： Wenyih Frank Lai , Harry William Deckman , James Alexander McHenry , Johannes Petrus Verduijn
发明人： Wenyih Frank Lai , Harry William Deckman , James Alexander McHenry , Johannes Petrus Verduijn
IPC分类号： B01D71/02 , B01J37/02 , B01D61/00
CPC分类号： B01D67/0083 , B01D67/0051 , B01D67/0097 , B01D71/028 , B01J37/0244 , B01J37/0246 , B01D2323/08 , B01J2229/64 , B01J2229/66 , Y10S977/701 , Y10S977/721
摘要： The present invention is directed toward a new zeolite membrane which exhibits a columnar cross-sectional morphology and preferred crystallographic orientation comprising a porous substrate having coated thereon a mesoporous growth enhancing layer and a layer of columnar zeolite crystals on said mesoporous growth enhancing layer, and wherein said mesoporous growth enhancing layer comprises nanocrystalline or colloidal sized zeolites, nanocrystalline or colloidal zeolite and metal oxide, or nanocrystalline or colloidal zeolite and colloidal metal, or nanocrystalline or colloidal zeolite, colloidal metal and metal oxide, and wherein said mesoporous growth enhancing layer has interstices of about 20 to about 2000 .ANG., and wherein said columnar zeolite layer is a polycrystalline layer wherein 99.9% of said columnar zeolite crystals have at least one point between adjacent crystals that is .ltoreq.20 .ANG.. The invention is further directed to a process of producing a zeolite membrane exhibiting a columnar crystallographic orientation.
摘要翻译：本发明涉及一种新的沸石膜，其显示出柱状横截面形态和优选的结晶取向，其包括在其上涂覆介孔生长增强层的多孔基材和所述介孔生长增强层上的柱状沸石晶体层，其中所述介孔生长增强层包括纳米晶体或胶体大小的沸石，纳米晶体或胶体沸石和金属氧化物，或纳米晶体或胶体沸石和胶体金属，或纳米晶体或胶体沸石，胶体金属和金属氧化物，并且其中所述介孔生长增强层具有间隙约20至约2000，并且其中所述柱状沸石层是多晶层，其中99.9％的所述柱状沸石晶体在相邻晶体之间具有至少一个点，为20。本发明进一步涉及一种制备呈现柱状结晶取向的沸石膜的方法。

2. 发明授权

US5672388A Membrane reparation and poer size reduction using interfacial ozone assisted chemical vapor deposition 失效
标题翻译：使用界面臭氧辅助化学气相沉积法进行膜修复和大小缩小
公开(公告)号：US5672388A
公开(公告)日：1997-09-30
申请号：US272360
申请日：1994-07-08
申请人： James Alexander McHenry , Harry William Deckman , Edward William Corcoran, Jr. , Wenyih Frank Lai , Horst Witzke
发明人： James Alexander McHenry , Harry William Deckman , Edward William Corcoran, Jr. , Wenyih Frank Lai , Horst Witzke
IPC分类号： B01D65/10 , B01D67/00 , B01D71/02 , B05D7/14 , B05D7/24 , C23C16/04 , C23C16/40 , C23C16/00
CPC分类号： B01D67/0088 , B01D67/0044 , B01D67/0072 , B01D71/02 , B01D71/028 , C23C16/045 , C23C16/40 , B01D2323/08
摘要： The instant invention is directed toward a process for enhancing the permselective properties, selectively sealing defects and pinholes, controllably altering the pore size and stabilizing the permselective properties of articles having apperatures therein comprising the steps of: simultaneously contacting an article having a first and second surface, said first and second surfaces being capable of passing ozone and silicon compounds therethrough and said first and second surfaces being oriented such that said silicon compounds and ozone can react across said first and second surfaces, with ozone on said first surface and a silicon compound on said second surface and wherein said contacting is conducted for a time and at a temperature and pressure sufficient to allow said ozone and said silicon compound to form a silicon oxide.
摘要翻译：本发明涉及增强渗透选择性能，选择性地密封缺陷和针孔的方法，可控制地改变孔径并稳定其中具有温度的制品的选择性选择性，其特征在于包括以下步骤：同时使具有第一和第二表面所述第一表面和第二表面能够通过臭氧和硅化合物，并且所述第一和第二表面定向成使得所述硅化合物和臭氧可以在所述第一表面和第二表面之间反应，并且在所述第一表面上具有臭氧，所述第二表面，其中所述接触进行一段时间，并且在足以允许所述臭氧和所述硅化合物形成氧化硅的温度和压力下进行。

3. 发明授权

US5716527A Zeolite membrane with a selectivity enhancing coating 失效
标题翻译：具有选择性增强涂层的沸石膜
公开(公告)号：US5716527A
公开(公告)日：1998-02-10
申请号：US272352
申请日：1994-07-08
申请人： Harry William Deckman , Edward William Corcoran, Jr. , James Alexander McHenry , Wenyih Frank Lai , Lothar Ruediger Czarnetzki , William Edward Wales
发明人： Harry William Deckman , Edward William Corcoran, Jr. , James Alexander McHenry , Wenyih Frank Lai , Lothar Ruediger Czarnetzki , William Edward Wales
IPC分类号： B01D67/00 , B01D71/02 , B01J37/02 , B01D61/00 , B01D39/00
CPC分类号： B01D67/0088 , B01D67/0051 , B01D71/028 , B01J37/0244 , B01J37/0246 , B01D2323/283 , B01D2325/20 , B01J2229/64 , B01J2229/66
摘要： Membranes useful in separating moleculres or catalytic conversions comprise a substrate, a zeolite or zeolite-like layer, a selectivity enhancing coating in contact with the zeolite layer and optionally a permeable intermediate layer in contact with the substrate the zeolite layer being in contact either with the substrate or the optional intermediate layer.
摘要翻译：用于分离分子或催化转化的膜包括底物，沸石或类沸石层，与沸石层接触的选择性增强涂层和任选的与基材接触的可渗透中间层，沸石层与衬底或可选的中间层。

4. 发明授权

US5968366A Zeolite containing composition with a selectivity enhancing coating 失效
标题翻译：含有选择性增强涂层的含沸石组合物
公开(公告)号：US5968366A
公开(公告)日：1999-10-19
申请号：US909981
申请日：1997-08-12
申请人： Harry William Deckman , Edward William Corcoran, Jr. , James Alexander Mc Henry , Wenyih Frank Lai , Lothar Ruediger Czarnetzki , William Edward Wales
发明人： Harry William Deckman , Edward William Corcoran, Jr. , James Alexander Mc Henry , Wenyih Frank Lai , Lothar Ruediger Czarnetzki , William Edward Wales
IPC分类号： B01D67/00 , B01D71/02 , B01J37/02 , B01D61/00 , B01D39/00
CPC分类号： B01D67/0088 , B01D69/12 , B01D71/028 , B01J37/0244 , B01J37/0246 , B01J2229/64 , B01J2229/66 , Y10S977/889
摘要： Compositions useful in separating molecules or catalytic conversions comprise a substrate, a zeolite or zeolite-like layer, a selectivity enhancing coating in contact with the zeolite layer and optionally a permeable intermediate layer in contact with the substrate the zeolite layer being in contact either with the substrate or the optional intermediate layer.
摘要翻译：用于分离分子或催化转化的组合物包括底物，沸石或沸石样层，与沸石层接触的选择性增强涂层和任选地与基底接触的可渗透中间层，沸石层与衬底或可选的中间层。

5. 发明授权

US10155665B2 Zeolite synthesis with dominant and secondary templates 有权
公开(公告)号：US10155665B2
公开(公告)日：2018-12-18
申请号：US14887464
申请日：2015-10-20
申请人： Wenyih Frank Lai , Nicholas S. Rollman , Jenna L. Walp , William W. Lonergan
发明人： Wenyih Frank Lai , Nicholas S. Rollman , Jenna L. Walp , William W. Lonergan
IPC分类号： C01B39/48 , B01J29/70 , C01B39/04
摘要： Methods are provided for synthesis of various types of zeolites using synthesis mixtures that contain a dominant structure directing agent and one or more secondary structure directing agents. Advantageously, the secondary structure directing agents may substantially not alter the crystal structure and/or morphology of the crystals generated by a synthesis mixture in the presence of the dominant structure directing agent.

6. 发明授权

US08557219B2 High throughput process for manufacturing molecular sieves 有权
标题翻译：用于制造分子筛的高通量过程
公开(公告)号：US08557219B2
公开(公告)日：2013-10-15
申请号：US11699168
申请日：2007-01-29
申请人： Ivy D. Johnson , Wenyih Frank Lai
发明人： Ivy D. Johnson , Wenyih Frank Lai
IPC分类号： C01B33/36 , C01B39/04 , C01B39/00
CPC分类号： C07B37/04 , B01J20/3028 , B01J29/04 , B01J29/06 , B01J29/40 , B01J29/7023 , B01J29/7038 , B01J29/80 , B01J29/86 , C01B37/02 , C01B39/02 , C01B39/04 , C01B39/40 , C07C2/66 , C07C6/126 , C07C29/36 , C07C51/235 , C09B67/0073 , C09B67/0096 , C10G45/64 , Y02P20/52 , C07C15/02 , C07C15/107 , C07C15/085 , C07C57/30 , C07C33/20
摘要： A method of crystallizing a crystalline molecular sieve having a pore size in the range of from about 2 to about 19 Å, said method comprising the steps of (a) providing a mixture comprising at least one source of ions of tetravalent element (Y), at least one hydroxide source (OH−), and water, said mixture having a solid-content in the range of from about 15 wt. % to about 50 wt. %; and (b) treating said mixture to form the desired crystalline molecular sieve with stirring at crystallization conditions sufficient to obtain a weight hourly throughput from about 0.005 to about 1 hr−1, wherein said crystallization conditions comprise a temperature in the range of from about 200° C. to about 500° C. and a crystallization time less than 100 hr.
摘要翻译：一种结晶分子筛的方法，其结晶分子筛的孔径在约2至约19的范围内，所述方法包括以下步骤：（a）提供包含至少一种四价元素（Y）离子源的混合物，至少一种氢氧化物源（OH-）和水，所述混合物的固体含量范围为约15wt。％至约50wt。％; 和（b）在足以从约0.005至约1小时-1获得重量小时产量的结晶条件下搅拌处理所述混合物以形成所需的结晶分子筛，其中所述结晶条件包括在约200 约500℃，结晶时间小于100小时。

7. 发明申请

US20130026070A1 Hydrocracking Catalysts Containing Stabilized Aggregates of Small Crystallites of Zeolite Y Associated Hydrocarbon Conversion Processes 有权
标题翻译：包含稳定的沸石小沸石聚集体的加氢裂化催化剂Y相关烃转化过程
公开(公告)号：US20130026070A1
公开(公告)日：2013-01-31
申请号：US13412945
申请日：2012-03-06
申请人： Christopher G. Oliveri , Wenyih Frank Lai , Ajit B. Dandekar , Scott J. Weigel , Jason Wu , Robert E. Kay
发明人： Christopher G. Oliveri , Wenyih Frank Lai , Ajit B. Dandekar , Scott J. Weigel , Jason Wu , Robert E. Kay
IPC分类号： C10G47/20 , B01J29/08 , B01J29/80 , B01J29/65 , B01J29/60 , B01J29/18 , B01J29/14 , C10G47/18 , B01J29/40 , B82Y30/00
CPC分类号： B01J35/002 , B01J29/084 , B01J29/126 , B01J29/146 , B01J29/166 , B01J29/80 , B01J35/023 , B01J35/04 , B01J35/1019 , B01J35/1061 , B01J35/1066 , B01J35/1085 , B01J35/109 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C01B39/24 , C10G47/18 , C10G47/20
摘要： This invention relates to hydrocracking catalysts utilizing stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 μm. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more. This invention also relates to the use of such catalysts in hydrocracking processes for the conversion of heavy oils into lighter fuel products. The invention is particularly suited for the selective production of diesel range products from gas oil range feedstock materials under hydrocracking conditions.
摘要翻译：本发明涉及使用聚集成更大二次粒子的沸石Y的小初级晶体的稳定聚集体的加氢裂化催化剂。至少80％的二次粒子可以包含至少5个初级微晶。初级微晶的尺寸可以为至多约0.5微米，或至多约0.3微米，并且二次颗粒的尺寸可以为至少约0.8微米，或至少约1.0微米。得到的稳定的聚集Y型沸石的二氧化硅与氧化铝的比例可以为4:1以上。本发明还涉及这种催化剂在加氢裂化方法中用于将重油转化成较轻燃料产物的用途。本发明特别适用于在加氢裂化条件下从瓦斯油原料中选择性生产柴油产品。

8. 发明申请

US20110021856A1 Method of Preparing a Molecular Sieve Composition 有权
标题翻译：分子筛组合物的制备方法
公开(公告)号：US20110021856A1
公开(公告)日：2011-01-27
申请号：US12896065
申请日：2010-10-01
申请人： Wenyih Frank Lai , Robert Ellis Kay
发明人： Wenyih Frank Lai , Robert Ellis Kay
IPC分类号： B01J29/04 , C01B39/02 , C01B39/04 , C07C2/66
CPC分类号： B01J29/70 , B01J29/04 , B01J29/06 , B01J29/7007 , B01J29/7038 , B01J29/80 , B01J37/0009 , B01J37/031 , B01J2229/12 , B01J2229/20 , B01J2229/62 , B01J2229/64 , C01B39/023 , C01B39/04 , C01B39/48 , C07C2/66 , C07C2529/70 , C07C2529/80 , Y02P20/52 , C07C15/085
摘要： A method of preparing a crystalline molecular sieve is provided, which method comprises (a) providing a reaction mixture comprising at least one source of ions of tetravalent element Y, at least one source of alkali metal hydroxide, water, optionally at least one seed crystal, and optionally at least one source of ions of trivalent element X, said reaction mixture having the following mole composition: Y:X2=10 to infinity OH−:Y=0.001 to 2 M+:Y=0.001 to 2 wherein M is an alkali metal and the amount of water is at least sufficient to permit extrusion of said reaction mixture; (b) extruding said reaction mixture to form a pre-formed extrudate; and (c) crystallizing said pre-formed extrudate under vapor phase conditions in a reactor to form said crystalline molecular sieve whereby excess alkali metal hydroxide is removed from the pre-formed extrudate during crystallization. The crystalline molecular sieve product is useful as catalyst in hydrocarbon conversion processes.
摘要翻译：提供一种制备结晶分子筛的方法，该方法包括（a）提供包含至少一种四价元素Y的离子源，至少一种碱金属氢氧化物源，水，任选至少一种晶种的离子的反应混合物和任选的至少一种三价元素X的离子源，所述反应混合物具有以下摩尔组成：Y：X2 = 10至无穷远OH-：Y = 0.001至2M +：Y = 0.001至2其中M为碱金属和水的量至少足以允许所述反应混合物的挤出; （b）挤出所述反应混合物以形成预成型的挤出物; 和（c）在气相条件下在反应器中使所述预形成的挤出物结晶以形成所述结晶分子筛，从而在结晶期间从预形成的挤出物中除去过量的碱金属氢氧化物。结晶分子筛产物可用作烃转化过程中的催化剂。

9. 发明授权

US07846418B2 MCM-22 family molecular sieve composition 有权
标题翻译： MCM-22家族分子筛组成
公开(公告)号：US07846418B2
公开(公告)日：2010-12-07
申请号：US11657192
申请日：2007-01-24
申请人： Wenyih Frank Lai , Robert Ellis Kay
发明人： Wenyih Frank Lai , Robert Ellis Kay
IPC分类号： C01B39/46 , B01J29/06 , C10G47/04
CPC分类号： B01J29/7038 , B01J35/002 , C01B37/02 , C01B39/48 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G65/10 , C07C15/107
摘要： An MCM-22 family molecular sieve having an X-ray diffraction pattern of the as-synthesized MCM-22 family molecular sieve including d-spacing maxima at 12.4±0.25, 3.57±0.07 and 3.42±0.07 Angstroms and at least one peak between 26.6° and 29° (2θ). The peak between 26.6° to 29° (2θ) has a two theta (2θ) of about 26.9°. A method of manufacturing an MCM-22 family molecular sieve, said method comprising the steps of (a) combining at least one silicon source, at least one source of alkali metal hydroxide, at least one directing-agent (R), water, and optionally one aluminum source, to form a mixture having the following mole composition: Si:Al2=10 to infinity H2O:Si=1 to 20 OH−:Si=0.001 to 2 M+:Si=0.001 to 2 R:Si=0.001 to 0.34 wherein M is an alkali metal; (b) treating said mixture at crystallization conditions for less than 72 hr to form a treated mixture having said MCM-22 family molecular sieve, wherein said crystallization conditions comprises a temperature range from about 160° C. to about 250° C.; and (c) recovering said MCM-22 family molecular sieve.
摘要翻译：具有所合成的MCM-22族分子筛的X射线衍射图的MCM-22族分子筛包括在12.4±0.25,3.57±0.07和3.42±0.07埃处的d间距最大值，以及26.6之间的至少一个峰 °和29°（2°）。 26.6°至29°（2θ）之间的峰值具有约26.9°的2θ（2θ）。一种制备MCM-22族分子筛的方法，所述方法包括以下步骤：（a）将至少一种硅源，至少一种碱金属氢氧化物源，至少一种导向剂（R），水和任选一个铝源，以形成具有以下摩尔组成的混合物：Si：Al2 = 10至无穷大H 2 O：Si = 1至20 OH-：Si = 0.001至2 M +：Si = 0.001至2 R：Si = 0.001至 0.34，其中M是碱金属; （b）在结晶条件下处理所述混合物小于72小时以形成具有所述MCM-22族分子筛的处理过的混合物，其中所述结晶条件包括约160℃至约250℃的温度范围; 和（c）回收所述MCM-22族分子筛。

10. 发明申请

US20100298598A1 Method of Preparing a Molecular Sieve Composition 有权
标题翻译：分子筛组合物的制备方法
公开(公告)号：US20100298598A1
公开(公告)日：2010-11-25
申请号：US12738055
申请日：2008-09-30
申请人： Wenyih Frank Lai , Robert Ellis Kay
发明人： Wenyih Frank Lai , Robert Ellis Kay
IPC分类号： B01J29/06 , C10G65/10 , C10G35/04 , C01B39/02 , C07C51/00 , C07C45/00 , C07C41/00 , C07C37/00 , C07C2/76 , C07C2/00 , C07C7/12
CPC分类号： B01J29/80 , B01J29/06 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/7007 , B01J29/7038 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J37/0018 , B01J2229/62 , B01J2229/64 , C01B39/02 , C01B39/46 , C01B39/48 , C09B62/02 , C10G11/05 , C10G25/03 , C10G29/205 , C10G45/00 , C10G45/54 , C10G45/64 , C10G47/16 , C10G50/00
摘要： This disclosure provides a method of preparing a crystalline molecular sieve comprising: (a) providing a reaction mixture comprising at least one source of ions of tetravalent element Y, at least one source of alkali metal hydroxide, water, optionally at least one seed crystal, and optionally at least one source of ions of trivalent element X, the reaction mixture having the following molar composition: Y:X2=2 to infinity, preferably from about 2 to about 1000, OH−:Y=0.001 to 2, preferably from 0.1 to 1, M+:Y=0.001 to 2, preferably from 0.01 to 2 wherein M is an alkali metal and the amount of water is at least sufficient to permit extrusion of the reaction mixture, wherein the reaction mixture is substantially free of crystalline molecular sieve; (b) extruding the reaction mixture to form a pre-formed extrudate; and (c) crystallizing the pre-formed extrudate in a liquid medium comprising water under liquid phase crystallization conditions to form a crystallized extrudate having the crystalline molecular sieve.
摘要翻译：本公开提供了制备结晶分子筛的方法，其包括：（a）提供包含至少一种四价元素Y的离子源，至少一种碱金属氢氧化物源，水，任选至少一种晶种的离子的反应混合物，和任选的至少一种三价元素X的离子源，所述反应混合物具有以下摩尔组成：Y：X2 = 2至无穷大，优选约2至约1000，OH-：Y = 0.001至2，优选0.1 至1，M +：Y = 0.001至2，优选0.01至2，其中M为碱金属，水的量至少足以允许反应混合物挤出，其中反应混合物基本上不含结晶分子筛 ; （b）挤出反应混合物以形成预成型的挤出物; 和（c）在液相结晶条件下将包含水的液体介质中的预成形挤出物结晶以形成具有结晶分子筛的结晶的挤出物。

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