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1. 发明授权

US09056823B2 Use of organic framework porous solid acid 有权
标题翻译：使用有机骨架多孔固体酸
公开(公告)号：US09056823B2
公开(公告)日：2015-06-16
申请号：US14131496
申请日：2012-07-06
申请人： Wenpeng Li , Fengshou Xiao , Haicheng Xiao , Fujian Liu , Yinghui Li , Xiangju Meng , Xianming Xu , Xiangmin Yu , Wei Zhang , Kezhong Xu , Guoquan Song , Haotian Pei , Fangwei Li , Qunying Zeng , Zhixiang Zhang , Yueman Li
发明人： Wenpeng Li , Fengshou Xiao , Haicheng Xiao , Fujian Liu , Yinghui Li , Xiangju Meng , Xianming Xu , Xiangmin Yu , Wei Zhang , Kezhong Xu , Guoquan Song , Haotian Pei , Fangwei Li , Qunying Zeng , Zhixiang Zhang , Yueman Li
IPC分类号： C07C67/08 , C07C45/65 , B01J31/10 , B01J37/10 , C07C45/46 , C08F112/36 , C08F8/36 , B01J27/055 , B01J35/02 , B01J37/00
CPC分类号： C07C45/65 , B01J27/055 , B01J31/10 , B01J35/023 , B01J37/0036 , B01J37/10 , C07C45/46 , C07C67/08 , C07C2601/14 , C08F8/36 , C08F112/36 , C07C49/84 , C07C69/14 , C07C69/24
摘要： The invention relates to a catalyst for the catalytic esterification and acylation reaction. The catalyst is prepared by the steps of adding a divinyl benzene monomer into a solvent prepared by mixing azobisisobutyronitrile, tetrahydrofuran and water, performing hydrothermal treatment at the normal temperature under the constant pressure, and volatilizing the solvent at the room temperature to obtain polydivinylbenzene; grinding the polydivinylbenzene into 200-mesh powder and performing degassing treatment under the nitrogen condition; adding polydivinylbenzene blocks into 1,1′,2-trichloroethane to explode and crack into small blocks, wherein the small blocks swell; evenly mixing 1,1′,2-trichloroethane and concentrated sulfuric acid, adding silver sulfate serving as a catalyst, adding processed polydivinylbenzene, performing sulfonation, filtering and washing with dioxane and water till it is neutral, performing drying, using dilute sulphuric acid to activate, performing washing till the it is neutral and performing drying. The catalyst has high catalytic activity and conversion rate.
摘要翻译：本发明涉及催化酯化和酰化反应的催化剂。该催化剂通过以下步骤制备：将二乙烯基苯单体加入到通过混合偶氮二异丁腈，四氢呋喃和水制备的溶剂中，在常压下恒温进行水热处理，并在室温下挥发溶剂得到聚二乙烯基苯; 将聚二乙烯基苯研磨成200目粉末，并在氮气条件下进行脱气处理; 将聚二乙烯基苯嵌段加入到1,1'，2-三氯乙烷中，爆炸裂成小块，其中小块膨胀; 均匀混合1,1'，2-三氯乙烷和浓硫酸，加入硫酸银作为催化剂，加入加工的聚二乙烯基苯，进行磺化，过滤并用二恶烷和水洗涤至中性，进行干燥，用稀硫酸激活，进行洗涤直到它是中性的并进行干燥。该催化剂具有较高的催化活性和转化率。

2. 发明申请

US20140235891A1 USE OF ORGANIC FRAMEWORK POROUS SOLID ACID 有权
标题翻译：有机骨架多孔固体酸的使用
公开(公告)号：US20140235891A1
公开(公告)日：2014-08-21
申请号：US14131496
申请日：2012-07-06
申请人： Wenpeng Li , Fengshou Xiao , Haicheng Xiao , Fujian Liu , Yinghui Li , Xiangju Meng , Xianming Xu , Xiangmin Yu , Wei Zhang , Kezhong Xu , Guoquan Song , Haotian Pei , Fangwei Li , Qunying Zeng , Zhixiang Zhang , Yeman Li
发明人： Wenpeng Li , Fengshou Xiao , Haicheng Xiao , Fujian Liu , Yinghui Li , Xiangju Meng , Xianming Xu , Xiangmin Yu , Wei Zhang , Kezhong Xu , Guoquan Song , Haotian Pei , Fangwei Li , Qunying Zeng , Zhixiang Zhang , Yeman Li
IPC分类号： C07C67/08 , C07C45/65
CPC分类号： C07C45/65 , B01J27/055 , B01J31/10 , B01J35/023 , B01J37/0036 , B01J37/10 , C07C45/46 , C07C67/08 , C07C2601/14 , C08F8/36 , C08F112/36 , C07C49/84 , C07C69/14 , C07C69/24
摘要： The invention relates to an application of organic framework porous solid acid. A catalyst for catalytic esterification and acylation reaction is prepared by the steps of adding a divinyl benzene monomer into a solvent prepared by mixing azobisisobutyronitrile, tetrahydrofuran and water, performing hydrothermal treatment at the normal temperature under the constant pressure, and volatilizing the solvent at the room temperature to obtain polydivinylbenzene; grinding the polydivinylbenzene into 200-mesh powder and performing degassing treatment under the nitrogen condition; adding polydivinylbenzene blocks into 1,1′,2-methyl chloroform to explode and crack into small blocks, wherein the small blocks swell; evenly mixing 1,1′,2-methyl chloroform and concentrated sulfuric acid, adding silver sulfate serving as a catalyst, adding processed polydivinylbenzene, performing sulfonation, filtering and washing with dioxane and water till it is neutral, performing drying, using dilute sulphuric acid to activate, performing washing till the it is neutral and performing drying. The catalyst is used for the catalytic esterification and the acylation reaction and has high catalytic activity and conversion rate.
摘要翻译：本发明涉及有机骨架多孔固体酸的应用。通过以下步骤制备催化酯化和酰化反应的催化剂：将二乙烯基苯单体加入到通过混合偶氮二异丁腈，四氢呋喃和水制备的溶剂中，在常压下在恒定压力下进行水热处理，并在室温下挥发溶剂温度得到聚二乙烯基苯; 将聚二乙烯基苯研磨成200目粉末，并在氮气条件下进行脱气处理; 将聚二乙烯基苯嵌段加入到1,1'，2-甲基氯仿中，将其破碎成小块，其中小块膨胀; 均匀混合1,1'，2-甲基氯仿和浓硫酸，加入硫酸银作为催化剂，加入加工的聚二乙烯基苯，进行磺化，过滤并用二恶烷和水洗涤至中性，用稀硫酸激活，进行洗涤直至其中性并进行干燥。该催化剂用于催化酯化和酰化反应，具有较高的催化活性和转化率。

3. 发明授权

US08840817B2 Preparation method for asphalt-based spherical activated carbon which requires no infusibilization process 有权
标题翻译：沥青基球形活性炭的制备方法，无需加工过程
公开(公告)号：US08840817B2
公开(公告)日：2014-09-23
申请号：US13695052
申请日：2012-02-20
申请人： Xiangmin Yu , Yizhou Kong
发明人： Xiangmin Yu , Yizhou Kong
IPC分类号： C01B31/08 , B01J20/30 , B01J20/20
CPC分类号： C01B31/089 , B01J20/20 , B01J20/28019 , B01J20/3007 , B01J20/3078 , C01B32/336 , C01B32/382
摘要： The present invention is a preparation method for asphalt-based spherical activated carbon which requires no infusibilization process. Placing coal tar asphalt into a melting device; introducing compressed air of 0.1 MPa-0.5 MPa into the device and stirring until a melting temperature of 280° C.-350° C. is reached; continuing for 2-8 hours until the base material has a softening point of 200° C.-260° C.; after cooling down, pulverizing the base material to obtain asphalt powder. Obtaining 34%-79% by mass of carbon powder, 1%-10% by mass of binder, and 20%-65% by mass of the asphalt powder and then forming spherical particles with a diameter of 0.5 mm-5 mm with the carbon powder, the binder and the asphalt powder at room temperature. Introducing the spherical particles of asphalt directly into an asphalt carbonization furnace for carbonization at a temperature of 600° C.-900° C. under protection of an inert gas to obtain asphalt spherical carbon. Asphalt spherical carbon is subject to activation treatment to obtain asphalt spherical activated carbon. The preparation method of the present invention reduces processing difficulty and production costs significantly.
摘要翻译：本发明是一种沥青基球形活性炭的制备方法，不需要进行渗透处理。将煤焦油沥青放入熔化装置; 将0.1MPa-0.5MPa的压缩空气引入装置中并搅拌直到达到280℃-350℃的熔融温度; 继续2-8小时，直到基材的软化点为200℃-260℃。冷却后，粉碎基材，得到沥青粉。得到34％〜79质量％的碳粉，1质量％-10质量％的粘合剂和20％-65质量％的沥青粉，然后形成直径为0.5毫米-5毫米的球形颗粒，碳粉，粘合剂和沥青粉末在室温下。将沥青的球形颗粒直接引入沥青碳化炉中，在600℃-900℃的温度下进行碳化，保护惰性气体得到沥青球形碳。沥青球形碳经活化处理得到沥青球形活性炭。本发明的制备方法显着降低了加工难度和生产成本。

4. 发明申请

US20130090508A1 Method for Preparing 1-Octene by Oligomerization of Ethylene 审中-公开
标题翻译：乙烯低聚制备1-辛烯的方法
公开(公告)号：US20130090508A1
公开(公告)日：2013-04-11
申请号：US13704961
申请日：2011-06-03
申请人： Gang Wang , Baojun Zhang , Jianzhong Li , Sihan Wang , Jiabo Qu , Defu He , Guizhi Wang , Qian Chen , Buwei Yu , Deshun Zhang , Libo Wang , Yali Wang , Liwei Liang , Yuxin Gao , Jie Li , Wenchao Zhang , Hua Li , Xiaoyu Gao , Shouhui Zha , Fuling Huang , Jing Wei , Xiuhui Wang , Xiangmin Yu , Jingying Zhao , Xuemei Han , Chunfeng Song , Junfeng Wei , Rui Meng
发明人： Gang Wang , Baojun Zhang , Jianzhong Li , Sihan Wang , Jiabo Qu , Defu He , Guizhi Wang , Qian Chen , Buwei Yu , Deshun Zhang , Libo Wang , Yali Wang , Liwei Liang , Yuxin Gao , Jie Li , Wenchao Zhang , Hua Li , Xiaoyu Gao , Shouhui Zha , Fuling Huang , Jing Wei , Xiuhui Wang , Xiangmin Yu , Jingying Zhao , Xuemei Han , Chunfeng Song , Junfeng Wei , Rui Meng
IPC分类号： C07C2/30
CPC分类号： C07C2/30 , B01J31/0231 , B01J31/143 , B01J31/2409 , B01J2231/20 , B01J2531/62 , C07C2/32 , C07C2531/02 , C07C2531/14 , C07C2531/22 , C07C11/02
摘要： Disclosed is a method for preparing 1-octene in the presence of a catalyst system for ethylene oligomerization, which includes: premixing a part of ethylene gas as raw material with a solvent, mixing with the components a+b, c and d of the catalyst system, and then sending in a reactor; directly sending the rest of ethylene gas in the reactor; discharging the resultant liquid from the upper part of the reactor into an overflow channel; adding a catalysis stopping agent to the overflow channel; and then separating the resultant liquid. The advantages of the method are high selectivity of 1-octene and high catalytic activity.
摘要翻译：公开了一种在乙烯低聚催化剂体系存在下制备1-辛烯的方法，其包括：将一部分乙烯气作为原料预先混合溶剂，与催化剂的组分a + b，c和d混合系统，然后在反应堆中发送; 直接将其余的乙烯气体送回反应堆; 将得到的液体从反应器的上部排出到溢流通道中; 向溢流通道加入催化剂; 然后分离所得液体。该方法的优点是1-辛烯的高选择性和高催化活性。

5. 发明申请

US20130241094A1 PREPARATION METHOD FOR ASPHALT-BASED SPHERICAL ACTIVATED CARBON WHICH REQUIRES NO INFUSIBILIZATION PROCESS 有权
标题翻译：不需要渗透过程的沥青基球形活性炭的制备方法
公开(公告)号：US20130241094A1
公开(公告)日：2013-09-19
申请号：US13695052
申请日：2012-02-20
申请人： Xiangmin Yu , Yizhou Kong
发明人： Xiangmin Yu , Yizhou Kong
IPC分类号： C01B31/08
CPC分类号： C01B31/089 , B01J20/20 , B01J20/28019 , B01J20/3007 , B01J20/3078 , C01B32/336 , C01B32/382
摘要： The present invention is a preparation method for asphalt-based spherical activated carbon which requires no infusibilization process. Placing coal tar asphalt into a melting device; introducing compressed air of 0.1 MPa-0.5 MPa into the device and stirring until a melting temperature of 280° C.-350° C. is reached; continuing for 2-8 hours until the base material has a softening point of 200° C.-260° C.; after cooling down, pulverizing the base material to obtain asphalt powder. Obtaining 34%-79% by mass of carbon powder, 1%-10% by mass of binder, and 20%-65% by mass of the asphalt powder and then forming spherical particles with a diameter of 0.5 mm-5 mm with the carbon powder, the binder and the asphalt powder at room temperature. Introducing the spherical particles of asphalt directly into an asphalt carbonization furnace for carbonization at a temperature of 600° C.-900° C. under protection of an inert gas to obtain asphalt spherical carbon. Asphalt spherical carbon is subject to activation treatment to obtain asphalt spherical activated carbon. The preparation method of the present invention reduces processing difficulty and production costs significantly.
摘要翻译：本发明是一种沥青基球形活性炭的制备方法，不需要进行渗透处理。将煤焦油沥青放入熔化装置; 将0.1MPa-0.5MPa的压缩空气引入装置中并搅拌直到达到280℃-350℃的熔融温度; 继续2-8小时，直到基材的软化点为200℃-260℃。冷却后，粉碎基材，得到沥青粉。得到34％〜79质量％的碳粉，1质量％-10质量％的粘合剂和20％-65质量％的沥青粉，然后形成直径为0.5毫米-5毫米的球形颗粒，碳粉，粘合剂和沥青粉末在室温下。将沥青的球形颗粒直接引入沥青碳化炉中，在600℃-900℃的温度下进行碳化，保护惰性气体得到沥青球形碳。沥青球形碳经活化处理得到沥青球形活性炭。本发明的制备方法显着降低了加工难度和生产成本。

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