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1. 发明授权

US06489371B2 Fischer-Tropsch processes and catalysts with promoters 失效
标题翻译：费 - 托法和助催化剂
公开(公告)号：US06489371B2
公开(公告)日：2002-12-03
申请号：US09939312
申请日：2001-08-24
申请人： Wenchun Chao , Kamel M. Makar , Leo E. Manzer , Munirpallam A. Subramanian
发明人： Wenchun Chao , Kamel M. Makar , Leo E. Manzer , Munirpallam A. Subramanian
IPC分类号： C07C2700
CPC分类号： C10G2/331 , B01J23/8896 , B01J27/12 , B01J27/125 , B01J27/128 , B01J37/0201 , C07C1/0435 , C07C1/044 , C07C1/0445 , C07C2521/02 , C07C2521/04 , C07C2523/34 , C07C2523/36 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/889 , C07C2527/12 , C07C2527/125 , C07C2527/14 , C10G2/332
摘要： A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process preferably includes at least cobalt, rhenium, and a promoter selected from the group including boron, phosphorus, potassium, manganese, and vanadium. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.
摘要翻译：公开了一种用于生产烃的方法。该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。根据本发明，该方法中使用的催化剂优选至少包含钴，铼和选自硼，磷，钾，锰和钒的助催化剂。催化剂还可以包含选自包括二氧化硅，二氧化钛，二氧化钛/氧化铝，氧化锆，氧化铝，氟化铝和氟化氧化铝的载体材料。

2. 发明授权

US06333294B1 Fischer-tropsch processes and catalysts with promoters 失效
标题翻译：费 - 托法和助催化剂
公开(公告)号：US06333294B1
公开(公告)日：2001-12-25
申请号：US09314811
申请日：1999-05-19
申请人： Wenchun Chao , Kamel M. Makar , Leo E. Manzer , Munirpallam A. Subramanian
发明人： Wenchun Chao , Kamel M. Makar , Leo E. Manzer , Munirpallam A. Subramanian
IPC分类号： B01J2300
CPC分类号： C10G2/331 , B01J23/8896 , B01J27/12 , B01J27/125 , B01J27/128 , B01J37/0201 , C07C1/0435 , C07C1/044 , C07C1/0445 , C07C2521/02 , C07C2521/04 , C07C2523/34 , C07C2523/36 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/889 , C07C2527/12 , C07C2527/125 , C07C2527/14 , C10G2/332
摘要： A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least cobalt, rhenium, and a promoter selected from the group including boron, phosphorus, potassium, manganese, and vanadium. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.
摘要翻译：公开了一种用于生产烃的方法。该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。根据本发明，用于该方法的催化剂至少包括钴，铼和选自硼，磷，钾，锰和钒的助催化剂。催化剂还可以包含选自包括二氧化硅，二氧化钛，二氧化钛/氧化铝，氧化锆，氧化铝，氟化铝和氟化氧化铝的载体材料。

3. 发明授权

US06727289B2 Boron promoted catalysts and fischer-tropsch processes 失效
标题翻译：硼促进了催化剂和费 - 托法
公开(公告)号：US06727289B2
公开(公告)日：2004-04-27
申请号：US10047231
申请日：2002-01-14
申请人： Olga Ionkina , Wenchun Chao , Munirpallam A. Subramanian , Leo E. Manzer , Kamel M. Makar , Ajoy P. Raje
发明人： Olga Ionkina , Wenchun Chao , Munirpallam A. Subramanian , Leo E. Manzer , Kamel M. Makar , Ajoy P. Raje
IPC分类号： C07C2700
CPC分类号： C10G2/332 , B01J21/02 , B01J23/74 , B01J23/75 , B01J23/89 , B01J23/8913 , C10G2/333
摘要： A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process includes at least a Fischer-Tropsch metal and boron. The Fischer-Tropsch metal preferably includes cobalt and optionally ruthenium or platinum. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.
摘要翻译：公开了一种用于生产烃的方法。该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。根据本发明，用于该方法的催化剂至少包括费 - 托金属和硼。费 - 托金属优选包括钴和任选的钌或铂。催化剂还可以包含选自包括二氧化硅，二氧化钛，二氧化钛/氧化铝，氧化锆，氧化铝，氟化铝和氟化氧化铝的载体材料。

4. 发明授权

US06759439B2 Fischer-tropsch processes and catalysts with promoters 失效
标题翻译：费 - 托法和助催化剂
公开(公告)号：US06759439B2
公开(公告)日：2004-07-06
申请号：US10308494
申请日：2002-12-03
申请人： Wenchun Chao , Kamel M. Makar , Leo E. Manzer , Munirpallam A. Subramanian
发明人： Wenchun Chao , Kamel M. Makar , Leo E. Manzer , Munirpallam A. Subramanian
IPC分类号： C07C2700
CPC分类号： C10G2/331 , B01J23/8896 , B01J27/12 , B01J27/125 , B01J27/128 , B01J37/0201 , C07C1/0435 , C07C1/044 , C07C1/0445 , C07C2521/02 , C07C2521/04 , C07C2523/34 , C07C2523/36 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/889 , C07C2527/12 , C07C2527/125 , C07C2527/14 , C10G2/332
摘要： A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention, the catalyst used in the process preferably includes at least cobalt, rhenium, and a promoter selected from the group including boron, phosphorus, potassium, manganese, and vanadium. The catalyst may also comprise a support material selected from the group including silica, titania, titania/alumina, zirconia, alumina, aluminum fluoride, and fluorided aluminas.
摘要翻译：公开了一种用于生产烃的方法。该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。根据本发明，该方法中使用的催化剂优选至少包含钴，铼和选自硼，磷，钾，锰和钒的助催化剂。催化剂还可以包含选自包括二氧化硅，二氧化钛，二氧化钛/氧化铝，氧化锆，氧化铝，氟化铝和氟化氧化铝的载体材料。

5. 发明授权

US06365544B2 Fischer-Tropsch processes and catalysts using fluorided alumina supports 失效
标题翻译：使用氟化氧化铝载体的费 - 托工艺和催化剂
公开(公告)号：US06365544B2
公开(公告)日：2002-04-02
申请号：US09314920
申请日：1999-05-19
申请人： Norman Herron , Leo E. Manzer , Munirpallam A. Subramanian
发明人： Norman Herron , Leo E. Manzer , Munirpallam A. Subramanian
IPC分类号： B01J2340
CPC分类号： C10G2/331 , B01J23/8896 , B01J27/12 , B01J27/125 , B01J27/128 , B01J37/0201 , C07C1/0435 , C07C1/044 , C07C1/0445 , C07C2521/02 , C07C2521/04 , C07C2523/34 , C07C2523/36 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/889 , C07C2527/12 , C07C2527/125 , C07C2527/14 , C10G2/332
摘要： A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention the catalyst used in the process includes at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium); and a support selected from the group consisting of an aluminum fluoride and fluorided aluminas.
摘要翻译：公开了一种用于生产烃的方法。该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。根据本发明，用于该方法的催化剂包括至少一种用于费 - 托反应的催化金属（例如铁，钴，镍和/或钌）; 和选自氟化铝和氟化氧化铝的载体。

6. 发明授权

US06368997B2 Fischer-Tropsch processes and catalysts using fluorided supports 失效
标题翻译：使用氟化载体的费 - 托工艺和催化剂
公开(公告)号：US06368997B2
公开(公告)日：2002-04-09
申请号：US09314921
申请日：1999-05-19
申请人： Norman Herron , Leo E. Manzer , Munirpallam A. Subramanian
发明人： Norman Herron , Leo E. Manzer , Munirpallam A. Subramanian
IPC分类号： C07C2700
CPC分类号： C10G2/331 , B01J23/8896 , B01J27/12 , B01J27/125 , B01J27/128 , B01J37/0201 , C07C1/0435 , C07C1/044 , C07C1/0445 , C07C2521/02 , C07C2521/04 , C07C2523/34 , C07C2523/36 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/889 , C07C2527/12 , C07C2527/125 , C07C2527/14 , C10G2/332
摘要： A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention the catalyst used in the process includes at least one catalytic metal selected for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium); and a support selected from the group consisting of fluorides and fluorided oxides of at least one element selected from the elements of Groups 2 through 15 of the periodic table of elements and elements with atomic numbers 58 through 71 (e.g., zinc, magnesium, calcium, barium, chromium, yttrium, lanthanum, samarium, europium and/or dysprosium).
摘要翻译：公开了一种用于生产烃的方法。该方法包括将包含氢气和一氧化碳的进料流与催化剂接触，所述反应区域保持在有效产生包含烃的流出物流的转化促进条件下。根据本发明，用于该方法的催化剂包括至少一种选择用于费 - 托反应的催化金属（例如铁，钴，镍和/或钌）; 选自氟化物和选自元素周期表第2〜15族元素中的至少一种元素的氟化物的载体，原子序数为58〜71的元素（例如锌，镁，钙，钡，铬，钇，镧，钐，铕和/或镝）。

7. 发明授权

US08282728B2 Materials with trigonal bipyramidal coordination and methods of making the same 有权
标题翻译：具有三角双锥体协调的材料和制造相同的方法
公开(公告)号：US08282728B2
公开(公告)日：2012-10-09
申请号：US12802700
申请日：2010-06-10
申请人： Munirpallam A. Subramanian , Arthur W. Sleight , Andrew E. Smith
发明人： Munirpallam A. Subramanian , Arthur W. Sleight , Andrew E. Smith
IPC分类号： C04B14/00
CPC分类号： C04B35/01 , C01G1/02 , C01G9/006 , C01G15/006 , C01G45/006 , C01G49/009 , C01P2002/52 , C01P2002/72 , C01P2002/77 , C01P2002/82 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C04B35/016 , C04B35/2675 , C04B35/44 , C04B35/45 , C04B35/462 , C04B35/6262 , C04B35/62675 , C04B2235/3206 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3232 , C04B2235/3265 , C04B2235/3272 , C04B2235/3281 , C04B2235/3284 , C04B2235/3286 , C04B2235/443 , C04B2235/5436 , C04B2235/5481 , C04B2235/761 , C04B2235/767 , C04B2235/768 , C09C1/00 , C09D11/037 , C09D11/322
摘要： Embodiments of compositions comprising materials satisfying the general formula AM1−xM′xM″yO3+y are disclosed, along with methods of making the materials and compositions. In some embodiments, M and M′ are +3 cations, at least a portion of the M cations and the M′ cations are bound to oxygen in trigonal bipyramidal coordination, and the material is chromophoric. In some embodiments, the material forms a crystal structure having a hexagonal unit cell wherein edge a has a length of 3.50-3.70 Å and edge c has a length of 10-13 Å. In other embodiments, edge a has a length of 5.5-7.0 Å. In particular embodiments, M′ is Mn, and Mn is bonded to oxygen with an apical Mn—O bond length of 1.80 Å to 1.95 Å. In some embodiments, the material is YIn1−xMnxO3, x is greater than 0.0 and less than 0.75, and the material exhibits a surprisingly intense blue color.
摘要翻译：公开了包含满足通式AM1-xM'xM“yO3 + y的材料的组合物的实施方案以及制备材料和组合物的方法。在一些实施方案中，M和M'是+ 3阳离子，M阳离子和M'阳离子的至少一部分在三角双锥体配位中与氧结合，并且该材料是发色体的。在一些实施方案中，材料形成具有六边形单元电池的晶体结构，其中边缘a具有3.50-3.70埃的长度，边缘c具有10-13的长度。在其他实施例中，边缘a具有5.5-7.0的长度。在具体实施方案中，M'是Mn，Mn键合到氧，其顶点Mn-O键长度为1.80至1.95。在一些实施方案中，材料是YIn1-xMnxO3，x大于0.0且小于0.75，并且材料表现出惊人的强烈的蓝色。

8. 发明授权

US6127585A Catalysts for halogenated hydrocarbon processing, their precursors and their preparation and use 失效
标题翻译：用于卤代烃加工的催化剂，其前体及其制备和用途
公开(公告)号：US6127585A
公开(公告)日：2000-10-03
申请号：US77267
申请日：1998-05-27
申请人： Timothy C. Duzick , Velliyur Nott Mallikarjuna Rao , Munirpallam A. Subramanian
发明人： Timothy C. Duzick , Velliyur Nott Mallikarjuna Rao , Munirpallam A. Subramanian
IPC分类号： B01J27/13 , C07B61/00 , C07C17/00 , C07C17/20 , C07C17/23 , C07C17/269 , C07C21/18 , C07C19/08 , B01T27/132 , B01T27/138
CPC分类号： C07C17/269 , B01J27/13 , C07C17/00 , C07C17/206 , C07C17/23
摘要： Processes are disclosed for decreasing the chlorine to carbon ratio for halogenated hydrocarbons containing chlorine and from 1 to 6 carbon atoms, in the presence of a multiphase catalyst. The processes each involve (1) preparing a single phase solid catalyst precursor which has a structure that collapses at a temperature of about 400.degree. C. or less and has the formula (NH.sub.3).sub.6 Ru.sub.l-r-s Co.sub.r Cr.sub.s MF.sub.6, where r+s is in the range of 0.00 to 0.99, and M is at least one trivalent metal selected from the group consisting of Al, Cr, Fe, V, Sc and Ga; and (2) producing the multiphase catalyst by heating the single phase solid catalyst precursor to about 400.degree. C. or less in an non-oxidizing atomsphere to produce a multiphase composition wherein a phase containing ruthenium is homogeneously dispersed with a phase containing metal fluoride.Also disclosed are single phase fluoride compositions having the formula (NH.sub.3).sub.6 Ru.sub.l-r-s Co.sub.r Cr.sub.s MF.sub.6, where r+s is in the range of 0.00 to 0.99, and M is at least one trivalent element selected from the group consisting of Al, Cr, Fe, V, Sc and Ga; and multiphase catalyst compositions consisting essentially of metallic ruthenium and fluorides of at least one element selected from the group consisting of Al, Co, Cr, Fe, V, Sc and Ga, wherein the ruthenium is homogeneously dispersed with phases of the fluorides.
摘要翻译： PCT No.PCT / US96 / 18967 Sec。 371日期：1998年5月27日 102（e）日期1998年5月27日PCT 1996年11月26日PCT公布。 WO97 / 19751 PCT出版物日期：1997年6月5日公开了在多相催化剂存在下降低含氯和1至6个碳原子的卤代烃的氯与碳比的方法。这些方法各自涉及（1）制备单相固体催化剂前体，其具有在约400℃或更低的温度下塌陷并具有式（NH 3）6 Rul-r-sCorCrsMF 6的结构，其中r + s为范围为0.00〜0.99，M为选自Al，Cr，Fe，V，Sc和Ga中的至少一种三价金属; 和（2）通过在非氧化性原子团中将单相固体催化剂前体加热至约400℃或更低来制备多相催化剂以产生多相组合物，其中含相的钌相与含有金属氟化物的相均匀分散。还公开了具有式（NH 3）6 Rul-r-sCorCrsMF 6的单相氟化物组合物，其中r + s在0.00至0.99的范围内，M是至少一种选自Al，Cr， Fe，V，Sc和Ga; 以及基本上由金属钌和氟化物组成的多相催化剂组合物，其选自Al，Co，Cr，Fe，V，Sc和Ga中的至少一种元素，其中钌与氟化物的相分散均匀。

9. 发明授权

US6096932A Fluorocarbon manufacturing process 失效
标题翻译：氟碳制造工艺
公开(公告)号：US6096932A
公开(公告)日：2000-08-01
申请号：US360959
申请日：1999-07-27
申请人： Munirpallam A. Subramanian
发明人： Munirpallam A. Subramanian
IPC分类号： C07B39/00 , C07C17/10 , C07C21/18
CPC分类号： C07B39/00 , C07C17/10
摘要： A process is disclosed for increasing the fluorine content of an olefinic compound of the formula C.sub.n H.sub.m F.sub.2n-m, where n is an integer from 2 to 6 and m is an integer from 1 to 2n. The process involves (a) contacting the olefinic compound with a metal fluoride composition of the formula (AgF)(MF.sub.2).sub.x where M is selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof and x is a number from 0 to 1, at a temperature above 200.degree. C. sufficient to transfer F from the metal fluoride composition to the olefinic compound, thereby producing a chemically reduced metal fluoride composition comprising metallic silver; (b) oxidizing the reduced metal fluoride composition from (a) in the presence of HF to regenerate the metal fluoride composition of the formula (AgF)(MF.sub.2).sub.x ; and (c) recycling regenerated metal fluoride composition of (b) to (a). Also disclosed are a novel composition of the formula Ag.sub.10 F.sub.8 C.sub.2 ; and a process for producing hexafluoroethane which involves heating Ag.sub.10 F.sub.8 C.sub.2 to a temperature sufficient for its decomposition.
摘要翻译：公开了用于提高式CnHmF 2 n-m的烯属化合物的氟含量的方法，其中n为2-6的整数，m为1至2n的整数。该方法包括（a）使烯烃化合物与式（AgF）（MF 2）x的金属氟化物组合物接触，其中M选自Mn，Fe，Co，Ni，Cu，Zn及其混合物，x 是从0到1的数，在高于200℃的温度下，足以将F从金属氟化物组合物转移到烯烃化合物，由此制备包含金属银的化学还原的金属氟化物组合物; （b）在HF存在下使（a）的还原金属氟化物组合物氧化以再生式（AgF）（MF 2）x的金属氟化物组合物; （c）回收（b）〜（a）的再生金属氟化物组合物。还公开了式Ag10F8C2的新型组合物; 以及涉及将Ag10F8C2加热到足以使其分解的温度的六氟乙烷的制造方法。

10. 发明授权

US5126316A Bi.sub.2 Sr.sub.3-x Y.sub.x Cu.sub.2 O.sub.8+y superconducting metal oxide compositions 失效
标题翻译： BI2SR3-XYXCU2O8 + Y超级金属氧化物组合物
公开(公告)号：US5126316A
公开(公告)日：1992-06-30
申请号：US236081
申请日：1988-08-24
申请人： Arthur W. Sleight , Munirpallam A. Subramanian
发明人： Arthur W. Sleight , Munirpallam A. Subramanian
IPC分类号： C01G1/00 , C01G29/00 , C04B35/45 , H01L39/02 , H01L39/12
CPC分类号： C04B35/4504 , C01G29/006 , C04B35/4521 , H01L39/126 , C01P2002/54 , C01P2002/77 , C01P2006/32 , C01P2006/40 , Y10S505/779 , Y10S505/782
摘要： Compositions having the nominal formula Bi.sub.2 Sr.sub.3-x Y.sub.x Cu.sub.2 O.sub.8+y wherein x is from about 0.05 to about 0.45 and y is from about 0 to about 1 are superconducting.
摘要翻译：具有标称式Bi2Sr3-xYxCu2O8 + y的组合物，其中x为约0.05至约0.45，y为约0至约1为超导体。

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