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    • 2. 发明授权
    • Compositions based on derivatives of silica modified by organic groups,
preparation and application thereof, particularly as cationic conductors
    • 基于有机基团改性的二氧化硅衍生物的组合物,其制备和应用,特别是作为阳离子导体
    • US4923950A
    • 1990-05-08
    • US167474
    • 1988-04-28
    • Lucienne RavaineMichel B. ArmandYves CharbouillotAbdelkader Hammou
    • Lucienne RavaineMichel B. ArmandYves CharbouillotAbdelkader Hammou
    • C01B33/155C03C3/00C08G77/02C08G77/22C08G77/26C08G77/28H01B1/04H01B1/12H01M6/18
    • H01M6/181C03C3/00C08G77/22H01B1/122
    • Composition based on derivatives of silica modified by organic groups, characterized in that said derivatives are amorphous solids having formula (I) SiO.sub.2-0.5(x+y) (Z.sup.1.sub.x (Z.sup.2).sub.y .multidot.(XA).sub.z, wherein Z.sup.1 is a group having formula (II), R.sup.1 being an alkylene having from 3 to 8 carbon atoms optionally interrupted by a heteroatomic group --NH--, R.sup.3 and R.sup.4 representing each --H or representing together a group --CH.dbd.CH--N.dbd.CH--, Z.sup.2 is a group --R.sup.2 --SO.sub.3 H, R.sup.2 being an alkylene having from 3 to 8 carbon atoms optionally interrupted by a heteroatomic group --NH--; XZ is an acid (case where X.dbd.H) or a salt (case where X.dbd.metal) soluble in water x is a number different from 0 and lower or equal to 1; z is a number which may vary from 0 to 0.5 and not higher than x; x and y being such that the sum (x+y) is higher or equal to 1/3; it being understood that the sum (x+y) is at the most equal to 1; and z is a number which is optionally nil and such that the ratio (z+y)/x is higher than 0 and lower than or equal to 1; its preparation and its application as an agent for the transmission of electromagnetic waves and/or electric currents.
    • PCT No.PCT / FR87 / 00261 Sec。 一九八六年四月二十八日 102(e)日期1988年4月28日PCT申请日1987年7月2日PCT公布。 出版物WO89 / 日期:1988年1月14日。基于有机基团改性的二氧化硅衍生物的组成,其特征在于所述衍生物为具有式(I)SiO 2 -0.5(x + y)(Z1x(Z2)yx(XA)z) 其中Z 1是具有式(II)的基团,R 1是具有3至8个碳原子的亚烷基,其任选地被杂原子基团-NH-,R3和R4代表每个-H或代表基团-CH = CH-N = CH-,Z2是基团-R2-SO3H,R2是具有3至8个碳原子的亚烷基,任选地被杂原子基团-NH-封闭; XZ是酸(X = H的情况)或盐(情况 其中X =金属)可溶于水x是不同于0且低于或等于1的数; z是可以在0至0.5之间并且不高于x的数; x和y使得(x + y)高于或等于1/3;应当理解,总和(x + y)最大等于1; z是任选地为零的数,并且使得比率(z + y)/ x高于0且低于或等于 至1; 其制备及其作为用于传输电磁波和/或电流的试剂的应用。
    • 7. 发明授权
    • Method of synthesis of sulphonylimides
    • 磺酰亚胺的合成方法
    • US5256821A
    • 1993-10-26
    • US587
    • 1993-01-05
    • Michel B. Armand
    • Michel B. Armand
    • C07C303/38C07C311/48
    • C07C303/38
    • Method for the synthesis of sulfonylimidides having the formula M((RSO.sub.2).sub.2 N).sub.y, wherein M is a metal or an ammonium radical quaternary or not, the Rs, which may be identical or similar are organic monovalent radicals, particularly hydrocarbyles and preferably perfluorohydrocarbyles, in C.sub.1 to C.sub.12, and y is the valence of M. On the one hand, silazane component selected amongst the silazane compounds M(((R.sub.2).sub.3 Si).sub.2 N).sub.y or the associations of a silazane derivative A((R.sub.2).sub.3 Si).sub.2 N or a fluoride M.sub.1 F.sub.z of low cross-linking energy is reacted with, on the other hand, at least one sulfonic halogenite component consisting of a sulfonyl fluoride RSO.sub.2 F or in the association of a sulfonyl chloride RSO.sub.2 Cl with a fluoride M.sub.1 F.sub.z, M, R and y having the above-mentioned significations, M being selected amongst the Ms and being optionally identical to M, z being the valence of M.sub.1 and R.sub.2 representing an alkyl in C.sub.1 to C.sub.4. The imidides obtained for which the R.sub.2 are perfluorated radicals and M is an alkaline metal such as Li are usable in association with polyethers for the production of materials of the ionic conduction type for all solid generators in thin films.
    • 合成具有式M((RSO 2)2 N)y的磺酰亚胺的方法,其中M是金属或铵基季铵化合物,可以相同或相似的R 5是有机单价基团,特别是烃基,优选全氟烃基 ,在C1至C12中,y为M的化合价。一方面,硅氮烷组分选自硅氮烷化合物M((((R2)3Si)2N)y或硅氮烷衍生物A((R2)3Si )2N或低交联能的氟化物M1Fz与另一方面与至少一种由磺酰氟RSO2F组成的磺酸卤化物组分或与磺酰氯RSO2Cl与氟化物M1Fz,M,R 和y具有上述含义,M选自Ms,并且任选地与M相同,z是M1和R2中的C 1至C 4的烷基的化合价。 获得的R2是全氟化自由基并且M是碱金属如Li的酰亚胺可用于制备薄膜中所有固体发生剂的离子传导型材料的聚醚。
    • 8. 发明授权
    • Metal-sulfur type cell having improved positive electrode
    • 具有改善的正极的金属硫型电池
    • US4833048A
    • 1989-05-23
    • US175782
    • 1988-03-31
    • Lutgard C. DejongheSteven J. ViscoCatherine C. MailheMichel B. Armand
    • Lutgard C. DejongheSteven J. ViscoCatherine C. MailheMichel B. Armand
    • H01M4/60H01M10/39
    • H01M4/60H01M10/39
    • An novel metal-sulfur type cell operable at a temperature of 200.degree. C. or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S).sub.y).sub.n wherein y=1 to 6; n=2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprisises one of more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associtated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.
    • 公开了一种能够以200Wrs / Kg或更好的能量密度在200℃或更低的温度下操作的新型金属硫型电池,其特征在于由具有以下通式的有机 - 硫化合物形成的有机硫阴极: (R(S)y)n,其中y = 1至6; n = 2〜20; 并且R是一个或多个具有1至20个碳原子的不同的脂族或芳族有机部分,当R包括一个或多个芳环或一个或多个氧,硫,氮时,可包括一个或多个氧,硫或氮杂原子 或当R包含脂族链时与该链相互结合的氟原子,其中脂族基可以是直链或支链,饱和或不饱和的,并且其中脂族链或芳环可以在其上具有取代基。