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1. 发明授权

US07648566B2 Methods and apparatus for carbon dioxide removal from a fluid stream 失效
标题翻译：从流体流中去除二氧化碳的方法和装置
公开(公告)号：US07648566B2
公开(公告)日：2010-01-19
申请号：US11558063
申请日：2006-11-09
申请人： Wei Wei , James Anthony Ruud , Anthony Yu-Chung Ku , Vidya Ramaswamy , Ke Liu
发明人： Wei Wei , James Anthony Ruud , Anthony Yu-Chung Ku , Vidya Ramaswamy , Ke Liu
IPC分类号： B01D53/22 , B01D53/62 , B01J19/24 , C01B3/50
CPC分类号： C01B3/16 , B01J19/2475 , B01J19/2485 , B01J2219/00108 , B01J2219/00123 , B01J2219/1946 , C01B3/501 , C01B2203/0283 , C01B2203/0405 , C01B2203/0475 , C01B2203/0485 , C01B2203/1064 , C01B2203/84 , C01B2203/86 , Y02C10/04 , Y02C10/10 , Y02P30/30 , Y10S48/05
摘要： An apparatus for producing hydrogen gas wherein the apparatus includes a reactor. In one embodiment, the reactor includes at least two conversion-removal portions. Each conversion-removal portion comprises a catalyst section configured to convert CO in the stream to CO2 and a membrane section located downstream of and in flow communication with the catalyst section. The membrane section is configured to selectively remove the CO2 from the stream and to be in flow communication with a sweep gas.
摘要翻译：一种生产氢气的装置，其中装置包括一个反应器。在一个实施方案中，反应器包括至少两个转化除去部分。每个转化除去部分包括催化剂部分，其构造成将物流中的CO转化为CO 2和位于催化剂部分下游并与催化剂部分流动连通的膜部分。膜部分被配置为选择性地从流中去除CO 2并与吹扫气体流动连通。

2. 发明申请

US20080112867A1 Methods and Apparatus for Carbon Dioxide Removal from a Fluid Stream 失效
标题翻译：从流体流中去除二氧化碳的方法和设备
公开(公告)号：US20080112867A1
公开(公告)日：2008-05-15
申请号：US11558063
申请日：2006-11-09
申请人： Wei Wei , James Anthony Ruud , Anthony Yu-Chung Ku , Vidya Ramaswamy , Ke Liu
发明人： Wei Wei , James Anthony Ruud , Anthony Yu-Chung Ku , Vidya Ramaswamy , Ke Liu
IPC分类号： B01D53/62
CPC分类号： C01B3/16 , B01J19/2475 , B01J19/2485 , B01J2219/00108 , B01J2219/00123 , B01J2219/1946 , C01B3/501 , C01B2203/0283 , C01B2203/0405 , C01B2203/0475 , C01B2203/0485 , C01B2203/1064 , C01B2203/84 , C01B2203/86 , Y02C10/04 , Y02C10/10 , Y02P30/30 , Y10S48/05
摘要： An apparatus for producing hydrogen gas wherein the apparatus includes a reactor. In one embodiment, the reactor includes at least two conversion-removal portions. Each conversion-removal portion comprises a catalyst section configured to convert CO in the stream to CO2 and a membrane section located downstream of and in flow communication with the catalyst section. The membrane section is configured to selectively remove the CO2 from the stream and to be in flow communication with a sweep gas.
摘要翻译：一种生产氢气的装置，其中装置包括一个反应器。在一个实施方案中，反应器包括至少两个转化除去部分。每个转化除去部分包括催化剂部分，其构造成将物流中的CO转化为CO 2，以及位于催化剂部分下游并与催化剂部分流动连通的膜部分。膜部分构造成从流中选择性地去除CO 2并与吹扫气体流动连通。

3. 发明授权

US08043418B2 Gas separator apparatus 有权
标题翻译：气体分离装置
公开(公告)号：US08043418B2
公开(公告)日：2011-10-25
申请号：US11608292
申请日：2006-12-08
申请人： James Anthony Ruud , Michael John Bowman , Kalya Vijaya Sarathy , Mohan Manoharan , Anthony Yu-Chung Ku , Vidya Ramaswamy , Patrick Roland Lucien Malenfant
发明人： James Anthony Ruud , Michael John Bowman , Kalya Vijaya Sarathy , Mohan Manoharan , Anthony Yu-Chung Ku , Vidya Ramaswamy , Patrick Roland Lucien Malenfant
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D61/38 , B01D67/0088 , B01D67/0093 , B01D69/10 , B01D69/141 , B01D71/024 , B01D71/027 , B01D71/028 , B01D71/40 , B01D71/44 , B01D2257/504 , B01D2325/10 , B01D2325/22 , Y02C10/10
摘要： An apparatus for separating at least one component from a mixture of a plurality of chemical species is provided. The apparatus comprises a membrane structure comprising a plurality of pores disposed within a matrix material to allow mass transport from a first surface of the membrane structure to a second surface of the membrane structure. The matrix material has a thermal conductivity of at least about 10 W/m/K; and a functional material disposed within at least a portion of the plurality of pores. The functional material has the property of promoting selective transport of at least one species through the membrane structure from the first surface to the second surface.
摘要翻译：提供了一种用于从多种化学物质的混合物中分离至少一种组分的装置。该装置包括膜结构，其包括设置在基质材料内的多个孔，以允许质量从膜结构的第一表面传输到膜结构的第二表面。基质材料具有至少约10W / m / K的热导率; 以及设置在所述多个孔的至少一部分中的功能材料。功能材料具有促进至少一种物质通过膜结构从第一表面到第二表面的选择性输送的性质。

4. 发明申请

US20090218275A1 MEMBRANE STRUCTURE AND METHOD OF MAKING 失效
标题翻译：膜结构和制备方法
公开(公告)号：US20090218275A1
公开(公告)日：2009-09-03
申请号：US12464272
申请日：2009-05-12
申请人： Vidya Ramaswamy , James Anthony Ruud , Anthony Yu-Chung Ku , William Hullinger Huber
发明人： Vidya Ramaswamy , James Anthony Ruud , Anthony Yu-Chung Ku , William Hullinger Huber
IPC分类号： B01D63/00 , B32B3/26
CPC分类号： B01D67/0062 , B01D69/12 , B01D71/022 , B01J2219/00835 , B01J2219/00907 , Y10T428/249981
摘要： A membrane structure is provided. The membrane structure includes a polymer layer having a plurality of pores; and a ceramic layer disposed on the polymer layer. The ceramic layer has a plurality of substantially unconnected pores. Each of the substantially unconnected pores is in fluid communication with at least one of the pores of the polymer layer. A method of manufacturing a membrane structure is provided. The method includes the steps of providing a polymer layer having a plurality of pores; and disposing a ceramic layer on the polymer layer. Disposing a ceramic layer includes depositing a metal layer on the polymer layer; and anodizing the metal layer to convert the metal layer into a porous layer. At least one of the depositing step and the anodizing step is performed as a continuous process. Alternatively, at least one of the depositing and the anodizing step is performed as a batch process.
摘要翻译：提供膜结构。膜结构包括具有多个孔的聚合物层; 以及设置在聚合物层上的陶瓷层。陶瓷层具有多个基本上未连接的孔。每个基本上未连接的孔与聚合物层的至少一个孔流体连通。提供一种制造膜结构的方法。该方法包括提供具有多个孔的聚合物层的步骤; 并在聚合物层上设置陶瓷层。布置陶瓷层包括在聚合物层上沉积金属层; 并阳极氧化金属层以将金属层转化为多孔层。沉积步骤和阳极氧化步骤中的至少一个作为连续工艺进行。或者，沉积和阳极化步骤中的至少一个作为分批处理进行。

5. 发明授权

US07396382B2 Functionalized inorganic membranes for gas separation 有权
标题翻译：用于气体分离的官能化无机膜
公开(公告)号：US07396382B2
公开(公告)日：2008-07-08
申请号：US11263165
申请日：2005-10-31
申请人： Anthony Yu-Chung Ku , James Anthony Ruud , Jennifer Lynn Molaison , Louis Andrew Schick , Vidya Ramaswamy
发明人： Anthony Yu-Chung Ku , James Anthony Ruud , Jennifer Lynn Molaison , Louis Andrew Schick , Vidya Ramaswamy
IPC分类号： B01D71/02
CPC分类号： B01D71/024 , B01D53/228 , B01D69/12 , B01D2323/08 , Y02C10/10
摘要： A porous membrane for separation of carbon dioxide from a fluid stream at a temperature higher than about 200° C. with selectivity higher than Knudsen diffusion selectivity. The porous membrane comprises a porous support layer comprising alumina, silica, zirconia or stabilized zirconia; a porous separation layer comprising alumina, silica, zirconia or stabilized zirconia, and a functional layer comprising a ceramic oxide contactable with the fluid stream to preferentially transport carbon dioxide. In particular, the functional layer may be MgO, CaO, SrO, BaO, La2O3, CeO2, ATiO3, AZrO3, AAl2O4, A1FeO3, A1MnO3, A1CoO3, A1NiO3, A2HfO3, A3CeO3, Li2ZrO3, Li2SiO3, Li2TiO3 or a mixture thereof; wherein A is Mg, Ca, Sr or Ba; A1 is La, Ca, Sr or Ba; A2 is Ca, Sr or Ba; and A3 is Sr or Ba.
摘要翻译：一种用于在高于约200℃的温度下将二氧化碳与流体物流分离的多孔膜，选择性高于克努森扩散选择性。多孔膜包括多孔支撑层，包括氧化铝，二氧化硅，氧化锆或稳定的氧化锆; 包括氧化铝，二氧化硅，氧化锆或稳定的氧化锆的多孔分离层和包含可与流体流接触以优先输送二氧化碳的陶瓷氧化物的功能层。特别地，功能层可以是MgO，CaO，SrO，BaO，La 2 O 3，CeO 2，ATiO 3 AZrO 3，AA 1，2 O 4，A 1，Fe 3，3， A 1，...，N 2，A 1，...，...，...，...，... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... NiO 3，3O 3，3O 3，3％，3％，3％，3％，3％ SUB 2 2 ZrO 3 3，Li 2 SiO 3 3，Li 2 TiO 3 或其混合物; 其中A为Mg，Ca，Sr或Ba; A 1是La，Ca，Sr或Ba; A 是Ca，Sr或Ba; 和A 3是Sr或Ba。

6. 发明授权

US08056731B2 Membrane structure and method of making 失效
标题翻译：膜结构及制作方法
公开(公告)号：US08056731B2
公开(公告)日：2011-11-15
申请号：US12464272
申请日：2009-05-12
申请人： Vidya Ramaswamy , James Anthony Ruud , Anthony Yu-Chung Ku , William Hullinger Huber
发明人： Vidya Ramaswamy , James Anthony Ruud , Anthony Yu-Chung Ku , William Hullinger Huber
IPC分类号： B01D71/02 , B01D71/06 , B01D61/00
CPC分类号： B01D67/0062 , B01D69/12 , B01D71/022 , B01J2219/00835 , B01J2219/00907 , Y10T428/249981
摘要： A membrane structure is provided. The membrane structure includes a polymer layer having a plurality of pores; and a ceramic layer disposed on the polymer layer. The ceramic layer has a plurality of substantially unconnected pores. Each of the substantially unconnected pores is in fluid communication with at least one of the pores of the polymer layer. A method of manufacturing a membrane structure is provided. The method includes the steps of providing a polymer layer having a plurality of pores; and disposing a ceramic layer on the polymer layer. Disposing a ceramic layer includes depositing a metal layer on the polymer layer; and anodizing the metal layer to convert the metal layer into a porous layer. At least one of the depositing step and the anodizing step is performed as a continuous process. Alternatively, at least one of the depositing and the anodizing step is performed as a batch process.
摘要翻译：提供膜结构。膜结构包括具有多个孔的聚合物层; 以及设置在聚合物层上的陶瓷层。陶瓷层具有多个基本上未连接的孔。每个基本上未连接的孔与聚合物层的至少一个孔流体连通。提供一种制造膜结构的方法。该方法包括提供具有多个孔的聚合物层的步骤; 并在聚合物层上设置陶瓷层。布置陶瓷层包括在聚合物层上沉积金属层; 并阳极氧化金属层以将金属层转化为多孔层。沉积步骤和阳极氧化步骤中的至少一个作为连续工艺进行。或者，沉积和阳极化步骤中的至少一个作为分批处理进行。

7. 发明授权

US07919025B2 Membrane structure and method of making 有权
标题翻译：膜结构及制作方法
公开(公告)号：US07919025B2
公开(公告)日：2011-04-05
申请号：US12687911
申请日：2010-01-15
申请人： Vidya Ramaswamy , Seth Thomas Taylor , James Anthony Ruud , Melissa Suzanne Sander , Anthony Yu-Chung Ku , Mohan Manoharan
发明人： Vidya Ramaswamy , Seth Thomas Taylor , James Anthony Ruud , Melissa Suzanne Sander , Anthony Yu-Chung Ku , Mohan Manoharan
IPC分类号： B29C65/00 , C25D11/04 , B01D24/00 , B01D39/00
CPC分类号： B01D67/0065 , B01D67/0088 , B01D69/02 , B01D2315/12 , B01D2321/168 , B01D2323/28 , B01D2323/286 , B01D2325/02 , Y10T156/10 , Y10T428/249953
摘要： A membrane structure is provided. The membrane structure includes a first layer having a plurality of pores; and a second layer disposed on the first layer. The second layer has a plurality of unconnected pores. At least a portion of the plurality of unconnected pores of the second layer is at least partially filled with a filler such that the first layer is substantially free of the filler. At least a portion of the plurality of unconnected pores of the second layer is in fluid communication with at least one of the pores of the first layer. A method of making a membrane structure is provided. The method includes the steps of providing a first layer having a plurality of interconnected pores; disposing a second layer on the first layer, and filling at least a portion of the unconnected pores of the second layer with a filler such that the first layer is substantially free of the filler. Disposing a second layer includes depositing a metal layer on the first layer; and anodizing the metal layer to convert the metal layer into porous oxide layer.
摘要翻译：提供膜结构。膜结构包括具有多个孔的第一层; 以及设置在第一层上的第二层。第二层具有多个未连接的孔。第二层的多个未连接孔的至少一部分至少部分地填充有填料，使得第一层基本上不含填料。第二层的多个未连接孔的至少一部分与第一层的至少一个孔流体连通。提供了制造膜结构的方法。该方法包括提供具有多个互连孔的第一层的步骤; 在第一层上设置第二层，并用填料填充第二层的至少一部分未连接的孔，使得第一层基本上不含填料。布置第二层包括在第一层上沉积金属层; 并将金属层阳极氧化以将金属层转化为多孔氧化物层。

8. 发明授权

US07896949B2 Membranes for separation of carbon dioxide 有权
标题翻译：用于分离二氧化碳的膜
公开(公告)号：US07896949B2
公开(公告)日：2011-03-01
申请号：US12107148
申请日：2008-04-22
申请人： Anthony Yu-Chung Ku , James Anthony Ruud , Vidya Ramaswamy , Patrick Daniel Willson , Yan Gao
发明人： Anthony Yu-Chung Ku , James Anthony Ruud , Vidya Ramaswamy , Patrick Daniel Willson , Yan Gao
IPC分类号： B01D71/02 , B01D67/00
CPC分类号： B01D53/228 , B01D67/0048 , B01D69/02 , B01D69/10 , B01D71/024 , B01D71/025 , B01D2257/504 , B01D2323/24 , B01D2325/02 , B01D2325/20 , B01D2325/22 , Y02C10/10
摘要： Methods for separating carbon dioxide from a fluid stream at a temperature higher than about 200° C. with selectivity higher than Knudsen diffusion selectivity include contacting a porous membrane with the fluid stream to preferentially transport carbon dioxide. The porous membrane includes a porous support and a continuous porous separation layer disposed on a surface of the porous support and extending between the fluid stream and the porous support layer. The porous support comprises alumina, silica, zirconia, stabilized zirconia, stainless steel, titanium, nickel-based alloys, aluminum-based alloys, zirconium-based alloys or a combination thereof. Median pore size of the porous separation layer is less than about 10 nm, and the porous separation layer comprises titania, MgO, CaO, SrO, BaO, La2O3, CeO2, HfO2, Y2O3, VOz, NbOz, TaOz, ATiO3, AZrO3, AAl2O4, A1FeO3, A1MnO3, A1CoO3, A1NiO3, A2HfO3, A3 CeO3, Li2ZrO3, Li2SiO3, Li2TiO3, Li2HfO3, A4N1yOz, YxN1yOz, LaxN1yOz, HfN2yOz, or a combination thereof; wherein A is La, Mg, Ca, Sr or Ba; A1 is La, Ca, Sr or Ba; A2 is Ca, Sr or Ba; A3 is Sr or Ba; A4 is Mg, Ca, Sr, Ba, Ti or Zr; N1 is V, Nb, Ta, Cr, Mo, W, Mn, Si or Ge; N2 is V, Mo, W or Si; x is 1 or 2; y ranges from 1 to 3; and z ranges from 2 to 7.
摘要翻译：以高于Knudsen扩散选择性的选择性高于约200℃的温度从流体物流中分离二氧化碳的方法包括使多孔膜与流体流接触以优先输送二氧化碳。多孔膜包括多孔载体和设置在多孔载体的表面上并在流体流和多孔载体层之间延伸的连续多孔分离层。多孔载体包括氧化铝，二氧化硅，氧化锆，稳定的氧化锆，不锈钢，钛，镍基合金，铝基合金，锆基合金或其组合。多孔分离层的中孔尺寸小于约10nm，多孔分离层包含二氧化钛，MgO，CaO，SrO，BaO，La2O3，CeO2，HfO2，Y2O3，VOz，NbOz，TaOz，ATiO3，AZrO3，AAl2O4 ，AlFeO3，AlMnO3，AlCoO3，AlNiO3，A2HfO3，A3 CeO3，Li2ZrO3，Li2SiO3，Li2TiO3，Li2HfO3，A4N1yOz，YxN1yOz，LaxN1yOz，HfN2yOz或其组合; 其中A是La，Mg，Ca，Sr或Ba; A1是La，Ca，Sr或Ba; A2是Ca，Sr或Ba; A3是Sr或Ba; A4是Mg，Ca，Sr，Ba，Ti或Zr; N1是V，Nb，Ta，Cr，Mo，W，Mn，Si或Ge; N2是V，Mo，W或Si; x为1或2; y范围从1到3; z范围从2到7。

9. 发明申请

US20100108241A1 MEMBRANE STRUCTURE AND METHOD OF MAKING 有权
标题翻译：膜结构和制备方法
公开(公告)号：US20100108241A1
公开(公告)日：2010-05-06
申请号：US12687911
申请日：2010-01-15
申请人： Vidya Ramaswamy , Seth Thomas Taylor , James Anthony Ruud , Melissa Suzanne Sander , Anthony Yu-Chung Ku , Mohan Manoharan
发明人： Vidya Ramaswamy , Seth Thomas Taylor , James Anthony Ruud , Melissa Suzanne Sander , Anthony Yu-Chung Ku , Mohan Manoharan
IPC分类号： B32B38/00 , B32B37/00
CPC分类号： B01D67/0065 , B01D67/0088 , B01D69/02 , B01D2315/12 , B01D2321/168 , B01D2323/28 , B01D2323/286 , B01D2325/02 , Y10T156/10 , Y10T428/249953
摘要： A membrane structure is provided. The membrane structure includes a first layer having a plurality of pores; and a second layer disposed on the first layer. The second layer has a plurality of unconnected pores. At least a portion of the plurality of unconnected pores of the second layer is at least partially filled with a filler such that the first layer is substantially free of the filler. At least a portion of the plurality of unconnected pores of the second layer is in fluid communication with at least one of the pores of the first layer. A method of making a membrane structure is provided. The method includes the steps of providing a first layer having a plurality of interconnected pores; disposing a second layer on the first layer, and filling at least a portion of the unconnected pores of the second layer with a filler such that the first layer is substantially free of the filler. Disposing a second layer includes depositing a metal layer on the first layer; and anodizing the metal layer to convert the metal layer into porous oxide layer.
摘要翻译：提供膜结构。膜结构包括具有多个孔的第一层; 以及设置在第一层上的第二层。第二层具有多个未连接的孔。第二层的多个未连接孔的至少一部分至少部分地填充有填料，使得第一层基本上不含填料。第二层的多个未连接孔的至少一部分与第一层的至少一个孔流体连通。提供了制造膜结构的方法。该方法包括提供具有多个互连孔的第一层的步骤; 在第一层上设置第二层，并用填料填充第二层的至少一部分未连接的孔，使得第一层基本上不含填料。布置第二层包括在第一层上沉积金属层; 并将金属层阳极氧化以将金属层转化为多孔氧化物层。

10. 发明申请

US20080134895A1 Gas Separator Apparatus 有权
标题翻译：气体分离器
公开(公告)号：US20080134895A1
公开(公告)日：2008-06-12
申请号：US11608292
申请日：2006-12-08
申请人： James Anthony Ruud , Michael John Bowman , Kalya Vijaya Sarathy , Mohan Manoharan , Anthony Yu-Chung Ku , Vidya Ramaswamy , Patrick Roland Lucien Malenfant
发明人： James Anthony Ruud , Michael John Bowman , Kalya Vijaya Sarathy , Mohan Manoharan , Anthony Yu-Chung Ku , Vidya Ramaswamy , Patrick Roland Lucien Malenfant
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D61/38 , B01D67/0088 , B01D67/0093 , B01D69/10 , B01D69/141 , B01D71/024 , B01D71/027 , B01D71/028 , B01D71/40 , B01D71/44 , B01D2257/504 , B01D2325/10 , B01D2325/22 , Y02C10/10
摘要： An apparatus for separating at least one component from a mixture of a plurality of chemical species is provided. The apparatus comprises a membrane structure comprising a plurality of pores disposed within a matrix material to allow mass transport from a first surface of the membrane structure to a second surface of the membrane structure. The matrix material has a thermal conductivity of at least about 10 W/m/K; and a functional material disposed within at least a portion of the plurality of pores. The functional material has the property of promoting selective transport of at least one species through the membrane structure from the first surface to the second surface.
摘要翻译：提供了一种用于从多种化学物质的混合物中分离至少一种组分的装置。该装置包括膜结构，其包括设置在基质材料内的多个孔，以允许质量从膜结构的第一表面传输到膜结构的第二表面。基质材料具有至少约10W / m / K的热导率; 以及设置在所述多个孔的至少一部分中的功能材料。功能材料具有促进至少一种物质通过膜结构从第一表面到第二表面的选择性输送的性质。

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