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1. 发明授权

US08628880B2 Redox flow batteries based on supporting solutions containing chloride 有权
标题翻译：基于含有氯化物的支持溶液的氧化还原液流电池
公开(公告)号：US08628880B2
公开(公告)日：2014-01-14
申请号：US12892693
申请日：2010-09-28
申请人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
发明人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
IPC分类号： H01M6/04
CPC分类号： H01M8/08 , H01M8/18 , H01M8/188 , H01M8/20 , H01M2300/0002 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
摘要： Redox flow battery systems having a supporting solution that contains Cl− ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42− and Cl− ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl− ions or a mixture of SO42− and Cl− ions.
摘要翻译：具有包含Cl-离子的支持溶液的氧化还原液流电池系统可以表现出改进的性能和特性。此外，具有混合的SO42-和Cl-离子的支持溶液可以提供增加的能量密度并提高一种或多种离子物质在阴极电解液和/或阳极电解液中的稳定性和溶解度。根据一个示例，钒基氧化还原液流电池系统的特征在于在支撑溶液中具有V2 +和V3 +的阳极电解液，以及在支持溶液中具有V4 +和V5 +的阴极电解液。支持溶液可以含有Cl-离子或SO42-和Cl-离子的混合物。

2. 发明申请

US20120077079A1 Redox Flow Batteries Based on Supporting Solutions Containing Chloride 有权
标题翻译：基于含有氯化物的溶液的氧化还原液流电池
公开(公告)号：US20120077079A1
公开(公告)日：2012-03-29
申请号：US12892693
申请日：2010-09-28
申请人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
发明人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
IPC分类号： H01M10/02
CPC分类号： H01M8/08 , H01M8/18 , H01M8/188 , H01M8/20 , H01M2300/0002 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
摘要： Redox flow battery systems having a supporting solution that contains Cl− ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42− and Cl− ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl− ions or a mixture of SO42− and Cl− ions.
摘要翻译：具有包含Cl-离子的支持溶液的氧化还原液流电池系统可以表现出改进的性能和特性。此外，具有混合的SO42-和Cl-离子的支持溶液可以提供增加的能量密度并提高一种或多种离子物质在阴极电解液和/或阳极电解液中的稳定性和溶解度。根据一个示例，钒基氧化还原液流电池系统的特征在于在支撑溶液中具有V2 +和V3 +的阳极电解液，以及在支持溶液中具有V4 +和V5 +的阴极电解液。支持溶液可以含有Cl-离子或SO42-和Cl-离子的混合物。

3. 发明申请

US20120077067A1 Fe-V Redox Flow Batteries 有权
标题翻译： Fe-V氧化还原电池
公开(公告)号：US20120077067A1
公开(公告)日：2012-03-29
申请号：US12892698
申请日：2010-09-28
申请人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
发明人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
IPC分类号： H01M4/56
CPC分类号： H01M8/184 , H01M2/1653 , H01M8/188 , H01M8/20 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
摘要： A redox flow battery having a supporting solution that includes Cl− anions is characterized by an anolyte having V2+ and V3+ in the supporting solution, a catholyte having Fe2+ and Fe3+ in the supporting solution, and a membrane separating the anolyte and the catholyte. The anolyte and catholyte can have V cations and Fe cations, respectively, or the anolyte and catholyte can each contain both V and Fe cations in a mixture. Furthermore, the supporting solution can contain a mixture of SO42− and Cl− anions.
摘要翻译：具有包含Cl-阴离子的支持溶液的氧化还原液流电池的特征在于在支持溶液中具有V2 +和V3 +的阳极电解液，在支持溶液中具有Fe2 +和Fe3 +的阴极电解液和分离阳极电解液和阴极电解液的膜。阳极电解液和阴极电解液可以分别具有V阳离子和Fe阳离子，或阳极电解液和阴极电解液各自含有混合物中的V和Fe阳离子。此外，支持溶液可以含有SO42-和阴离子的混合物。

4. 发明授权

US09960443B2 Redox flow batteries having multiple electroactive elements 有权
公开(公告)号：US09960443B2
公开(公告)日：2018-05-01
申请号：US13246444
申请日：2011-09-27
申请人： Wei Wang , Liyu Li , Zhenguo Yang , Zimin Nie
发明人： Wei Wang , Liyu Li , Zhenguo Yang , Zimin Nie
IPC分类号： H01M8/18 , H01M8/20 , H01M2/16
CPC分类号： H01M8/188 , H01M2/1653 , H01M8/20 , Y02E60/528
摘要： Introducing multiple redox reactions with a suitable voltage range can improve the energy density of redox flow battery (RFB) systems. One example includes RFB systems utilizing multiple redox pairs in the positive half cell, the negative half cell, or in both. Such RFB systems can have a negative electrolyte, a positive electrolyte, and a membrane between the negative electrolyte and the positive electrolyte, in which at least two electrochemically active elements exist in the negative electrolyte, the positive electrolyte, or both.

5. 发明申请

US20120077068A1 Redox Flow Batteries Having Multiple Electroactive Elements 有权
标题翻译：具有多个电活性元素的氧化还原液流电池
公开(公告)号：US20120077068A1
公开(公告)日：2012-03-29
申请号：US13246444
申请日：2011-09-27
申请人： Wei Wang , Liyu Li , Zhenguo Yang , Zimin Nie
发明人： Wei Wang , Liyu Li , Zhenguo Yang , Zimin Nie
IPC分类号： H01M4/38 , H01M4/36
CPC分类号： H01M8/188 , H01M2/1653 , H01M8/20 , Y02E60/528
摘要： Introducing multiple redox reactions with a suitable voltage range can improve the energy density of redox flow battery (RFB) systems. One example includes RFB systems utilizing multiple redox pairs in the positive half cell, the negative half cell, or in both. Such RFB systems can have a negative electrolyte, a positive electrolyte, and a membrane between the negative electrolyte and the positive electrolyte, in which at least two electrochemically active elements exist in the negative electrolyte, the positive electrolyte, or both.
摘要翻译：在合适的电压范围内引入多种氧化还原反应可以提高氧化还原液流电池（RFB）系统的能量密度。一个例子包括在正半衰期，负半小区或两者中使用多个氧化还原对的RFB系统。这样的RFB系统可以具有负电解质，正电解质和负电解质和正电解质之间的膜，其中至少两个电化学活性元素存在于负电解质，正电解质或两者中。

6. 发明授权

US08771856B2 Fe-V redox flow batteries 有权
标题翻译： Fe-V氧化还原电池
公开(公告)号：US08771856B2
公开(公告)日：2014-07-08
申请号：US12892698
申请日：2010-09-28
申请人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
发明人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
IPC分类号： H01M8/18 , H01M8/20
CPC分类号： H01M8/184 , H01M2/1653 , H01M8/188 , H01M8/20 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
摘要： A redox flow battery having a supporting solution that includes Cl− anions is characterized by an anolyte having V2+ and V3+ in the supporting solution, a catholyte having Fe2+ and Fe3+ in the supporting solution, and a membrane separating the anolyte and the catholyte. The anolyte and catholyte can have V cations and Fe cations, respectively, or the anolyte and catholyte can each contain both V and Fe cations in a mixture. Furthermore, the supporting solution can contain a mixture of SO42− and Cl− anions.
摘要翻译：具有包含Cl-阴离子的支持溶液的氧化还原液流电池的特征在于在支持溶液中具有V2 +和V3 +的阳极电解液，在支持溶液中具有Fe2 +和Fe3 +的阴极电解液和分离阳极电解液和阴极电解液的膜。阳极电解液和阴极电解液可以分别具有V阳离子和Fe阳离子，或阳极电解液和阴极电解液各自含有混合物中的V和Fe阳离子。此外，支持溶液可以含有SO42-和阴离子的混合物。

7. 发明申请

US20120107660A1 Redox Flow Batteries Based on Supporting Solutions Comprising a Mixture of Acids 审中-公开
标题翻译：基于包含酸混合物的支持溶液的氧化还原液流电池
公开(公告)号：US20120107660A1
公开(公告)日：2012-05-03
申请号：US13338791
申请日：2011-12-28
申请人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
发明人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
IPC分类号： H01M4/36
CPC分类号： H01M8/08 , H01M8/18 , H01M8/188 , H01M8/20 , H01M2300/0002 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
摘要： Redox flow battery systems having a supporting solution that contains Cl” ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42− and Cl− ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl− ions or a mixture of SO42− and Cl− ions.
摘要翻译：具有包含Cl“离子的支持溶液的氧化还原液流电池系统可以表现出改进的性能和特性。此外，具有混合的SO42-和Cl-离子的支持溶液可以提供增加的能量密度并提高一种或多种离子物质在阴极电解液和/或阳极电解液中的稳定性和溶解度。根据一个示例，钒基氧化还原液流电池系统的特征在于在支撑溶液中具有V2 +和V3 +的阳极电解液，以及在支持溶液中具有V4 +和V5 +的阴极电解液。支持溶液可以含有Cl-离子或SO42-和Cl-离子的混合物。

8. 发明申请

US20130266836A1 Hybrid Energy Storage Systems Utilizing Redox Active Organic Compounds 有权
标题翻译：利用氧化还原活性有机化合物的混合能量储存系统
公开(公告)号：US20130266836A1
公开(公告)日：2013-10-10
申请号：US13439083
申请日：2012-04-04
申请人： Wei Wang , Wu Xu , Liyu Li , Zhenguo Yang
发明人： Wei Wang , Wu Xu , Liyu Li , Zhenguo Yang
IPC分类号： H01M10/05 , H01M4/13 , H01M10/02 , H01M4/64
CPC分类号： H01M8/188 , H01M12/08 , Y02E60/128 , Y02E60/528
摘要： Redox flow batteries (RFB) have attracted considerable interest due to their ability to store large amounts of power and energy. Non-aqueous energy storage systems that utilize at least some aspects of RFB systems are attractive because they can offer an expansion of the operating potential window, which can improve on the system energy and power densities. One example of such systems has a separator separating first and second electrodes. The first electrode includes a first current collector and volume containing a first active material. The second electrode includes a second current collector and volume containing a second active material. During operation, the first source provides a flow of first active material to the first volume. The first active material includes a redox active organic compound dissolved in a non-aqueous, liquid electrolyte and the second active material includes a redox active metal.
摘要翻译：氧化还原电池（RFB）由于能够存储大量电能和能量而引起了相当大的兴趣。利用RFB系统的至少一些方面的非水能量存储系统是有吸引力的，因为它们可以提供操作电位窗口的扩展，这可以提高系统能量和功率密度。这种系统的一个示例具有分离第一和第二电极的分离器。第一电极包括第一集电器和包含第一活性材料的体积。第二电极包括第二集电器和包含第二活性材料的体积。在操作期间，第一源提供第一活性材料流到第一体积。第一活性物质包括溶解在非水电解液中的氧化还原活性有机化合物，第二活性物质包括氧化还原活性金属。

9. 发明授权

US09130218B2 Hybrid energy storage systems utilizing redox active organic compounds 有权
标题翻译：利用氧化还原活性有机化合物的混合储能系统
公开(公告)号：US09130218B2
公开(公告)日：2015-09-08
申请号：US13439083
申请日：2012-04-04
申请人： Wei Wang , Wu Xu , Liyu Li , Zhenguo Yang
发明人： Wei Wang , Wu Xu , Liyu Li , Zhenguo Yang
IPC分类号： H01M8/18 , H01M12/08
CPC分类号： H01M8/188 , H01M12/08 , Y02E60/128 , Y02E60/528
摘要： Redox flow batteries (RFB) have attracted considerable interest due to their ability to store large amounts of power and energy. Non-aqueous energy storage systems that utilize at least some aspects of RFB systems are attractive because they can offer an expansion of the operating potential window, which can improve on the system energy and power densities. One example of such systems has a separator separating first and second electrodes. The first electrode includes a first current collector and volume containing a first active material. The second electrode includes a second current collector and volume containing a second active material. During operation, the first source provides a flow of first active material to the first volume. The first active material includes a redox active organic compound dissolved in a non-aqueous, liquid electrolyte and the second active material includes a redox active metal.
摘要翻译：氧化还原电池（RFB）由于能够存储大量电能和能量而引起了相当大的兴趣。利用RFB系统的至少一些方面的非水能量存储系统是有吸引力的，因为它们可以提供操作电位窗口的扩展，这可以提高系统能量和功率密度。这种系统的一个示例具有分离第一和第二电极的分离器。第一电极包括第一集电器和包含第一活性材料的体积。第二电极包括第二集电器和包含第二活性材料的体积。在操作期间，第一源提供第一活性材料流到第一体积。第一活性物质包括溶解在非水电解液中的氧化还原活性有机化合物，第二活性物质包括氧化还原活性金属。

10. 发明申请

US20100311577A1 CaO Based Carbon Dioxide Absorbent and Method of Making 审中-公开
标题翻译： CaO基二氧化碳吸收剂及其制备方法
公开(公告)号：US20100311577A1
公开(公告)日：2010-12-09
申请号：US12479320
申请日：2009-06-05
申请人： Liyu Li , David L. King , Jun Liu , Kake Zhu , Zimin Nie , Christopher J. Howard
发明人： Liyu Li , David L. King , Jun Liu , Kake Zhu , Zimin Nie , Christopher J. Howard
IPC分类号： B01J20/04 , B01J20/30
CPC分类号： B01J20/3078 , B01D53/62 , B01D2251/402 , B01D2251/404 , B01D2257/504 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/30 , B01J20/3433 , B01J20/3483 , B82Y30/00 , Y02A50/2342 , Y02C10/04
摘要： A method for making a class of relatively stable porous carbon dioxide absorbents by mixing inert nanoparticles with a CaO precursor followed by high temperature calcination. In the preferred embodiments of this invention this process takes place in the essential absence of nitrates. In some embodiments of the invention the method further includes forming the inert nanoparticles-doped porous CaO material by decomposing a mixture of inert particles and CaO precursor material.
摘要翻译：通过将惰性纳米颗粒与CaO前体混合并进行高温煅烧来制备一类相对稳定的多孔二氧化碳吸收剂的方法。在本发明的优选实施方案中，该方法基本上不存在硝酸盐。在本发明的一些实施方案中，该方法还包括通过分解惰性颗粒和CaO前体材料的混合物来形成惰性纳米颗粒掺杂的多孔CaO材料。

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