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1. 发明授权

US09174928B2 Process for improving the selectivity of an EO catalyst 有权
标题翻译：提高EO催化剂选择性的方法
公开(公告)号：US09174928B2
公开(公告)日：2015-11-03
申请号：US13456774
申请日：2012-04-26
申请人： Wayne Errol Evans , Jeffrey Michael Kobe , Marek Matusz
发明人： Wayne Errol Evans , Jeffrey Michael Kobe , Marek Matusz
IPC分类号： C07D301/03 , C07C213/04 , C07D301/12
CPC分类号： C07C213/04 , C07D301/12 , Y02P20/52 , C07C215/08
摘要： Processes for the epoxidation of ethylene are provided in which, following start-up, an epoxidation catalyst is contacted with a feed comprising ethylene, oxygen, carbon dioxide in an amount below 2.0 vol. %, and a chloride moderator to achieve a desired work rate at a first operating temperature T1. The composition of the feed is subsequently adjusted (e.g., by decreasing the ethylene concentration, decreasing the oxygen concentration, increasing the carbon dioxide concentration and/or adjusting the concentration of the chloride moderator) so as to increase the first operating temperature T1 to a second operating temperature T2 while maintaining the desired work rate. As the catalyst activity declines, the composition of the feed is further adjusted so as to maintain the desired work rate at the second operating temperature T2.
摘要翻译：提供了用于环氧化乙烯的方法，其中在启动之后，将环氧化催化剂与包含乙烯，氧，二氧化碳的进料接触，其量低于2.0体积％。％和氯化物调节剂，以在第一工作温度T1达到所需的加工速率。随后调整进料的组成（例如，通过降低乙烯浓度，降低氧浓度，增加二氧化碳浓度和/或调节氯化物调节剂的浓度），以便将第一操作温度T1增加至第二工作温度T2，同时保持所需的工作速率。随着催化剂活性的降低，进料的组成进一步调节，以便在第二工作温度T2保持所需的加工速率。

2. 发明授权

US09527787B2 Process for the preparation of alkylene carbonate and/or alkylene glycol 有权
标题翻译：制备碳酸亚烷基酯和/或亚烷基二醇的方法
公开(公告)号：US09527787B2
公开(公告)日：2016-12-27
申请号：US13462490
申请日：2012-05-02
申请人： Wayne Errol Evans , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten , Martin Lysle Hess
发明人： Wayne Errol Evans , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten , Martin Lysle Hess
IPC分类号： B01J19/00 , C07C29/12 , B01D53/02 , B01D53/70 , C07C29/10
CPC分类号： C07C29/12 , B01D53/02 , B01D53/70 , B01D2253/112 , B01D2255/104 , B01D2257/2068 , C07C29/106 , Y02P20/154 , Y02P20/52 , C07C31/202
摘要： The invention provides a reaction system for the production of an alkylene carbonate and/or an alkylene glycol comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an iodide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of iodide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and/or an alkylene glycol.
摘要翻译：本发明提供了一种用于生产碳酸亚烷基酯和/或亚烷基二醇的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含碘化物羧化催化剂的羧化区; 以及一个或多个纯化区，其含有能够减少包含循环气体的进料中的含碘化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和/或亚烷基二醇的方法。

3. 发明授权

US08858893B2 Process for the preparation of an alkylene carbonate and an alkylene glycol 有权
标题翻译：制备碳酸亚烷基酯和亚烷基二醇的方法
公开(公告)号：US08858893B2
公开(公告)日：2014-10-14
申请号：US13591982
申请日：2012-08-22
申请人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
发明人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
IPC分类号： B01J8/00 , C07C29/12 , C07C29/10 , C07D301/10
CPC分类号： C07D301/10 , B01D2255/104 , B01D2255/2022 , B01D2255/2092 , B01D2257/2062 , B01D2259/40 , C07C29/106 , C07C29/12 , Y02C10/08 , Y02P20/52 , C07C31/202
摘要： The invention provides a reaction system for the production of an alkylene carbonate comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an bromide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of bromide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and an alkylene glycol.
摘要翻译：本发明提供了一种用于生产碳酸亚烷基酯的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含溴化羧化催化剂的羧化区; 以及一个或多个净化区，其含有能够减少包含循环气体的进料中的含溴化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和亚烷基二醇的方法。

4. 发明授权

US08273912B2 Process for the preparation of an alkylene carbonate and an alkylene glycol 有权
标题翻译：制备碳酸亚烷基酯和亚烷基二醇的方法
公开(公告)号：US08273912B2
公开(公告)日：2012-09-25
申请号：US12464972
申请日：2009-05-13
申请人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
发明人： Wayne Errol Evans , Martin Lysle Hess , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten
IPC分类号： C07C69/00
CPC分类号： C07D301/10 , B01D2255/104 , B01D2255/2022 , B01D2255/2092 , B01D2257/2062 , B01D2259/40 , C07C29/106 , C07C29/12 , Y02C10/08 , Y02P20/52 , C07C31/202
摘要： The invention provides a reaction system for the production of an alkylene carbonate comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an bromide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of bromide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and an alkylene glycol.
摘要翻译：本发明提供了一种用于生产碳酸亚烷基酯的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含溴化羧化催化剂的羧化区; 以及一个或多个净化区，其含有能够减少包含循环气体的进料中的含溴化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和亚烷基二醇的方法。

5. 发明授权

US08742147B2 Process for improving the selectivity of an EO catalyst 有权
标题翻译：提高EO催化剂选择性的方法
公开(公告)号：US08742147B2
公开(公告)日：2014-06-03
申请号：US13310273
申请日：2011-12-02
申请人： Wayne Errol Evans , Marek Matusz , Paul Michael McAllister
发明人： Wayne Errol Evans , Marek Matusz , Paul Michael McAllister
IPC分类号： C07D301/03 , C07C43/00 , C07C31/18 , C07C29/03
CPC分类号： C07D303/04 , Y02P20/142
摘要： The present invention relates to a process for improving the overall selectivity of an EO process for converting ethylene to ethylene oxide utilizing a highly selective EO silver catalyst containing a rhenium promoter wherein following normal operation a chloride strip of the chloride on the surface of the catalyst is conducted in order to remove a portion of the chlorides on the surface of the catalyst. The chloride strip involves the addition of certain saturated hydrocarbons to the feed. Following the chloride strip, the catalyst is optionally re-optimized.
摘要翻译：本发明涉及使用含有铼助催化剂的高度选择性的EO银催化剂来改善EO转化为环氧乙烷的EO方法的总体选择性的方法，其中在正常操作之后，催化剂表面上氯化物的氯化物条是进行以除去催化剂表面上的一部分氯化物。氯化物条包括向进料中加入某些饱和烃。在氯化带之后，任选地重新优化催化剂。

6. 发明授权

US08742146B2 Process for improving the selectivity of an EO catalyst 有权
标题翻译：提高EO催化剂选择性的方法
公开(公告)号：US08742146B2
公开(公告)日：2014-06-03
申请号：US13310246
申请日：2011-12-02
申请人： Martin Lysle Hess , Wayne Errol Evans , Jeffery Michael Kobe , Marek Matusz
发明人： Martin Lysle Hess , Wayne Errol Evans , Jeffery Michael Kobe , Marek Matusz
IPC分类号： C07D301/03 , C07C43/00 , C07C31/18 , C07C29/03
CPC分类号： C07D301/10 , B01J23/96 , B01J38/02 , Y02P20/142 , Y02P20/584
摘要： The present invention relates to a process for improving the overall selectivity of an EO process for converting ethylene to ethylene oxide utilizing a highly selective EO silver catalyst containing a rhenium promoter wherein following normal operation a hard strip of the chloride on the surface of the catalyst is conducted in order to remove a portion of the chlorides on the surface of the catalyst. Following the hard strip, the catalyst is optionally re-optimized. Surprisingly, it has been found that the selectivity of the catalyst following the hard strip may be substantially higher than the selectivity prior to the hard strip.
摘要翻译：本发明涉及使用含有铼助催化剂的高度选择性的EO银催化剂来改善EO转化成环氧乙烷的EO方法的整体选择性的方法，其中在正常操作之后，催化剂表面上的氯化物的硬条是进行以除去催化剂表面上的一部分氯化物。在硬条之后，任选地重新优化催化剂。令人惊奇的是，已经发现，跟随硬带的催化剂的选择性可能显着高于硬条之前的选择性。

7. 发明授权

US08357812B2 Process for preparing a rejuvenated epoxidation catalyst 失效
标题翻译：制备振兴环氧化催化剂的方法
公开(公告)号：US08357812B2
公开(公告)日：2013-01-22
申请号：US11613849
申请日：2006-12-20
申请人： Wayne Errol Evans , Marek Matusz
发明人： Wayne Errol Evans , Marek Matusz
IPC分类号： C07D301/10
CPC分类号： C07D301/10 , B01J23/50 , B01J23/66 , B01J38/48 , B01J38/66 , Y02P20/584
摘要： A process for preparing a rejuvenated epoxidation catalyst, for the epoxidation of one or more olefins using the rejuvenated epoxidation catalyst to produce olefin oxide, and for the production of a 1,2-diol, a 1,2-diol ether, or an alkanol amine from the olefin oxide, the process comprising: providing a quantity of spent epoxidation catalyst having a cumulative alkylene oxide production of 0.16 kT/m3 of the spent epoxidation catalyst or more; and, depositing additional silver on the spent epoxidation catalyst in an amount of 0.2% w or more, based on the weight of the spent epoxidation catalyst.
摘要翻译：一种制备环氧化催化剂的方法，用于环氧化一种或多种烯烃，使用复原的环氧化催化剂制备烯烃氧化物，以及用于生产1,2-二醇，1,2-二醇醚或链烷醇该方法包括：提供一定量的废环氧化催化剂，其具有0.16kT / m3的废环氧化催化剂或更多的累积环氧烷产生量; 并且基于废环氧化催化剂的重量，在废环氧化催化剂上以0.2％（重量）以上的量沉积额外的银。

8. 发明授权

US08193374B2 Process for the preparation of alkylene carbonate and/or alkylene glycol 有权
标题翻译：制备碳酸亚烷基酯和/或亚烷基二醇的方法
公开(公告)号：US08193374B2
公开(公告)日：2012-06-05
申请号：US12465492
申请日：2009-05-13
申请人： Wayne Errol Evans , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten , Martin Lysle Hess
发明人： Wayne Errol Evans , Marek Matusz , Eugene Marie Godfried Andre Van Kruchten , Martin Lysle Hess
IPC分类号： C07D317/08 , C07C31/18 , C07C27/00
CPC分类号： C07C29/12 , B01D53/02 , B01D53/70 , B01D2253/112 , B01D2255/104 , B01D2257/2068 , C07C29/106 , Y02P20/154 , Y02P20/52 , C07C31/202
摘要： The invention provides a reaction system for the production of an alkylene carbonate and/or an alkylene glycol comprising: an epoxidation zone containing an epoxidation catalyst located within an epoxidation reactor; a carboxylation zone containing an iodide-containing carboxylation catalyst located within an alkylene oxide absorber; and one or more purification zones containing a purification absorbent capable of reducing the quantity of iodide-containing impurities in a feed comprising a recycle gas, which purification zones are located upstream from the epoxidation zone; and a process for the production of an alkylene carbonate and/or an alkylene glycol.
摘要翻译：本发明提供了一种用于生产碳酸亚烷基酯和/或亚烷基二醇的反应体系，包括：含有位于环氧化反应器内的环氧化催化剂的环氧化区; 含有位于烯化氧吸收剂内的含碘化物羧化催化剂的羧化区; 以及一个或多个纯化区，其含有能够减少包含循环气体的进料中的含碘化物杂质的净化吸收剂，该净化区位于环氧化区的上游; 以及制备碳酸亚烷基酯和/或亚烷基二醇的方法。

9. 发明授权

US07348444B2 Process for the production of an olefin oxide 失效
标题翻译：生产烯烃氧化物的方法
公开(公告)号：US07348444B2
公开(公告)日：2008-03-25
申请号：US10816480
申请日：2004-04-01
申请人： Wayne Errol Evans , Marek Matusz
发明人： Wayne Errol Evans , Marek Matusz
IPC分类号： C07D323/02 , C07D317/44 , B01J20/34 , B01J23/60
CPC分类号： C07C29/106 , C07D301/10 , Y02P20/52 , C07C31/202
摘要： A process for the production of an olefin oxide, which process comprises reacting a feed comprising an olefin and oxygen in the presence of a silver-containing catalyst, wherein before the catalyst has reached an advanced stage of ageing the reaction temperature is above 255° C. and the olefin content of the feed is above 25 mole-%, relative to the total feed.
摘要翻译：一种制备烯烃氧化物的方法，该方法包括在含银催化剂存在下使包含烯烃和氧的进料反应，其中在催化剂达到老化之前，反应温度高于255℃ 并且相对于总进料，进料的烯烃含量高于25摩尔％。

10. 发明授权

US08546592B2 Olefin epoxidation process 有权
标题翻译：烯烃环氧化工艺
公开(公告)号：US08546592B2
公开(公告)日：2013-10-01
申请号：US13246325
申请日：2011-09-27
申请人： Wayne Errol Evans , Paul Michael McAllister , Randall Clayton Yeates , Jeffrey Michael Kobe
发明人： Wayne Errol Evans , Paul Michael McAllister , Randall Clayton Yeates , Jeffrey Michael Kobe
IPC分类号： C07D301/03 , C07C29/00
CPC分类号： C07D301/10 , C07D301/04
摘要： A process for the production of an olefin oxide, which process comprises reacting a feed comprising an olefin and oxygen in a reactor tube in the presence of a silver-containing catalyst, wherein the presence of water in the catalyst bed is controlled such that the ratio of the partial pressure of water (PPH2O) divided by the vapor pressure of water (VPH2O) is less than 0.006, preferably less than 0.004.
摘要翻译：一种生产烯烃氧化物的方法，该方法包括在含银催化剂存在下，使反应器管中含有烯烃和氧的进料反应，其中催化剂床中的水的存在被控制，的水分压（PPH2O）除以水的蒸气压（VPH2O）小于0.006，优选小于0.004。

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