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1. 发明授权

US4945137A Binder combinations and a process for the production of flat materials 失效
标题翻译：粘合剂组合和生产平板材料的工艺
公开(公告)号：US4945137A
公开(公告)日：1990-07-31
申请号：US415863
申请日：1989-10-02
申请人： Walter Schafer , Hans Rudolph , Rolf Dhein , Hanns-Peter Muller , Michael Sonntag , Christian Wamprecht , Harald Blum , Walter Krauss
发明人： Walter Schafer , Hans Rudolph , Rolf Dhein , Hanns-Peter Muller , Michael Sonntag , Christian Wamprecht , Harald Blum , Walter Krauss
IPC分类号： C08L33/06 , C03C25/10 , C08F8/32 , C08K3/28 , C08K5/17 , C08K5/353 , C08K13/02 , C08L33/04 , C08L35/00 , C08L101/00 , C08L101/08 , C09D7/12 , C09D201/08
CPC分类号： C08K5/17 , C08F8/32 , C08K3/28 , C08K5/353
摘要： A binder for a coating composition is a combination of(a) polymers containing intramolecular carboxylic anhydride groups and having an average molecular weight of from 500 to 25,000 and(b) organic compounds containing 4,5-dihydrooxazole groups in a quantity corresponding to an equivalent ratio of carboxylic anhydride groups to 4,5-dihydrooxazole groups of from 0.5:1 to 2:1, and contains from 0.005 to 5% by weight, based on the weight of components (a) and (b), of ammonia, a primary amine or secondary amine.
摘要翻译：用于涂料组合物的粘合剂是（a）含有分子内羧酸酐基团并且平均分子量为500至25,000的聚合物和（b）含有相当于当量的4,5-二氢恶唑基团的有机化合物的组合羧酸酐基团与4,5-二氢恶唑基团的比例为0.5:1至2:1，并且基于组分（a）和（b）的重量，含有0.005至5重量％的氨，伯胺或仲胺。

2. 发明授权

US4248978A Pulverulent coating composition 失效
标题翻译：粉末涂料组合物
公开(公告)号：US4248978A
公开(公告)日：1981-02-03
申请号：US35220
申请日：1979-05-02
申请人： Eckhard de Cleur , Rolf Dhein , Hans Rudolph , Hans J. Kreuder , Hanns P. Muller , Walter Schafer , Kuno Wagner , Kurt Findeisen
发明人： Eckhard de Cleur , Rolf Dhein , Hans Rudolph , Hans J. Kreuder , Hanns P. Muller , Walter Schafer , Kuno Wagner , Kurt Findeisen
IPC分类号： C09D5/03 , C08G18/00 , C08G18/78 , C08G18/79 , C09D5/46 , C09D175/00 , C08L75/00
CPC分类号： C08G18/78 , C08G18/797 , C09D175/00 , C08G2150/20
摘要： Compounds having a melting point above 40.degree. C. which compounds contain uretone imine groups and which are substantially free from volatile isocyanate blocking agents which are split off under stoving conditions are excellent crosslinking agents for pulverulent coating compositions based on hydroxyl groups-containing polymers.
摘要翻译：具有高于40℃的化合物，其中含有脲基亚胺基团并且基本上不含在挥发性条件下分离的挥发性异氰酸酯封闭剂的化合物是用于基于含羟基聚合物的粉末涂料组合物的优异交联剂。

3. 发明授权

US5405664A Tubular casing with an organochlorine-free coating impermeable to oxygen and water vapor, a process for its production and its use 失效
标题翻译：具有不透氧和无水蒸汽的无机氯涂层的管状套管，其生产和使用的过程
公开(公告)号：US5405664A
公开(公告)日：1995-04-11
申请号：US19396
申请日：1993-02-18
申请人： Kirkor Sirinyan , Hanns-Peter Muller , Rolf Dhein , Gunter Weber , Sebastian Meyer-Stork , Michael Stiem
发明人： Kirkor Sirinyan , Hanns-Peter Muller , Rolf Dhein , Gunter Weber , Sebastian Meyer-Stork , Michael Stiem
IPC分类号： A22C13/00 , B32B7/02 , B32B23/08 , B32B27/08 , B32B27/40 , B65D25/06 , B65D65/40
CPC分类号： A22C13/0013 , A22C2013/004 , A22C2013/0053 , A22C2013/0096 , Y10S206/802 , Y10T428/1324
摘要： This invention relates to a multilayer organochlorine-free tubular casing consiting ofa. a regenerated cellulose substrate,b. optionally a layer of primer,c. a 5 to 40 .mu.m thick, organochlorine-free polymeric water vapor barrier layer which is characterized in that it has a permeability to water vapor of at most 50 g/m.sup.2.24 h and a surface tension.ltoreq.34 mN/m,d. a 5 to 40 .mu.m thick, polymeric organochlorine-free oxygen barrier layer, characterized in that it has a permeability to oxygen of at most 120 cm.sup.3 /m.sup.2.24 h bar and a surface tension of.gtoreq.38 N/m.The invention also relates to its use as a casing for sausages of the Kochwurst and Bruhwurst type.
摘要翻译：本发明涉及一种多层不含有机氯的管状套管，再生纤维素基质，b。任选一层底漆，c。 5〜40μm厚的无有机氯聚合物水蒸气阻隔层，其特征在于其具有至多50g / m 2·24小时的水蒸气渗透性，表面张力为34mN / m， d。厚度为5〜40μm的聚合无机氧阻隔层，其特征在于，其具有至多120cm 3 / m 2·24h·bar的表面张力和≥3N/ m 2的表面张力。本发明还涉及其作为Kochwurst和Brühwwst型香肠肠衣的用途。

4. 发明授权

US5374704A Pure, in particular catalyst-free polyurethanes 失效
标题翻译：纯的，特别是无催化剂的聚氨酯
公开(公告)号：US5374704A
公开(公告)日：1994-12-20
申请号：US166760
申请日：1993-12-14
申请人： Hanns-Peter Muller , Rolf Dhein , Herbert Hugl , Heinz Pudleiner
发明人： Hanns-Peter Muller , Rolf Dhein , Herbert Hugl , Heinz Pudleiner
IPC分类号： A61L24/00 , A61L27/00 , A61L27/18 , A61L29/00 , A61L29/06 , A61L31/06 , B65D65/38 , C08G18/08 , C08G18/10 , C08G18/44 , C08G18/73 , C08G18/75 , C08G18/77 , C08J5/18
CPC分类号： C08G18/773 , A61L27/18 , A61L29/06 , A61L31/06 , C08G18/10 , C08G18/44 , C08G18/75
摘要： The present invention is directed to pure polyurethanes which are biocompatible. These pure polyurethanes comprise the reaction product of:a) a pre-adduct containing NCO groups and comprising the reaction product ofi) a diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof, withii) a macrodiol having a molecular weight of from 500 to 10,000 wherein said components i) and ii) reacted at temperatures of from 90.degree.-150.degree. C.; withb) a chain extender having a molecular weight of from 62 to 400 and being selected from the group consisting of aliphatic diols, cycloaliphatic diols, and mixtures thereof, and optionally,c) additional diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof,wherein said component c), when added, is added either simultaneously with component b) or separately from component b), the quantities of components a)i), a)ii), and c) being such that the molar ratio of diisocyanate to macrodiol is from 1.5:1 to 22:1, and the reaction of components a) and b) and optionally component c) is conducted at temperatures of from 90.degree. to 230.degree. C., with the proviso that the reaction conditions are maintained until said polyurethane has a melt viscosity of at least 2500 mPa.s at 120.degree. C.
摘要翻译：本发明涉及生物相容的纯聚氨酯。这些纯聚氨酯包括以下物质的反应产物：a）含有NCO基团的预加合物，其包含i）选自脂族二异氰酸酯，脂环族二异氰酸酯及其混合物的二异氰酸酯的反应产物，ii）具有分子量为500至10,000，其中所述组分i）和ii）在90-150℃的温度下反应; 其中b）分子量为62至400的扩链剂，并且选自脂族二醇，脂环族二醇及其混合物，以及任选地，c）另外的二异氰酸酯，其选自脂族二异氰酸酯，脂环族脂族二异氰酸酯及其混合物，其中所述组分c）在加入时与组分b）同时加入或与组分b）分开加入，组分a）i），a）ii）和c）的数量使得二异氰酸酯与大分子二醇的摩尔比为1.5:1至22:1，组分a）和b）和任选组分c）的反应在90℃至230℃的温度下进行，条件是维持反应条件，直到所述聚氨酯在120℃下的熔体粘度为至少2500mPa.s。

5. 发明授权

US5942593A Cycloaliphatic thermoplastic polyurethane elastomers 失效
标题翻译：环脂族热塑性聚氨酯弹性体
公开(公告)号：US5942593A
公开(公告)日：1999-08-24
申请号：US805840
申请日：1997-03-03
申请人： Heinz Pudleiner , Rolf Dhein , Herbert Hugl , Hanns-Peter Muller , Herbert Heidingsfeld , Hans-Georg Hoppe
发明人： Heinz Pudleiner , Rolf Dhein , Herbert Hugl , Hanns-Peter Muller , Herbert Heidingsfeld , Hans-Georg Hoppe
IPC分类号： B29D99/00 , A61L29/06 , B29K75/00 , C08G18/10 , C08G18/12 , C08G18/42 , C08G18/44 , C08G18/48 , C08G18/65 , C08G18/66 , C08G18/73 , C08G18/75
CPC分类号： C08G18/4854 , A61L29/06 , C08G18/12 , C08G18/44
摘要： A process for the preparation of a polyurethane-urea elastomer having a mole ratio of NCO groups to all active hydrogen atoms in the range of 0.9 to 1.2 is disclosed. The process comprise reacting (A), (B) and (C.2) for form an NCO-containing prepolymer and then reacting said prepolymer with (C.1) and (D). Accordingly (A) is 5-isocyanato-1-(isocyanatomethyl)-1,1,3-trimethylcyclohexane or bis-(4-isocyanatocyclohexyl)-methane,(B) is polytetrahydrofuran or hexanediol polycarbonate and (C.2) is a chain extender. (C.1) is 5-amino-3-amino-methyl-1,3,3-trimethylcyclohexane or bis-(4-aminocyclohexyl)-methane and (D) is a molecular weight regulator. The elastomer thus produced is particularly suitable for the preparation of moldings, films, flexible tubing (for medical purposes) and catheters.
摘要翻译：公开了一种制备具有NCO基摩尔数与所有活性氢原子在0.9至1.2范围内的聚氨酯 - 脲弹性体的方法。该方法包括使（A），（B）和（C.2）反应形成含NCO的预聚物，然后使所述预聚物与（C.1）和（D）反应。因此（A）是5-异氰酸基-1-（异氰酸根合甲基）-1,1,3-三甲基环己烷或双 - （4-异氰酸根合环己基） - 甲烷，（B）是聚四氢呋喃或己二醇聚碳酸酯，（C.2）延长剂（C.1）是5-氨基-3-氨基 - 甲基-1,3,3-三甲基环己烷或双 - （4-氨基环己基） - 甲烷，（D）是分子量调节剂。如此制备的弹性体特别适用于制备模制品，薄膜，柔性管（用于医疗用途）和导管。

6. 发明授权

US5430121A Thermoplastic polyurethanes modified by siloxane block copolymers 失效
标题翻译：通过硅氧烷嵌段共聚物改性的热塑性聚氨酯
公开(公告)号：US5430121A
公开(公告)日：1995-07-04
申请号：US169096
申请日：1993-12-17
申请人： Heinz Pudleiner , Herbert Hugl , Rolf Dhein , Hanns-Peter Muller
发明人： Heinz Pudleiner , Herbert Hugl , Rolf Dhein , Hanns-Peter Muller
IPC分类号： C08G18/12 , C08G18/40 , C08G18/61 , C08G77/458 , C08L75/00
CPC分类号： C08G77/458 , C08G18/12 , C08G18/4009 , C08G18/61
摘要： The invention relates to thermoplastic polyurethanes modified with segmented siloxane block copolymers which are based on relatively high molecular weight dihydroxy compounds, diisocyanates, and difunctional chain extenders. The application also relates to their use in the medical field, and particularly as a catheter material.
摘要翻译：本发明涉及用基于相对高分子量的二羟基化合物，二异氰酸酯和双功能扩链剂的分段硅氧烷嵌段共聚物改性的热塑性聚氨酯。本申请还涉及其在医疗领域中的使用，特别是导管材料。

7. 发明授权

US5179146A Modified polyisocyanates, a process for their production and their use 失效
标题翻译：改性聚异氰酸酯，其生产工艺及其使用
公开(公告)号：US5179146A
公开(公告)日：1993-01-12
申请号：US860622
申请日：1992-03-30
申请人： Hanns-Peter Muller , Geza Avar , Christian Weber , Karl-Heinz Dorner , Alexander Karbach , Christian Lindner , Rolf Dhein
发明人： Hanns-Peter Muller , Geza Avar , Christian Weber , Karl-Heinz Dorner , Alexander Karbach , Christian Lindner , Rolf Dhein
IPC分类号： C08G18/63 , C08G18/70 , C08G18/72 , C08G18/81 , C08J3/20 , C08L51/04 , C08L55/00 , C08L55/02 , C08L75/00 , C08L75/04
CPC分类号： C08G18/708
摘要： Modified polyisocyanates having an NCO group content of from 10 to 45% by weight, comprising a a) a polyisocyanate component consisting essentially of an organic polyisocyanate having an NCO group content of from 15 to 50% by weight which is liquid at room temperature, and b) 2 to 100% by weight, based on the weight of component a), of a polymer modifier consisting of at least one graft rubber which is dispersed in swollen form in component a), and a process for the production of the new modified polyisocyanates are described. The modified polyisocyanates are also useful in the production of plastics by the isocyanate polyaddition process.
摘要翻译： NCO基团含量为10〜45重量％的改性多异氰酸酯，其包含aa）主要由NCO基含量为15〜50重量％的有机多异氰酸酯组成的多异氰酸酯组分，其在室温下为液体，b ）2至100重量％，基于组分a）的重量，由至少一种分散在组分a）中的溶胀形式的接枝橡胶组成的聚合物改性剂，以及制备新的改性多异氰酸酯的方法被描述。改性的多异氰酸酯也可用于通过异氰酸酯加聚方法生产塑料。

8. 发明授权

US4895921A Water soluble or dispersible blocked polyisocyanates and a process for their preparation and use 失效
标题翻译：水溶性或分散性封端多异氰酸酯及其制备和使用方法
公开(公告)号：US4895921A
公开(公告)日：1990-01-23
申请号：US253179
申请日：1988-10-04
申请人： Walter Schafer , Hanns P. Muller , Rolf Dhein
发明人： Walter Schafer , Hanns P. Muller , Rolf Dhein
IPC分类号： C07C275/54 , C07C273/18 , C07C275/00 , C07D251/34 , C08G18/08 , C08G18/62 , C08G18/78 , C08G18/79 , C08G18/80
CPC分类号： C07D251/34 , C08G18/0819 , C08G18/6216 , C08G18/7818 , C08G18/791 , C08G18/8061 , C08G18/807
摘要： The present invention is directed to water soluble or dispersible blocked polyisocyanates which contain(a) a statistical average per molecule of at least one structural unit corresponding to the formula:B--CO--NH-- wherein B denotes a group obtainable by removal of the acidic hydrogen atom from a monofunctional blocking agent for organic isocyanates and(b) structural units corresponding to the formula ##STR1## in a quantity sufficient to ensure the solubility or dispersibility of the blocked polyisocyanate in water,the blocked polyisocyanates containing on statistical average a total of at least two structural units corresponding to the formulae (a) and (b) per molecule.The present invention also relates to a process for the preparation of these blocked polyisocyanates and to their use in combination with water soluble or dispersible organic compounds containing at least two isocyanate-reactive groups for the production of coated substrates which are cured by heating.
摘要翻译：本发明涉及水溶性或分散性封端多异氰酸酯，其含有（a）每分子至少一个对应于下式的结构单元的统计平均数：B-CO-NH-，其中B表示可通过除去酸来自用于有机异氰酸酯的单官能封端剂的氢原子和（b）对应于式“IMAGE”的结构单元，其量足以确保封端多异氰酸酯在水中的溶解度或分散性，所述封闭多异氰酸酯含有统计学上的平均值每个分子对应于式（a）和（b）的至少两个结构单元。本发明还涉及一种制备这些封端多异氰酸酯的方法，以及它们与含有至少两个异氰酸酯反应性基团的水溶性或分散性有机化合物的组合用于生产通过加热固化的涂覆基材的用途。

9. 发明授权

US4619966A Process for the production of coated substrates 失效
标题翻译：生产涂层基材的方法
公开(公告)号：US4619966A
公开(公告)日：1986-10-28
申请号：US795965
申请日：1985-11-07
申请人： Walter Schafer , Manfred Hajek , Hanns P. Muller , Rolf Dhein , Rolf Kuchenmeister , Armin Sickert
发明人： Walter Schafer , Manfred Hajek , Hanns P. Muller , Rolf Dhein , Rolf Kuchenmeister , Armin Sickert
IPC分类号： B05D5/00 , B05D7/24 , B05D7/26 , C08G18/08 , C08G18/28 , C08G18/38 , C08G18/83 , C09D175/00 , C08L75/04
CPC分类号： C08G18/3838 , C08G18/0819 , C08G18/285 , C08G18/83
摘要： The present invention is directed to a process for the production of water- and solvent-resistant coated substrates by coating heat-resistant substrates with a solution or dispersion of an anionic group-containing polyisocyanate addition product in an aqueous solvent or dispersant and subsequently thermally treating the coating at a temperature of about 60.degree. to 200.degree. C., with evaporation or vaporization of the solvent or dispersant and simultaneous crosslinking of the polyisocyanate addition product which has been applied to the substrate, characterized in that incorporated anionic structural units corresponding to the formula ##STR1## are used in a quantity of about 5 to 1000 milliequivalents per 100 g of solids and the solids are based on reaction products of organic polyisocyanates with salts of cyanamide and bases selected from ammonia, primary and secondary amines having a minimum pKb value of 3.1, tertiary amines and mixtures thereof. The present invention also relates to the aqueous solutions or dispersions of anionically-modified polyisocyanate addition products.
摘要翻译：本发明涉及通过用含有阴离子基团的多异氰酸酯加成产物在水性溶剂或分散剂中的溶液或分散体涂覆耐热基材并随后热处理来生产耐水和耐溶剂的涂布基材的方法该涂层在约60℃至200℃的温度下，通过溶剂或分散剂的蒸发或蒸发，以及已经施加到基材上的多异氰酸酯加成产物的同时交联，其特征在于结合的阴离子结构单元对应于式“IMAGE”的使用量为每100g固体约5至1000毫当量，固体是基于有机多异氰酸酯与氰胺和选自氨，最小pKb值的伯胺和仲胺的碱的反应产物 3.1，叔胺及其混合物。本发明还涉及阴离子改性的多异氰酸酯加成产物的水溶液或分散体。

10. 发明授权

US4611034A Branched thermoplastically processible impact-resistant polyamides 失效
标题翻译：分支热塑性可加工的耐冲击聚酰胺
公开(公告)号：US4611034A
公开(公告)日：1986-09-09
申请号：US749999
申请日：1985-07-01
申请人： Rolf-Volker Meyer , Friedrich Fahnler , Rolf Dhein , Dietrich Michael , Kurt Weirauch , Walter Schafer
发明人： Rolf-Volker Meyer , Friedrich Fahnler , Rolf Dhein , Dietrich Michael , Kurt Weirauch , Walter Schafer
IPC分类号： C08G69/00 , C08G18/10 , C08G18/80 , C08G69/14 , C08G69/18 , C08G69/20 , C08G69/40 , C08F283/04
CPC分类号： C08G69/40 , C08G18/10 , C08G18/8074 , C08G69/18
摘要： Polyamide block copolymers obtained by activated anionic polymerization of lactams having at least 5 ring members in the presence of basic catalysts, polyisocyanates as activators and amino-terminated polyethers, which are characterized in that the amino-terminated polyethers have a functionality of at least 3.0 preferably at least 3.2, and a molecular weight of at least 3500, and the polyisocyanates are aliphatic or cycloaliphatic polyisocyanates.
摘要翻译：通过在碱性催化剂，多异氰酸酯作为活化剂和氨基封端的聚醚存在下具有至少5个环成员的内酰胺的活性阴离子聚合获得的聚酰胺嵌段共聚物，其特征在于氨基封端的聚醚具有至少3.0的官能度至少3.2，分子量至少为3500，多异氰酸酯是脂族或脂环族多异氰酸酯。

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