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1. 发明授权

US5292807A Compositions of cyclic isourea component with carboxyl component 失效
标题翻译：具有羧基成分的环状异脲组分的组成
公开(公告)号：US5292807A
公开(公告)日：1994-03-08
申请号：US9516
申请日：1993-01-27
申请人： Walter Schafer , Hanns P. Muller , Hans-Joachim Kreuder , Manfred Bock , Knud Reuter
发明人： Walter Schafer , Hanns P. Muller , Hans-Joachim Kreuder , Manfred Bock , Knud Reuter
IPC分类号： B05D1/02 , C08G18/10 , C08G71/00 , C08G73/00 , C09D133/08 , C09D175/00 , C09D175/02 , C08G12/32 , C08G18/38 , C08G59/14 , C08L33/08
CPC分类号： C08G18/10 , C09D133/08
摘要： The present invention relates to compositions which are storage stable at room temperature and containA) at least one compound having at least two cyclic isourea groups per molecule andB) at least one compound having at least two carboxyl groups per molecule,in an amount sufficient to provide a molar ratio of isourea groups to carboxyl groups of 0.5:1 to 1.5:1.
摘要翻译：本发明涉及在室温下储存稳定的组合物，其含有A）至少一种每分子具有至少两个环状异脲基团的化合物，和B）至少一种每分子具有至少两个羧基的化合物，其量足够以使异脲与羧基的摩尔比为0.5:1-1.5:1。

2. 发明授权

US5534601A Polyisocyanate-modified dicarboxylic (poly) anhydrides 失效
标题翻译：多异氰酸酯改性二羧酸（聚）酸酐
公开(公告)号：US5534601A
公开(公告)日：1996-07-09
申请号：US504159
申请日：1995-07-19
申请人： Knud Reuter , Walter Schafer , Hanns P. Muller , Hans-Ulrich Meier-Westhues , Lothar Kahl , Manfred Bock
发明人： Knud Reuter , Walter Schafer , Hanns P. Muller , Hans-Ulrich Meier-Westhues , Lothar Kahl , Manfred Bock
IPC分类号： C08G18/02 , C08G18/34 , C08G18/64 , C09D5/03 , C09D5/46 , C09D7/12 , C09D163/00 , C09D175/00 , C09D175/04
CPC分类号： C08G18/64 , C08G18/34 , C09D163/00 , C08G2150/20
摘要： Polyisocyanate-modified dicarboxylic (poly)anhydrides which are solid below 40.degree. C., liquid above 120.degree. C. and based on the reaction product of organic polyisocyanates with more than equivalent quantities, based on the NCO/COOH reaction, of dicarboxylic (poly)anhydrides containing free carboxyl groups and optional subsequent modification of the reaction product with less than equivalent quantities, based on the anhydride groups, of anhydride-reactive amino and/or hydroxyl groups; and powder coating compositions containing as binder these polyisocyanate-modified dicarboxylic (poly)anhydrides as curing agents for polyepoxides.
摘要翻译：固体低于40℃的多异氰酸酯改性的二羧酸（聚）酸酐，液体高于120℃，基于NCO / COOH反应的有机多异氰酸酯与多于等当量的反应产物的二羧酸（聚）含有游离羧基的酸酐和任选的随后的基于酸酐基团的酸酐反应性氨基和/或羟基基团的等价量的反应产物的随后修饰; 和作为粘合剂的这些多异氰酸酯改性的二羧酸（聚）酸酐作为聚环氧化物固化剂的粉末涂料组合物。

3. 发明授权

US4900800A Powder lacquer and its use for coating heat-resistant substrates 失效
标题翻译：粉末漆及其用于涂覆耐热基材的用途
公开(公告)号：US4900800A
公开(公告)日：1990-02-13
申请号：US73927
申请日：1987-07-15
申请人： Reinhard Halpaap , Josef Pedain , Hans-Joachim Kreuder , Gerhard Klein , Walter Schafer , Dieter Arlt
发明人： Reinhard Halpaap , Josef Pedain , Hans-Joachim Kreuder , Gerhard Klein , Walter Schafer , Dieter Arlt
IPC分类号： C08G18/72 , C08G18/02 , C08G18/16 , C08G18/73 , C08G18/79 , C08G18/80 , C09D5/03 , C09D5/46 , C09D175/00 , C09D175/04
CPC分类号： C08G18/8058 , C08G18/791 , C08G18/8009 , C08G2150/20
摘要： The present invention relates to a powder lacquer containing a mixture of(A) a polyisocyanate component in power form which is solid below about 40.degree. C. and liquid above about 150.degree. C. and(B) a organic polyhydroxyl component in powder form which is solid below about 40.degree. C. and liquid above about 150.degree. C.,components (A) and (B) being present in quantities corresponding to an equivalent ratio of isocyanate groups to hydroxyl groups of about 0.6:1 to 1.2:1, characterized in that component (A) is based on a polyisocyanate or polyisocyanate mixture which(a) does not contain any blocking agents for isocyanate groups,(b) has a content of free isocyanate groups (expressed as NCO) attached to tertiary, aliphatic or cycloaliphatic carbon atoms of about 8 to 24% by weight and an average NCO functionality of at least 2.1,(c) has a urethane group content (expressed as --NH--CO--O--) of about 3 to 30% by weight and(d) has an isocyanurate group content (expressed as C.sub.3 N.sub.3 O.sub.3) of 0 to about 30% by weight.The present invention also relates to the use of this powder lacquer for the production of coatings on heat-resistant substrates by methods known in powder lacquer technology.
摘要翻译：本发明涉及一种粉末漆，其含有（A）固体低于约40℃的功率形式的多异氰酸酯组分和高于约150℃的液体的混合物和（B）粉末形式的有机多羟基组分，固体低于约40℃，液体高于约150℃，组分（A）和（B）的存在量相当于异氰酸酯基与羟基的当量比为约0.6:1至1.2:1，其特征在于组分（A）是基于多异氰酸酯或多异氰酸酯混合物，其中（a）不含任何异氰酸酯基团的封端剂，（b）具有连接到叔脂族或叔碳原子上的游离异氰酸酯基团（表示为NCO）约8至24重量％的脂环族碳原子和平均NCO官能度至少为2.1，（c）具有约3至30重量％的氨基甲酸酯基含量（表示为-NH-CO-O-）和（ d）具有0至约的异氰脲酸酯基含量（表示为C 3 N 3 O 3） 30重量％。本发明还涉及这种粉末漆用于通过粉末漆技术中已知的方法在耐热基材上生产涂层的用途。

4. 发明授权

US4707386A Process for the production of sheet structures 失效
标题翻译：生产薄片结构的方法
公开(公告)号：US4707386A
公开(公告)日：1987-11-17
申请号：US944782
申请日：1986-12-22
申请人： Walter Schafer , Hanns P. Muller , Rolf Kuchenmeister , Armin Sickert
发明人： Walter Schafer , Hanns P. Muller , Rolf Kuchenmeister , Armin Sickert
IPC分类号： C09D175/04 , B05D7/26 , C08G59/40 , C08L63/00 , C09D163/00 , C09D175/00 , C09J175/00 , B05D3/02
CPC分类号： C08L63/00 , C08G59/4014 , C09D175/00 , C09J175/00
摘要： The present invention relates to a process for the production of water- and solvent-resistant coatings by coating substrates with an aqueous coating composition containing as binder a mixture of(1) reaction products, containing anionic structural units of the formula ##STR1## in a quantity of 5 to 1200 milliequivalents per 100 g of said reaction products, obtained by reacting organic polyisocyanates with salts of cyanamide and bases selected from ammonia, volatile primary and secondary amines having a pKb-value of at least 3.1 and any volatile aliphatic tertiary amines and(2) polyepoxides having at least two epoxide groups per molecule and an epoxide equivalent of at least about 80, said polyepoxides being used in a quantity corresponding to an equivalent ratio of epoxide groups to anionic structural units of about 0.1:1 to 3:1, andcross-linking the binder at a temperature of about 5 to 200.degree. C. The present invention is also directed to the aqueous coating composition based on components 1 and 2.
摘要翻译：本发明涉及一种通过用水性涂料组合物涂覆基材来生产耐水和耐溶剂的涂料的方法，该水性涂料组合物含有（1）含有下式的阴离子结构单元的反应产物的混合物：通过使有机多异氰酸酯与氰胺和选自氨的碱，pKb值至少为3.1的挥发性伯和仲胺反应获得的每100克所述反应产物的量为5至1200毫当量，以及任何挥发性脂族叔胺，（2）每分子具有至少两个环氧基团和至少约80个环氧当量的聚环氧化物，所述聚环氧化物的使用量相当于环氧基团与阴离子结构单元的当量比为约0.1:1至3:1 并在约5至200℃的温度下交联粘合剂。本发明还涉及基于化合物的水性涂料组合物 1号和2号。

5. 发明授权

US4918135A Process for the preparation of aqueous polymer dispersions the dispersions obtained by the process and their use for the production of coatings 失效
标题翻译：制备聚合物水性聚合物的方法分散了通过该方法获得的分散体及其用于生产涂料的用途
公开(公告)号：US4918135A
公开(公告)日：1990-04-17
申请号：US335816
申请日：1989-04-10
申请人： Joachim Probst , Walter Schafer , Klaus Schuster , Heinrich Alberts , Hanns P. Muller , Adolf Schmidt , Wolfhart Wieczorrek
发明人： Joachim Probst , Walter Schafer , Klaus Schuster , Heinrich Alberts , Hanns P. Muller , Adolf Schmidt , Wolfhart Wieczorrek
IPC分类号： B01F17/52 , C08F2/24 , C08F2/26 , C09D133/06
CPC分类号： C08F2/24 , C09D133/06
摘要： An improved coating for heat resistant substrates is an aqueous dispersion of polymers prepared by polymerization of olefinically unsaturated monomers in an aqueous medium in the presence of radical formers and emulsifiers, wherein the emulsifiers are polyisocyanate addition products having a molecular weight below 20,000 and containing from 5 to 1000 milliequivalents of anionic structures corresponding to the following formula--NH--CO--N.sup..crclbar. --C.tbd.Nincorporated therein per 100 g of solids content.
摘要翻译：用于耐热基材的改进的涂层是通过在自由基形成剂和乳化剂存在下在水性介质中聚合烯属不饱和单体制备的聚合物的水分散体，其中乳化剂是分子量低于20,000的多异氰酸酯加成产物，并含有5 至每1000克固体含量相应于下式-NH-CO-N（ - ） - C 3BOND N的1000毫当量阴离子结构。

6. 发明授权

US4895921A Water soluble or dispersible blocked polyisocyanates and a process for their preparation and use 失效
标题翻译：水溶性或分散性封端多异氰酸酯及其制备和使用方法
公开(公告)号：US4895921A
公开(公告)日：1990-01-23
申请号：US253179
申请日：1988-10-04
申请人： Walter Schafer , Hanns P. Muller , Rolf Dhein
发明人： Walter Schafer , Hanns P. Muller , Rolf Dhein
IPC分类号： C07C275/54 , C07C273/18 , C07C275/00 , C07D251/34 , C08G18/08 , C08G18/62 , C08G18/78 , C08G18/79 , C08G18/80
CPC分类号： C07D251/34 , C08G18/0819 , C08G18/6216 , C08G18/7818 , C08G18/791 , C08G18/8061 , C08G18/807
摘要： The present invention is directed to water soluble or dispersible blocked polyisocyanates which contain(a) a statistical average per molecule of at least one structural unit corresponding to the formula:B--CO--NH-- wherein B denotes a group obtainable by removal of the acidic hydrogen atom from a monofunctional blocking agent for organic isocyanates and(b) structural units corresponding to the formula ##STR1## in a quantity sufficient to ensure the solubility or dispersibility of the blocked polyisocyanate in water,the blocked polyisocyanates containing on statistical average a total of at least two structural units corresponding to the formulae (a) and (b) per molecule.The present invention also relates to a process for the preparation of these blocked polyisocyanates and to their use in combination with water soluble or dispersible organic compounds containing at least two isocyanate-reactive groups for the production of coated substrates which are cured by heating.
摘要翻译：本发明涉及水溶性或分散性封端多异氰酸酯，其含有（a）每分子至少一个对应于下式的结构单元的统计平均数：B-CO-NH-，其中B表示可通过除去酸来自用于有机异氰酸酯的单官能封端剂的氢原子和（b）对应于式“IMAGE”的结构单元，其量足以确保封端多异氰酸酯在水中的溶解度或分散性，所述封闭多异氰酸酯含有统计学上的平均值每个分子对应于式（a）和（b）的至少两个结构单元。本发明还涉及一种制备这些封端多异氰酸酯的方法，以及它们与含有至少两个异氰酸酯反应性基团的水溶性或分散性有机化合物的组合用于生产通过加热固化的涂覆基材的用途。

7. 发明授权

US4619966A Process for the production of coated substrates 失效
标题翻译：生产涂层基材的方法
公开(公告)号：US4619966A
公开(公告)日：1986-10-28
申请号：US795965
申请日：1985-11-07
申请人： Walter Schafer , Manfred Hajek , Hanns P. Muller , Rolf Dhein , Rolf Kuchenmeister , Armin Sickert
发明人： Walter Schafer , Manfred Hajek , Hanns P. Muller , Rolf Dhein , Rolf Kuchenmeister , Armin Sickert
IPC分类号： B05D5/00 , B05D7/24 , B05D7/26 , C08G18/08 , C08G18/28 , C08G18/38 , C08G18/83 , C09D175/00 , C08L75/04
CPC分类号： C08G18/3838 , C08G18/0819 , C08G18/285 , C08G18/83
摘要： The present invention is directed to a process for the production of water- and solvent-resistant coated substrates by coating heat-resistant substrates with a solution or dispersion of an anionic group-containing polyisocyanate addition product in an aqueous solvent or dispersant and subsequently thermally treating the coating at a temperature of about 60.degree. to 200.degree. C., with evaporation or vaporization of the solvent or dispersant and simultaneous crosslinking of the polyisocyanate addition product which has been applied to the substrate, characterized in that incorporated anionic structural units corresponding to the formula ##STR1## are used in a quantity of about 5 to 1000 milliequivalents per 100 g of solids and the solids are based on reaction products of organic polyisocyanates with salts of cyanamide and bases selected from ammonia, primary and secondary amines having a minimum pKb value of 3.1, tertiary amines and mixtures thereof. The present invention also relates to the aqueous solutions or dispersions of anionically-modified polyisocyanate addition products.
摘要翻译：本发明涉及通过用含有阴离子基团的多异氰酸酯加成产物在水性溶剂或分散剂中的溶液或分散体涂覆耐热基材并随后热处理来生产耐水和耐溶剂的涂布基材的方法该涂层在约60℃至200℃的温度下，通过溶剂或分散剂的蒸发或蒸发，以及已经施加到基材上的多异氰酸酯加成产物的同时交联，其特征在于结合的阴离子结构单元对应于式“IMAGE”的使用量为每100g固体约5至1000毫当量，固体是基于有机多异氰酸酯与氰胺和选自氨，最小pKb值的伯胺和仲胺的碱的反应产物 3.1，叔胺及其混合物。本发明还涉及阴离子改性的多异氰酸酯加成产物的水溶液或分散体。

8. 发明授权

US4921996A Isocyanato-acylurethanes, a process for their preparation and their use 失效
标题翻译：异氰酸酯 - 氨基甲酸酯，其制备方法及其用途
公开(公告)号：US4921996A
公开(公告)日：1990-05-01
申请号：US227980
申请日：1988-08-02
申请人： Walter Schafer , Hanns P. Muller , Tillmann Hassel
发明人： Walter Schafer , Hanns P. Muller , Tillmann Hassel
IPC分类号： C07C275/60 , C07C67/00 , C07C239/00 , C08F20/36 , C08G18/70 , C08G18/71 , C08G18/78
CPC分类号： C08G18/714 , C08F20/36 , C08G18/701 , C08G18/7806
摘要： The present invention relates to isocyanto-acylurethanes corresponding to Formula I ##STR1## wherein R has a valency of m+n and is a hydrocarbon group,R' is a hydrocarbon group andm and n may be identical or different, and each have a value of 1 or 2.The present invention also relates to a process for preparation of these isocyanato-acylurethanes which comprises reacting isocyanato-carboxylic acid chlorides with carbamic acid esters. Finally, the present invention is directed to the use of these isocyanato-acylurethanes as intermediate products for the production of thermally cross-linkable synthetic resins or synthetic resin precursors and also as intermediate products for the preparation of cross-linking agents for synthetic resins.
摘要翻译：本发明涉及对应于式I的异氰酸基 - 酰基氨基甲酸酯（I）其中R具有m + n的化合价并且是烃基，R'是烃基，m和n可以相同或不同，以及各自具有1或2的值。本发明还涉及这些异氰酸酯基 - 氨基甲酸酯的制备方法，其包括使异氰酸根合羧酸氯化物与氨基甲酸酯反应。最后，本发明涉及这些异氰酸酯基 - 氨基甲酸酯作为生产可热交联的合成树脂或合成树脂前体的中间产物以及用作制备用于合成树脂的交联剂的中间产品的用途。

9. 发明授权

US4904750A Ester-urethane derivatives of (meth)-acrylic acid for dental materials 失效
标题翻译：用于牙科材料的（甲基）丙烯酸的酯 - 氨基甲酸酯衍生物
公开(公告)号：US4904750A
公开(公告)日：1990-02-27
申请号：US287424
申请日：1988-12-20
申请人： Jurgen Reiners , Carlhans Suling , Walter Schafer , Hanns P. Muller , Wolfgang Podszun , Jens Winkel
发明人： Jurgen Reiners , Carlhans Suling , Walter Schafer , Hanns P. Muller , Wolfgang Podszun , Jens Winkel
IPC分类号： A61K6/083 , A61K6/09 , C07C271/22 , C08F20/34 , C08F220/36 , C08F290/00 , C08F299/00 , C08G18/67 , C08G18/72
CPC分类号： A61K6/0017 , A61K6/09 , C07C271/22 , C08G18/672 , C08G18/72
摘要： Dental fillings, coatings and teeth are formed of polymers and copolymers of a polyfunctional ester-urethane derivative of (meth)-acrylic acid of the formula ##STR1## in which A is a straight-chain or branched aliphatic radical which has 2 to 20 carbon atoms and optionally contains 1 to 3 oxygen bridges, an aromatic radical with 6 to 24 carbon atoms, an araliphatic radical with 7 to 26 carbon atoms or a cycloaliphatic radical with 6 to 26 carbon atoms,r denotes the number of chains starting from A and denotes a number from 2 to 6,R.sup.1 and R.sup.2 are identical and denote hydrogen or are different and denote hydrogen and methyl,n denotes a number from 0 to 5 independently for each chain starting from A,X stands for the group ##STR2## in which Y denotes a divalent (cyclo)aliphatic radical which has 2 to 15 carbon atoms and optionally contains ester, ether or urethane groups,Z denotes a divalent straight-chain or branched aliphatic hydrocarbon radical which has 3 to 15 carbon atoms and can optionally contain 1 to 3 oxygen bridges and can optionally be substituted by 1 to 4 additional (meth)-acrylate radicals andR.sup.3 denotes hydrogen or methyl independently for each chain starting from A.
摘要翻译：牙科填充物，涂料和牙齿由式（IMA）（I）的（甲基）丙烯酸的多官能酯 - 氨基甲酸酯衍生物的聚合物和共聚物形成，其中A是直链或支链脂族基团，其具有2 至20个碳原子，并且任选地含有1至3个氧桥，具有6至24个碳原子的芳族基团，具有7至26个碳原子的芳脂族基团或具有6至26个碳原子的脂环族基团，r表示链起始数从A表示2至6的数，R1和R2相同并且表示氢或不同，表示氢和甲基，n表示从A开始独立地为0至5的数，X表示< IMAGE>其中Y表示具有2至15个碳原子并且任选地含有酯，醚或氨基甲酸酯基团的二价（环）脂族基团，Z表示具有3至15个碳原子的二价直链或支链脂族烃基， ca n任选地含有1至3个氧桥，并且可以任选地被1至4个另外的（甲基）丙烯酸酯基团取代，并且对于从A开始的每个链，R 3表示氢或甲基。

10. 发明授权

US4739094A Alkoxylated aminopolyethers, a process for their preparation 失效
标题翻译：烷氧基化氨基聚醚，其制备方法
公开(公告)号：US4739094A
公开(公告)日：1988-04-19
申请号：US807388
申请日：1985-12-10
申请人： Jan Mazanek , Hanns P. Muller , Roland Nast , Wolfgang Oberkirch , Franz-Moritz Richter , Walter Schafer
发明人： Jan Mazanek , Hanns P. Muller , Roland Nast , Wolfgang Oberkirch , Franz-Moritz Richter , Walter Schafer
IPC分类号： F23K1/02 , C08G65/26 , C08G65/32 , C10L1/32
CPC分类号： C10L1/326 , C08G65/2624
摘要： New alkoxylated aminopolyethers of the formula ##STR1## in which Q denotes a polyalkylene oxide radical which has a valency corresponding to n, which has a structure derived from an aminopolyether by removal of the terminal amino groups and which has an average molecular weight of 82 to 30,000,A.sub.1 and A.sub.2 denote identical or different mono- or polyalkylene oxide radicals of the type (RO).sub.y,whereineach radical R represents an alkylene radical with 2 to 40 C atoms andy represents an integer from 1 to 200,B.sub.1 and B.sub.2 denote identical or different mono- or polyalkylene oxide radicals of the type (R'O).sub.z,whereinat least 50% of the R' radicals represent a --CH.sub.2 --CH.sub.2 -- group,the other R' radicals which may be present each represent an alkylene radical with 3 to 40 C atoms andz represents an integer from 1 to 300,Z denotes hydrogen, ##STR2## wherein M.sup..sym. represents one equivalent of a metal ion or represents NH.sub.4.sup..sym. andn denotes an integer from 1 to 30,a process for their preparation and coal/water slurries containing them.
摘要翻译：其中Q表示具有对应于n的化合价的聚亚烷基氧基的新的烷氧基化氨基聚醚，其具有通过除去末端氨基而衍生自氨基聚醚的结构，其平均分子量为82〜 30,000，A1和A2表示类型（RO）y相同或不同的单 - 或聚环氧烷基，其中每个基团R表示具有2至40个C原子的亚烷基，y表示1至200的整数，B1和B2 表示类型（R'O）z的相同或不同的单 - 或聚环氧烷基团，其中至少50％的R'基团表示-CH 2 -CH 2 - 基团，可以存在的另一个R'基团表示具有3至40个C原子的亚烷基，z表示1至300的整数，Z表示氢，其中M（+）表示1当量的金属离子或表示NH 4（+），n表示 1〜30，其制备方法和煤/ 含水的泥浆含有它们。

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