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1. 发明授权

US06268415B1 Stabilized adhesive compositions containing highly soluble, photostable benzotriazole UV absorbers and laminated articles derived therefrom 有权
标题翻译：含有高度可溶性，光稳定性苯并三唑UV吸收剂和由其衍生的层压制品的稳定化粘合剂组合物
公开(公告)号：US06268415B1
公开(公告)日：2001-07-31
申请号：US09303582
申请日：1999-05-03
申请人： Walter Renz , Joseph Suhadolnik , Mervin Gale Wood, Jr. , Ramanathan Ravichandran , Revathi Iyengar , Luther A. R. Hall
发明人： Walter Renz , Joseph Suhadolnik , Mervin Gale Wood, Jr. , Ramanathan Ravichandran , Revathi Iyengar , Luther A. R. Hall
IPC分类号： C08K534
CPC分类号： B32B17/10761 , C08K5/3475 , C09J11/06 , F24S23/82 , Y02E10/40 , Y10T428/31551 , Y10T428/31786 , Y10T428/31855
摘要： Adhesive compositions are rendered stable against degradation caused by ultraviolet light through the incorporation of a highly soluble, photostable benzotriazole UV absorber which is substituted in the ortho position of the hydroxyphenyl ring by &agr;-cumyl or phenyl. Examples of such compounds are 2-(2-hydroxy-3-&agr;-cumyl-5-tert-octylphenyl)-2H-benzotriazole, 5-chloro-2-(2-hydroxy-3-&agr;-cumyl-5-tert-octylphenyl)-2H-benzotriazole, 5-fluoro-2-(2-hydroxy-3-&agr;-cumyl-5-tert-octylphenyl)-2H-benzotriazole, 2-(2-hydroxy-3-&agr;-cumyl-5-tert-butylphenyl)-2H-benzotriazole, 5-chloro-2-(2-hydroxy-3-&agr;-cumyl-5-tert-butylphenyl)-2H-benzotriazole and 5-fluoro-2-(2-hydroxy-3-&agr;-cumyl-5-tert-butylphenyl)-2H-benzotriazole. These compounds exhibit excellent photostability and are highly soluble in adhesive formulations. The laminated articles derived from these compositions include, for example, solar control films, films and glazings, UV absorbing glasses and glass coatings, windscreens, retroreflective sheetings and signs, solar reflectors, optical films and the like.
摘要翻译：粘合剂组合物通过并入通过α-枯基或苯基在羟基苯基的邻位被取代的高度可溶的光稳定的苯并三唑UV吸收剂而使紫外线引起的降解变得稳定。这些化合物的实例是2-（2-羟基-3-α-枯基-5-叔辛基苯基）-2H-苯并三唑，5-氯-2-（2-羟基-3-α-枯基-5-叔丁基苯基）辛基苯基）-2H-苯并三唑，5-氟-2-（2-羟基-3-α-枯基-5-叔辛基苯基）-2H-苯并三唑，2-（2-羟基-3-α-枯基-5- 叔丁基苯基）-2H-苯并三唑，5-氯-2-（2-羟基-3-α-枯基-5-叔丁基苯基）-2H-苯并三唑和5-氟-2-（2-羟基-3- α-枯基-5-叔丁基苯基）-2H-苯并三唑。这些化合物表现出优异的光稳定性，并且在粘合剂制剂中高度可溶。衍生自这些组合物的层压制品包括例如太阳能控制薄膜，薄膜和玻璃，紫外线吸收玻璃和玻璃涂层，挡风玻璃，反光片和标志，太阳能反射器，光学膜等。

2. 发明授权

US06187845B1 Stabilized adhesive compositions containing highly soluble, red-shifted, photostable benzotriazole UV absorbers and laminated articles derived therefrom 有权
标题翻译：含有高度可溶，红移，光稳定的苯并三唑UV吸收剂和由其衍生的层压制品的稳定的粘合剂组合物
公开(公告)号：US06187845B1
公开(公告)日：2001-02-13
申请号：US09303583
申请日：1999-05-03
申请人： Walter Renz , Mervin Gale Wood, Jr. , Joseph Suhadolnik , Ramanathan Ravichandran , Revathi Iyengar
发明人： Walter Renz , Mervin Gale Wood, Jr. , Joseph Suhadolnik , Ramanathan Ravichandran , Revathi Iyengar
IPC分类号： C08K53472
CPC分类号： B32B17/10743 , B32B17/10678 , C08K5/3475 , C09J11/06 , F24S23/82 , F24S2025/601 , Y02E10/40
摘要： Adhesive compositions are rendered stable against degradation caused by ultraviolet light through the incorporation of selected highly soluble, red-shifted, photostable benzotriazole UV absorbers which absorb light strongly in the 350 to 400 nm range. These UV absorbers exhibit excellent photostability and are highly soluble in adhesive formulations. The laminated articles derived from these compositions include, for example, solar control films, films and glazings, UV absorbing glasses and glass coatings, windscreens, retroreflective sheetings and signs, solar reflectors, optical films and the like.
摘要翻译：粘合剂组合物通过引入在350至400nm范围内强烈吸收光的所选择的高度可溶性，红移，光稳定的苯并三唑UV吸收剂而使紫外线引起的降解变得稳定。这些UV吸收剂表现出优异的光稳定性，并且在粘合剂配方中高度可溶。衍生自这些组合物的层压制品包括例如太阳能控制薄膜，薄膜和玻璃，紫外线吸收玻璃和玻璃涂层，挡风玻璃，反光片和标志，太阳能反射器，光学膜等。

3. 发明授权

US06191199B1 Stabilized adhesive compositions containing highly soluble, high extinction photostable hydroxyphenyl-s-triazine UV absorbers and laminated articles derived therefrom 有权
标题翻译：含有高度可溶，高消光的光稳定性羟基苯基-s-三嗪紫外线吸收剂和由其衍生的层压制品的稳定粘合剂组合物
公开(公告)号：US06191199B1
公开(公告)日：2001-02-20
申请号：US09303581
申请日：1999-05-03
申请人： Walter Renz , Mervin Gale Wood, Jr. , Joseph Suhadolnik , Ramanathan Ravichandran , Revathi Iyengar
发明人： Walter Renz , Mervin Gale Wood, Jr. , Joseph Suhadolnik , Ramanathan Ravichandran , Revathi Iyengar
IPC分类号： C08K534
CPC分类号： B32B7/12 , B32B17/10678 , B32B17/10743 , B32B27/18 , B32B2307/40 , C09J11/06 , C09J11/08
摘要： Adhesive compositions are rendered stable against degradation caused by ultraviolet light through the incorporation of a highly soluble, high extinction, photostable hydroxyphenyl-s-triazine UV absorber. An example of such compounds is 2,4-bis(2,4-dimethylphenyl)-6-[2-hydroxy-4-(3-nonyloxy*-2-hydroxypropyloxy)-5-&agr;-cumylphenyl]-s-triazine (* denotes a mixture of octyloxy, nonyloxy and decyloxy groups). Such compounds exhibit high extinction, excellent photostability and are highly soluble in adhesive formulations. The laminated articles derived from these compositions include, for example, solar control films, films and glazings, UV absorbing glasses and glass coatings, windscreens, retroreflective sheetings and signs, solar reflectors, optical films and the like.
摘要翻译：粘合剂组合物通过引入高度可溶的高消光，光稳定的羟基苯基-s-三嗪UV吸收剂而使紫外线引起的降解变得稳定。这种化合物的实例是2,4-双（2,4-二甲基苯基）-6- [2-羟基-4-（3-壬基氧基-2-羟基丙氧基）-5-α-枯基苯基] -s-三嗪（ *表示辛氧基，壬氧基和癸氧基的混合物）。这些化合物具有高消光性，优异的光稳定性，并且在粘合剂制剂中高度可溶。衍生自这些组合物的层压制品包括例如太阳能控制薄膜，薄膜和玻璃，紫外线吸收玻璃和玻璃涂层，挡风玻璃，反光片和标志，太阳能反射器，光学膜等。

4. 发明授权

US06225384B1 Stabilized adhesive compositions containing highly soluble, high extinction, photostable hydroxyphenyl-s-trianzine UV absorbers and laminated articles derived therefrom 有权
标题翻译：含有高度可溶，高消光，光稳定的羟基苯基-s-三氮嗪紫外线吸收剂和由其衍生的层压制品的稳定粘合剂组合物
公开(公告)号：US06225384B1
公开(公告)日：2001-05-01
申请号：US09551033
申请日：2000-04-17
申请人： Walter Renz , Mervin Wood , Joseph Suhadonlik , Ramanathan Ravichandran , Revathi Iyengar , Pascal Hayoz
发明人： Walter Renz , Mervin Wood , Joseph Suhadonlik , Ramanathan Ravichandran , Revathi Iyengar , Pascal Hayoz
IPC分类号： C08K534
CPC分类号： B32B7/12 , B32B17/10678 , B32B17/10743 , B32B27/18 , B32B2307/40 , C09J11/06 , C09J11/08
摘要： Adhesive compositions are rendered stable against degradation caused by ultraviolet light through the incorporation of a highly soluble, high extinction, photostable hydroxyphenyl-s-triazine UV absorber or mixtures of s-triazine UV absorbers. An example of such compounds is 2,4-bis(2,4-dimethylphenyl)-6-[2-hydroxy-4-(3-nonyloxy*-2-hydroxypropyloxy)-5-&agr;-cumylphenyl]-s-triazine (* denotes a mixture of octyloxy, nonyloxy and decyloxy groups). Such compounds exhibit high extinction, excellent photostability and are highly soluble in adhesive formulations. The laminated articles derived from these compositions include, for example, solar control films, films and glazings, UV absorbing glasses and glass coatings, windscreens, retroreflective sheetings and signs, solar reflectors, optical films and the like.
摘要翻译：粘合剂组合物通过引入高度可溶，高消光，光稳定的羟基苯基-s-三嗪UV吸收剂或s-三嗪UV吸收剂的混合物而使紫外线引起的降解变得稳定。这种化合物的实例是2,4-双（2,4-二甲基苯基）-6- [2-羟基-4-（3-壬基氧基-2-羟基丙氧基）-5-α-枯基苯基] -s-三嗪（ *表示辛氧基，壬氧基和癸氧基的混合物）。这些化合物具有高消光性，优异的光稳定性，并且在粘合剂制剂中高度可溶。衍生自这些组合物的层压制品包括例如太阳能控制薄膜，薄膜和玻璃，紫外线吸收玻璃和玻璃涂层，挡风玻璃，反光片和标志，太阳能反射器，光学膜等。

5. 发明申请

US20050019507A1 Poly(viny lalcohol)-co-poly(n-vinyl formamide) copolymers 审中-公开
标题翻译：聚（乙烯醇）共聚物（n-乙烯基甲酰胺）共聚物
公开(公告)号：US20050019507A1
公开(公告)日：2005-01-27
申请号：US10499854
申请日：2002-12-16
申请人： Walter Renz , Ramanathan Ravichandran , Andrew Naisby , Joseph Suhadolnik , Mervin Wood , Rong Xiong
发明人： Walter Renz , Ramanathan Ravichandran , Andrew Naisby , Joseph Suhadolnik , Mervin Wood , Rong Xiong
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , C08F8/00 , C08F8/12 , C09D11/00 , B32B5/16
CPC分类号： C08F8/00 , B41M5/506 , B41M5/508 , B41M5/52 , B41M5/5218 , B41M5/5227 , B41M5/5236 , B41M5/5254 , B41M5/5281 , C08F8/12 , C09D11/30 , Y10T428/252 , Y10T428/254 , Y10T428/256 , Y10T428/258 , Y10T428/259 , Y10T428/31576 , Y10T428/31591 , Y10T428/31895 , C08F226/02 , C08F216/06 , C08F218/08
摘要： Disclosed are ink jet recording media systems that comprise a poly(vinyl alcohol)-co-poly(N-vinyl formamide) copolymer of the formula, wherein n is between 0 and about 20 mole percent, m is between about 50 and about 97 mole percent, x is between 0 and about 20 mole percent, y is between 0 and about 20 mole percent, z is between 0 and about 2 mole percent and x+y is between about 3 and about 20 mole percent, R1 and R3 are independently H; 3-propionic add or C1-C6 alkyl ester thereof; or is 2-methyl-3-propionic acid or C1-C6 alkyl ester thereof, and R2 and R4 are independently H or C1-C6 alkyl.
摘要翻译：公开了包含下式的聚（乙烯醇） - 共 - （N-乙烯基甲酰胺）共聚物的喷墨记录介质体系，其中n为0至约20摩尔％，m为约50至约97摩尔 x为0至约20摩尔％，y为0至约20摩尔％，z为0至约2摩尔％，x + y为约3至约20摩尔％，R1和R3独立地为 H; 3-丙酸加成或其C1-C6烷基酯; 或者是2-甲基-3-丙酸或其C1-C6烷基酯，R2和R4独立地是H或C1-C6烷基。

6. 发明授权

US07173071B2 Photo-cured and stabilized coatings 有权
标题翻译：光固化和稳定涂层
公开(公告)号：US07173071B2
公开(公告)日：2007-02-06
申请号：US10838473
申请日：2004-05-04
申请人： Joseph Suhadolnik , Mervin Wood , Ramanathan Ravichandran , Walter Renz , Andrea Roberts , Nancy Cliff , Eugene Sitzman , David Bramer
发明人： Joseph Suhadolnik , Mervin Wood , Ramanathan Ravichandran , Walter Renz , Andrea Roberts , Nancy Cliff , Eugene Sitzman , David Bramer
IPC分类号： C08J3/28 , C08K5/3475 , C08F2/50 , C09D4/02 , C09D175/16
CPC分类号： C09D4/06 , C09D4/00
摘要： Photo-curable coating formulations which comprise a durable and/or red-shifted reactable hydroxyphenylbenzotriazole ultraviolet light absorber (UVA) are effectively photocured employing a combination of α-hydroxy ketone and bisacylphosphine oxide photoinitiators. The reactable UVA's are reacted into the coating upon curing. The combination of the photoinitiators bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and 1-hydroxycyclohexylphenylketone is especially effective for this purpose.
摘要翻译：使用α-羟基酮和双酰基氧化膦光引发剂的组合，有效地光固化包含耐久和/或红移反应性羟基苯基苯并三唑紫外光吸收剂（UVA）的光固化涂料制剂。固化后可反应的UVA反应成涂层。光引发剂双（2,4,6-三甲基苯甲酰基）苯基氧化膦和1-羟基环己基苯基酮的组合对于此目的是特别有效的。

7. 发明申请

US20050123691A1 Photo-cured and stabilized coatings 审中-公开
标题翻译：光固化和稳定涂层
公开(公告)号：US20050123691A1
公开(公告)日：2005-06-09
申请号：US11035162
申请日：2005-01-13
申请人： Joseph Suhadolnik , Mervin Wood , Ramanathan Ravichandran , Walter Renz , Andrea Smith , Nancy Cliff , Eugene Sitzmann , David Bramer
发明人： Joseph Suhadolnik , Mervin Wood , Ramanathan Ravichandran , Walter Renz , Andrea Smith , Nancy Cliff , Eugene Sitzmann , David Bramer
IPC分类号： G03F7/004 , B05D3/06 , C08F2/48 , C09D4/00 , C09D4/06 , C09D5/32 , B05D3/00
CPC分类号： C08F2/48 , C09D4/06 , C08F290/14
摘要： Photo-cureable coating formulations which comprise a durable and/or red-shifted hydroxyphenylbenzotriazole ultraviolet light absorber (UVA) are effectively photocured employing a combination of α-hydroxy ketone and bisacylphosphine oxide photoinitiators. The combination of the photoinitiators bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and 1-hydroxycyclohexylphenylketone is especially effective for this purpose.
摘要翻译：使用α-羟基酮和双酰基氧化膦光引发剂的组合，可有效地光固化包含持久和/或红移羟基苯基苯并三唑紫外光吸收剂（UVA）的可光固化涂料配方。光引发剂双（2,4,6-三甲基苯甲酰基）苯基氧化膦和1-羟基环己基苯基酮的组合对于此目的是特别有效的。

8. 发明申请

US20050020729A1 Poly(vinylalcohol)-co-poly(vinylamine)polymers comprising functional moieties 失效
标题翻译：包含官能部分的聚（乙烯醇） - 共聚（乙烯基胺）聚合物
公开(公告)号：US20050020729A1
公开(公告)日：2005-01-27
申请号：US10499855
申请日：2002-12-16
申请人： Walter Renz , Ramanathan Ravichandran , Andrew Naisby , Joseph Suhadolnik , Melvin Wood , Rong Xiong
发明人： Walter Renz , Ramanathan Ravichandran , Andrew Naisby , Joseph Suhadolnik , Melvin Wood , Rong Xiong
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , C08F8/00 , C08F8/12 , C09D11/00 , C03C17/00 , C08F12/28 , C08K3/10 , C08K3/26 , C08K3/34 , C09D5/00
CPC分类号： B41M5/52 , B41M5/506 , B41M5/508 , B41M5/5218 , B41M5/5227 , B41M5/5236 , B41M5/5254 , B41M5/5281 , C08F8/00 , C08F8/12 , C09D11/30 , Y10T428/256 , Y10T428/263 , C08F216/06 , C08F226/02 , C08F218/08
摘要： The invention relates to poly(vinylalcohol)-co-poly(vinylamine) copolymers represented as formula (I), where B is greater than or equal to 1, L is independently of each other a chemical linking group which is —NH—, —N═, >N−, >N++
摘要翻译：本发明涉及式（I）表示的聚（乙烯醇） - 共聚（乙烯基胺）共聚物，其中B大于或等于1，L彼此独立地为-NH-， N =，> N-，> N + +， - 或-CO-，共聚物衍生自式（II）的预聚物，其中R 1和R 3独立地为H; 3-丙酸或其C1-C6烷基酯; 或者是2-甲基-3-丙酸或其C1-C6烷基酯，R2和R4独立地为H或C1-C6烷基，x + y + z为约3至约50摩尔％，q，n和m 一起构成摩尔百分数的剩余部分，指数x，y，z，n，m-和q独立地可以是0，如果q不是0，则b也可以是0。

9. 发明申请

US20070160780A1 Poly(vinyl alcohol)-co-poly(N-vinyl formamide) copolymers 审中-公开
标题翻译：聚（乙烯醇） - 共 - 聚（N-乙烯基甲酰胺）共聚物
公开(公告)号：US20070160780A1
公开(公告)日：2007-07-12
申请号：US11715779
申请日：2007-03-08
申请人： Walter Renz , Ramanathan Ravichandran , Andrew Naisby , Joseph Suhadolnik , Mervin Wood , Rong Xiong
发明人： Walter Renz , Ramanathan Ravichandran , Andrew Naisby , Joseph Suhadolnik , Mervin Wood , Rong Xiong
IPC分类号： B41M5/50
CPC分类号： C08F8/00 , B41M5/506 , B41M5/508 , B41M5/52 , B41M5/5218 , B41M5/5227 , B41M5/5236 , B41M5/5254 , B41M5/5281 , C08F8/12 , C09D11/30 , Y10T428/252 , Y10T428/254 , Y10T428/256 , Y10T428/258 , Y10T428/259 , Y10T428/31576 , Y10T428/31591 , Y10T428/31895 , C08F226/02 , C08F216/06 , C08F218/08
摘要： Disclosed are ink jet recording media systems that comprise poly(vinyl alcohol)-co-poly(N-vinyl formamide) copolymers of the formula wherein m is 0-15 mole percent, n is 50 to 99 mole percent and x is 1 to 50 mole percent.
摘要翻译：公开了包含下式的聚（乙烯醇） - 共 - （N-乙烯基甲酰胺）共聚物的喷墨记录介质体系，其中m为0-15摩尔％，n为50-99摩尔％，x为1-50 摩尔％。

10. 发明授权

US07384464B2 Ink jet and recording material 失效
标题翻译：喷墨和记录材料
公开(公告)号：US07384464B2
公开(公告)日：2008-06-10
申请号：US11086644
申请日：2005-03-22
申请人： Mervin G. Wood , Robert E. Detlefsen , Joseph Suhadolnik , Walter Renz
发明人： Mervin G. Wood , Robert E. Detlefsen , Joseph Suhadolnik , Walter Renz
IPC分类号： C09D11/02 , B41J2/01 , B41M5/00
CPC分类号： H01B7/046 , B41M5/5227 , C08K5/3412 , C09D7/48 , C09D11/30 , C09D11/38
摘要： The present invention relates to an ink-jet ink, an ink-jet recording material or an ink-jet system containing at least one water-soluble hindered amine compound of the general formula (I): wherein G1 and G2 are independently alkyl 1 to 4 carbon atoms or are together pentamethylene; Z1 and Z2 are each methyl, or Z1 and Z2 together form an unsubstituted linking moiety or a linking moiety substituted by one or more groups selected from an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or an urethane group; E is alkoxy of 1 to 18 carbon atoms, cycloalkoxy of 5 to 12 carbon atoms or aralkoxy of 7 to 15 carbon atoms, or E is —O-T-(OH)b; T is a straight or branched chain alkylene of 1 to 18 carbon atoms, cycloalkylene of 5 to 18 carbon atoms, cycloalkenylene of 5 to 18 carbon atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms substituted by phenyl or by phenyl substituted by one or two alkyl groups of 1 to 4 carbon atoms; b is 1, 2 or 3 with the proviso that b cannot exceed the number of carbon atoms in T, and when b is 2 or 3, each hydroxyl group is attached to a different carbon atoms of T; and, HY is an inorganic or organic acid; and, wherein the total change of cations is equal to the total charge of anions.
摘要翻译：本发明涉及含有至少一种通式（I）的水溶性受阻胺化合物的喷墨油墨，喷墨记录材料或喷墨系统：其中G 1 和G 2 2独立地是1至4个碳原子的烷基或者是五亚甲基; Z 1和Z 2各自为甲基，或Z 1和Z 2 2一起形成未取代的连接部分或由一个或多个选自酯，醚，羟基，氧代，羟腈，酰胺，氨基，羧基或氨基甲酸酯基团的基团取代的连接部分; E为1至18个碳原子的烷氧基，5至12个碳原子的环烷氧基或7至15个碳原子的芳烷氧基，或E为-O-T（OH）b。 T是1至18个碳原子的直链或支链亚烷基，5至18个碳原子的亚环烷基，5至18个碳原子的亚环烯基，1至4个碳原子被苯基或苯基取代的直链或支链亚烷基 1个或2个碳原子数为1〜4的烷基; b为1,2或3，条件是b不能超过T中的碳原子数，当b为2或3时，每个羟基与T的不同碳原子相连; HY为无机酸或有机酸; 并且其中阳离子的总变化等于阴离子的总电荷。

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