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    • 1. 发明授权
    • Method for the measurement of the total content of organic carbon and
nitrogen in water
    • 用于测量水中有机碳和氮的总含量的方法
    • US5292666A
    • 1994-03-08
    • US880576
    • 1992-05-08
    • Walter FabinskiPeter HubschmannPeter SchlauChristian Wolff
    • Walter FabinskiPeter HubschmannPeter SchlauChristian Wolff
    • G01N33/18G01N33/00G01N21/00
    • G01N33/1846Y10T436/176152Y10T436/177692Y10T436/23Y10T436/235
    • A method for measuring of the total content of organic carbon and of nitrogen in water. The total organic carbon value is obtained correctly as the sum of the liquid, dissolved, and solid materials of a sample of the water. The device comprises a non-dispersive infrared (NDIR) gas analyzer for the simultaneous measurement of the concentration of the gas components carbon dioxide CO.sub.2 and nitrogen oxide NO. The NDIR gas analyzer includes a phase separator (50), a thermal reactor (52), a double cooler (70), two valves (54, 56), as well as two amplifiers (58, 60) for the pneumatic signals of the receiver detectors (30, 36) with a display (62. 64) for the measured concentrations, total organic carbon and total nitrogen. The sample is split in a phase separator (50) into a gaseous and into a liquid part. The gaseous part, which comprises substantially the inorganic part of the carbon, the total inorganic carbon part in the form of carbon dioxide CO.sub.2 gas, is cooled in a cooler to such an extent that a substantial part its water vapor content is deposited in the cooler by condensation. The dried gaseous part is led as comparison gas through the comparison cuvette. This step serves to compensate the total inorganic carbon part of the sample and to compensate for unavoidable water vapor cross-sensitivities during the measurement of the carbon dioxide CO.sub.2 concentration and of the nitrogen oxide NO concentration.
    • 一种用于测量水中有机碳和氮的总含量的方法。 总有机碳值正确地作为水样品的液体,溶解和固体物质的总和获得。 该装置包括用于同时测量气体成分二氧化碳CO2和氮氧化物NO的浓度的非分散红外(NDIR)气体分析仪。 NDIR气体分析仪包括相分离器(50),热反应器(52),双重冷却器(70),两个阀(54,56)以及两个放大器(58,60),用于 接收器检测器(30,36),其具有用于测量浓度的显示器(62.64),总有机碳和总氮。 样品在相分离器(50)中分成气态并进入液体部分。 基本上包含碳的无机部分的气体部分是二氧化碳CO 2气体形式的总无机碳部分在冷却器中被冷却至使其大部分水汽含量沉积在冷却器中的程度 通过冷凝。 干燥的气体部分作为比较气体通过比较反应杯引导。 该步骤用于补偿样品的总无机碳部分并补偿在测量二氧化碳CO 2浓度和氮氧化物NO浓度期间不可避免的水蒸气交叉敏感性。
    • 2. 发明授权
    • Apparatus for the measurement of the total content of organic carbon and
nitrogen in water
    • 用于测量水中有机碳和氮的总含量的装置
    • US5340542A
    • 1994-08-23
    • US71106
    • 1993-06-04
    • Walter FabinskiPeter HubschmannPeter SchlauChristian Wolff
    • Walter FabinskiPeter HubschmannPeter SchlauChristian Wolff
    • G01N33/18G01N21/00G01N33/00
    • G01N33/1846Y10T436/176152Y10T436/177692Y10T436/23Y10T436/235
    • The invention relates to a method for measuring of the total content of organic carbon and of nitrogen in water. The total organic carbon value is obtained correctly as the sum of the liquid, dissolved, and solid materials of a sample of the water. The device comprises a non-dispersive infrared (NDIR) gas analyzer for the simultaneous measurement of the concentration of the gas components carbon dioxide CO.sub.2 and nitrogen oxide NO. The NDIR gas analyzer includes a phase separator (50), a thermal reactor (52), a double cooler (70), two valves (54, 56), as well as two amplifiers (58, 60) for the pneumatic signals of the receiver detectors (30, 36) with a display (62. 64) for the measured concentrations, total organic carbon and total nitrogen. The sample is split in a phase separator (50) into a gaseous and into a liquid part. The gaseous part, which comprises substantially the inorganic part of the carbon, the total inorganic carbon part in the form of carbon dioxide CO.sub.2 gas, is cooled in a cooler to such an extent that a substantial part its water vapor content is deposited in the cooler by condensation. The dried gaseous part is led as comparison gas through the comparison cuvette. This step serves to compensate the total inorganic carbon part of the sample and to compensate for unavoidable water vapor cross-sensitivities during the measurement of the carbon dioxide CO.sub.2 concentration and of the nitrogen oxide NO concentration.
    • 本发明涉及一种测量水中有机碳和氮的总含量的方法。 总有机碳值正确地作为水样品的液体,溶解和固体物质的总和获得。 该装置包括用于同时测量气体成分二氧化碳CO2和氮氧化物NO的浓度的非分散红外(NDIR)气体分析仪。 NDIR气体分析仪包括相分离器(50),热反应器(52),双重冷却器(70),两个阀(54,56)以及两个放大器(58,60),用于 接收器检测器(30,36),其具有用于测量浓度的显示器(62.64),总有机碳和总氮。 样品在相分离器(50)中分成气态并进入液体部分。 基本上包含碳的无机部分的气体部分是二氧化碳CO 2气体形式的总无机碳部分在冷却器中被冷却至使其大部分水汽含量沉积在冷却器中的程度 通过冷凝。 干燥的气体部分作为比较气体通过比较反应杯引导。 该步骤用于补偿样品的总无机碳部分并补偿在测量二氧化碳CO 2浓度和氮氧化物NO浓度期间不可避免的水蒸气交叉敏感性。