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1. 发明授权

US5773635A Preparation of polyenecarbonyl compounds having a high content of the all-E isomer, and of their acetals or ketals 失效
标题翻译：具有全E异构体含量高的多烯羰基化合物及其缩醛或缩酮的制备
公开(公告)号：US5773635A
公开(公告)日：1998-06-30
申请号：US498840
申请日：1995-07-06
申请人： Walter Dobler , Wolfgang Krause , Joachim Paust , Otto Worz , Udo Rheude , Wolfram Burst , Gunter Dauwel , Armin Bertram , Bernhard Schulz , Gunter Wegner , Peter Munster , Hansgeorg Ernst , Arno Kochner , Heinz Etzrodt
发明人： Walter Dobler , Wolfgang Krause , Joachim Paust , Otto Worz , Udo Rheude , Wolfram Burst , Gunter Dauwel , Armin Bertram , Bernhard Schulz , Gunter Wegner , Peter Munster , Hansgeorg Ernst , Arno Kochner , Heinz Etzrodt
IPC分类号： C07C51/16 , C07C403/00 , C07C403/20
CPC分类号： C07C403/20 , C07C403/16 , C07B2200/09 , C07C2101/16
摘要： A process for preparing polyenecarbonyl compounds having a high all-E content and their acetals or ketals by aldol condensation or Horner-Emmons reaction comprises carrying out the reaction, for the purposes of the preferred formation of a double bond of E configuration and in order to maintain the E configuration of the double bonds in the stating compounds as completely as possible, in the presence of oxygen or an oxygen-inert gas mixture or nitric oxide or a nitric oxide-inert gas mixture and/or in the presence of specific stable radicals and/or in the presence of quinones or quinone derivatives.
摘要翻译：通过醛醇缩合或霍纳 - 埃蒙斯反应制备具有高全E含量的多元羰基化合物及其缩醛或缩酮的方法包括进行反应，为了优选形成E构型的双键，为了在氧气或氧惰性气体混合物或一氧化氮或一氧化氮惰性气体混合物的存在下和/或在特定的稳定基团的存在下，尽可能地完全地保持化合物中双键的E构型和/或在醌或醌衍生物的存在下。

2. 发明授权

US5382732A 2,5-bis(1,1-dialkoxy-2-propyl)-2,5-dihydrofurans, the preparation thereof and the use thereof for the preparation of carotenoids 失效
标题翻译： 2,5-双（1,1-二烷氧基-2-丙基）-2,5-二氢呋喃，其制备方法及其用于制备类胡萝卜素
公开(公告)号：US5382732A
公开(公告)日：1995-01-17
申请号：US67618
申请日：1993-05-27
申请人： Juergen Frank , Udo Rheude , Bernhard Schulz , Joachim Paust , Eckhard Hickmann
发明人： Juergen Frank , Udo Rheude , Bernhard Schulz , Joachim Paust , Eckhard Hickmann
IPC分类号： B01J27/128 , B01J27/138 , C07B61/00 , C07C47/21 , C07C403/24 , C07D307/28 , C07C403/06
CPC分类号： C07C403/24 , C07D307/28
摘要： A process of preparing symmetric C.sub.40 -carotenoids by reacting a C.sub.15 -triphenylphosphonium salt of the formula ##STR1## and a 2,5-bis(1,1-dialkoxy-2-propyl)-2,5-dihydrofuran to form a reaction product containing a diacetyl and a triphenylphosphonium salt, adding a strong base to the reaction product to convert the triphenylphosphonium salt to a carbenium ion, hydrolyzing the diacetyl to a dialdehyde, subjecting the dialdehyde and the carbenium ion to a Wittig reaction to prepare a Wittig reaction product, and converting the Wittig reaction product to the C.sub.40 -carotenoid by acid treatment.
摘要翻译：通过使式（I）所示的C 15 - 三苯基鏻盐与2,5-双（1,1-二烷氧基-2-丙基）-2,5-二氢呋喃反应制备对称C 40 - 类胡萝卜素的方法，以形成反应产物含有二乙酰基和三苯基鏻盐，向反应产物中加入强碱以将三苯基鏻盐转化为碳鎓离子，将二乙酰基水解成二醛，使二醛和碳鎓离子进行维t希反应以制备Wittig反应产物，并通过酸处理将维蒂希反应产物转化为C40-类胡萝卜素。

3. 发明授权

US5300658A 2,5-bis(1,1-dialkoxy-2-propyl)-2,5-dihydrofurans, the preparation thereof and the use thereof for the preparation of carotenoids 失效
标题翻译： 2,5-双（1,1-二烷氧基-2-丙基）-2,5-二氢呋喃，其制备方法及其用于制备类胡萝卜素
公开(公告)号：US5300658A
公开(公告)日：1994-04-05
申请号：US866590
申请日：1992-04-10
申请人： Juergen Frank , Udo Rheude , Bernhard Schulz , Joachim Paust , Eckhard Hickmann
发明人： Juergen Frank , Udo Rheude , Bernhard Schulz , Joachim Paust , Eckhard Hickmann
IPC分类号： B01J27/128 , B01J27/138 , C07B61/00 , C07C47/21 , C07C403/24 , C07D307/28
CPC分类号： C07C403/24 , C07D307/28
摘要： 2,5-bis(1,1-dialkoxy-2-propyl)-2,5-dihydrofurans of the formula I ##STR1## where R.sup.1 and R.sup.2 can be identical or different and can be alkyl of 1 to 4 carbons, the preparation thereof by reaction of 2,5-dialkoxy-2,5-dihydrofurans of the formula II ##STR2## In the presence of protic acids or Lewis acids with an alkyl propenyl ether of the formula III ##STR3## and the use thereof for preparing 2,7-dimethyl-2,4,6-octatrienedial and symmetric C.sub.40 -carotenoids such as .beta.-carotene, canthaxanthin and astaxanthin, are described.
摘要翻译：式（Ⅰ）的2,5-双（1,1-二烷氧基-2-丙基）-2,5-二氢呋喃其中R 1和R 2可以相同或不同并且可以是1至4个碳的烷基，其通过式II的2,5-二烷氧基-2,5-二氢呋喃的反应制备（II）在质子酸或路易斯酸与式III的烷基丙烯基醚存在下（IMAGE） III）及其用于制备2,7-二甲基-2,4,6-辛二烯和对称的C40-类胡萝卜素如β-胡萝卜素，角黄素和虾青素的用途。

4. 发明授权

US4105855A Manufacture of symmetrical carotenoids 失效
标题翻译：对称类胡萝卜素的制造
公开(公告)号：US4105855A
公开(公告)日：1978-08-08
申请号：US652190
申请日：1976-01-26
申请人： Bernhard Schulz , Joachim Paust , Joachim Schneider
发明人： Bernhard Schulz , Joachim Paust , Joachim Schneider
IPC分类号： C07C403/24 , C07C1/32 , C07C13/20 , C07C45/51 , C07C47/21 , C07C67/00 , C07C401/00 , C07C403/00 , C07D309/12 , C07F9/54 , C07C3/00 , C07C13/28
CPC分类号： C07C403/24 , C07C1/324 , C07C403/08 , C07C403/12 , C07C45/515 , C07C47/21 , C07D309/12 , C07F9/5428 , C07C2101/16
摘要： Symmetrical carotenoids are prepared from the half-molecules by dimerizing the phosphonium salts of the half-molecules with peroxides, peroxo compounds or peroxy compounds in an alkaline medium.
摘要翻译：通过在碱性介质中将半分子的鏻盐与过氧化物，过氧化合物或过氧化合物二聚化，从半分子制备对称类胡萝卜素。

5. 发明授权

US4191692A Manufacture of tocopherol 失效
标题翻译：生育酚生产
公开(公告)号：US4191692A
公开(公告)日：1980-03-04
申请号：US896479
申请日：1978-04-14
申请人： Paul Grafen , Henning Kroesche , Bernhard Schulz , Joachim Paust , Sigberg Pfohl
发明人： Paul Grafen , Henning Kroesche , Bernhard Schulz , Joachim Paust , Sigberg Pfohl
IPC分类号： C07D311/72
CPC分类号： C07D311/72
摘要： In the manufacture of tocopherol (vitamin E) by reaction of isophytol with trimethylhydroquinone in the presence of zinc chloride and acid in a hydrocarbon solvent one of the starting compounds, isophytol, is pretreated with small amounts of ammonia or an amine.Tocopherol is obtained in higher yield and purity.
摘要翻译：在氯化锌和酸在烃溶剂存在下，通过异山梨醇与三甲基对苯二酚的反应制造生育酚（维生素E），其中一种起始化合物异山梨醇，用少量的氨或胺进行预处理。以更高的产率和纯度获得生育酚。

6. 发明授权

US4435427A Stable injectable .beta.-carotene micellar solutions and their preparation 失效
标题翻译：稳定的注射β-胡萝卜素胶束溶液及其制备
公开(公告)号：US4435427A
公开(公告)日：1984-03-06
申请号：US329124
申请日：1981-12-09
申请人： Peter P. Hoppe , Joachim U. Schneider , Bernhard Schulz , Hubert Tiefenbacher
发明人： Peter P. Hoppe , Joachim U. Schneider , Bernhard Schulz , Hubert Tiefenbacher
IPC分类号： A61K9/00 , A61K9/107 , A61K47/14 , A61K47/26 , A61K47/44 , A61K31/015
CPC分类号： A61K9/0019 , A61K9/1075 , A61K47/14 , A61K47/26 , A61K47/44
摘要： A process for the preparation of .beta.-carotene micellar solutions, wherein a non-ionic emulsifier which is suitable for the preparation of micellar solutions is heated at from 160.degree. to 180.degree. C. and a total of from 20 to 30% by weight, based on the emulsifier, of .beta.-carotene is introduced in the presence of a conventional antioxidant, the hot homogeneous mixture is cooled rapidly to below 100.degree. C. by adding water, and the formulation is brought to the desired concentration of from 3 to 6% by weight by adding further water, and the .beta.-carotene micellar solutions obtained by this process. The non-ionic emulsifiers used in this process have an HLB value of from 12 to 16, and are in particular oxyethylated triglycerides of fatty acids of 12 to 18 carbon atoms containing 20-60 oxyethylene units. Parenteral admininstration of the stable .beta.-carotene micellar solutions according to the invention to cattle relieves the disturbed estrus cycle and impaired fertility caused by .beta.-carotene deficiency.
摘要翻译：制备β-胡萝卜素胶束溶液的方法，其中适用于制备胶束溶液的非离子乳化剂在160℃至180℃下加热，总共加入20至30重量％基于乳化剂，在常规抗氧化剂存在下引入β-胡萝卜素，将热均匀混合物通过加入水快速冷却至低于100℃，并将制剂达到所需浓度为3至6 通过加入另外的水重量％，以及通过该方法获得的β-胡萝卜素胶束溶液。在该方法中使用的非离子乳化剂具有12-16的HLB值，特别是含有20-60个氧乙烯单元的12-18个碳原子的脂肪酸的氧乙酸化甘油三酸酯。根据本发明的稳定的β-胡萝卜素胶束溶液的肠胃外施用可以缓解由β-胡萝卜素缺乏引起的扰乱的发情周期和受损的生育力。

7. 发明授权

US4121189A Electrical resistor and method of making same 失效
标题翻译：电阻及其制作方法
公开(公告)号：US4121189A
公开(公告)日：1978-10-17
申请号：US775723
申请日：1977-03-08
申请人： Karl-Heinz Kuhl , Eberhard Muranka , Bernhard Schulz , Asmund Tielens
发明人： Karl-Heinz Kuhl , Eberhard Muranka , Bernhard Schulz , Asmund Tielens
IPC分类号： H01C1/148 , H01C1/12 , H01C3/00 , H01C3/20 , H01C1/02
CPC分类号： H01C1/12 , H01C3/20 , Y10T29/49087 , Y10T29/49089
摘要： An electrical resistor and method of making same comprising an elongated resistor element having end sections and a resistance material extending therebetween, and a connecting part which is pressed onto at least one end section of the resistor for being bonded with the resistor element, the connecting part comprising a terminal lug having a first end section extending along and contacting an end of the resistor element and a second terminal end, and a cap received over and securing together the first end section of the terminal lug and its contacted end of the resistor element.
摘要翻译：一种电阻器及其制造方法，包括具有端部和在其之间延伸的电阻材料的细长电阻元件，以及连接部件，其被压到所述电阻器的至少一个端部以与所述电阻器元件接合，所述连接部件包括端子凸耳，其具有沿着电阻元件的端部延伸并且接触电阻器元件的端部的第一端部部分和第二端子端子，以及容纳在端子凸耳的第一端部部分和电阻器元件的接触端部上的盖子。

8. 发明授权

US4843171A 1,1-dialkoxy-2-methyl-4,4-diacyloxy-2-butenes 失效
标题翻译： 1,1-二烷氧基-2-甲基-4,4-二酰氧基-2-丁烯
公开(公告)号：US4843171A
公开(公告)日：1989-06-27
申请号：US68442
申请日：1987-07-01
申请人： Bernhard Schulz , Rolf Fischer
发明人： Bernhard Schulz , Rolf Fischer
IPC分类号： C07C67/02 , C07C69/007 , C07C69/16 , C07C69/28 , C07C69/78 , C07D317/30
CPC分类号： C07C403/14 , C07C403/10 , C07C69/16 , C07C2101/16
摘要： 1,1-Dialkoxy-2-methyl-4,4-diacyloxy-2-butenes having the general structure: ##STR1## in which R.sub.1 represents alkyl substituents having from 1 to 5 carbon atoms, or both R.sub.1 substituents together represent a single ethylene or propylene substituent, or a single C.sub.1 -C.sub.2 alkyl substituent, and R.sub.2 represents alkyl substituents having from 1 to 5 carbon atoms, or cycloalkyl substituent having from 5 to 7 carbon atoms, or aromatic substituents (preferably phenyl substituents). These new compounds are useful as building blocks in the synthesis of terpenes and carotenoids.
摘要翻译：具有一般结构的1,1-二烷氧基-2-甲基-4,4-二酰氧基-2-丁烯：其中R 1表示具有1至5个碳原子的烷基取代基，或两个R 1取代基一起代表单个乙烯或丙烯取代基，或单个C 1 -C 2烷基取代基，R 2表示具有1至5个碳原子的烷基取代基，或具有5至7个碳原子的环烷基取代基或芳族取代基（优选苯基取代基）。这些新化合物可用作合成萜烯和类胡萝卜素的结构单元。

9. 发明授权

US4127455A Manufacture of symmetrical carotenoids 失效
标题翻译：对称类胡萝卜素的制造
公开(公告)号：US4127455A
公开(公告)日：1978-11-28
申请号：US817252
申请日：1977-07-20
申请人： Bernhard Schulz , Hans Grassner , Peter Jaeger , Heinz Nohe
发明人： Bernhard Schulz , Hans Grassner , Peter Jaeger , Heinz Nohe
IPC分类号： C07F9/54 , C09B61/00 , C25B3/10 , C25B3/02 , C07C11/21
CPC分类号： C25B3/10 , C07F9/5428
摘要： Symmetrical carotenoids are manufactured from the molecular halves thereof by a process wherein phosphonium salts of the molecular halves of these symmetrical carotenoids are oxidized electrochemically in a solvent and in the presence of a base, causing the molecular halves to dimerize, with elimination of substituted phosphine oxide.
摘要翻译：对称类胡萝卜素由其分子半部分制造，其中这些对称类胡萝卜素的分子一半的鏻盐在溶剂中和碱存在下被电化学氧化，导致分子一半二聚，同时消除取代的氧化膦。

10. 发明申请

US20080296264A1 Electrical service switching device with an arc blowout device 失效
标题翻译：具有电弧喷射装置的电气切换装置
公开(公告)号：US20080296264A1
公开(公告)日：2008-12-04
申请号：US12153978
申请日：2008-05-28
申请人： Bernhard Schulz , Andre Dickgiesser
发明人： Bernhard Schulz , Andre Dickgiesser
IPC分类号： H01H9/44
CPC分类号： H01H9/446 , H01H9/346 , H01H9/443 , H01H11/0006 , H01H71/0228
摘要： The disclosure relates to an electrical service switching device, in particular a circuit breaker, motor circuit breaker or the like, having a housing which has two housing halves and connecting means for electrical connection to busbars and/or power lines, having at least one electrical switching contact on which an arc is struck in an initial arcing chamber on disconnection of the electrical contact, with an arc quenching unit being provided adjacent to this, in order to quench the arc. An AC blowout device which comprises two iron plates adjacent to the initial chamber area in the lateral direction and guides the arc into the arc quenching device by magnetic interaction during AC operation, is provided. The housing wall has an opening in the area of the iron plates, through which a permanent magnet can be inserted in order to create an AC/DC blowout device, which guides the arc into the arc quenching device in both AC and DC operation, when the housing is assembled.
摘要翻译：本公开涉及一种电气服务切换设备，特别是断路器，电动机断路器等，其具有壳体，该壳体具有两个壳体半部和用于电连接到母线和/或电力线的连接装置，该电气连接装置具有至少一个电气在电接触断开时在初始电弧室中撞击电弧的开关触点，与其相邻设置有电弧熄弧单元，以便淬火电弧。一种交流喷出装置，其特征在于，具有在横向方向上与所述初始室区域相邻的两个铁板，并且在交流动作期间通过磁相互作用将所述电弧引导到所述灭弧装置。壳体壁在铁板的区域中具有开口，通过该开口可以插入永磁体以形成AC / DC喷出装置，其在AC和DC操作中将电弧引导到灭弧装置中，当时外壳组装。

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