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    • 9. 发明授权
    • Continuous preparation of copolyamides
    • 连续制备共聚酰胺
    • US5030709A
    • 1991-07-09
    • US501034
    • 1990-03-29
    • Gunter PipperEckhard M. Koch
    • Gunter PipperEckhard M. Koch
    • C08G69/26C08G69/28C08G69/36
    • C08G69/265C08G69/28C08G69/36
    • Copolyamides which contain units of the formula --NH--(CH.sub.2).sub.4 --NH are prepared by a continuous process in whicha) an aqueous solution of from 5 to 80% by weight of a salt of 1,4-diaminobutane, and dicarboxylic acids and from 20 to 95% by weight of further polyamide-forming starting materials are heated to a temperature above the melting point of the copolyamide, with the addition of diamines and with vaporization of water, under superatmospheric pressure,b) the vapor phase and prepolymer are brought into intimate contact with one another,c) the prepolymer is separated from the vapor phase and the polymer is discharged after a total residence time of not more than 30 minutes, andd) diamines are separated off from the vapor phase and recycled to a).
    • 包含式-NH-(CH 2)4 -NH的单元的共聚酰胺通过连续方法制备,其中a)5-80重量%的1,4-二氨基丁烷的盐和二羧酸的水溶液 和20至95重量%的另外的聚酰胺形成原料在超大气压下加热至高于共聚酰胺熔点的温度,加入二胺并蒸发水,b)气相和预聚物 彼此紧密接触,c)将预聚物与气相分离,聚合物在总停留时间不超过30分钟后排出,并且d)将二胺从气相中分离并再循环至 一个)。