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1. 发明申请

WO2005121218A2 METHOD FOR MODIFYING FIBROUS SUBSTRATES WITH SILOXANE COPOLYMERS 审中-公开
标题翻译：用于修饰的纤维状基材中的方法硅氧烷共聚物
公开(公告)号：WO2005121218A2
公开(公告)日：2005-12-22
申请号：PCT/EP2005005952
申请日：2005-06-02
申请人： WACKER CHEMIE GMBH , HERZIG CHRISTIAN , BECKER RICHARD , BURGER WILLIBALD , HOHBERG THOMAS
发明人： HERZIG CHRISTIAN , BECKER RICHARD , BURGER WILLIBALD , HOHBERG THOMAS
IPC分类号： A61K8/06 , A61K8/893 , A61K8/896 , A61K8/898 , A61Q5/02 , A61Q5/06 , A61Q5/12 , C08G77/04 , C08G77/388 , C08G77/458 , C14C9/00 , D06M15/643 , D06M15/653 , D21H19/32 , A61K7/06
CPC分类号： A61K8/898 , A61K8/068 , A61K8/893 , A61Q5/02 , A61Q5/06 , A61Q5/12 , C08G77/388 , C08G77/458 , D06M15/3568 , D06M15/643 , D06M15/6436 , D06M15/647 , D06M15/653 , D06M2200/50 , D21H19/32
摘要： The invention relates to a method for modifying fibrous substrates with siloxane copolymers that can be produced by reacting, in a first step, organopolysiloxanes (1), which, per molecule, have at least one Si-bound hydrogen atom, preferably at least two Si-bound hydrogen atoms, with, to a large extent, linear oligomeric or polymeric compounds (2) of general formula R -(A-CnH2n)m-A -H, in which: R represents a monovalent optionally substituted hydrocarbon radical, to which Si-H groups can be attached during a hydrosilylation reaction, preferably a hydrocarbon radical having an aliphatic C-C multiple bond; A represents a bivalent polar organic radical selected from the group consisting of -O-, -C(O)-O-, -O-C(O)-, -O-C(O)-O-, -C(O)-NH-, -NH-C(O)-, a urethane radical and a urea radical; A represents a bivalent polar organic radical selected from the group consisting of -O-, -NH- and -NR'- (whereby R' represents a monovalent hydrocarbon radical having 1 to 18 carbon atoms); n represents an integer from 1 to 20, and; m is equal to 0 or a whole positive integer. In a second step, the intermediate products (4) having the H-A -groups obtained in the aforementioned manner are reacted with organic compounds (5) that, per molecule, have at least two isocyanate groups.
摘要翻译：公开的是由具有在第一步骤中有机聚硅氧烷（1）中，每分子具有至少一个Si键合的氢原子修改与硅氧烷共聚物制备的纤维基材的制造方法，优选至少两个Si键合的氢原子的，具有基本上线性低聚或聚合化合物（2 ）通式R <1> - （A-为C n H 2n）后毫安<1> -H，其中R <1>为一价任选取代的烃基，可以在氢化硅烷化反应连接于Si-H基团，优选脂肪族 CC多重键的烃基，a是一个二价的极性有机基团选自-O - 的基团，-C（O）-O - ， - OC（O）中选择 - ， - OC（O）-O-，-C （O）-NH-，-NH-C（O） - ，氨基甲酸乙酯基团和脲基团，<1>为二价极性有机基团选自-O - 的基团， - NH-和-NR' - 选择（其中 R“是一价的煤烃基的碳原子数为1〜18）中，n是从1至20的整数和m是0或一个正整数，反应时，和（在第二步骤因此HA获得具有中间体<1>基团 4）（用有机化合物5），每分子具有至少两个异氰酸酯基团，进行反应。

2. 发明申请

WO2004056907A3 HYDROPHILIC COPOLYSILOXANES AND METHOD FOR THE PRODUCTION THEREOF 审中-公开
标题翻译：亲水性硅氧烷聚合物及其生产方法
公开(公告)号：WO2004056907A3
公开(公告)日：2004-09-16
申请号：PCT/EP0314494
申请日：2003-12-18
申请人： WACKER CHEMIE GMBH , HERZIG CHRISTIAN , DORMEIER SIEGFRIED
发明人： HERZIG CHRISTIAN , DORMEIER SIEGFRIED
IPC分类号： C08G18/32 , C08G18/61 , C08G18/73 , C08G77/26 , C08G18/28 , C08G77/46
CPC分类号： C08G77/46 , C08G18/3275 , C08G18/61 , C08G18/73 , C08G77/452 , C08G77/458
摘要： Disclosed are novel hydrophilic copolysiloxanes that are produced by reacting organopolysiloxanes (1) comprising at least one Si-bonded hydrogen atom, preferably at least two Si-bonded hydrogen atoms, per molecule with mostly linear oligomeric or polymeric compounds (2) of general formula R -(A-CnH2n)m-A -H, wherein R represents a monovalent optionally substituted hydrocarbon radical to which Si-H groups can be attached in a hydrosilylation reaction, preferably a hydrocarbon radical containing a multiple aliphatic C-C bond, A represents a bivalent, polar organic radical selected among the group comprising -O-, -C(O)-O-, -O-C(O)-, -O-C(O)-O-, -C(O)-NH-, -NH-C(O)-, a urethane radical, and a urea radical, A represents a bivalent, polar organic radical selected among the group comprising -O-, -NH-, and -NR'- (R' representing a monovalent hydrocarbon radical containing 1 to 18 carbon atoms), n represents a whole number between 1 and 20, and m represents a positive whole number, in a first step, and reacting the obtained intermediate products (4) containing H-A groups with organic compounds (5) comprising at least two isocyanate groups per molecule in a second step, provided that the water content of compounds (1) and (2) which are used for producing the hydrophilic copolysiloxanes is less than 2000 ppm.
摘要翻译：描述的是新的亲水性硅氧烷共聚物在第一步骤中的有机聚硅氧烷（1）具有至少一个Si键合的氢原子制备的由每分子优选至少两个硅键合氢原子，（具有基本上线性的低聚或聚合化合物（2）通式我）：R <1> - （A-为C n H 2n）后毫安<1> -H，其中R <1>为一价任选取代的烃基，可以在氢化硅烷化反应附着到Si-H基，优选脂族CC -Mehrfachbindung指具有烃基，a是一个二价的极性有机基团选自O-的基团，-C（O）-O - ， - OC（O）中选择 - ， - OC（O）-O-，-C（O ）-NH-，-NH-C（O） - ，氨基甲酸乙酯基团和脲基团，<1>为二价极性有机基团选自O-组成的组， - NH-和-NR' - （其中R“是一个具有1至18个碳原子的一价烃基预兆基），n是从1至20的整数，m是正整数，进行反应，因此，HA获得具有中间体（在第二步骤4）（用有机化合物<1>基团5）每分子具有至少两个异氰酸酯基团，进行反应，条件是所述化合物的水含量用于制备的硅氧烷共聚物，条件亲水性（1）和（2）大于2000重量ppm以下。

3. 发明申请

WO2004065441A3 SILICONE POLYMERISATES 审中-公开
标题翻译：含硅聚合物
公开(公告)号：WO2004065441A3
公开(公告)日：2005-09-09
申请号：PCT/EP0314490
申请日：2003-12-18
申请人： WACKER CHEMIE GMBH , STARK KURT , HERZIG CHRISTIAN , HOEGL CHRISTIAN
发明人： STARK KURT , HERZIG CHRISTIAN , HOEGL CHRISTIAN
IPC分类号： C08F283/12 , C08F290/14 , C08L51/08 , C09D151/08 , C09J151/08 , A61K7/00 , C08F2/00
CPC分类号： C08F283/12 , C08F290/14 , C08L51/085 , C09D151/085 , C09J151/085
摘要： The invention relates to silicone polymerisates produced by radical polymerisation of ethylenically non-saturated monomers in the presence of polysiloxane. The inventive polymerisates are characterised in polymerisation of a) 60-99.99 mass % one or several monomers of a group comprising vinyl esters of linear or branched alkylcarboxylic acids having 1-15 C atoms, alcohol methacrylates and acrylates having 1-15 C atoms, aromatic vinyl compounds, olefins, dienes and vinyl halides in the presence of b) 0.01-40 mass % at least one type of branched polysiloxane whose lipophilic siloxane part contains branched structures and whose hydrophilic polymer organic part can be linear or branched, the mass percentage values relate to the total mass of a) and b).
摘要翻译：本发明涉及一种含聚硅氧烷的聚合物他hältlich通过在聚硅氧烷的存在下烯属不饱和单体的自由基聚合的装置，作为其特征在于：a）60〜99.99重量的选自的无支链的乙烯酯的一种或多种单体的％或支链烷基羧酸的 1至15个C原子，甲基丙烯酸酯和具有1至15个C原子，乙烯基芳族化合物，烯烃，二烯和乙烯基卤化物，在b为0.01的存在下）的醇的40重量％的至少一种支化聚硅氧烷％的丙烯酸酯聚合，所述亲脂性含有支链硅氧烷结构，以及其亲水Organopolymerteil可以是直链或支链的，其中附图以重量％基于的总重量计）和b）。

4. 发明专利

JP2005179663A Method for producing organosilicon compound 审中-公开
标题翻译：生产有机硅化合物的方法
公开(公告)号：JP2005179663A
公开(公告)日：2005-07-07
申请号：JP2004355914
申请日：2004-12-08
申请人： Wacker Chemie Gmbh , ワツカー−ケミーゲゼルシヤフトミツトベシユレンクテルハフツングWacker−Chemie GmbH
发明人： OCHS CHRISTIAN , HERZIG CHRISTIAN
IPC分类号： C07F7/18 , C08G77/06 , C08G77/38 , C08G77/46
CPC分类号： C08G77/38 , C08G77/06 , C08G77/46
摘要： PROBLEM TO BE SOLVED: To provide a method for giving a synthetic polyfunctional organosilicon compound, capable of easily preventing the compound from containing by-products as far as possible at a low cost. SOLUTION: This method comprises adding a hydrogen atom combined with Si to a compound having an aliphatic unsaturated carbon-carbon-multiple bond and an ether oxygen atom in the presence of a carbinol group, wherein the reaction mixture contains at least one kind of cyclic ether as another component, so that the hydrogen atom combined with the Si is added to the compound having the aliphatic unsaturated carbon-carbon-multiple bond and the ether oxygen atom. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供一种能够以低成本尽可能地容易地防止化合物含有副产物的合成多官能有机硅化合物的方法。解决方案：该方法包括在甲醇基团存在下，将与Si结合的氢原子加入到具有脂族不饱和碳 - 碳 - 多键和醚氧原子的化合物中，其中反应混合物含有至少一种的环醚作为另外的成分，使得与Si结合的氢原子加入到具有脂族不饱和碳 - 碳 - 多重键和醚氧原子的化合物中。版权所有（C）2005，JPO＆NCIPI

5. 发明专利

JP2000169586A ALKENYLATED SILOXANE COPOLYMER, ITS PRODUCTION, CROSSLINKABLE COMPOSITION CONTAINING THE SILOXANE COPOLYMER, USE OF THE COMPOSITION, SILOXANE COPOLYMER HAVING HYDROGEN ATOM BOUND TO Si, AND ITS PRODUCTION 失效
公开(公告)号：JP2000169586A
公开(公告)日：2000-06-20
申请号：JP34349699
申请日：1999-12-02
申请人： WACKER CHEMIE GMBH
发明人： HERZIG CHRISTIAN
IPC分类号： C08G77/20 , C08G77/48 , C08G77/50 , C08L83/05 , C08L83/14 , C09D183/14
摘要： PROBLEM TO BE SOLVED: To obtain an alkenylated copolymer at a low temperature in a short time by reacting a compound having three aliphatic double bonds with an organoxiloxane in the presence of a catalyst, reacting the obtained hydrocarbon-siloxane copolymer with an α,ω-dialkenylsiloxane polymer in the presence of a catalyst, and equilibrating the obtained siloxane copolymer with an organopolysiloxane. SOLUTION: This compound having three aliphatic double bonds is represented by the formula (wherein R2 is a trivalent or tetravalent hydrocarbon group; R3 is H or alkyl; and x is 3 or 4). An organosiloxane has terminal hydrogen atoms bound to an Si atom. A catalyst serves to accelerate the addition of the hydrogen atoms bound to an Si atom onto the aliphatic double bonds. The ratio of the hydrogen atoms bound to an Si atom in the organosiloxane to aliphatic double bonds in the compound is (1.3 to 10):1. The ratio of the aliphatic double bonds in the α,ω-dialkenylsiloxane polymer used to the hydrogen atoms bound to an Si atom in the hydrocarbon-siloxane copolymer used is (1.2 to 10):1. A crosslinkable composition is obtained which is suitable for the production of a coating capable of rejecting a tacky material.

6. 发明专利

JPH10316756A COMPOSITION FROM OXYGENOUS PHOSPHAZENE AND TERTIARY ALCOHOL, ITS PREPARATION AND PROCESS FOR EQUILIBRATING AND/OR CONDENSING ORGANOSILICON COMPOUND 失效
公开(公告)号：JPH10316756A
公开(公告)日：1998-12-02
申请号：JP12341898
申请日：1998-05-06
申请人： WACKER CHEMIE GMBH
发明人： DEUBZER BERNWARD , HERZIG CHRISTIAN , STALLBAUER REINHARD
IPC分类号： B01J27/16 , C07B61/00 , C07C31/02 , C07C33/18 , C07C35/00 , C07F7/08 , C07F7/18 , C07F9/06 , C07F9/26 , C08G77/06 , C08G77/08 , C08G77/10 , C08G79/025
摘要： PROBLEM TO BE SOLVED: To obtain a composition which forms a catalyst having high activity of equilibrating and/or condensing an organosilicon compound simply in a manner in which the formation of free hydrogen chloride is small and controlled by mixing an oxygenous phosphazene with a tertiary alcohol at a specified temperature under a specified pressure. SOLUTION: An oxygenous phosphazene is mixed with a tertiary alcohol at a temperature of 0-70 deg.C, desirably 0-20 deg.C under atmospheric pressure i.e. 900-1,100 hPa to form a composition. It is desirable that the temperature is kept 40 deg.C or below by removing the heat of reaction by a suitable cooling means. It is desirable that the reaction is carried out in an atmosphere substantially free from oxygen and water. The oxygenous phosphazene is one represented by the formula (wherein Y is chlorine or hydroxyl; and n is 0-8, desirably 1-3) or a condensate thereof. The tertiary alcohol is exemplified by tertiary butanol or dimethylpropanol. It is desirable that 1-300 ppm of this composition is used as the catalyst for equilibrating and condensing an organosilicon compound.

7. 发明专利

JPH11315085A ORGANOSILOXANE COMPOUND HAVING ALKENYL GROUP AND ITS PRODUCTION 失效
公开(公告)号：JPH11315085A
公开(公告)日：1999-11-16
申请号：JP5416899
申请日：1999-03-02
申请人： WACKER CHEMIE GMBH
发明人： HERZIG CHRISTIAN , DEUBZER BERNWARD DIPL CHEM DR , WEIS JOHANN DR , KARLOU-EYRISCH KAMELIA , NUYKEN OSKAR
IPC分类号： B01J31/24 , C07B61/00 , C07C6/06 , C07F7/08 , C07F7/18 , C08G77/20 , C08G77/38
摘要： PROBLEM TO BE SOLVED: To obtain the subject new organosiloxane compound under use of readily available starting substances by a simple method. SOLUTION: This compound has a unit represented by formula I [R is a 1-8C monovalent hydrocarbon not containing an aliphatic carbon-carbon-multiple bond; R is a 1-8C monovalent hydrocarbon; (a) is 0 or 1; (b) and (c) and each 0-3; A is a group of the formula: (R )d -Y-(-CH=CHR )2 (R is a 1-6C divalent hydrocarbon; R is H or a 1-20C monovalent hydrocarbon; Y is a 2-20C trivalent hydrocarbon; (d) is 0 or 1). The compound is obtained by reacting an organosilicon compound having a unit of formula II (B is a group of formula III) with an α-olefin of the formula: R -CH=CH2 (preferably ethylene) in the presence of a metathesis catalyst (preferably ruthenium complex) selected from a group comprising transition metal compounds or transition metal complexes from subgroups of the groups IV to VIII of the periodic table. The reaction is preferably carried out under homogeneous catalytic reaction.

8. 发明申请

WO2009019143A2 QUATERNARY AMMONIA GROUPS COMPRISING ORGANOSILICON COMPOUND AND THE PRODUCTION THEREOF 审中-公开
标题翻译：含季铵的有机硅化合物和它们的生产
公开(公告)号：WO2009019143A2
公开(公告)日：2009-02-12
申请号：PCT/EP2008059761
申请日：2008-07-25
申请人： WACKER CHEMIE AG , HERZIG CHRISTIAN , DORMEIER SIEGFRIED
发明人： HERZIG CHRISTIAN , DORMEIER SIEGFRIED
IPC分类号： C08G77/388
CPC分类号： C08G77/388 , B01F17/0071
摘要： The invention relates to quaternary ammonia groups comprising organosilicon compounds (1) having at least one Si-bonded group G of the general formula (I), wherein Y is a bivalent organic radical having 1 to 100 carbon atoms that can contain one or more ether oxygen atoms and/or one or more hydroxy groups, R1 is a univalent organic radical having 1 to 30 carbon atoms, R2 is a methyl or ethyl radical, A is a univalent organic radical having at least 4 carbon atoms and being substituted with at least 2 hydroxy groups, and L- is a counterion to the positive charge on the quaternary nitrogen group, selected from anions of inorganic or organic acids HL.
摘要翻译：（1）含有通式（I）中至少一个Si键合的组G，其中Y是二价有机基团具有1至100个碳原子，其含有一个或多个醚氧原子和/或一个或多个羟基基团含季铵的有机硅化合物可以手段，R 1为碳原子数1〜30的1价有机基团，R 2为甲基或乙基，a为一价取代有至少2个羟基基团的有机基团具有至少4个碳原子的装置。指L-抗衡离子为对从无机酸或有机酸的HL的阴离子中选择的季铵化氮基的正电荷。

9. 发明申请

WO2007060113A3 METHOD FOR PREPARING ?-KETOCARBONYL-FUNCTIONAL ORGANO-SILICIUM COMPOUNDS 审中-公开
标题翻译：用于生产SS-酮羰基官能的有机硅化合物
公开(公告)号：WO2007060113A3
公开(公告)日：2007-07-26
申请号：PCT/EP2006068421
申请日：2006-11-14
申请人： WACKER CHEMIE AG , HERZIG CHRISTIAN , JOACHIMBAUER MARTINA
发明人： HERZIG CHRISTIAN , JOACHIMBAUER MARTINA
IPC分类号： C07F7/00 , C08G77/388
CPC分类号： C08G77/388
摘要： The invention relates to a novel method for producing ß-ketocarbonyl-functional organo-silicium compounds, which consists of reacting diketens (1) of general formula (I), wherein R 3 represents a hydrogen atom or a hydrocarbon radical having 1 - 18 carbon atoms, with organo-silicium compounds (2) which contain, per molecule, at least one Si bound radical A of general formula -R 1 -NR 2 2
摘要翻译：描述的是用于测试酮羰基官能的有机硅化合物的制备新方法，其特征在于，所述通式（I），其中R ^{3 表示氢原子或碳原子数1〜18的烃基的双烯酮（1），用有机硅化合物（2）含有至少一个硅键接的基团A的通式-R ^{1 -NR ^{2 ₂}}}

10. 发明申请

WO2007023084A2 ORGANOPOLYSILOXANES AND METHOD FOR THE PRODUCTION THEREOF 审中-公开
标题翻译：有机聚硅氧烷及其制造方法
公开(公告)号：WO2007023084A2
公开(公告)日：2007-03-01
申请号：PCT/EP2006065168
申请日：2006-08-09
申请人： WACKER CHEMIE AG , HERZIG CHRISTIAN , LAUTENSCHLAGER HANS
发明人： HERZIG CHRISTIAN , LAUTENSCHLAGER HANS
IPC分类号： C08G77/50
CPC分类号： C08G77/50
摘要： The invention relates to organopolysiloxane compounds containing per-molecule at least one structural unit of general formula (I) O 3-a/2 R a Si-Y (SiR a O 3-a/2 ) b , wherein R can be identical or different and represents an organic monovalent SiC-bonded group which comprises from 1 to 30 carbon atoms and can contain one or several O atoms, a is 0 or 1 and b is an integer number ranging from 1 to 11.
摘要翻译：本发明涉及有机聚硅氧烷每分子含有通式（I）中的至少一种结构单元的化合物：0 _{3-A / 2 - [R _{一的Si-Y（SIR _{一< / SUB> 0 _{3-A / 2 ）_{b'/ SUB包含>，其中R可以相同或不同，并表示一价的SiC键合的有机基团的碳原子数为1〜30，一个或多个N和/或O原子可以包括装置; Y代表的二到zwölfwertigen组织。基团，具有1至30个碳原子，其可以包含一个或多个O原子的装置; a为0或1，b为1〜11的整数}}}}}

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