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1. 发明申请

WO1997048742A1 AGGREGATE SUPPORTS AND OLEFIN POLYMERIZATION CATALYSTS SUPPORTED THEREON 审中-公开
标题翻译：聚合物支持和支持的烯烃聚合催化剂
公开(公告)号：WO1997048742A1
公开(公告)日：1997-12-24
申请号：PCT/US1997011951
申请日：1997-06-19
申请人： W. R. GRACE & CO.-CONN.
发明人： W. R. GRACE & CO.-CONN. , DENTON, Dean, Alexander , CARNEY, Michael, J.
IPC分类号： C08F10/00
CPC分类号： B01J31/143 , B01J31/122 , B01J31/1616 , B01J31/38 , B01J37/0009 , B01J37/0045 , C08F4/02 , C08F10/00 , C08F4/025
摘要： The present invention relates to a novel loose aggregate catalyst support composition characterized in that the aggregate has a surface area from about 100-1000m /g, an average particle size of from about 5-250 microns, a pore volume of from about 0.5 to 3.0 cc/g in pores having pore diameters under 1000 Angstroms, and preferably having an AQI hardness of greater than 10, and wherein the aggregate particles comprise the following components: 1) porous solid particles from organic, inorganic oxide materials and mixtures thereof, sais particles having an average particle size of less than 30 microns; and 2) a binder to loosely bind the particles from 1) together. In another embodiment, the catalytic support material of the present invention is combined with chromium compounds, Ziegler-Natta and Metallocene, or Ni based complexes, Pd based complexes catalytic materials resulting in catalytically active compositions when appropriately activated. Further disclosed are methods for making the support and catalysts and methods for using these compositions.
摘要翻译：本发明涉及一种新的松散骨料催化剂载体组合物，其特征在于聚集体的表面积为约100-1000m 2 / g，平均粒度为约5-250微米，孔体积为约孔径在1000埃以下，优选AQI硬度大于10的孔中为0.5〜3.0cc / g，其中聚集体颗粒包含以下组分：1）来自有机，无机氧化物材料及其混合物的多孔固体颗粒，平均粒度小于30微米的酱粒; 和2）将颗粒从1）松散地结合在一起的粘合剂。在另一个实施方案中，本发明的催化载体材料与适当活化的铬化合物，齐格勒 - 纳塔和茂金属或Ni基络合物，Pd基配合物催化材料结合，产生催化活性组合物。进一步公开了制备载体和催化剂的方法以及使用这些组合物的方法。

2. 发明申请

WO1997032925A1 FUNCTIONAL BARRIER IN OXYGEN SCAVENGING FILM 审中-公开
标题翻译：氧气遮蔽膜中的功能障碍
公开(公告)号：WO1997032925A1
公开(公告)日：1997-09-12
申请号：PCT/US1997003528
申请日：1997-03-07
申请人： W. R. GRACE & CO.-CONN.
发明人： W. R. GRACE & CO.-CONN. , BANSLEBEN, Donald, A. , BECRAFT, Michael, L. , BLINKA, Thomas, A. , MIRANDA, Nathanael, R. , SPEER, Drew, V.
IPC分类号： C08K05/00
CPC分类号： B32B27/08 , B32B27/18 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2323/10 , B32B2367/00 , B32B2377/00 , B32B2439/00 , B65D81/267 , C08K5/0008 , C08K5/098 , C08K2201/012
摘要： An article of manufacture includes an oxygen scavenger, and a polymer selected from the group consisting of a polymer derived from a propylene monomer, a polymer derived from a methyl acrylate monomer, a polymer derived from a butyl acrylate monomer, a polymer derived from a methacrylic acid monomer, polyethylene terephthalate glycol (PETG), amorphous nylon, ionomer, and a polymeric blend indluding a polyterpene. The article can be in the form of e.g. a film, a polymeric functional barrier coating on an oxygen scavenging lacquer, or a gasket. A package can be made from this article for containing an oxygen-sensitive article such as food. The described polymers reduce or block the migration of odor causing by-products of an oxygen scavenging process. A method of making an article of manufacture having reduced migration of by-products of an oxygen scavenging reaction includes providing an article including an oxygen scavenger and the above-described polymer; and exposing the article to actinic radiation.
摘要翻译：制造方法包括除氧剂和选自丙烯单体的聚合物，衍生自丙烯酸甲酯单体的聚合物，衍生自丙烯酸丁酯单体的聚合物，衍生自甲基丙烯酸甲酯的聚合物的聚合物酸性单体，聚对苯二甲酸乙二醇酯二醇（PETG），无定形尼龙，离聚物和包含多萜烯的聚合共混物。该物品可以是例如，氧气清除漆上的膜，聚合物功能性阻隔涂层或垫圈。可以从本文制成一个包装，用于含有氧敏感物品如食物。所描述的聚合物降低或阻断引起氧清除过程的副产物的气味的迁移。制造具有减少氧清除反应副产物迁移的制品的方法包括提供包含除氧剂和上述聚合物的制品; 并将物品暴露于光化辐射。

3. 发明申请

WO1998013314A1 COMPOSITION AND METHOD TO REMOVE ASBESTOS 审中-公开
标题翻译：去除ASBESTOS的组合物和方法
公开(公告)号：WO1998013314A1
公开(公告)日：1998-04-02
申请号：PCT/US1997011445
申请日：1997-07-07
申请人： W. R. GRACE & CO.-CONN.
发明人： W. R. GRACE & CO.-CONN. , BLOCK, Jacob
IPC分类号： C04B14/40
CPC分类号： A62D3/36 , A62D2101/41 , B09B3/0066 , C04B28/14 , C04B41/4556 , Y10S588/901 , C04B14/40
摘要： A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30 % by weight of an inorganic acid, and from about 0.1 to about 4 % by weight of a hexafluorosilicate of ammonia, an alkali metal or an alkaline earth metal. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
摘要翻译：公开了一种用于将含温石棉的材料转化成非石棉材料的组合物，其中所述组合物包含水，至少约30重量％的无机酸和约0.1至约4重量％的六氟硅酸盐的氨，碱金属或碱土金属。公开了使用本发明的组合物将含石棉材料转化成非石棉材料的方法。

4. 发明申请

WO1994014059A1 LOW OXYGEN TRANSMISSION IMAGING SYSTEM 审中-公开
标题翻译：低氧传输成像系统
公开(公告)号：WO1994014059A1
公开(公告)日：1994-06-23
申请号：PCT/US1993011871
申请日：1993-12-07
申请人： W. R. GRACE & CO.-CONN.
发明人： W. R. GRACE & CO.-CONN. , BULL, Christopher , BARMORE, Charles, Rice
IPC分类号： G01N31/22
CPC分类号： G01N15/08 , G01N31/225 , Y10S436/904 , Y10T436/20 , Y10T436/209163
摘要： A method of detecting the permeability of an article to oxygen is disclosed. A fluorescent redox indicator, preferably riboflavin, is dispersed in a carrier and placed on an impermeable substrate. The article to be measured is placed adjacent to the carrier. Residual oxygen is removed, the redox indicator is photoreduced, the article and carrier are exposed to oxygen, and the indicator is exposed to UV light.
摘要翻译：公开了一种检测制品对氧气的渗透性的方法。荧光氧化还原指示剂，优选核黄素，分散在载体中并置于不渗透的基质上。要测量的物品放置在载体附近。去除残留的氧，氧化还原指示剂被光还原，制品和载体暴露于氧气，并将指示剂暴露于紫外线。

5. 发明申请

WO1997019032A1 MULTIPURPOSE ADMIXTURE FOR HYDRAULIC CEMENT COMPOSITION 审中-公开
标题翻译：用于液压水泥组合物的多用途粘合剂
公开(公告)号：WO1997019032A1
公开(公告)日：1997-05-29
申请号：PCT/US1996018300
申请日：1996-11-15
申请人： W. R. GRACE & CO.-CONN. , JEKNAVORIAN, Ara, A. , SHEN, Ding, Feng
发明人： W. R. GRACE & CO.-CONN.
IPC分类号： C04B22/00
CPC分类号： C04B28/02 , C04B24/16 , C04B22/08 , C04B24/122 , C04B24/18 , C04B2103/10 , C04B2103/302 , C04B2103/40 , C04B22/085
摘要： Exemplary multifunctional hydraulic cement composition admixtures of the invention comprise a set accelerator, preferably a calcium salt, and a fatty acid aminosulfonic acid surfactant. Further exemplary admixtures additionally comprise a water reducing agent, such as a lignosulfonate, and/or an early strength enhancing agent, such as an alkanolamine.
摘要翻译：本发明的示例性多功能水硬性水泥组合物混合物包含凝固促进剂，优选钙盐和脂肪酸氨基磺酸表面活性剂。另外的示例性外加剂还包含减水剂，例如木质素磺酸盐和/或早强增强剂，例如链烷醇胺。

6. 发明申请

WO1994025146A1 POLYIMIDE MEMBRANE FOR SEPARATION OF SOLVENTS FROM LUBE OIL 审中-公开
标题翻译：用于从润滑油中分离溶剂的聚酰亚胺膜
公开(公告)号：WO1994025146A1
公开(公告)日：1994-11-10
申请号：PCT/US1994002853
申请日：1994-03-16
申请人： W. R. GRACE & CO.-CONN.
发明人： W. R. GRACE & CO.-CONN. , WHITE, Lloyd, Steven , WANG, I-Fan , MINHAS, Bhupender, Singh
IPC分类号： B01D71/64
CPC分类号： B01D61/02 , B01D71/64
摘要： An improved asymmetric membrane fashioned from a polyimide for the liquid separation of solvents from lube oil. The membrane is based on a fully imidized polymer based on 5(6)-amino-1-(4'-aminophenyl)-1,3-trimethylindane polymer and benzophenone tetracarboxylic dianhydride.
摘要翻译：由聚酰亚胺形成的改进的不对称膜，用于从润滑油中分离溶剂。膜基于基于5（6） - 氨基-1-（4'-氨基苯基）-1,3-三甲基茚满聚合物和二苯甲酮四羧酸二酐的完全酰亚胺化的聚合物。

7. 发明申请

WO1992018551A1 TIN CATALYSTS FOR HYDROLYSIS OF LATENT AMINE CURING AGENTS 审中-公开
标题翻译：用于水解羟胺固化剂的TIN催化剂
公开(公告)号：WO1992018551A1
公开(公告)日：1992-10-29
申请号：PCT/US1992003018
申请日：1992-04-15
申请人： W. R. GRACE & CO.-CONN.
发明人： W. R. GRACE & CO.-CONN. , BUSH, Richard, Wayne , CARNEY, Eugene Edward
IPC分类号： C08G59/68
CPC分类号： C08G59/70 , C08G18/10 , C08G18/244 , C08G59/4014 , C08G59/685 , C08G18/3256 , C08G18/3253
摘要： A tin catalyst constituting an organotin compound modified with an amine is used to catalyze the hydrolysis of latent amine curing agents in amine-curable polymeric compositions. The tin catalyst is formed from the reaction product of a stannous alkanoate and an amine, optionally in the form of an adduct with water. A preferred catalyst is the reaction product of stannous octoate and ethylenediamine.

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