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1. 发明申请

US20060166085A1 Ion conducting battery separator for lithium batteries, method for the production and use thereof 有权
标题翻译：用于锂电池的离子导电电池隔板，其制造和使用方法
公开(公告)号：US20060166085A1
公开(公告)日：2006-07-27
申请号：US10519097
申请日：2003-07-21
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M4/00 , H01M2/14 , B05D5/12 , B05D3/12 , B05D1/02 , B05D1/18
CPC分类号： H01M2/162 , H01B1/122 , H01M2/145 , H01M2/1646 , H01M2/1666 , H01M10/0525 , H01M10/4235
摘要： The invention relates to separators for lithium batteries and to a process for producing them, and also to their use. The separators of the invention for lithium batteries, based on a sheetlike flexible substrate provided with a plurality of openings and having a porous inorganic electrically insulating coating on and in said substrate, said coating closing the openings in the substrate, the material of the substrate being selected from woven or non-woven electrically nonconductive polymeric fibers and the inorganic electrically conductive coating comprising metal oxide particles, are notable for the fact that the separators have lithium ion conducting properties without the presence of an electrolyte. After filling them with an additional lithium ion conducting electrolyte, the resulting ion conduction is much higher than in the case of conventional combinations of non-lithium ion conducting separators and electrolyte. The separators of the invention are especially suitable for use in high power lithium batteries.
摘要翻译：本发明涉及锂电池用隔膜及其制造方法，也涉及其用途。本发明的用于锂电池的隔板基于设置有多个开口的片状柔性基板，并且在所述基板上和之上具有多孔无机电绝缘涂层，所述涂层封闭基板中的开口，基板的材料为选自织造或非织造非导电聚合物纤维和包含金属氧化物颗粒的无机导电涂层是显着的，因为隔板具有锂离子传导性能而不存在电解质。在用额外的锂离子传导电解质填充它们之后，所得到的离子传导比非传统的非锂离子传导隔离物和电解质的组合的情况高得多。本发明的分离器特别适用于大功率锂电池。

2. 发明申请

US20060024569A1 Separator for use in high-energy batteries and method for the production thereof 有权
标题翻译：用于高能电池的分离器及其制造方法
公开(公告)号：US20060024569A1
公开(公告)日：2006-02-02
申请号：US10524669
申请日：2003-07-04
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M2/16 , B05D7/02
CPC分类号： H01M2/162 , H01M2/1646 , H01M2/1666 , H01M2/1686 , H01M10/0525 , Y10T428/249955 , Y10T428/249957
摘要： The present invention relates to electrical separators, especially for use in lithium high energy batteries, and to a process for making them. Separators for use in lithium high energy batteries have to have a very low weight and a very low thickness. It has been found that, surprisingly, such separators having a weight of less than 50 g/m2 and a thickness of less than 35 μm are preparable by applying a ceramic coating to a polymeric web less than 30 μm in thickness, these separators being very useful in lithium high energy batteries when pyrogenic oxides of the elements Al, Si and/or Zr are used as a particulate pore-forming component.
摘要翻译：本发明涉及特别用于锂高能电池的电隔离器及其制造方法。用于锂高能电池的分离器必须具有非常低的重量和非常低的厚度。已经发现，令人惊讶的是，通过将陶瓷涂层施加到小于30μm的聚合物网上，可以制备重量小于50g / m 2和厚度小于35μm的这种隔板这些隔板在锂高能电池中非常有用，当元素Al，Si和/或Zr的热解氧化物用作颗粒成孔组分时。

3. 发明申请

US20080248381A1 Ceramic Separator for Electrochemcial Cells With Improved Conductivity 审中-公开
标题翻译：陶瓷分离器电化学电池改善电导率
公开(公告)号：US20080248381A1
公开(公告)日：2008-10-09
申请号：US10575274
申请日：2004-08-19
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M2/16 , H01M2/00
CPC分类号： H01M2/145 , H01M2/1646 , H01M2/1686 , H01M10/0525
摘要： Separator for an electrochemical cell comprising a flexible perforate carrier having a ceramic coating on and in the carrier, the ceramic coating comprising from 75 to 99 parts by mass of oxidic particles selected from particles of ZrO2, SiO2 and Al2O3 and comprising from 1 to 25 parts by mass of zeolite particles. These separators exhibit distinctly improved ion conductivity after filling with an electrolyte and are useful as separators in lithium ion batteries in particular.
摘要翻译：用于电化学电池的分离器包括在载体上和载体上具有陶瓷涂层的柔性穿孔载体，所述陶瓷涂层包含75至99质量份的选自ZrO 2颗粒，SiO 2，含有1〜25质量份的沸石颗粒的2'和2“O 3 O 3。这些分离器在填充电解质后显示出明显改善的离子传导性，并且特别用作锂离子电池中的分离器。

4. 发明申请

US20080032197A1 Inorganic Separator-Electrode-Unit for Lithium-Ion Batteries, Method for the Production Thereof and Use Thereof in Lithium Batteries 有权
标题翻译：锂离子电池无机分离器 - 电极单元及其生产方法及其在锂电池中的应用
公开(公告)号：US20080032197A1
公开(公告)日：2008-02-07
申请号：US11577542
申请日：2004-10-21
申请人： Gerhard Horpel , Volker Hennige , Christian Hying , Sven Augustin
发明人： Gerhard Horpel , Volker Hennige , Christian Hying , Sven Augustin
IPC分类号： H01M4/48 , H01M4/08 , H01M4/36
CPC分类号： H01M10/052 , H01M2/1646 , H01M2/166 , H01M4/0404 , H01M4/131 , H01M4/1391 , H01M4/621 , H01M2004/027 , H01M2004/028 , Y10T29/49114
摘要： The present invention concerns separator-electrode assemblies for lithium batteries and also a process for their production. The separator-electrode assemblies (SEAs) comprise a porous electrode useful as an electrode, ie. Positive (cathode) or negative (anode) electrode, in a lithium battery and a separator layer applied to this electrode. The separator electrode assembly (SEA) is characterized in that it has an inorganic separator layer comprising at least two fractions of metal oxide particles different from each other in their average particle size and/or in the metal, and an electrode whose active mass particles are bonded together and to the current collector by inorganic adhesive. The separator-electrode assembly of the invention has the advantage that it is simple to manufacture as one component and that distinctly higher temperatures can be employed in production than in the production of conventional separator-electrode assemblies, since the electrode does not contain heat-sensitive organic materials.
摘要翻译：本发明涉及用于锂电池的分离器 - 电极组件，以及它们的生产方法。分离器电极组件（SEA）包括可用作电极的多孔电极，即，在正极（阴极）或负极（阳极）电极中的锂电池和分隔层施加到该电极上。分离器电极组件（SEA）的特征在于其具有包含在平均粒径和/或金属中彼此不同的金属氧化物颗粒的至少两个部分的无机隔离层和活性质量颗粒为通过无机粘合剂结合在一起并与集电体接合。本发明的分离器 - 电极组件的优点在于，作为一个部件制造简单，并且在生产中可以使用明显更高的温度，而不是生产常规的隔离器 - 电极组件，因为电极不含有热敏感有机材料。

5. 发明申请

US20050084761A1 Electric separator, method for the production and use thereof 有权
标题翻译：电分离器，其生产和使用方法
公开(公告)号：US20050084761A1
公开(公告)日：2005-04-21
申请号：US10504144
申请日：2003-01-15
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M2/14 , H01M2/16
CPC分类号： H01M2/162 , H01M2/1646 , H01M2/1666
摘要： The present invention relates to electrical separators and to a process for making them. An electrical separator is a separator used in batteries and other arrangements in which electrodes have to be separated from each other while maintaining ion conductivity for example. The separator is preferably a thin porous insulating material possessing high ion permeability, good mechanical strength and long-term stability to the chemicals and solvents used in the system, for example in the electrolyte of the battery. In batteries, the separator should fully electrically insulate the cathode from the anode. Moreover, the separator has to be permanently elastic and to follow movements in the system, for example in the electrode pack in the course of charging and discharging. This object is achieved by an electrical separator according to the invention, comprising a sheetlike flexible substrate having a multiplicity of openings and having a coating on and in said substrate, said substrate being a polymeric nonwoven and said coating being a porous electrically insulating ceramic coating, said separator being characterized by a thickness of less than 80 μm.
摘要翻译：本发明涉及电动分离器及其制造方法。电分离器是用于电池和其它布置的隔板，其中电极必须彼此分离，同时保持例如离子传导性。隔膜优选是具有高离子渗透性，良好的机械强度和对系统中使用的化学品和溶剂的长期稳定性的薄多孔绝缘材料，例如在电池的电解质中。在电池中，分离器应使阴极与阳极完全电绝缘。此外，分离器必须是永久的弹性的并且可以跟随系统中的运动，例如在充电和放电过程中的电极组中。该目的通过根据本发明的电气分离器实现，其包括具有多个开口的片状柔性基底，并且在所述基底上和所述基底中具有涂层，所述基底是聚合物非织造材料，所述涂层是多孔电绝缘陶瓷涂层，所述分离器的特征在于小于80μm的厚度。

6. 发明申请

US20060172641A1 Textile substrates having self-cleaning properties 失效
标题翻译：具有自清洁性能的纺织基材
公开(公告)号：US20060172641A1
公开(公告)日：2006-08-03
申请号：US11312340
申请日：2005-12-21
申请人： Volker Hennige , Christian Hying , Gerhard Horpel , Markus Oles , Edwin Nun , Bernhard Schleich
发明人： Volker Hennige , Christian Hying , Gerhard Horpel , Markus Oles , Edwin Nun , Bernhard Schleich
IPC分类号： B32B5/02 , B32B27/04 , B32B27/12 , D04H3/04
CPC分类号： D06M13/50 , D06M11/79 , D06M11/83 , D06M23/08 , D06M2200/05 , Y10T442/20 , Y10T442/2041 , Y10T442/2131 , Y10T442/2164 , Y10T442/2221
摘要： The present invention relates to a vapor-pervious water-impervious substrate, preferably a fibrous nonwoven web, which can be used in particular as a textile continuous sheet material, for example as an awning or as an inlet in apparel. The substrate according to the present invention may have self-cleaning properties. The substrate according to the present invention is simple to produce in an at least two-step process wherein a coating on the fibers of the substrate is produced in the first step and then hydrophobic particles are applied to the coated fibers by means of an adhesion promoter.
摘要翻译：本发明涉及可透气的不透水基材，优选纤维非织造纤维网，其可特别用作织物连续片材，例如作为遮阳篷或作为服装的入口。根据本发明的基底可以具有自清洁性质。根据本发明的基材易于以至少两步法生产，其中在第一步中制备基材纤维上的涂层，然后通过粘合促进剂将疏水性颗粒施加到涂覆的纤维上。

7. 发明申请

US20060003230A1 Pyrogenic oxidic powder, production thereof and use thereof in a separatior for an electrochemical cell 有权
标题翻译：热分解氧化粉末，其制备方法及其在电化学电池分离中的用途
公开(公告)号：US20060003230A1
公开(公告)日：2006-01-05
申请号：US10534952
申请日：2003-11-05
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： H01M2/16
CPC分类号： H01M10/052 , B82Y30/00 , C01B33/18 , C01F7/021 , C01F7/043 , C01G1/02 , C01G25/00 , C01P2004/64 , C01P2006/12 , C01P2006/40 , H01M2/166 , H01M10/0525 , H01M10/0565 , Y10T428/2982
摘要： A pyrogenic oxidic powder composed of particles, comprising (i) atoms of an element of groups 3A, 4A, 3B or 4B of the periodic table of the elements, and (ii) oxygen atoms, said particles being characterized by lithium atoms attached to said atoms via an oxygen bridge.
摘要翻译：由颗粒组成的热解氧化粉末，其包含（i）元素周期表的3A，4A，3B或4B族元素的原子，和（ii）氧原子，所述颗粒的特征在于与所述原子通过氧桥。

8. 发明申请

US20050221165A1 Electrical separator comprising a shut-down mechanism, method for the production thereof and its use in kithium batteries 失效
标题翻译：电分离器包括关闭机构，其制造方法及其在锂电池中的应用
公开(公告)号：US20050221165A1
公开(公告)日：2005-10-06
申请号：US10524145
申请日：2003-07-08
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： B05D1/12 , C08J7/06 , D06M11/45 , D06M11/48 , D06M11/79 , D06M13/513 , D06M15/227 , D06M23/08 , H01M2/00 , H01M2/14 , H01M2/16 , H01M10/0525 , H01M10/36 , H01M10/50
CPC分类号： D06M15/227 , C08J7/06 , D06M11/45 , D06M11/48 , D06M11/79 , D06M13/513 , D06M23/08 , H01M2/145 , H01M2/1613 , H01M2/162 , H01M2/164 , H01M2/1646 , H01M2/1653 , H01M2/166 , H01M2/1666 , H01M10/0525
摘要： The present invention relates to electrical separators for batteries, especially lithium batteries, having a shutdown mechanism and also a process for their production. An electrical separator is a separator which is used in batteries and other systems in which electrodes have to be separated from each other while maintaining ion conductivity for example. Safety is very important in lithium batteries, since in contrast to other types of battery (Pb, NiCd, NiMeH) the solvent for the electrolyte is not water but a combustible solvent, for example organic carbonates. This is why it is absolutely necessary for a separator for lithium cells to possess a suitable shutdown mechanism and at the same time for it not to be able to melt down. This object is achieved by an electrical separator according to the invention that comprises a shutdown layer which consists of particles which melt at a desired temperature, close the pores of the separator and so stop ion flow. Since the separator also comprises a porous inorganic (ceramic) layer on a carrier, the cells cannot melt down as a result of a completely melted separator.
摘要翻译：本发明涉及一种具有关机机构的电池隔离器，特别是锂电池，以及其制造方法。电分离器是用于电池和其它系统的隔板，其中电极必须彼此分离，同时保持例如离子传导性。安全性在锂电池中是非常重要的，因为与其他类型的电池（Pb，NiCd，NiMeH）相反，电解质的溶剂不是水而是可燃溶剂，例如有机碳酸盐。这就是为什么锂离子电池隔板绝对需要具有合适的关断机制，同时又不能熔化的原因。该目的通过根据本发明的电分离器实现，其包括由在所需温度下熔化的颗粒组成的关闭层，闭合分离器的孔并停止离子流。由于分离器还包含载体上的多孔无机（陶瓷）层，所以由于完全熔化的分离器，电池不能熔化。

9. 发明申请

US20050087491A1 Hybrid membrane, method for producing the same and use of said membrane 审中-公开
标题翻译：杂交膜，其制造方法和所述膜的使用
公开(公告)号：US20050087491A1
公开(公告)日：2005-04-28
申请号：US10498501
申请日：2003-01-15
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： B01D53/22 , B01D61/02 , B01D61/14 , B01D61/36 , B01D67/00 , B01D69/06 , B01D69/10 , B01D69/12 , B01D69/14 , B01D71/12 , B01D71/16 , B01D71/24 , B01D71/38 , B01D71/48 , B01D71/52 , B01D71/54 , B01D71/56 , B01D71/64 , B01D71/70 , D06M11/45 , D06M11/46 , D06M11/79 , D06M15/07 , D06M15/09 , D06M15/333 , D06M15/507 , D06M15/564 , D06M15/59 , D06M15/643 , D06M101/18 , D06M101/22 , D06M101/26 , D06M101/28 , D06M101/32 , D06M101/34 , B01D61/00
CPC分类号： B01D67/009 , B01D53/228 , B01D69/10 , B01D69/122 , B01D69/141 , B01D71/24 , B01D71/38 , B01D71/56 , B01D71/70
摘要： A description is given of a hybrid membrane which combines the advantages of the inorganic membranes, such as solvent resistance and stability, with the advantages of the organic membrane materials. The hybrid membrane described is composed of a ceramic support layer which is applied on a support comprising polymer fibers, and an organic, selective layer. The separating properties of the membranes can be tailored by varying the polymers and/or the way in which the polymer materials are treated and/or the conditions under which the polymeric selective separating layer is produced.
摘要翻译：给出了将无机膜的优点如耐溶剂性和稳定性与有机膜材料的优点相结合的混合膜的描述。所述的混合膜由施加在包含聚合物纤维的支持体和有机选择层上的陶瓷支撑层组成。膜的分离性质可以通过改变聚合物和/或聚合物材料的处理方式和/或产生聚合物选择性分离层的条件来调整。

10. 发明申请

US20080245735A1 Ceramic Flexible Membrane Providing Improved Adhesion to the Support Fleece 有权
标题翻译：陶瓷柔性膜提高了对支撑羊毛的粘附力
公开(公告)号：US20080245735A1
公开(公告)日：2008-10-09
申请号：US10575268
申请日：2004-08-19
申请人： Volker Hennige , Christian Hying , Gerhard Horpel
发明人： Volker Hennige , Christian Hying , Gerhard Horpel
IPC分类号： C04B35/106 , B32B5/02 , B01D61/14 , H01M2/14 , B05D5/10
CPC分类号： B01D67/0048 , B01D53/228 , B01D69/10 , B01D71/02 , B01D2323/345 , B01D2325/24 , H01M2/145 , H01M2/166 , H01M2/1686 , Y10T442/2402
摘要： The present invention relates to flexible ceramic membranes which, depending on embodiment, are useful as separators for batteries, especially lithium batteries, and also a process for their production.Ceramic or hybridic membranes have the disadvantage that, whatever the level of flexibility already achieved, they tend to crumble off the ceramic coating on bending. This is prevented by the present membranes, which comprise, on and in a polymeric nonwoven, a solidified ceramic coating which is constructed from two fractions of metal oxide particles of different size and which adheres to the polymeric nonwoven through a network constructed by two different adhesion promoters.
摘要翻译：本发明涉及柔性陶瓷膜，其取决于实施方式，可用作电池，特别是锂电池的隔板，以及它们的制造方法。陶瓷或杂化膜的缺点在于，无论所达到的灵活程度如何，它们都会在弯曲时破坏陶瓷涂层。这通过本发明的膜阻止，其在聚合物非织造材料中和聚合物非织造材料中包含由两种不同尺寸的金属氧化物颗粒组分构成的陶瓷涂层，并且通过由两种不同粘合剂构成的网络粘附到聚合物非织造材料上发起人。

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