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    • 9. 发明授权
    • Metal alloy fine particles and method for producing thereof
    • 金属合金微粒及其制造方法
    • US06875253B2
    • 2005-04-05
    • US10467593
    • 2002-02-06
    • Hideo DaimonYukiko KurobeNaoki Toshima
    • Hideo DaimonYukiko KurobeNaoki Toshima
    • B22F1/00B22F9/24B22F9/30C22C1/04C22C5/04G11B5/706
    • B82Y30/00B22F1/0018B22F9/24B22F9/30B22F2998/00C22C1/04C22C1/0491C22C5/04G11B5/70615G11B5/70621Y10S977/777
    • A novel method for preparing fine particles comprising a transition metal and a noble metal which are monodispersed and have almost no particle diameter distribution, and are transferable to a CuAu-I type L10 ordered phase, with safety and at a low cost, wherein a salt or a complex of at least one transition metal selected from Fe and Co and a salt or a complex of at least one transition metal selected from Pt and Pd (exclusive of the combination of Co—Pd) is dissolved in an organic solvent miscible with water or an alcohol in the presence of an organic protecting agent, and the resultant solution is heated under reflux in the presence of an alcohol in an inert atmosphere, to thereby prepare a binary alloy comprising a transition metal and a noble metal, or a salt or a complex of at least one element selected from the group consisting of Cu, Bi, Sb, Sn, Pb and Ag is further dissolved in the above solvent and the resultant solution is heated under reflux in the presence of an alcohol in an inert atmosphere, to thereby prepare a ternary alloy comprising a transition metal, a noble metal and an additional element.
    • 一种制备包含单分散且几乎不具有粒径分布的过渡金属和贵金属的微粒的新颖方法,可以安全和低成本转移至CuAu-I型L10有序相,其中盐 或选自Fe和Co的至少一种过渡金属和选自Pt和Pd的至少一种过渡金属的盐或络合物(不包括Co-Pd的组合)的络合物溶解在与水混溶的有机溶剂中 或醇在有机保护剂存在下,在醇的存在下在惰性气氛中加热回流,由此制备包含过渡金属和贵金属或盐的二元合金或 将选自Cu,Bi,Sb,Sn,Pb和Ag中的至少一种元素的络合物进一步溶解在上述溶剂中,并将所得溶液在醇的存在下加热回流 惰性气氛,由此制备包含过渡金属,贵金属和附加元素的三元合金。