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1. 发明申请

US20070149827A1 Process for preparing fluorohalogenethers 有权
公开(公告)号：US20070149827A1
公开(公告)日：2007-06-28
申请号：US11634145
申请日：2006-12-06
申请人： Vito Tortelli , Pierangelo Calini , Alberto Zompatori , Emanuela Antenucci
发明人： Vito Tortelli , Pierangelo Calini , Alberto Zompatori , Emanuela Antenucci
IPC分类号： C07C41/22
CPC分类号： C07C41/06 , C07C41/22 , C07C41/24 , C07C43/123 , C07C43/17
摘要： A process for preparing fluorovinylethers having general formula: RfO—CF═CF2 (IA) wherein Rf is a fluorinated or perfluorinated alkyl or cycloalkyl substituent; comprising the following reaction steps: 1) reaction of a hypofluorite of formula RfOF, wherein Rf is as above, with an olefin of formula: CY″Y═CY′CI (II) wherein Y, Y′ and Y″, equal to or different from each other, are H, Cl, Br, with the proviso that Y, Y′ and Y″ are not contemporaneously hydrogen; 2) dehalogenation or dehydrohalogenation of the fluorohalogenethers obtained in step 1) and obtainment of vinyl ethers of formula: RfO—CYI═CYIIF (IV) wherein YI and YII, equal to or different from each other, have the meaning of H, Cl, Br with the proviso that YI and YII are not both H; 3) fluorination with fluorine of the vinyl ethers (IV) and obtainment of fluorohalogenethers of formula: RfO—CFYI—CF2YII (I) wherein YI, YII, equal to or different from each other, are Cl, Br, H with the proviso that YI and YII cannot be contemporaneously equal to H; 4) dehalogenation or dehydrohalogenation of the fluorohalogenethers (I) and obtainment of the fluorovinylethers (IA).

2. 发明申请

US20050171388A1 Process for preparing fluorohalogenethers 有权
标题翻译：制备氟卤醚的方法
公开(公告)号：US20050171388A1
公开(公告)日：2005-08-04
申请号：US11044022
申请日：2005-01-28
申请人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
发明人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
IPC分类号： C07C41/18 , C07C41/05 , C07C41/24 , C07C41/48 , C07C43/12 , C07C43/17 , C07C43/313 , C07C43/315 , C07C41/16
CPC分类号： C07C41/48 , C07C43/313 , C07C43/315
摘要： A process for preparing (per)fluorohalogenethers having general formula: wherein: A and A′, equal to or different from each other, are selected among Cl, Br and H; m=1, 2; n=0, 1; R′ is a C1-C3 (per)fluoroalkyl substituent; R is a (per)fluoropolyether substituent; z and z′ are 1 or zero, X1=F, CF3; by reaction of carbonyl compounds having formula: (R′)n—C(O)(F)q(CF2ORI) (II) wherein: R′ and n are as above; q=0, 1; RI is a (per)fluoro-polyether substituent; in liquid phase, with elemental fluorine and with olefinic compounds of formula: CAF=CA′F2 (III) wherein A and A′ are as above, at temperatures from −120° C. to −20° C., preferably from −100° C. to −40° C.
摘要翻译：制备具有以下通式的（全）氟卤醚的方法：其中：A和A'彼此相同或不同，选自Cl，Br和H; m = 1,2; n = 0,1; R'是C 1 -C 3 -C 3（全）氟烷基取代基; R是一个（全）氟聚醚取代基; z和z'为1或0，X 1 = F，CF 3 3; 通过具有下式的羰基化合物的反应：<？in-line-formula description =“In-line formula”end =“lead”→（R'）n -C（O）（F）（II）（II）<？in-line-formula description =“In-line Formulas”end =“tail 其中：R'和n如上所述; q = 0,1; R 1是（全）氟 - 聚醚取代基; 在液相中使用元素氟和具有下式的烯属化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CAF = CA'F 2 III）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A和A'如上所述，在-120℃至-20℃的温度下，优选地 -100°C至-40°C

3. 发明授权

US07208638B2 Process for preparing fluorohalogenethers 有权
标题翻译：制备氟卤醚的方法
公开(公告)号：US07208638B2
公开(公告)日：2007-04-24
申请号：US11044022
申请日：2005-01-28
申请人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
发明人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
IPC分类号： C07C41/18
CPC分类号： C07C41/48 , C07C43/313 , C07C43/315
摘要： A process for preparing (per)fluorohalogenethers having general formula: wherein: A and A′, equal to or different from each other, are selected among Cl, Br and H; m=1, 2; n=0, 1; R′ is a C1 to C3 (per)fluoroalkyl substituent; R is a (per)fluoropolyether substituent; z and z′ are 1 or zero, X1=F, CF3; by reaction of carbonyl compounds having formula: (R′)n—C(O)(F)q(CFX1(CF2)z(CH2)z′OR1) (II) wherein: R′ and n are as above; q=0, 1; X1=F or CF3; z=0 or 1; R1 is a (per)fluoropolyether substituent; in liquid phase, with elemental fluorine and with olefinic compounds of formula: CAF=CA′F2 (III) wherein A and A′ are as above, at temperatures from −120° C. to −20° C., preferably from −100° C. to −40° C.
摘要翻译：制备具有以下通式的（全）氟卤醚的方法：其中：A和A'彼此相同或不同，选自Cl，Br和H; m = 1,2; n = 0,1; R'是C 3〜C 3（全）氟烷基取代基的C 1〜C 3。 R是一个（全）氟聚醚取代基; z和z'为1或0，X 1 = F，CF 3 3; 通过具有下式的羰基化合物的反应：<？in-line-formula description =“In-line formula”end =“lead”→（R'）n -C（O）（F）（CF 2）（CF 2）2（CF 2）2（CF 2）（CH 2）_{其中：R'和n分别为以上; q = 0,1; X 1 = F或CF 3 N; z = 0或1; R 1是一个（全）氟聚醚取代基; 在液相中使用元素氟和具有下式的烯属化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CAF = CA'F 2 III）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A和A'如上所述，在-120℃至-20℃的温度下，优选地 -100°C至-40°C}

4. 发明申请

US20070004940A1 Process for preparing fluorohalogenethers 有权
标题翻译：制备氟卤醚的方法
公开(公告)号：US20070004940A1
公开(公告)日：2007-01-04
申请号：US11044021
申请日：2005-01-28
申请人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
发明人： Vito Tortelli , Stefano Millefanti , Pierangelo Calini
IPC分类号： C07C43/02 , C07C43/20
CPC分类号： C07C43/123 , C07C41/01 , C07C43/126
摘要： A process for preparing (per)fluorohalogenethers having general formula: wherein: A and A′, equal to our different from each other, are selected among Cl, Br, H; m=1, 2; n=0, 1; R1 is a fluorinated substituent, preferably perfluorinated, selected from the following groups: C1-C20 linear or branched alkylic; C3-C7 cycloalkylic; aromatic, C6-C10 arylalkyl; heterocyclic or C5-C10-alkylheterocyclic; preferably perfluoroalkyl; R′ is as defined in the application; by reaction of carbonyl compounds having formula: wherein: R1 and n are as above; u=0, 1; R′ is as defined in the application; in liquid phase, with elemental fluorine and with olefinic compounds of formula: CAF═CA′F2 (III) wherein A and A′ are as above, at temperatures from −120° C. to −20° C., preferably from −100° C. to −40° C., optionally in the presence of an inert solvent under the reaction conditions.
摘要翻译：制备具有以下通式的（全）氟卤醚的方法：其中：A和A'等于我们彼此不同，选自Cl，Br，H; m = 1,2; n = 0,1; R 1是优选全氟化的氟化取代基，其选自以下基团：C 1 -C 20直链或支链烷基; C 3 -C 7环烷基; 芳族C 6 -C 10芳基烷基; 杂环或C 5 -C 10 - 烷基杂环; 优选全氟烷基; R'如申请中所定义; 通过具有下式的羰基化合物的反应：其中：R 1和n如上所述; u = 0，1; R'如申请中所定义; 在液相中使用元素氟和具有下式的烯属化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CAF-CA'F 2 III）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A和A'如上所述，在-120℃至-20℃的温度下，优选地 -100℃至-40℃，任选在惰性溶剂存在下，在反应条件下进行。

5. 发明授权

US07795477B2 Process for preparing fluorohalogenethers 有权
标题翻译：制备氟卤醚的方法
公开(公告)号：US07795477B2
公开(公告)日：2010-09-14
申请号：US11636509
申请日：2006-12-11
申请人： Vito Tortelli , Pierangelo Calini , Alberto Zompatori , Emanuela Antenucci
发明人： Vito Tortelli , Pierangelo Calini , Alberto Zompatori , Emanuela Antenucci
IPC分类号： C07C41/22
CPC分类号： C07C41/06 , C07C17/04 , C07C17/23 , C07C17/25 , C07C41/24 , C07C19/12 , C07C19/14 , C07C21/18 , C07C43/123 , C07C43/17
摘要： A process for preparing perfluorovinylethers having general formula: RfO—CF═CF2 (IA) where Rf is a C1-C3 alkyl perfluorinated substituent, comprises the steps of: 1a) fluorinating olefins of formula: CY″Y═CY′Cl (II) where Y, Y′ and Y″, equal to or different from each other, are H, Cl, Br, and are not contemporaneously hydrogen; and obtaining fluorohalogencarbons of formula: FCY″Y—CY′ClF (III) where Y, Y′ and Y″ are as above; 2a) dehalogenating or dehydrohalogenating fluorohalogencarbons (III) and obtaining fluorohalogenolefins of formula: FCYI═CYIIF (IV) where YI and YII, equal to or different from each other, are H, Cl, Br and are not contemporaneously H; 3a) reacting a hypofluorite of formula RfOF and a fluorohalogenolefin (IV), and obtaining the fluorohalogenethers of formula: RfO—CFYI—CF2YII (I) where YI, YII, equal to or different from each other, are Cl, Br, H and are not be contemporaneously H; and 4a) dehalogenating or dehydrohalogenating compounds (I) and obtaining perfluorovinylethers (IA).
摘要翻译：一种制备具有以下通式的全氟乙烯基醚的方法：RfO-CF = CF2（IA）其中Rf为C1-C3烷基全氟取代基，包括以下步骤：1a）氟化式：CY“Y = C''Cl（II）其中Y，Y'和Y“彼此相同或不同，为H，Cl，Br，并非同时为氢; 并获得式：FCY“Y-CY'ClF（III）的氟代卤素，其中Y，Y'和Y”如上所述; 2a）脱卤或脱卤化氢氟代烃（III）并得到式（Ⅳ）的氟卤代烯烃，其中YI和YII彼此相同或不同，为H，Cl，Br，不同时为H; 3a）使式RfOF的次氟化物与氟代卤代烯烃（IV）反应，得到其中YI，YII彼此相同或不同的式RfO-CFYI-CF2YII（I）的氟代醚，为Cl，Br，H和不是同时H 和4a）脱卤或脱卤化氢化合物（I）并获得全氟乙烯基醚（IA）。

6. 发明授权

US06835856B2 Process for preparing fluorohalogenethers 有权
标题翻译：制备氟卤醚的方法
公开(公告)号：US06835856B2
公开(公告)日：2004-12-28
申请号：US10633565
申请日：2003-08-05
申请人： Vito Tortelli , Pierangelo Calini
发明人： Vito Tortelli , Pierangelo Calini
IPC分类号： C07C4106
CPC分类号： C07C41/06 , C07C43/123 , C07C43/126
摘要： A process for preparing (per)fluorohalogenethers having general formula (I): (R)nC(F)mOCAF—CA′F2 (I) wherein: A and A′, equal to or different the one from the other, are Cl or Br or one is selected from A and A′ and hydrogen and the other is halogen selected from Cl, Br; R═F, or a fluorinated, preferably perfluorinated, substituent, selected from the following groups: linear or branched C1-C20 alkyl more preferably C1-C10; C3-C7 cycloalkyl; aromatic, C6-C10 arylalkyl, alkylaryl; C5-C10 heterocyclic or alkylheterocyclic; when R is fluorinated or perfluorinated alkyl, cycloalkyl, arylalkyl, alkylaryl, it can optionally contain in the chain one or more oxygen atoms; when R is fluorinated it can optionally contain one or more H atoms and/or one or more halogen atoms different from F: n is an integer and is 1 or 2; m=3-n; by reaction of carbonyl compounds having formula (II): (R)pC(F)q(O) (II) wherein: p is an integer and is 1 or 2; q is an integer and is zero or 1, R is as above; in liquid phase with elemental fluorine and with olefinic compounds having formula (III): CAF═CA′F (III) wherein A and A′ are as above, at temperatures in the range from −120° C. to −20° C.
摘要翻译：制备具有通式（I）的（全）氟卤醚的方法：其中：A和A'彼此相同或不同的是Cl或Br或一个选自A和A'，氢和另一个是选自Cl，Br的卤素; R = F或氟化，优选全氟化的取代基，选自以下基团：直链或支链C 1 -C 20烷基，更优选C 1 -C 10; C3-C7环烷基; 芳基，C 6 -C 10芳基烷基，烷基芳基; C5-C10杂环或烷基杂环; 当R是氟化或全氟化的烷基，环烷基，芳基烷基，烷基芳基时，它可以任选地在链中含有一个或多个氧原子;当R是氟化时，它可任选地含有一个或多个H原子和/或一个或多个不同于 F：n为整数，为1或2; m = 3-n; 通过具有式（II）的羰基化合物的反应：其中：p为整数，为1或2; q为整数且为零或1，R如上所述;在液相中含有元素氟和具有式（III）的烯属化合物：其中A和A'如上所述，在-120℃的温度范围内 -20℃

7. 发明授权

US07157600B2 Process for preparing (per) fluorohalogenethers 有权
标题翻译：制备（全）氟卤醚的方法
公开(公告)号：US07157600B2
公开(公告)日：2007-01-02
申请号：US10795995
申请日：2004-03-10
申请人： Vito Tortelli , Pierangelo Calini , Stefano Millefanti
发明人： Vito Tortelli , Pierangelo Calini , Stefano Millefanti
IPC分类号： C07C39/82
CPC分类号： C07C303/22 , C07C309/82
摘要： A process for preparing (per)fluorohalogenethers containing the —SO2F group, having general formula (I): FSO2—R—CF2OCAF—CA′F2 (I) wherein: A and A′, equal to or different from each other, are Cl or Br; R has the following meanings: a (per)fluorinated, preferably perfluorinated, substituent, optionally containing one or more oxygen atoms; by reaction of carbonyl compounds having formula (II): FSO2—R—COF (II) wherein R is as above; in liquid phase with elemental fluorine and with olefinic compounds having formula (III): CAF═CA′F (III) wherein A and A′ are as above, operating at temperatures from −120° C. to −20° C., optionally in the presence of a solvent inert under the reaction conditions.
摘要翻译：用于制备含（具有通式（I）的-SO 2 F基团的（每个）氟卤醚的方法：<？in-line-formula description =“In-line Formulas”end =“lead” α→FSO 2→R-CF 2→OCAF-CA'F 2（I）<βin-line-formula description =“In 其中：A和A'彼此相同或不同，为Cl或Br; R具有以下含义：任选含有一个或多个氧原子的（全）氟化的，优选全氟化的取代基; 通过具有式（II）的羰基化合物的反应：<？in-line-formula description =“In-line Formulas”end =“lead”→> FSO 2 -R-COF（II）？in-line-formula description =“In-line formula”end =“tail”？>其中R如上所述; （III）的烯属化合物：＆lt;线内公式描述=“In-line formula”end =“lead”？> CAF-CA'F（III） line-formula description =“In-line Formulas”end =“tail”？>其中A和A'如上所述，在-120℃至-20℃的温度下操作，任选地在溶剂存在下在反应条件下惰性。

8. 发明授权

US07019177B2 Process for preparing fluorohalogenethers 有权
标题翻译：制备氟卤醚的方法
公开(公告)号：US07019177B2
公开(公告)日：2006-03-28
申请号：US10766215
申请日：2004-01-29
申请人： Vito Tortelli , Pierangelo Calini
发明人： Vito Tortelli , Pierangelo Calini
IPC分类号： C07C41/06
CPC分类号： C08G65/007
摘要： A process for preparing (per)fluorohalogenethers having general formula (II): R′CF2OCFA-CA′F2 (II) wherein:— A and A′, equal to or different from each other, are H, Cl or Br but they cannot be both H; R′ has the following meanings: RO—, wherein R is a (per)fluorinated substituent, selected from the following groups: linear or branched C1–C20 alkyl; C3–C7 cycloalkyl; aromatic, C6–C10 arylalkyl or alkylaryl; C5–C10 heterocyclic or alkylheterocyclic; or a perfluoropolyether substituent T-Rf— wherein T=—OCF2OCFA-CA′F2, —OCF2XI, wherein XI=F, CF3, Cl; Rf is a perfluorooxyalkylene chain; by reaction of carbonyl compounds having formula R″COF (III) wherein R″=RO—, or R″=Q-Rf— wherein Q=—OCOF, —OCF2XI; in liquid phase with elemental fluorine and with olefinic compounds having formula CAF=CA′F (IV), at temperatures from −120° C. to −20° C.
摘要翻译：制备具有通式（II）的（全）氟卤醚的方法：<？in-line-formula description =“In-line formula”end =“lead”→R'CF 2 OCFA- 其中：A和A'等于或不同于每一个，其中：A和A'等于或不同于每个其他的是H，Cl或Br，但它们不能都是H; R'具有以下含义：RO-，其中R是选自以下基团的（全）氟化取代基：直链或支链C 1 -C 20烷基; C 3 -C 7环烷基; 芳香族，C 6 -C 10芳基烷基或烷基芳基; C 5 -C 10 - 杂环或烷基杂环; 或全氟聚醚取代基TR f其中T = -OCF 2 OCFA-CA'F 2，-OCF 2 I 在液相中与元素氟和具有式CAF = CA'F（IV）的烯属化合物在-120℃至-20℃的温度下反应。

9. 发明授权

US06936668B2 Amorphous perfluorinated copolymers 有权
标题翻译：无定形全氟化共聚物
公开(公告)号：US06936668B2
公开(公告)日：2005-08-30
申请号：US10913539
申请日：2004-08-09
申请人： Marco Apostolo , Francesco Triulzi , Vincenzo Arcella , Vito Tortelli , Pierangelo Calini
发明人： Marco Apostolo , Francesco Triulzi , Vincenzo Arcella , Vito Tortelli , Pierangelo Calini
IPC分类号： G02B6/00 , B29D11/00 , C08F8/20 , C08F8/22 , C08F214/18 , C08F216/12 , C08F234/00 , C08J5/00 , C08K5/00 , C08L29/10 , G02B1/04 , C08F114/18
CPC分类号： G02B1/046 , B29D11/00721 , C08F8/22 , C08L45/00 , C08F214/18
摘要： Amorphous perfluorinated copolymers, comprising cyclic perfluorinated units deriving from at least two different perfluorinated comonomers, optionally with units deriving from a perfluorinated monomer containing at least one olefinic unsaturation (perfluoroolefin), or comprising cyclic perfluorinated units and units deriving from a perfluorinated monomer containing at least one olefinic unsaturation, said perfluorinated copolymers having the following combination of properties: substantial absence of unstable polar end groups, polymer Tg higher than 120° C., narrow monomeric composition distribution.
摘要翻译：无定形全氟化共聚物，包含衍生自至少两种不同全氟化共聚单体的环状全氟化单元，任选地衍生自含有至少一种烯属不饱和（全氟烯烃）的全氟化单体的单元，或包含环状全氟化单元和衍生自至少含有全氟化单体的单元所述全氟化共聚物具有以下性质的组合：基本上不存在不稳定的极性端基，高于120℃的聚合物Tg，窄的单体组成分布。

10. 发明申请

US20050009944A1 Amorphous perfluorinated copolymers 有权
公开(公告)号：US20050009944A1
公开(公告)日：2005-01-13
申请号：US10913539
申请日：2004-08-09
申请人： Marco Apostolo , Francesco Triulzi , Vincenzo Arcella , Vito Tortelli , Pierangelo Calini
发明人： Marco Apostolo , Francesco Triulzi , Vincenzo Arcella , Vito Tortelli , Pierangelo Calini
IPC分类号： G02B6/00 , B29D11/00 , C08F8/20 , C08F8/22 , C08F214/18 , C08F216/12 , C08F234/00 , C08J5/00 , C08K5/00 , C08L29/10 , G02B1/04 , C08F114/18
CPC分类号： G02B1/046 , B29D11/00721 , C08F8/22 , C08L45/00 , C08F214/18
摘要： Amorphous perfluorinated copolymers, comprising cyclic perfluorinated units deriving from at least two different perfluorinated comonomers, optionally with units deriving from a perfluorinated monomer containing at least one olefinic unsaturation (perfluoroolefin), or comprising cyclic perfluorinated units and units deriving from a perfluorinated monomer containing at least one olefinic unsaturation, said perfluorinated copolymers having the following combination of properties: substantial absence of unstable polar end groups, polymer Tg higher than 120° C., narrow monomeric composition distribution.

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