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1. 发明申请

US20110086760A1 SUSPENSION CONCENTRATES IN OIL OF SULFONYLUREAS AND COMBINATIONS WITH FLUROXYPYR OR OTHER AGROCHEMICALS 审中-公开
标题翻译：磺化油中的悬浮浓度和与氟氧化合物或其他农业化合物的结合
公开(公告)号：US20110086760A1
公开(公告)日：2011-04-14
申请号：US12994796
申请日：2008-05-28
申请人： Victor Casana Giner , Miguel Gimeno Sierra , Bárbara Gimeno Sierra
发明人： Victor Casana Giner , Miguel Gimeno Sierra , Bárbara Gimeno Sierra
IPC分类号： A01N47/34 , A01N47/36 , A01N57/20 , A01N25/32 , A01P13/00
CPC分类号： A01N43/40 , A01N25/04 , A01N43/60 , A01N47/36 , A01N25/30 , A01N37/10 , A01N37/40 , A01N37/48 , A01N39/02 , A01N39/04 , A01N41/10 , A01N43/653 , A01N43/80 , A01N43/90 , A01N47/30 , A01N57/20 , A01N25/02 , A01N2300/00
摘要： Agricultural suspension in oil of Sulfonylureas and combinations with Fluroxypyr or other appropriate herbicides or agrochemicals are disclosed. The resulting formulations have improved stability regarding physicochemical properties of the formulation, as well as stability of the active ingredients allowing to make mixtures not yet available in the market.
摘要翻译：公布了磺酰脲油的农药悬浮液和氟吡菌胺或其他合适的除草剂或农药的组合。所得制剂对于制剂的物理化学性质以及活性成分的稳定性具有改善的稳定性，使得混合物尚未在市场上获得。

2. 发明授权

US09006145B2 Agrochemical formulations of microcapsules for compounds containing carboxamide groups 有权
标题翻译：含有羧酰胺基团的化合物的微胶囊化学制剂
公开(公告)号：US09006145B2
公开(公告)日：2015-04-14
申请号：US13266992
申请日：2009-04-30
申请人： Victor Casaña Giner , Miguel Gimeno Sierra , Bárbara Gimeno Sierra
发明人： Victor Casaña Giner , Miguel Gimeno Sierra , Bárbara Gimeno Sierra
IPC分类号： A01N25/28 , A01N47/36 , A01N47/28 , A01N47/34 , A01N37/24 , A01N43/32 , A01N43/40 , A01N43/56 , A01N43/78 , A01N47/38
CPC分类号： A01N25/28 , A01N37/24 , A01N43/32 , A01N43/40 , A01N43/56 , A01N43/78 , A01N47/28 , A01N47/34 , A01N47/36 , A01N47/38 , A01N25/04 , A01N2300/00
摘要： The present invention is directed towards microcapsules, uses and methods of microencapsulation with improved properties regarding agglomeration, bleeding and control of the reaction. The invention is especially suitable for chemical compounds with at least one carboxamide group, preferably for microencapsulation of those compounds wherein the carbonyl group is attached to a nitrogen atom or nitrogenated heterocycle and wherein the microencapsulation reaction may be too vigorous. The microcapsules are characterized by a mixed glycoluril-polyurea polymer wall, wherein the polyurea groups come from a urea-formaldehyde resin and not from isocyanate monomers or prepolymers. The process of making such microcapsules a dispersant in the oil phase of the type of block copolymer of vinylpyrrolidone/vinylalkene and/or vinylpyrrolidone/vinyl acetate and the microencapsulation reaction may be carried out without the presence of any polyamine/polyol acting as a catalyst.
摘要翻译：本发明涉及微胶囊，微胶囊化的用途和方法，其具有关于聚集，渗色和反应控制的改进的性质。本发明特别适用于具有至少一个羧酰胺基团的化合物，优选用于将羰基连接到氮原子或含氮杂环上的那些化合物的微囊化，并且其中微囊化反应可能太剧烈。微胶囊的特征在于混合的甘脲 - 聚脲聚合物壁，其中聚脲基团来自脲 - 甲醛树脂，而不是来自异氰酸酯单体或预聚物。制备这种微胶囊在乙烯基吡咯烷酮/乙烯基链烯烃和/或乙烯基吡咯烷酮/乙酸乙烯酯的嵌段共聚物类型的油相中的分散剂和微胶囊化反应的方法可以在不存在用作催化剂的任何多胺/多元醇的情况下进行。

3. 发明授权

US08293733B2 Oil dispersions of nAChR binding neonicotinoids 有权
标题翻译： nAChR结合新烟碱类的油分散体
公开(公告)号：US08293733B2
公开(公告)日：2012-10-23
申请号：US13254785
申请日：2010-03-04
申请人： Victor Casaña Giner , Miguel Gimeno Sierra , Bárbara Gimeno Sierra
发明人： Victor Casaña Giner , Miguel Gimeno Sierra , Bárbara Gimeno Sierra
IPC分类号： A61K31/535 , A61K31/435 , A61K31/44 , A61K31/34 , A61K31/426 , A01N43/08 , A01N43/78
CPC分类号： A01N51/00 , A01N43/40 , A01N43/78 , A01N47/40 , A01N25/04 , A01N25/30 , A01N47/34 , A01N53/00 , A01N2300/00
摘要： Selective insect neonicotinoids is a class of pesticide active ingredients that share some characteristics in their chemical structures and bind to the nAChR acetylcholine receptors. Formulation of such compounds in oil suspension or oil dispersion is challenging due to their electrostatic interactions of the heteroatoms in oily media, that lead to irreversible flocculation or diminished homogeneicity and bleeding of such oil dispersions. Imidacloprid, Thiamethoxam, Thiachloprid, Nitenpyram, Acetamiprid, Clothianidin and Dinetofuran and derivatives thereof with nAChR binding ability are successfully formulated in oil suspension with the use of certain copolymeric anionic fatty-acid based dispersants, sorbitan derivatives, ionic surfactants, other non-ionic surfactants and inorganic polyvalent cationic salt dispersed in the oil. The formulations this way produced show excellent storage stability properties regarding physiochemical parameters, including stability of the neonicotinoid active ingredient, reduced bleeding, and complete redispersibility. Further, they show excellent biological efficacy due to the reduced and homogeneous particle size below 2 μm when diluted—emulsified—in water.
摘要翻译：选择性昆虫新烟碱类是一类农药活性成分，在其化学结构中具有一些特征，并与nAChR乙酰胆碱受体结合。这种化合物在油悬浮液或油分散体中的配制是具有挑战性的，因为它们在油性介质中的杂原子的静电相互作用，导致不可逆的絮凝或这种油分散体的均匀性下降和渗色。使用某些共聚阴离子脂肪酸基分散剂，脱水山梨糖醇衍生物，离子表面活性剂，其他非离子表面活性剂，成功配制了具有nAChR结合能力的吡虫啉，噻虫嗪，噻虫啉，Nitenpyram，Acetamiprid，Clothianidin和Dinetofuran及其衍生物和分散在油中的无机多价阳离子盐。通过这种方式制备的制剂显示了关于生理化学参数的优异的储存稳定性，包括新烟碱活性成分的稳定性，降低的出血和完全的再分散性。此外，当稀释乳化在水中时，由于减小且均匀的粒径小于2μm，它们显示出优异的生物学效力。

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