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1. 发明授权

US5514738A 1-hydrocarbyloxy-piperidine compounds containing silane groups for use as stabilizers for organic materials 失效
标题翻译：含有硅烷基的1-烃氧基 - 哌啶化合物用作有机材料的稳定剂
公开(公告)号：US5514738A
公开(公告)日：1996-05-07
申请号：US374058
申请日：1995-01-19
申请人： Valerio Borzatta , Primo Carrozza , Ramanathan Ravichandran
发明人： Valerio Borzatta , Primo Carrozza , Ramanathan Ravichandran
IPC分类号： C09K15/32 , C07F7/08 , C07F7/10 , C07F7/18 , C07F7/21 , C08G77/26 , C08G77/28 , C08G77/38 , C08G77/388 , C08K5/544 , C08L23/00 , C08L87/00 , C08L101/00 , C08K5/3435
CPC分类号： C08K5/5442 , C07F7/0854 , C07F7/0859 , C07F7/21 , C08G77/26 , C08G77/388 , C08L101/00
摘要： New stabilizers of the formula (I) ##STR1## in which m+n is a number from 1 to 100 and n varies from zero to 90% of the sum of m+n,A is --O-- or ##STR2## where R.sub.6 is e.g. hydrogen or C.sub.1 -C.sub.18 alkyl, R.sub.1 and R.sub.4 which can be identical or different are C.sub.1 -C.sub.8 alkyl, phenyl, C.sub.1 -C.sub.8 alkoxy, OH, ONa or OK,R.sub.2 is C.sub.2 -C.sub.12 alkylene or also a direct bond if A is --O-- and R.sub.1 and R.sub.4 are C.sub.1 -C.sub.8 alkyl or phenyl,R.sub.3 is C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.2 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkenyl, C.sub.7 -C.sub.12 aralkyl, a saturated or unsaturated radical of a bicyclic or tricyclic C.sub.7 -C.sub.12 hydrocarbon or C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by C.sub.1 -C.sub.8 alkyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl,X.sub.1 is as defined for R.sub.1 or is a group (R.sub.7).sub.3 SiO-- with R.sub.7 being C.sub.1 -C.sub.8 alkyl,X.sub.2 is e.g. hydrogen, Na, K, C.sub.1 -C.sub.8 alkyl or a group (R.sub.7).sub.3 Si--,and, if m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together can also be a direct bond.
摘要翻译：式（I）的新稳定剂其中m + n为1至100的数，n为m + n之和的0至90％，A为-O-或其中R6是例如氢或C1-C18烷基，可以相同或不同的R1和R4是C1-C8烷基，苯基，C1-C8烷氧基，OH，ONa或OK，R2是C2-C12亚烷基，或者如果A是-O-，R1也是直接键 R 4是C 1 -C 8烷基或苯基，R 3是C 1 -C 18烷基，C 5 -C 12环烷基，C 2 -C 18烯基，C 5 -C 12环烯基，C 7 -C 12烷基，二环或三环C 7 -C 12烃或C 6 -C 10芳基的饱和或不饱和基团，未取代或被C 1 -C 8烷基取代，R 5为氢，C 1 -C 18烷基，C 5 -C 12环烷基或苯基，X 1如对R 1所定义，或为（R7）3SiO-，其中R7为C1-C8烷基，X2为例如氢，Na，K，C1-C8烷基或基团（R7）3Si-，并且如果m + n为3至10的数，则X1和X2一起也可以是直接键。

2. 发明授权

US5324834A Piperidine-triazine co-oligomers for use as stabilizers for organic materials 失效
标题翻译：哌啶 - 三嗪共聚物，用作有机材料的稳定剂
公开(公告)号：US5324834A
公开(公告)日：1994-06-28
申请号：US49239
申请日：1993-04-16
申请人： Valerio Borzatta , Primo Carrozza
发明人： Valerio Borzatta , Primo Carrozza
IPC分类号： C07D401/12 , C08G73/02 , C08G73/06 , C07D251/00 , C07D413/00 , C08K5/34 , C08K5/35
CPC分类号： C07D401/12 , C08G73/0273 , C08G73/0644
摘要： The present invention relates to novel co-oligomers containing recurring units of the formulae (Ia) and (Ib) ##STR1## which have a number average molecular weight of e.g. from 1,000 to 5,000 and a (Ia):(Ib) ratio of e.g. 1:1, and in which R.sub.1 and R.sub.5 are e.g. N-(2,2,6,6-tetramethyl-4-piperidyl)-n-butylamino, R.sub.2 is e.g. 2,2,6,6-tetramethyl-4-piperidyl, R.sub.3 is e.g. hexamethylene, R.sub.4 is e.g. hydrogen and X is e.g. a group ##STR2## These compounds are particularly suitable for stabilizing organic materials against light, heat and oxidation.
摘要翻译：本发明涉及含有数均分子量为例如式（Ia）和（Ib）的重复单元的新型共低聚物。 1,000至5,000和（Ia）（Ib）比例。 1：1，其中R1和R5是例如。 N-（2,2,6,6-四甲基-4-哌啶基） - 正丁基氨基， 2,2,6,6-四甲基-4-哌啶基，R 3是例如。六亚甲基，氢和X是例如。一组这些化合物特别适用于稳定有机材料，防止光，热和氧化。

3. 发明授权

US5219905A Piperidine compounds containing silane groups for use as stabilisers for organic materials 失效
标题翻译：含有硅烷组合物的管道化合物用作有机材料的稳定剂
公开(公告)号：US5219905A
公开(公告)日：1993-06-15
申请号：US805429
申请日：1991-12-11
申请人： Primo Carrozza , Valerio Borzatta
发明人： Primo Carrozza , Valerio Borzatta
IPC分类号： C07F7/12 , C07F7/08 , C07F7/18 , C07F7/21 , C08G77/26 , C08G77/38 , C08G77/388 , C08K5/54 , C08K5/5419 , C08K5/544 , C08K5/55 , C08L83/04 , C08L83/08 , C08L101/00
CPC分类号： C08K5/5442 , C07F7/0854 , C07F7/0896 , C07F7/184 , C08G77/26 , C08G77/388 , C08L101/00 , C08L2201/08
摘要： The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which A is e.g. a group of the formula ##STR2## where R.sub.4 is e.g. hydrogen or methyl, X.sub.3 is e.g. --O-- or --NH-- and R.sub.5 ' is e.g. ethylene, propylene or decamethylene, R.sub.1 is e.g. methyl, methoxy, ethoxy or OH, R.sub.2 and R.sub.3 are e.g. methyl, m+n is e.g. a number from 1 to 40, n varies e.g. from zero to 50% of the sum m+n, X.sub.1 is e.g. as defined for R.sub.1 or is a group (CH.sub.3).sub.3 SiO-- and X.sub.2 is e.g. hydrogen, methyl, ethyl, a group (CH.sub.3).sub.3 Si-- or a group ##STR3## and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together also form a direct bond. The compounds of the formula (I) are effective in stabilising an organic material against thermal, oxidative and light-induced degradation.

4. 发明授权

US5321066A Piperdine compounds containing silane groups for use as stabilizers for organic materials 失效
标题翻译：含有硅烷基的哌啶化合物用作有机材料的稳定剂
公开(公告)号：US5321066A
公开(公告)日：1994-06-14
申请号：US19520
申请日：1993-02-19
申请人： Primo Carrozza , Valerio Borzatta
发明人： Primo Carrozza , Valerio Borzatta
IPC分类号： C07F7/12 , C07F7/08 , C07F7/18 , C07F7/21 , C08G77/26 , C08G77/38 , C08G77/388 , C08K5/54 , C08K5/5419 , C08K5/544 , C08K5/55 , C08L83/04 , C08L83/08 , C08L101/00 , C07F7/10
CPC分类号： C08K5/5442 , C07F7/0854 , C07F7/0896 , C07F7/184 , C08G77/26 , C08G77/388 , C08L101/00 , C08L2201/08
摘要： The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which A is e.g. a group of the formula ##STR2## where R.sub.4 is e.g. hydrogen or methyl, X.sub.3 is e.g. --O-- or --NH-- and R.sub.5 ' is e.g. ethylene, propylene or decamethylene, R.sub.1 is e.g. methyl, methoxy, ethoxy or OH, R.sub.2 and R.sub.3 are e.g. methyl, m+n is e.g. a number from 1 to 40, n varies e.g. from zero to 50% of the sum m+n, X.sub.1 is e.g. as defined for R.sub.1 or is a group (CH.sub.3).sub.3 SiO-- and X.sub.2 is e.g. hydrogen, methyl, ethyl, a group (CH.sub.3).sub.3 Si-- or a group ##STR3## and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together also form a direct bond. The compounds of the formula (I) are effective in stabilising an organic material against thermal, oxidative and light-induced degradation.
摘要翻译：本发明涉及式（I）的新型哌啶化合物，其中A为例如。一组式为“IMAGE”，其中R4为例如。氢或甲基，X3是例如。 -O-或-NH-和R5'是例如。乙烯，丙烯或十亚甲基。甲基，甲氧基，乙氧基或OH，R2和R3是例如。甲基，m + n为例如。 1到40的数，n变化例如从总和m + n的零到50％，X1是例如。如对R 1所定义或是基团（CH 3）3 SiO-和X 2是例如。氢，甲基，乙基，基团（CH 3）3 Si-或基团，当m + n为3〜10的数时，X1和X2一起也形成直接键。式（I）的化合物有效地稳定有机材料以防止热，氧化和光诱导的降解。

5. 发明授权

US6005036A Polysilanes 失效
标题翻译：聚硅烷
公开(公告)号：US6005036A
公开(公告)日：1999-12-21
申请号：US981433
申请日：1997-12-22
申请人： Primo Carrozza , Valerio Borzatta , Chryssostomos Chatgilialoglu
发明人： Primo Carrozza , Valerio Borzatta , Chryssostomos Chatgilialoglu
IPC分类号： C08K5/55 , C08G77/60 , C08L23/02 , C08L83/05 , C08L83/10 , C08L83/16 , C08L101/00 , C08K5/54
CPC分类号： C08L23/02 , C08L101/00 , C08L83/16
摘要： A composition containing an organic material subject to oxidative, thermal or actinic degradation can be stabilized by an effective amount of at least one polysilane compound of formula I ##STR1## Preferred compounds are where q is zero, p is 2 to 50, m is zero, R.sub.1 is alkyl, phenyl or benzyl, and A and B are independently hydrogen or a group --Si(E).sub.3 where E is alkyl. These compounds can also be copolymeric having a random, alternate or block distribution of individual structural units. These compounds are particularly suitable as process stabilizers.
摘要翻译： PCT No.PCT / EP96 / 02667 Sec。 371 1997年12月22日第 102（e）日期1997年12月22日PCT提交1996年6月20日PCT公布。公开号WO97 / 02322 日期1997年1月23日含有氧化，热或光化降解的有机材料的组合物可以通过有效量的至少一种式I的聚硅烷化合物来稳定。优选的化合物是其中q为0，p为2至50，m 苯基或苄基，且A和B独立地是氢或基团-Si（E）3，其中E是烷基。这些化合物也可以是具有各个结构单元的随机，交替或嵌段分布的共聚物。这些化合物特别适合作为工艺稳定剂。

6. 发明授权

US5726226A Peperidine compounds containing silane groups as stabilizers for organic materials 失效
标题翻译：含有硅烷基的Peperidine化合物作为有机材料的稳定剂
公开(公告)号：US5726226A
公开(公告)日：1998-03-10
申请号：US836949
申请日：1997-05-22
申请人： Valerio Borzatta , Primo Carrozza
发明人： Valerio Borzatta , Primo Carrozza
IPC分类号： C07F7/10 , C07F7/08 , C07F7/18 , C08G77/26 , C08G77/388 , C08K5/544 , C08L23/00 , C08L23/02 , C08L83/04 , C08L101/00
CPC分类号： C08K5/5442 , C07F7/0854 , C08G77/26 , C08G77/388 , C08L23/02
摘要： Compounds of formula (I) ##STR1## in which m+n is a number from 1 to 100 and n varies from zero to 90% of the sum of m+n; R.sub.1 and R.sub.3, which may be identical or different, are for example C.sub.1 -C.sub.18 alkyl or phenyl; R.sub.2 is C.sub.2 -C.sub.12 alkylene; G is for example a group of formula (IId) ##STR2## in which R.sub.5 and R.sub.6 are for example hydrogen; R.sub.4 is for example C.sub.1 -C.sub.18 alkyl; L.sub.1 has for example any one of the meanings given to R.sub.1 or is a group (R.sub.28).sub.3 SiO-- where R.sub.28 is C.sub.1 -C.sub.18 alkyl; and L.sub.2 is for example hydrogen, Na, K, C.sub.1 -C.sub.8 alkyl or a group (R.sub.28).sub.3 Si-- with R.sub.28 as defined above. The compounds of formula (I) are useful as light, heat and oxidation stabilizers for organic materials.
摘要翻译： PCT No.PCT / EP95 / 04546 Sec。 371日期：1997年5月22日 102（e）日期1997年5月22日PCT提交1995年11月18日PCT公布。 WO96 / 17002 PCT出版物日期：1996年6月6日，式（I）的化合物其中m + n为1〜100的数，n为m + n之和的0〜90％。 R 1和R 3可以相同或不同，例如为C 1 -C 18烷基或苯基; R2是C2-C12亚烷基; G例如是式（IId）（IId）的基团，其中R5和R6是例如氢; R4是例如C1-C18烷基; L1具有例如给定R 1的任何一个或是R 28为C 1 -C 18烷基的基团（R 28）3 SiO - 和L 2例如是氢，Na，K，C 1 -C 8烷基或具有如上定义的R 28的基团（R 28）3 Si-。式（I）化合物可用作有机材料的光，热和氧化稳定剂。

7. 发明授权

US5561179A Piperidine compounds containing silane groups as stabilizers for organic materials 失效
标题翻译：含有硅烷基的哌啶化合物作为有机材料的稳定剂
公开(公告)号：US5561179A
公开(公告)日：1996-10-01
申请号：US560263
申请日：1995-11-21
申请人： Valerio Borzatta , Primo Carrozza
发明人： Valerio Borzatta , Primo Carrozza
IPC分类号： C08G77/14 , C08G77/22 , C08G77/26 , C08G77/28 , C08G77/388 , C08K5/5419 , C08L83/04 , C08L83/08 , C09K15/32 , C08K5/3492 , C07D211/48 , C07D211/58 , C07D401/02 , C07D401/14 , C08K5/3435
CPC分类号： C09K15/32 , C08G77/26 , C08G77/388
摘要： Compounds of the formula (I) ##STR1## in which m and n are numbers from 1 to 50; A is --O-- or >N--R.sub.6 where R.sub.6 is e.g. hydrogen or C.sub.1 -C.sub.18 alkyl; R.sub.1 and R.sub.4, which may be identical or different, are C.sub.1 -C.sub.18 alkyl, phenyl, C.sub.1 -C.sub.8 alkoxy, OH, ONa or OK; R.sub.2 is e.g. C.sub.2 -C.sub.12 alkylene; R.sub.3 is e.g. hydrogen or C.sub.1 -C.sub.8 alkyl; R.sub.5 is e.g. a group of the formula ##STR2## in which R.sub.9 is e.g. 2,2,6,6-tetramethyl-4-piperidyl; A' has one of the meanings of A; p is e.g. 1 and R.sub.10 is e.g. C.sub.2 -C.sub.18 alkylene; X.sub.1 has one of the meanings of R.sub.1 or is a group (R.sub.27).sub.3 SiO-- where R.sub.27 is C.sub.1 -C.sub.18 alkyl; X.sub.2 is hydrogen, Na, K, C.sub.1 -C.sub.8 alkyl or a group (R.sub.27).sub.3 Si-- with R.sub.27 as defined above and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together can also represent a direct linkage; are useful as stabilizers for organic materials against degradation induced by light, heat or oxidation.
摘要翻译：式（I）的化合物其中m和n是1至50的数字; A是-O-或> N-R6，其中R6是例如。氢或C 1 -C 18烷基; 可以相同或不同的R 1和R 4是C 1 -C 18烷基，苯基，C 1 -C 8烷氧基，OH，ONa或OK; R2是例如 C2-C12亚烷基; R3是例如氢或C 1 -C 8烷基; R5是例如其中R9为例如式的组。 2,2,6,6-四甲基-4-哌啶基; A'具有A的含义之一; p是例如。 1和R10是例如 C2-C18亚烷基; X1具有R 1的含义之一，或为R 27为C 1 -C 18烷基的基团（R 27）3 SiO - X 2是氢，Na，K，C 1 -C 8烷基或具有如上定义的R 27的基团（R 27）3 Si-，当m + n是3至10的数时，X 1和X 2也可以表示直接键; 可用作有机材料的稳定剂，以防止由光，热或氧化引起的降解。

8. 发明授权

US5418267A Piperidine compounds containing silane groups for use as stabilizers for organic materials 失效
标题翻译：含有硅烷基的哌啶化合物用作有机材料的稳定剂
公开(公告)号：US5418267A
公开(公告)日：1995-05-23
申请号：US234892
申请日：1994-04-28
申请人： Primo Carrozza , Valerio Borzatta
发明人： Primo Carrozza , Valerio Borzatta
IPC分类号： C07F7/12 , C07F7/08 , C07F7/18 , C07F7/21 , C08G77/26 , C08G77/38 , C08G77/388 , C08K5/54 , C08K5/5419 , C08K5/544 , C08K5/55 , C08L83/04 , C08L83/08 , C08L101/00 , C07F7/10
CPC分类号： C08K5/5442 , C07F7/0854 , C07F7/0896 , C07F7/184 , C08G77/26 , C08G77/388 , C08L101/00 , C08L2201/08
摘要： The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which A is e.g. a group of the formula ##STR2## where R.sub.4 is e.g. hydrogen or methyl, X.sub.3 is e.g. --O-- or --NH-- and R.sub.5' is e.g. ethylene, propylene or decamethylene, R.sub.1 is e.g. methyl, methoxy, ethoxy or OH, R.sub.2 and R.sub.3 are e.g. methyl, m+n is e.g. a number from 1 to 40, n varies e.g. from zero to 50% of the sum m+n, X.sub.1 is e.g. as defined for R.sub.1 or is a group (CH.sub.3).sub.3 SiO-- and X.sub.2 is e.g. hydrogen, methyl, ethyl, a group (CH.sub.3).sub.3 Si-- or a group ##STR3## and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together also form a direct bond. The compounds of the formula (I) are effective in stabilizing an organic material against thermal, oxidative and light-induced degradation.
摘要翻译：本发明涉及式（I）的新型哌啶化合物，其中A为例如。一组式为“IMAGE”，其中R4为例如。氢或甲基，X3是例如。 -O-或-NH-和R5'是例如。乙烯，丙烯或十亚甲基。甲基，甲氧基，乙氧基或OH，R2和R3是例如。甲基，m + n为例如。 1到40的数，n变化例如从总和m + n的零到50％，X1是例如。如对R 1所定义或是基团（CH 3）3 SiO-和X 2是例如。氢，甲基，乙基，基团（CH 3）3 Si-或基团，当m + n为3〜10的数时，X1和X2一起也形成直接键。式（I）的化合物有效地稳定有机材料以防止热，氧化和光诱导的降解。

9. 发明授权

US06538055B1 Polysilane stabitizers containing sterically hindered amine groups 失效
标题翻译：含有空间位阻胺基团的聚硅烷稳定剂
公开(公告)号：US06538055B1
公开(公告)日：2003-03-25
申请号：US09959171
申请日：2001-10-18
申请人： Primo Carrozza , Valerio Borzatta , Giovanni Da Roit , Chryssostomos Chatgilialoglu
发明人： Primo Carrozza , Valerio Borzatta , Giovanni Da Roit , Chryssostomos Chatgilialoglu
IPC分类号： C08K5544
CPC分类号： C08G77/60
摘要： A compound containing a silane backbone and a group of formula (A) wherein R is hydrogen, C1-C8alkyl, —O, —OH, —CH2CN, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C6alkenyl, C7-C9phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C1-C4alkyl; or C1-C8acyl; is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.
摘要翻译：含有硅烷骨架和式（A）的基团的化合物，其中R是氢，C 1 -C 8烷基，-O，-OH，-CH 2 CN，C 1 -C 18烷氧基，C 5 -C 12环烷氧基，C 3 -C 6烯基，未被取代或取代的C 7 -C 9苯基烷基在苯基上有1,2或3个C 1 -C 4烷基; 或C 1 -C 8酰基; 用于稳定有机材料以防止由光，热或氧化引起的降解。

10. 发明授权

US5578665A Piperidine compounds containing silane groups for use as stabilizers for organic materials 失效
公开(公告)号：US5578665A
公开(公告)日：1996-11-26
申请号：US399666
申请日：1995-03-07
申请人： Primo Carrozza , Valerio Borzatta
发明人： Primo Carrozza , Valerio Borzatta
IPC分类号： C07F7/12 , C07F7/08 , C07F7/18 , C07F7/21 , C08G77/26 , C08G77/38 , C08G77/388 , C08K5/54 , C08K5/5419 , C08K5/544 , C08K5/55 , C08L83/04 , C08L83/08 , C08L101/00 , C07F7/10
CPC分类号： C08K5/5442 , C07F7/0854 , C07F7/0896 , C07F7/184 , C08G77/26 , C08G77/388 , C08L101/00 , C08L2201/08
摘要： The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which A is e.g. a group of the formula ##STR2## where R.sub.4 is e.g. hydrogen or methyl, X.sub.3 is e.g. --O-- or --NH-- and R.sub.5 ' is e.g. ethylene, propylene or decamethylene, R.sub.1 is e.g. methyl, methoxy, ethoxy or OH, R.sub.2 and R.sub.3 are e.g. methyl, m+n is e.g. a number from 1 to 40, n varies e.g. from zero to 50% of the sum m+n, X.sub.1 is e.g. as defined for R.sub.1 or is a group (CH.sub.3).sub.3 SiO-- and X.sub.2 is e.g. hydrogen, methyl, ethyl, a group (CH.sub.3).sub.3 Si-- or a group ##STR3## and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together also form a direct bond. The compounds of the formula (I) are effective in stabilizing an organic material against thermal, oxidative and light-induced degradation.

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