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    • 5. 发明申请
    • AQUEOUS ELECTROPHORETIC DEPOSITION
    • 水性电泳沉积
    • WO2010034826A2
    • 2010-04-01
    • PCT/EP2009/062472
    • 2009-09-25
    • KATHOLIEKE UNIVERSITEIT LEUVEN, K.U.LEUVEN R&DFRANSAER, JanNEIRINCK, BramVAN DER BIEST, OmerVLEUGELS, Jozef
    • FRANSAER, JanNEIRINCK, BramVAN DER BIEST, OmerVLEUGELS, Jozef
    • C25D13/04C25D13/18
    • C09D5/448A23P20/10C08L89/00C09D5/024C09D7/65C25D13/04C25D13/18
    • From an environmental, safety and economic perspective water should be the solvent of choice for electrophoretic deposition under industrial circumstances. However, because of the electrolytic decomposition of water, the majority of EPD is carried out in non-aqueous solvents. Approaches of the art for aqueous deposition involve the separation of the reaction and deposition front by means of a membrane, the use of palladium electrodes to absorb the formed hydrogen, addition of chemicals to suppress the electrolysis reaction, or lowering voltages below the threshold for water electrolysis. With the first two solutions, the production of coatings is impractical since the deposit is not formed on the electrode, or the electrode material is not suitable since the substrate is usually prescribed by the application. The use of specialty chemicals is expensive and difficult to control. Low voltages have been used to form high quality deposits from aqueous systems but they display very low deposition rates, which are not attractive from an economical perspective. Present invention provides a system and a means for which high voltages can be used in the electrophoretic deposition from aqueous suspensions without decomposition of water at satisfying deposition rates. It shows that the deposits obtained show a high green density with excellent surface quality.
    • 从环境,安全和经济的角度来看,水应该是工业环境下电泳沉积的首选溶剂。 但是,由于水的电解分解,大部分EPD是在非水溶剂中进行的。 用于水性沉积的技术方法涉及通过膜分离反应和沉积前沿,使用钯电极吸收形成的氢,添加化学物质以抑制电解反应或将电压降低到水的阈值以下 电解。 对于前两种解决方案,由于在电极上不形成沉积物,所以涂层的生产是不切实际的,或者电极材料不适合,因为基材通常由应用规定。 特种化学品的使用昂贵且难以控制。 低电压已被用于从含水系统形成高质量沉积物,但它们显示非常低的沉积速率,这从经济角度来看并不具吸引力。 本发明提供了一种系统和一种装置,其中可以在含水悬浮液的电泳沉积中使用高电压而不会以满意的沉积速率分解水。 这表明获得的沉积物表现出高的生坯密度和优异的表面质量。
    • 10. 发明申请
    • LIQUID METAL SALTS
    • 液体金属盐
    • WO2011109878A1
    • 2011-09-15
    • PCT/BE2011/000010
    • 2011-03-14
    • KATHOLIEKE UNIVERSITEIT LEUVENBINNEMANS, KoenBROOKS, Niel, RichardFRANSAER, JanSCHALTIN, Stijn
    • BINNEMANS, KoenBROOKS, Niel, RichardFRANSAER, JanSCHALTIN, Stijn
    • C07F1/00C07F3/00C25D15/00
    • C07F1/005C23C18/31C25D3/20C25D3/38C25D3/46C25D3/54C25D3/665
    • A liquid metal salt in which a metal (M) ion is surrounded by neutral ligands (L), or by a combination of neutral ligands (L) and negatively charged ligands (Y) such that the total negative charge of the total number of negatively charged ligands (Y) is smaller than the oxidation state of the metal ion so that the metal complex has an overall positive charge, with at least one counter anion (X), wherein M is a metal selected from the group consisting of copper, zinc, silver, gold, platinum, cobalt, nickel, tungsten, molybdenum and aluminium.; L is a neutral ligand and is selected from the group consisting of aceto- nitrile, propionitrile, butyronitrile, isobutyronitrile, acrylonitrile, 2-hydroxycyano-ethane, phenylacetonitrile, benzonitrile benzylnitrile, DMF, acetamide, N,N-dimethylacetamide, formamide, N-methylformamide, N-methylacetamide, DMSO, dimethylsulfone, hexa- methylphosphoramide, N-methylpyrrolidone, pyridine, morpholine, THF, diethyl ether, dimethoxyethane, bis(2-methoxyethyl) ether, triglyme, tetraglyme, pentaglyme, hexa- glyme, 1,4-dioxane, methanol, ethanol, propanol, butanol, ethyleneglycol, polyethylene- glycol, water, trialkylphosphine oxides, triaryl-phosphine oxides, trialkylphosphate, pyrazole, 3-alkylpyrazoles, 5-alkylpyrazoles, 3,5-dimethylpyrazole, imidazole, 1-alkyl- imidazoles, 1,2-dimethylimidazole, 2-imidazolid-inone, thiabendazole, ammonia, tetramethylenesulfoxide, urea, Ν,Ν,Ν',Ν'-tetramethylurea, thiourea, lactams, hydroxypyridines, 2-pyridone, pyridine-N-oxide, picoline-N-oxide, 2,6-lutidine, 2,6- lutidine N-oxide, pyrazine, pyrazine-N-oxide, 1,4-dithiane monosulfoxide, 2,2'-bipyridine, 1,10-phenanthroline, 2,6,2', 2"-terpyridine, ethylenediamine, diethyl enetriamine, 1,2,3- triaminopropane, cyclam, crown ethers and thiacrown ethers; Y is selected from the group consisting of chloride, bromide, iodide, thiocyanate, formate, acetate, trifluoroacetate, propionate, butyrate, pentanoate, hexanoate, benzoate, glycolate, heptafluorobutanate, alkylsulfate, octylsulfate, dodecylsulfate, triflate, methanesulfonate, nitrate, dicyanamide, tricyano-methanide, bis(trifluoromethylsulfonyl)-imide or bis(perfluoroalkylsulfonyl)- imide, dimethylphosphate, diethylphosphate, dialkylphosphate, saccharinate, acesulfamate and tosylate; and X is a counter anion selected from the group consisting of hexafluoro- phosphate, tetrafluoroborate, bis(trifluoromethylsulfonyl)imide (bistriflimide), bis(tri- fluoroalkylsulfonyl)imide, dicyanamide, triflate, methanesulfonate and trifluoroacetate; and uses thereof in an electrodeposition process, for electrodeposition of a metal M, for battery application; for electrochromic device, in fuel cells, for electropolishing and for electroless deposition of a metal M.
    • 其中金属(M)离子被中性配体(L)包围的液态金属盐,或通过中性配体(L)和带负电荷的配体(Y)的组合使得总负电荷总负数 带电配体(Y)小于金属离子的氧化态,使得金属络合物具有总体正电荷,至少有一个抗衡阴离子(X),其中M是选自铜,锌 ,银,金,铂,钴,镍,钨,钼和铝。 L是中性配体,选自乙腈,丙腈,丁腈,异丁腈,丙烯腈,2-羟基氰基乙烷,苯乙腈,苄腈苄腈,DMF,乙酰胺,N,N-二甲基乙酰胺,甲酰胺, 甲基甲酰胺,N-甲基乙酰胺,DMSO,二甲基砜,六甲基磷酰胺,N-甲基吡咯烷酮,吡啶,吗啉,THF,乙醚,二甲氧基乙烷,双(2-甲氧基乙基)醚,三甘醇二甲醚,四甘醇二甲醚,五甘醇二甲醚,六甘醇二甲醚, 二恶烷,甲醇,乙醇,丙醇,丁醇,乙二醇,聚乙二醇,水,三烷基氧化膦,三芳基膦氧化物,磷酸三烷基酯,吡唑,3-烷基吡唑,5-烷基吡唑,3,5-二甲基吡唑,咪唑, - 咪唑,1,2-二甲基咪唑,2-咪唑烷酮,噻菌灵,氨,四甲基亚砜,脲,α,α,α',α'-四甲基脲,硫脲,内酰胺,羟基吡啶,2-吡啶酮,吡啶-N-氧化物 ,甲基吡啶-N-氧化物,2,6-二甲基吡啶, 2,6-二甲基吡啶N-氧化物,吡嗪,吡嗪-N-氧化物,1,4-二噻烷单亚砜,2,2'-联吡啶,1,10-菲咯啉,2,6,2',2“ - 三联吡啶,乙二胺 ,二乙基三乙胺,1,2,3-三氨基丙烷,环己烷,冠醚和噻吩醚; Y选自氯化物,溴化物,碘化物,硫氰酸盐,甲酸盐,乙酸盐,三氟乙酸盐,丙酸盐,丁酸盐,戊酸盐,己酸盐,苯甲酸盐,乙醇酸盐,七氟丁酸盐,烷基硫酸盐,辛基硫酸盐,十二烷基硫酸盐,三氟甲磺酸盐,甲磺酸盐,硝酸盐, 三(三氟甲基磺酰基) - 酰亚胺或双(全氟烷基磺酰基) - 酰亚胺,磷酸二甲酯,磷酸二乙酯,磷酸二烷基酯,糖精,乙酰氨基磺酸酯和甲苯磺酸酯; 并且X是选自六氟磷酸盐,四氟硼酸盐,双(三氟甲磺酰基)酰亚胺(双三氟酰亚胺),双(三氟烷基磺酰基)酰亚胺,二氰胺,三氟甲磺酸酯,甲磺酸盐和三氟乙酸盐的抗衡阴离子; 并将其用于电沉积工艺中,用于电沉积金属M,用于电池应用; 用于电致变色装置,在燃料电池中,用于电解抛光和金属M的无电沉积。