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    • 3. 发明专利
    • Detergent and dispersive additive in lubricating oils for internal combustion engines and process for preparing thereof
    • CZ292648B6
    • 2003-11-12
    • CZ299796
    • 1995-04-13
    • MOL MAGYAR OLAJ & GAZIPARI RTVESZPREMI EGYETEM
    • DENES FERENCKIS JANOSBALADINCZ JENOAUER JANOSDEAK GYULABARTHA LASLOHANCSOK JENOKOVACS MAGDA
    • C08F8/46C10M129/95C10M133/52C10M133/56C10M145/16C10M149/02C10M149/06C10M159/12C10M177/00
    • The present invention relates to a lubricating oil additive for internal combustion engines comprising imide and/or ester and/or ester amide derivatives of a reaction product of an unsaturated polyisobutylene and unsaturated reactive dicarboxylic acids and/or anhydrides thereof. The comprised polyisobutylene reaction product has number average molecular weight within the range of 800 to 15 000 and the unsaturated reactive dicarboxylic acids and/or anhydrides thereof are preferably represented by maleic anhydride containing in average 1.6 to 6.0 succinic anhydride derivative per polyisobutylene chain and having concentration of molecules, containing more than one succinic anhydride derivative, higher than 25 percent. Polyisobutylene is grafted or reacted with a copolymer containing succinic anhydride, whereby the copolymer is obtained from a reactive low-molecular co-monomer having molecular weight lower than 500 and containing an olefinic double bond, or from a mixture of such co-monomers and from unsaturated reactive dicarboxylic acid and/or anhydride thereof, preferably maleic anhydride, using molar ratio maleic anhydride : co-monomer : polyisobutylene within the range of 1.2 to 5.5 : 0.1 to 3.5 : 1. Expansion of molecular weight distribution makes less than 70 percent based on the starting polyisobutylene, and succinic anhydride group of the copolymer attached to the polyisobutylene are reacted in the ratio 0.7 to 5.5 with a compound containing at least bifunctional amine and/or hydroxyl groups. A process for preparing such additive is based on an addition reaction by means of which maleic anhydride and the co-monomer with olefinic double bond or a copolymer thereof are grafted to the polyisobutylene in the presence of a radical initiator. The obtained product is then reacted in the presence of a catalyst with compounds containing one or more bifunctional amino and/or hydroxyl groups.
    • 10. 发明专利
    • ES2128606T3
    • 1999-05-16
    • ES95105672
    • 1995-04-13
    • MOL MAGYAR OLAJ & GAZIPARI RTVESZPREMI EGYETEM
    • DENES FERENC DRKIS JANOSBALADINCZ JENOAUER JANOSDEAK GYULA DRBARTHA LASZLO DR
    • C08F8/46C10M129/95C10M133/52C10M133/56C10M145/16C10M149/02C10M149/06C10M159/12C10M177/00
    • An additive for lubricating oils of internal combustion engines containing the imide- and/or ester and/or ester-amide, derivatives of the reaction product of an unsaturated polyisobutylene and some unsaturated reactive dicarboxylic acids and/or their anhydride comprising the reaction product of a polyisobutylene of a number average molecular weight 800 - 30 000 and an unsaturated reactive dicarboxylic acid and/or its anhydride, preferably maleic anhydride containing 1.6 - 6.0 SA - derivative per polyisobutylene chain on the average having a concentration of molecules containing more than one SA - derivative more than 25 weight percent and the polyisobutylene is grafted or reacted with an SA containing copolymer formed from a more reactive, low molecular weight comonomer of a molecular weight less than 500, containing olefinic double bond or from a mixture of such comonomers and from unsaturated reactive dicarboxylic acid and/or their anhydride, preferably maleic anhydride using the molar ratio 1.2 - 5.5 : 0.1 - 3.5 : 1 = MAH : comonomer : polyisobutylene, and in which the widening of the molecular weight distribution is less than 70 percent, referred to the starting polyisobutylene, while the SA groups of the copolymer linked to the polyisobutylene are reacted, in a 0.7 - 5.5 ratio, with compound containing at least bifunctional amine and/or hydroxyl groups. The invention disclosed the process of preparation of the additive.