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    • 1. 发明申请
    • PROCESS FOR POLYMER MIXTURE HYDROCONVERSION
    • WO2020129020A1
    • 2020-06-25
    • PCT/IB2019/061213
    • 2019-12-20
    • ENI S.P.A.VERSALIS S.P.A.
    • BALDUCCI, DanieleGUIDETTI, StefaniaSCAVELLO, FrancescoVECCHINI, NicolaMARIANI, Paolo
    • C10G1/00C10G1/08C10G1/10C10G47/02C10G47/26
    • The present invention relates to a process for the hydroconversion of mixtures of polymers or plastics which comprises the pre-treatment of the mixtures through methods selected from mechanical methods, chemical methods, thermal methods, or combinations thereof forming a pre-treated charge. The pre-treated charge is mixed with a hydrocarbon vacuum residue, optionally pre-heated, to form a reactant mixture. The reactant mixture is fed to a hydroconversion section in slurry phase, together with a catalyst precursor containing Molybdenum, and a stream containing hydrogen, forming a reaction effluent. The effluent is separated into at least one high-pressure and high-temperature separator in a vapour phase and a slurry phase. The separate vapour phase is sent to a gas treatment section with the function of separating a liquid fraction from the gas containing hydrogen and hydrocarbon gases having from 1 to 4 carbon atoms; said liquid fraction comprising naphtha, atmospheric gas oil (AGO), vacuum gas oil (VGO). The slurry phase is then sent to a separation section that has the function of separating the fractions of the Vacuum Gas Oil (VGO), Heavy Vacuum Gas Oil (HVGO), Light Vacuum Gas Oil (LVGO), Atmospheric Gas Oil (AGO), from a stream of heavy organic products which contains asphaltenes, unconverted charge, catalyst and solid formed during the hydroconversion reaction. This stream of heavy organic products is partly recirculated to the hydroconversion section and partly forms a purge stream.
    • 6. 发明申请
    • POLYMER COMPOSITION WITH IMPROVED BARRIER PROPERTIES
    • WO2019220303A1
    • 2019-11-21
    • PCT/IB2019/053916
    • 2019-05-13
    • VERSALIS S.P.A.
    • SCAVELLO, FrancescoBALDUCCI, DanieleCASTIGLIONI, AndreaMARIANI, Paolo
    • C08K3/04C08L23/04
    • A polymer composition comprising:(a) at least one homopolymer or copolymer of ethylene;(b) at least one paste with a high concentration of an exfoliated layered material comprising:(i) from 1% by weight to 20% by weight, preferably from 10% by weight to 18% by weight, of at least one exfoliated layered material;(ii) from 10% by weight to 90% by weight, preferably from 15% by weight to 85% by weight, of at least one first additive selected from liquid stabilizers at room temperature;(iii) from 0% by weight to 15% by weight, preferably from 3% by weight to 8% by weight, of at least one organic solvent;(iv) from 0% by weight to 30% by weight, preferably from 5% by weight to 20% by weight, of at least one second additive selected from: light stabilizers, ultraviolet ray stabilizers (UV absorbers), metallic stearates, alcohols, ketones, ethers, glycols or poly-alkylene glycols;the sum of (i) + (ii) + (iii) + (iv) being equal to 100.Said polymer composition can be advantageously used for producing manufactured articles, such as films or slabs, having improved barrier properties and good mechanical properties. Said polymer composition can also be advantageously used for producing manufactured articles, such as films or slabs, having good electrical conductivity properties. Said films or slabs can, in turn, be advantageously used in various applications such as, for example, the production of manufactured articles with reduced gas permeability for packaging and tanks, or manufactured articles with improved electrical conductivity for 3D printing applications, or manufactured articles with improved electromagnetic radiation shielding (EMI shielding).
    • 9. 发明公开
    • CROSSLINKABLE COMPOSITION COMPRISING POLYETHYLENE AND USE THEREOF FOR ROTATIONAL MOLDING
    • 包含聚乙烯的可交联组合物及其用于旋转模塑的用途
    • EP3204451A1
    • 2017-08-16
    • EP15788215.0
    • 2015-10-08
    • Versalis S.p.A.
    • MARIANI, PaoloBALDUCCI, Daniele
    • C08L23/06B29C41/00
    • Crosslinkable composition comprising: (a) from 80% by weight to 98% by weight, preferably from 85% by weight to 95% by weight, of at least one high density polyethylene (HDPE); (b) from 2% by weight to 20% by weight, preferably from 5% by weight to 15% by weight, of at least one linear low density polyethylene (LLDPE); (c) from 0.2 parts by weight to 1.5 parts by weight, preferably from 0.5 parts by weight to 0.8 parts by weight, with respect to 100 parts by weight of (a)+(b), of at least one crosslinking agent selected from organic peroxides; (d) from 0.2 parts by weight to 2.5 parts by weight, preferably from 0.5 parts by weight to 1.0 parts by weight, with respect to 100 parts by weight of (a)+(b), of at least one co-crosslinking agent selected from allyl compounds. Said crosslinkable composition can advantageously be used in rotational molding (“rotomolding”).
    • 可交联组合物,其包含:(a)80重量%至98重量%,优选85重量%至95重量%的至少一种高密度聚乙烯(HDPE); (b)2重量%至20重量%,优选5重量%至15重量%的至少一种线性低密度聚乙烯(LLDPE); (c)相对于100重量份的(a)+(b),0.2重量份至1.5重量份,优选0.5重量份至0.8重量份的至少一种选自 有机过氧化物; (d)相对于100重量份的(a)+(b),0.2重量份至2.5重量份,优选0.5重量份至1.0重量份的至少一种共交联剂 选自烯丙基化合物。 所述可交联组合物可有利地用于旋转模塑(“滚塑”)。