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    • 4. 发明授权
    • Copolymers of alpha-methylstyrene and vinyltoluene and process for their preparation
    • α-甲基苯乙烯和乙烯醇的共聚物及其制备方法
    • US3803079A
    • 1974-04-09
    • US26182572
    • 1972-06-12
    • VELSICOL CHEMICAL CORP
    • HOKAMA T
    • C08F12/12C09D11/10C08F1/72C08F19/02C08F41/02
    • C08F212/12C09D11/108C08F4/14
    • This invention discloses a thermoplastic hydrocarbon resin having a ring and ball softening point of from about 275* to about 350* F and a number average molecular weight of from about 1,500 to about 3,000 comprising a blend of alpha-methylstyrene and vinyltoluene copolymers wherein about 45 to 60 weight percent of said blend consists of a copolymer having an alphamethylstyrene to vinyltoluene weight ratio of from about 70:30 to about 90:10, and a number average molecular weight above about 4000, wherein about 30 to 60 weight percent of said blend consists of a copolymer having an alpha-methylstyrene to vinyltoluene weight ratio of from about 40:60 to about 60:40, and a number average molecular weight below about 2000 and wherein the total blend contains from about 50 to about 90 weight percent alpha-methylstyrene and from about 10 to about 50 weight percent vinyltoluene; and further discloses a process for the preparation of said resin which comprises continuously polymerizing a monomer mixture containing from about 50 to about 90 weight percent alpha-methylstyrene and from about 10 to about 50 weight percent vinyltoluene dissolved in an inert organic reaction medium at a concentration of from about 5 to about 20 weight percent, which has been precooled to a temperature between about 0* and about 50*C in the presence of a catalytic amount of water and a Friedel-Crafts halide at atmospheric pressure and adiabatic conditions.