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1. 发明授权

US06835797B2 Process for producing oligocarbonates 有权
标题翻译：生产寡聚碳酸酯的方法
公开(公告)号：US06835797B2
公开(公告)日：2004-12-28
申请号：US10103921
申请日：2002-03-22
申请人： Uwe Hucks , Rolf Bachmann , Franz Ferdinand Rhiel , Thomas Fischer , Silke Kratschmer
发明人： Uwe Hucks , Rolf Bachmann , Franz Ferdinand Rhiel , Thomas Fischer , Silke Kratschmer
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： A continuous process for producing oligocarbonate is disclosed. The process entails in sequence the steps of a) reacting a dihydroxyaryl compound with a diaryl carbonate in the presence of a catalyst to obtain a melt and avoiding removal of released monohydroxyaryl compound and b) withdrawing the monohydroxyaryl compound by flash evaporation and c) heating the melt obtained under vacuum in an evaporator equipped with sump receiver and d) repeating at least once steps b) and then c) each at gradually increased temperatures and lowered pressures.
摘要翻译：公开了连续生产低聚碳酸酯的方法。该方法按照以下步骤进行：a）在催化剂存在下使二羟基芳基化合物与碳酸二芳基酯反应，得到熔体，避免去除脱离的单羟基芳基化合物，和b）通过闪蒸蒸发除去单羟基芳基化合物，和c）加热在装有贮槽接收器的蒸发器中在真空下获得熔体，d）重复至少一次步骤b），然后c）逐渐升高温度和降低的压力。

2. 发明授权

US06887970B2 Method for producing polycarbonates 有权
标题翻译：聚碳酸酯的制备方法
公开(公告)号：US06887970B2
公开(公告)日：2005-05-03
申请号：US10473316
申请日：2002-03-13
申请人： Silke Kratschmer , Uwe Hucks , Michael Prein
发明人： Silke Kratschmer , Uwe Hucks , Michael Prein
IPC分类号： C08G64/30 , C08G64/00
CPC分类号： C08G64/307
摘要： The invention relates to a continuous method for producing polycarbonates by transesterifying diaryl carbonates with dihydroxyaryl compounds in the presence of quaternary onium compounds. The invention also relates to polycarbonates produced thereby and products produced from said polycarbonates.
摘要翻译：本发明涉及通过在季鎓化合物的存在下将碳酸二芳基酯与二羟基芳基化合物酯交换来生产聚碳酸酯的连续方法。本发明还涉及由此生产的聚碳酸酯和由所述聚碳酸酯生产的产品。

3. 发明授权

US06887968B2 Process for the recycling of polycarbonates 失效
标题翻译：聚碳酸酯回收工艺
公开(公告)号：US06887968B2
公开(公告)日：2005-05-03
申请号：US10229787
申请日：2002-08-28
申请人： Heinrich Hähnsen , Uwe Hucks , Silke Kratschmer , Manfred Schraut
发明人： Heinrich Hähnsen , Uwe Hucks , Silke Kratschmer , Manfred Schraut
IPC分类号： C08G64/40 , C08G64/42 , C08G64/00
CPC分类号： C08G64/42
摘要： A process for making a high molecular weight (co)polycarbonate resin is disclosed. The process entails (i) obtaining at least one member selected from the group low molecular weight residue (weight average molecular weight 15,000 to 30,000) of aromatic (co)polycarbonate production, waste of (co)polycarbonate production, remainders of (co)polycarbonate production and (co)polycarbonate recyclate (ii) melting the said member in a suitable vessel to obtain a melt and (iii) feeding the melt into a reactor optionally along with at least one bisphenol or oligocarbonate having terminal OH groups and further optionally with a transesterification catalyst, and (iv) subjecting the melt to transesterification reaction at a temperature of 250 to 350° C., at a pressure below 5 mbar and residence time of 0.02-4 hours.
摘要翻译：公开了制备高分子量（共）聚碳酸酯树脂的方法。该方法包括：（i）获得选自芳族（共）聚碳酸酯生产的低分子量残余物（重均分子量为15,000至30,000）中的至少一种，（共）聚碳酸酯生产的废弃物，（共）聚碳酸酯的剩余物生产和（共）聚碳酸酯回收（ii）在合适的容器中熔化所述构件以获得熔体，和（iii）将熔体任选地与至少一种具有末端OH基的双酚或低聚碳酸酯一起进料到反应器中，酯交换催化剂，和（iv）在250-350℃的温度，低于5mbar的压力和0.02-4小时的停留时间下对熔体进行酯交换反应。

4. 发明授权

US06630563B2 Process for continuous production of polycarbonates and a reactor therefor 有权
公开(公告)号：US06630563B2
公开(公告)日：2003-10-07
申请号：US10127786
申请日：2002-04-22
申请人： Uwe Hucks , Thomas König , Silke Kratschmer , Eike Schulz Van Endert , Klaus Schröder , Hans-Peter Hoffmann
发明人： Uwe Hucks , Thomas König , Silke Kratschmer , Eike Schulz Van Endert , Klaus Schröder , Hans-Peter Hoffmann
IPC分类号： C08G6400
CPC分类号： B01J19/006 , B01J3/006 , B01J19/02 , B01J19/18 , B01J19/1862 , B01J2219/00092 , B01J2219/00094 , B01J2219/00182 , B01J2219/00779 , B01J2219/0277 , B01J2219/182 , C08G64/205 , Y10T428/31504
摘要： A process for producing polycarbonate is disclosed. The process entails obtaining an oligocarbonate produced by transesterification of diaryl carbonate with dihydroxyaryl compound in the presence of catalysts and introducing the oliogocarbonate into a reactor that enables continuous formation of free films at a rate higher than 10. The reactor including a horizontal cylinder equipped with a heating jacket, at least one vapor outlet, a feed nozzle an outlet nozzle, a rotatable cylindrical basket having a cylindrical perforated wall and annular discs positioned at intervals around the periphery of said basket and along the length thereof, and means for rotating said basket, the interior of said basket including no central shaft, the diameter of the cylindrical basket corresponding to about ⅔ of the diameter of the horizontal cylinder, and said discs being formed of perforated sheet metal.

5. 发明授权

US06703473B2 Process for producing polycarbonate 有权
标题翻译：生产聚碳酸酯的方法
公开(公告)号：US06703473B2
公开(公告)日：2004-03-09
申请号：US10038953
申请日：2002-01-02
申请人： Uwe Hucks , Kaspar Hallenberger , Silke Kratschmer , Michael Prein , Steffen Kühling
发明人： Uwe Hucks , Kaspar Hallenberger , Silke Kratschmer , Michael Prein , Steffen Kühling
IPC分类号： C08G6400
CPC分类号： C08G64/406 , C08G64/307
摘要： An improvement to the melt transesterification reaction of diaryl carbonate with dihydroxy aryl compound is disclosed. The improvement entails the following steps (i) introducing the resulting vapor stream at the mid-height of a first distillation column, and (ii) separating the vapor stream into a top product containing high purity monohydroxy aryl compound and a first bottom product, and (iii) recycling the high purity monohydroxy aryl compound of (ii) to the reaction, and (iv) introducing the first bottom product at mid-height of a second distillation column, and (v) separating said first bottom product into high boiling bottom by-product and overhead remaining constituents, and (vi) introducing the overhead remaining constituents at mid-height of a third distillation column, and (vii) separating said overhead remaining constituents into overhead low-boiling fractions and bottom or product side stream that contains diaryl carbonate product, and (viii) recycling the diaryl carbonate product directly to the transesterification reaction.
摘要翻译：公开了碳酸二芳酯与二羟基芳基化合物的熔融酯交换反应的改进。改进需要以下步骤：（i）将所得蒸汽流引入第一蒸馏塔的中间高度，和（ii）将蒸汽流分离成含有高纯度单羟基芳基化合物和第一底部产物的顶部产物，以及（iii）将（ii）的高纯度单羟基芳基化合物再循环到反应中，和（iv）在第二蒸馏塔的中间部分引入第一底部产物，和（v）将所述第一底部产物分离成高沸点底部副产物和塔顶残留组分，和（vi）在第三蒸馏塔的中间高度引入塔顶剩余成分，和（vii）将塔顶剩余组分分离成塔顶低沸点馏分和底部或产物侧流，其含有碳酸二芳基酯产物，和（viii）将碳酸二芳基酯产物直接再循环到酯交换反应中。

6. 发明授权

US06740730B1 Polycarbonate and molded polycarbonate articles 失效
标题翻译：聚碳酸酯和聚碳酸酯制品
公开(公告)号：US06740730B1
公开(公告)日：2004-05-25
申请号：US10031502
申请日：2002-01-15
申请人： Silke Kratschmer , Uwe Hucks , Lothar Bunzel
发明人： Silke Kratschmer , Uwe Hucks , Lothar Bunzel
IPC分类号： C08G6400
CPC分类号： C08G64/307 , C08G64/14
摘要： The invention relates to a novel polycarbonate and its use a material in the production of molded articles and semifinished products, especially for transparent articles such as data memories or radio compact discs, slabs, cellular sheets, films, housings, panes, especially panes for motor vehicles, diffusion glasses, but also for electrical applications or the constructions of houses.
摘要翻译：本发明涉及一种新型聚碳酸酯及其在制造模制品和半成品中的材料，特别是用于透明制品如数据存储器或无线电光盘，板，蜂窝片，薄膜，壳体，窗格，尤其是用于电动机的窗格车辆，扩散眼镜，还可用于电气应用或房屋建筑。

7. 发明授权

US06596840B1 Method for producing modified polycarbonates 有权
标题翻译：改性聚碳酸酯的制备方法
公开(公告)号：US06596840B1
公开(公告)日：2003-07-22
申请号：US10031630
申请日：2002-01-15
申请人： Silke Kratschmer , Uwe Hucks , Lothar Bunzel
发明人： Silke Kratschmer , Uwe Hucks , Lothar Bunzel
IPC分类号： C08G6400
CPC分类号： C08G64/14 , C08G64/307
摘要： A process for the synthesis of polycarbonate is disclosed. The process entails reacting in the presence of at least one phosphonium salt as catalyst, at least one diphenol, at least one carbonic acid diester, and at least one alkyl group-substituted phenol chain terminator. The chain terminator is introduced in free form or as a transesterifiable compound under the conditions of the synthesis. The polycarbonate thus produced is suitable for preparing a variety of molded articles.
摘要翻译：公开了一种合成聚碳酸酯的方法。该方法需要在至少一种鏻盐作为催化剂，至少一种二酚，至少一种碳酸二酯和至少一个烷基取代的苯酚链终止剂存在下反应。该链终止剂在合成条件下以游离形式或作为可酯交换化合物引入。由此生产的聚碳酸酯适于制备各种模塑制品。

8. 发明授权

US06770731B2 Polycarbonate having pronounced shear thinning behavior 有权
标题翻译：聚碳酸酯具有明显的剪切变稀行为
公开(公告)号：US06770731B2
公开(公告)日：2004-08-03
申请号：US10104573
申请日：2002-03-22
申请人： James Mason , Silke Kratschmer , Uwe Hucks
发明人： James Mason , Silke Kratschmer , Uwe Hucks
IPC分类号： C08G600
CPC分类号： C08G64/06 , C08G64/307
摘要： A branched melt-polymerized polycarbonate having pronounced non-Newtonian flow behavior is disclosed. The polycarbonate is suitable for preparing molding compositions and the preparation of a variety of molded articles.
摘要翻译：公开了具有显着的非牛顿流动性的支化熔融聚合的聚碳酸酯。聚碳酸酯适用于制备模塑组合物和制备各种模塑制品。

9. 发明授权

US06747118B2 Storage of phosphonium phenolate catalysts and their use as interesterification catalysts 失效
标题翻译：磷酸鏻催化剂的储存及其作为酯交换催化剂的用途
公开(公告)号：US06747118B2
公开(公告)日：2004-06-08
申请号：US10407972
申请日：2003-04-05
申请人： Melanie Moethrath , Uwe Hucks , Silke Kratschmer , Johann Rechner
发明人： Melanie Moethrath , Uwe Hucks , Silke Kratschmer , Johann Rechner
IPC分类号： C08G600
CPC分类号： B01J31/0268 , B01J2231/14 , B01J2231/40 , B01J2231/49 , C07F9/54 , C08G64/307
摘要： A process for preparing a melt transesterification catalyst is disclosed. The process entails (i) obtaining a phenol adduct of phosphonium phenolatein the form of crystalline solid and (ii) storing the solid phenol adductin a closed container at relative humidity of 30 to 70 % and at temperature of −30 to 50° C. The thus prepared catalyst is suitable in the production of polycarbonate in the melt transesterification process.
摘要翻译：公开了一种制备熔体酯交换催化剂的方法。该方法包括：（i）以结晶固体的形式获得苯酚盐的苯酚加合物，和（ii）将固体苯酚加合物在30至70％的相对湿度和-30至50℃的温度下封闭。因此制备的催化剂适用于在熔融酯交换过程中生产聚碳酸酯。

10. 发明授权

US06710153B2 Method for producing phosphonium phenolates 失效
标题翻译：苯酚酚盐生产方法
公开(公告)号：US06710153B2
公开(公告)日：2004-03-23
申请号：US10168166
申请日：2002-06-17
申请人： Lothar Bunzel , Uwe Hucks , Annett König , Silke Kratschmer
发明人： Lothar Bunzel , Uwe Hucks , Annett König , Silke Kratschmer
IPC分类号： C08G6400
CPC分类号： C08G64/30 , C07C37/00 , C07F9/54 , C07C39/04
摘要： A process for the production of phosphonium phenolates is disclosed. The process entails reacting a phosphonium halide and phenol in an aqueous alkaline solution. The phosphonium phenolate produced is separated from the synthesis mixture by crystallization
摘要翻译：公开了一种生产苯酚鏻的方法。该方法需要在碱性水溶液中使卤化鏻和苯酚反应。通过结晶将生产的苯酚鏻与合成混合物分离

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