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1. 发明授权

US5817871A Preparation of amines 失效
标题翻译：胺的制备
公开(公告)号：US5817871A
公开(公告)日：1998-10-06
申请号：US921769
申请日：1997-08-15
申请人： Uwe Dingerdissen , Gunter Lauth , Andreas Henne , Peter Stops , Karsten Eller , Eugen Gehrer
发明人： Uwe Dingerdissen , Gunter Lauth , Andreas Henne , Peter Stops , Karsten Eller , Eugen Gehrer
IPC分类号： B01J27/18 , B01J27/182 , B01J27/185 , B01J27/188 , C07B61/00 , C07C209/60 , C07C211/03 , C07C211/05 , C07C211/06 , C07C211/07 , C07C211/08 , C07C211/35
CPC分类号： C07C211/35 , C07C209/60 , C07C211/07 , C07C2101/08
摘要： A process for preparing an amine by catalytic reaction of an olefin with ammonia or a primary or secondary amine by contacting a mixture of the reactants in a reactor at 200.degree. to 400.degree. C. and an elevated pressure up to 700 bar in the presence of a catalyst consisting essentially of an X-ray amorphous (non-crystalline) mesoporous catalyst, some of which may have a microporous non-crystalline content. The catalyst has the composition a MO.sub.2 * b Q.sub.2 O.sub.3 * c P.sub.2 O.sub.5 where Q is at least one of the trivalent elements aluminum, boron, chromium, iron or gallium, and M is at least one of the tetravalent elements silicon, titanium or germanium. The molar ratio of a:b is from 0.5:1 to 1000:1 and the molar ratio of c:b is from 0 to 2:1. As prepared and used in the process, this non-crystalline catalyst has a specific BET surface area of from 200 to 1000 m.sup.2 /g.
摘要翻译：通过使烯烃与氨或伯胺或仲胺进行催化反应来制备胺的方法，该方法是将反应物的混合物在200-400℃的反应器和高达700巴的升高的压力下反应，主要由X射线无定形（非结晶）介孔催化剂组成的催化剂，其中一些可能具有微孔非晶体含量。催化剂具有以下组成：MO2 * b Q2O3 * c P2O5其中Q是三价元素铝，硼，铬，铁或镓中的至少一种，M是四价元素硅，钛或锗中的至少一种。 a:b的摩尔比为0.5:1-1000:1，c:b的摩尔比为0-2:1。在该方法中制备和使用时，该非结晶催化剂的BET比表面积为200-1000m2 / g。

2. 发明授权

US6143934A Preparation of amines from olefins over boron beta-zeolites 失效
标题翻译：通过硼β-沸石从烯烃制备胺
公开(公告)号：US6143934A
公开(公告)日：2000-11-07
申请号：US341
申请日：1998-01-20
申请人： Uwe Dingerdissen , Rudolf Kummer , Peter Stops , Ulrich Muller , Jurgen Herrmann , Karsten Eller
发明人： Uwe Dingerdissen , Rudolf Kummer , Peter Stops , Ulrich Muller , Jurgen Herrmann , Karsten Eller
IPC分类号： B01J29/86 , C07B61/00 , C07C209/60 , C07C211/07 , C07C211/35 , C07C209/00
CPC分类号： C07C209/60
摘要： In a process for preparing amines of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 are hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl,R.sup.1 and R.sup.2 are together a saturated or unsaturated, divalent C.sub.3 -C.sub.9 -alkylene chain andR.sup.3 and R.sup.5 are each C.sub.21 -C.sub.200 -alkyl, C.sub.21 -C.sub.200 -alkenyl or together are a divalent C.sub.2 -C.sub.12 -alkylene chain,by reacting olefins of the general formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are as defined above, with ammonia or primary or secondary amines of the general formula III ##STR3## where R.sup.1 and R.sup.2 are as defined above, at from 200 to 350.degree. C. and pressures of from 100 to 300 bar in the presence of a zeolitic catalyst, the zeolitic catalyst used is a boron BETA-zeolite.
摘要翻译： PCT No.PCT / EP96 / 03634 371日期1998年1月20日 102（e）1998年1月20日PCT PCT 1996年8月19日PCT公布。出版物WO97 / 07088 日期：1997年2月27日在制备通式I的胺的方法中，其中R 1，R 2，R 3，R 4，R 5，R 6为氢，C 1 -C 20 - 烷基，C 2 -C 20 - 烯基，C 2 -C 20炔基，C 3 C 20 - 环烷基，C 4 -C 20 - 烷基环烷基，C 4 -C 20 - 环烷基烷基，芳基，C 7 -C 20 - 烷基芳基或C 7 -C 20 - 芳烷基，R 1和R 2一起是饱和或不饱和的二价C 3 -C 9 - 亚烷基链和R 3 和R 5各自为C 21 -C 20 - 烷基，C 21 -C 2-链烯基或一起为二价C 2 -C 12 - 亚烷基链，其中R 3，R 4，R 5和R 6如上定义的通式II的烯烃与氨或通式III的伯胺或仲胺，其中R 1和R 2如上定义，在沸石催化剂存在下，在200-350℃和100-300巴的压力下，所用的沸石催化剂是硼 BETA-沸石。

3. 发明授权

US06441110B1 Method for producing halogen-free reactive polyisobutene 失效
标题翻译：生产无卤素的反应性聚异丁烯的方法
公开(公告)号：US06441110B1
公开(公告)日：2002-08-27
申请号：US09367194
申请日：1999-08-06
申请人： Christoph Sigwart , Thomas Narbeshuber , Karsten Eller , Manfred Barl , Rolf Fischer , Eugen Gehrer
发明人： Christoph Sigwart , Thomas Narbeshuber , Karsten Eller , Manfred Barl , Rolf Fischer , Eugen Gehrer
IPC分类号： C08F424
CPC分类号： C08F110/10 , C08F10/10 , C08F4/24 , C08F4/20 , C08F4/025
摘要： A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 50 mol % and an average molecular weight Mn of 280-10000 dalton by the cationic polymerization in the liquid phase of isobutene or hydrocarbon mixtures comprising isobutene comprises polymerizing at from −30° C. to +40° C. in the presence of a heterogeneous polymerisation catalyst comprising one or more oxides of the elements of transition groups V and VI of the Periodic Table of the Elements or in the presence of a heterogeneous polymerization catalyst comprising one or more oxidic compounds of one or more elements of transition groups V and VI of the Periodic Table of the Elements supported on a non-zeolitic oxidic support material which is not an oxygen-containing zirconium compound, the catalyst not containing a technically effective amount of halogen.
摘要翻译：通过在异丁烯或包含异丁烯的烃混合物的液相中的阳离子聚合制备末端双键含量大于50mol％，平均分子量Mn为280-10000dalton的无卤活性聚异丁烯的方法包括聚合在-30℃至+ 40℃下，在包含元素周期表的过渡基团V和VI的元素的一种或多种氧化物的非均相聚合催化剂的存在下，或在非均相聚合催化剂包含负载在不是含氧锆化合物的非沸石氧化载体材料上的元素周期表的一个或多个过渡基团V和VI元素的一种或多种氧化化合物，该催化剂不含技术上有效量的卤素。

4. 发明授权

US5773660A Preparation of amines from olefins over hexagonal faujasites 失效
标题翻译：在六边形八面体上由烯烃制备胺
公开(公告)号：US5773660A
公开(公告)日：1998-06-30
申请号：US784548
申请日：1997-01-21
申请人： Karsten Eller , Rudolf Kummer , Eugen Gehrer
发明人： Karsten Eller , Rudolf Kummer , Eugen Gehrer
IPC分类号： B01J29/08 , C07B43/04 , C07B61/00 , C07C209/60 , C07C211/03 , C07C211/07 , C07C209/02
CPC分类号： C07C209/60
摘要： A process for preparing amines of the formula I ##STR1## where R.sup.1,R.sup.2,R.sup.3,R.sup.4,R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl, R.sup.1 and R.sup.2 are together a saturated or unsaturated C.sub.3 -C.sub.9 -alkylene dichain, and R.sup.3 or R.sup.5 is C.sub.21 -C.sub.200 -alkyl or C.sub.21 -C.sub.200 -alkenyl or together they are a C.sub.2 -C.sub.12 -alkylene dichain, by reacting olefins of the formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each as defined above, with ammonia or primary or secondary amines of the formula III ##STR3## where R.sup.1 and R.sup.2 are each as defined above, at temperatures from 200.degree. to 350.degree. C. and pressures from 100 to 300 bar in the presence of a heterogeneous catalyst using a heterogeneous catalyst comprising hexagonal faujasite.
摘要翻译：制备式I的胺的方法其中R 1，R 2，R 3，R 4，R 5和R 6各自为氢，C 1 -C 20 - 烷基，C 2 -C 20 - 烯基，C 2 -C 20 - 炔基，C 3 -C 20 - 环烷基，C 4 -C 20 - 烷基环烷基，C 4 -C 20 - 环烷基烷基，芳基，C 7 -C 20 - 烷基芳基或C 7 -C 20 - 芳烷基，R 1和R 2一起是饱和或不饱和的C 3 -C 9 - 亚烷基二烯基，R3或 R5是C21-C200-烷基或C21-C200-烯基，或者它们一起是C2-C12-亚烷基二烯，通过使式II的烯烃（II）反应，其中R3，R4，R5和R6各自定义与式III（III）的氨或伯胺或仲胺，其中R 1和R 2各自如上定义，在200-350℃的温度和100-300巴的压力下，在存在使用包含六边形八面沸石的多相催化剂的多相催化剂。

5. 发明授权

US5880321A Preparation of 1,1-diphenylethanes 失效
标题翻译：制备1,1-二苯基乙烷
公开(公告)号：US5880321A
公开(公告)日：1999-03-09
申请号：US46692
申请日：1998-03-24
申请人： Eugen Gehrer , Karsten Eller , Gunther Effler
发明人： Eugen Gehrer , Karsten Eller , Gunther Effler
IPC分类号： C07C2/66 , C07C17/266 , C07C17/269 , C07C45/69 , C07C67/293 , C07C1/20
CPC分类号： C07C2/66 , C07C17/266 , C07C17/269 , C07C45/69 , C07C2529/70
摘要： In a process for preparing unsubstituted or substituted 1,1-diphenylethanes by catalytic reaction of benzene and styrene in the presence of a zeolite catalyst, it being possible for benzene and styrene each independently to have 1 to 5 substituents selected from halogen, C.sub.1-10 -alkyl, C.sub.1-10 -alkoxy, C.sub.1-10 -acyl, C.sub.1-10 -acyloxy or cyano, the zeolite catalyst is of the EMT or ZSM-20 type.
摘要翻译：在沸石催化剂存在下，通过苯和苯乙烯的催化反应制备未取代或取代的1,1-二苯基乙烷的方法中，苯和苯乙烯各自独立地具有1至5个选自卤素，C 1-10的取代基 - 烷基，C 1-10 - 烷氧基，C 1-10酰基，C 1-10 - 酰氧基或氰基，沸石催化剂为EMT或ZSM-20型。

6. 发明授权

US5763668A Process for aminating a mixture obtained in cracking a mineral oil fraction with ammonia or a primary or secondary amine over specific heterogeneous catalysts 失效
$Process for aminating a mixture obtained in cracking a mineral oil fraction with ammonia or a primary or secondary amine over specific heterogeneous catalysts$
标题翻译：在特定的非均相催化剂上胺化与氨或伯或仲胺裂解矿物油馏分获得的混合物的方法
公开(公告)号：US5763668A
公开(公告)日：1998-06-09
申请号：US675731
申请日：1996-07-03
申请人： Uwe Dingerdissen , Jurgen Herrmann , Karsten Eller
发明人： Uwe Dingerdissen , Jurgen Herrmann , Karsten Eller
IPC分类号： B01J29/04 , B01J29/08 , B01J29/40 , C07B61/00 , C07C209/00 , C07C209/02 , C07C209/60 , C07C211/01 , C07C211/33
CPC分类号： C07C209/02 , Y02P20/582
摘要： Amines are prepared by reacting a mixture obtained in the cracking of mineral oil fractions with ammonia or a primary or secondary amine of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 --C.sub.20 -alkylaryl or C.sub.7 --C.sub.20 -aralkyl or together are a saturated or unsaturated C.sub.2 -C.sub.12 -alkylene ene chain, at from 200.degree. to 350.degree. C. and from 100 to 300 bar in the presence of a heterogeneous catalyst, by a process which comprises using one or more members of the following classes as the heterogeneous catalyst: a) zeolites b) aluminosilicates c) hydrothermally prepared phosphates d) mesoporous oxides having a large surface area e) pillared interlayered clays (PILCs) f) amorphous oxides which are prepared by the sol-gel process g) acid-treated sheet silicates
摘要翻译：通过使在矿物油馏分裂解中获得的混合物与氨或通式I的伯胺或仲胺反应制备胺，其中R1和R2各自为氢，C1-C20烷基，C2- C20-烯基，C2-C20-炔基，C3-C20-环烷基，C4-C20-烷基环烷基，C4-C20-环烷基烷基，芳基，C7-C20-烷基芳基或C7-C20-芳烷基或一起是饱和或不饱和的C2- 在多相催化剂存在下，在200-350℃和100-300巴条件下，通过包括使用一种或多种以下类别的成员作为多相催化剂的方法：a）沸石b）铝硅酸盐c）水热制备的磷酸盐d）具有大表面积的介孔氧化物e）柱状层间粘土（PILC）f）通过溶胶 - 凝胶法制备的无定形氧化物g）酸处理的片状硅酸盐

7. 发明授权

US5786510A Preparation of amines from olefins over crystalline oxides based on aluminum phosphates and having faujasite structure 失效
标题翻译：基于磷酸铝制成结晶氧化物并具有八面沸石结构的烯烃中的胺
公开(公告)号：US5786510A
公开(公告)日：1998-07-28
申请号：US784772
申请日：1997-01-16
申请人： Karsten Eller , Rudolf Kummer , Peter Stops
发明人： Karsten Eller , Rudolf Kummer , Peter Stops
IPC分类号： B01J29/83 , C07B61/00 , C07C209/60 , C07C211/07 , C07C211/30 , C07C209/02
CPC分类号： C07C209/60 , Y02P20/582
摘要： A process for the preparation of amines of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 denote hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkynyl, C.sub.3 -C.sub.20 cycloalkyl, C.sub.4 -C.sub.20 alkylcycloalkyl, C.sub.4 -C.sub.20 cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 alkylaryl or C.sub.7 -C.sub.20 aralkyl, R.sup.1 and R.sup.2 together denote a saturated or unsaturated C.sub.3 -C.sub.9 alkylene dichain and R.sup.3 or R.sup.5 denotes C.sub.21 -C.sub.200 alkyl, C.sub.21 -C.sub.200 alkenyl or they together form a C.sub.2 -C.sub.12 alkylene dichain, by the reaction of olefins of the general formula II ##STR2## in which R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the aforementioned meanings, with ammonia or primary or secondary amines of the general formula III ##STR3## in which R.sup.1 and R.sup.2 have the aforementioned meanings, at temperatures ranging from 200.degree. to 350.degree. C. and pressures of from 100 to 300 bar in the presence of a heterogeneous catalyst, wherein the heterogeneous catalysts used are crystalline oxides based on aluminum phosphates and having faujasite structure.
摘要翻译：制备通式I的胺的方法（Ⅰ）其中R1，R2，R3，R4，R5和R6表示氢，C1-C20烷基，C2-C20炔基，C3-C20环烷基， C 4 -C 20烷基环烷基，C 4 -C 20环烷基烷基，芳基，C 7 -C 20烷基芳基或C 7 -C 20芳烷基，R 1和R 2一起表示饱和或不饱和的C 3 -C 9亚烷基二酮，R 3或R 5表示C 21 -C 200烷基，C 21 -C 20烯基或者它们一起形成C 2 -C 12亚烷基二酮，通过其中R3，R4，R5和R6具有上述含义的通式II（II）的烯烃与一般的氨或伯或仲胺反应，式III（III）其中R1和R2具有上述含义，在200〜350℃的温度和100〜300巴的压力下，在多相催化剂存在下使用，其中使用的多相催化剂是基于磷酸铝并具有八面沸石结构的结晶氧化物。

8. 发明授权

US5900508A Preparation of amines from olefins over zeolites of the type PSH-3, MCM-22, SSZ-25 or mixtures thereof 失效
标题翻译：由PSH-3，MCM-22，SSZ-25类型的沸石或其混合物的烯烃制备胺
公开(公告)号：US5900508A
公开(公告)日：1999-05-04
申请号：US683227
申请日：1996-07-18
申请人： Karsten Eller , Ulrich Muller , Rudolf Kummer , Peter Stops
发明人： Karsten Eller , Ulrich Muller , Rudolf Kummer , Peter Stops
IPC分类号： B01J29/70 , B01J29/74 , B01J29/76 , B01J29/78 , C07B61/00 , C07C209/60 , C07C211/03 , C07C211/17 , C07C211/21 , C07C211/23 , C07C211/27 , C07C211/35 , C07C211/45
CPC分类号： C07C209/60 , Y02P20/582
摘要： A process for the preparation of amines by reacting an olefin with ammonia or a primary or secondary amine at a temperature of from 200 to 350.degree. C. and a pressure of from 100 to 300 bar in the presence of at least one zeolite having the specific structure type PSH-3, MCM-22 or SSZ-25, as identified by X-ray diffractogram, or mixtures of these zeolites. These specific catalysts are broadly identified as alumina zeolites and may be modified by ion exchange, doping with other metals, by dealumination to remove or replace the alumina content and by other well known after treatments such as calcination, acid-treatment and the like. Monoolefins are preferred reactants but di- and polyolefins also can be reacted with relatively high selectivity and less tendency toward polymerization.
摘要翻译：一种通过使烯烃与氨或伯胺或仲胺在200-350℃的温度和100-300巴的压力下在至少一种具有特定的沸点的沸石存在下反应来制备胺的方法结构型PSH-3，MCM-22或SSZ-25，通过X射线衍射图鉴定，或这些沸石的混合物。这些特定的催化剂被广泛地认定为氧化铝沸石，并且可以通过离子交换，掺杂其它金属，通过脱铝来除去或替代氧化铝含量，以及通过煅烧，酸处理等处理之后熟知的其它催化剂进行改性。单烯烃是优选的反应物，但是二烯烃和聚烯烃也可以以相对高的选择性和较少的聚合倾向反应。

9. 发明授权

US5886226A Process for producing amines from olefins on zeolites of types SSZ-33, CIT-1 or mixtures thereof 失效
标题翻译：在SSZ-33，CIT-1型沸石及其混合物上由烯烃生产胺的方法
公开(公告)号：US5886226A
公开(公告)日：1999-03-23
申请号：US406
申请日：1998-01-29
申请人： Karsten Eller , Rudolf Kummer , Peter Stops
发明人： Karsten Eller , Rudolf Kummer , Peter Stops
IPC分类号： C07D295/02 , B01J29/70 , C07B61/00 , C07C209/60 , C07C211/07 , C07D207/323
CPC分类号： C07C209/60
摘要： A process for preparing amines of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl,R.sup.1 and R.sup.2 are together a saturated or unsaturated C.sub.3 -C.sub.9 -alkylene dichain, andR.sup.3 or R.sup.5 are each C.sub.21 -C.sub.200 -alkyl or C.sub.21 -C.sub.200 -alkenyl or together a C.sub.2 -C.sub.12 -alkylene dichain by reacting olefins of the general formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each as defined above, with ammonia or primary or secondary amines of the general formula III ##STR3## where R.sup.1 and R.sup.2 are each as defined above, at temperatures from 200.degree. to 350.degree. C. and pressures from 100 to 300 bar in the presence of a heterogeneous catalyst, comprises using a heterogeneous catalyst comprising zeolites of the type SSZ-26, SSZ-33, CIT-1 or mixtures thereof.
摘要翻译： PCT No.PCT / EP96 / 05406 Sec。 371日期1998年1月29日 102（e）1998年1月29日PCT PCT 1996年12月4日PCT公布。公开号WO97 / 21661 日期：1996年6月19日制备通式I（I）的胺的方法，其中R 1，R 2，R 3，R 4，R 5和R 6各自为氢，C 1 -C 20 - 烷基，C 2 -C 20 - 烯基，C 2 C 20 - 炔基，C 3 -C 20 - 环烷基，C 4 -C 20 - 烷基环烷基，C 4 -C 20 - 环烷基烷基，芳基，C 7 -C 20 - 烷基芳基或C 7 -C 20 - 芳烷基，R 1和R 2一起是饱和或不饱和的C 3 -C 9 - 亚烷基二烯和R3或R5各自为C 21 -C 200 - 烷基或C 21 -C 200-链烯基或通过使上述定义的通式II的烯烃与C 2 -C 12 - 亚烷基二醇的氨或仲胺或仲胺在非均相催化剂的存在下，在200℃至350℃的温度和100至300巴的压力下，通式III“IMAGE”包括使用包含SSZ-26型，SSZ-33型沸石， CIT-1或其混合物。

10. 发明授权

US5739405A Preparation of amines from olefins over zeolites of the type SSZ-37 失效
标题翻译：通过SSZ-37型沸石从烯烃制备胺
公开(公告)号：US5739405A
公开(公告)日：1998-04-14
申请号：US760296
申请日：1996-12-04
申请人： Karsten Eller , Rudolf Kummer , Peter Stops
发明人： Karsten Eller , Rudolf Kummer , Peter Stops
IPC分类号： B01J29/06 , C07B61/00 , C07C209/60 , C07C211/03 , C07C211/07 , C07C211/17 , C07C211/21 , C07C211/25 , C07C211/26 , C07C211/35 , C07C211/40 , C07C211/45
CPC分类号： C07C209/60 , Y02P20/582
摘要： A process for the preparation of amines of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 denote hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.3 -C.sub.20 cycloalkyl, C.sub.4 -C.sub.20 alkylcycloalkyl, C.sub.4 -C.sub.20 cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 alkylaryl, or C.sub.7 -C.sub.20 aralkyl, R.sup.1 and R.sup.2 together denote a saturated or unsaturated C.sub.3 -C.sub.9 alkylene dichain and R.sup.3 or R.sup.5 denotes C.sub.21 -C.sub.200 alkyl, C.sub.21 -C.sub.200 alkenyl or they together form a C.sub.2 -C.sub.12 alkylene dichain, by the reaction of olefins of the general formula II ##STR2## in which R.sup.3, R.sup.4, R.sup.5, and R.sup.6 have the above meanings, with ammonia or primary or secondary amines of the general formula III ##STR3## in which R.sup.1 and R.sup.2 have the above meanings, at temperatures ranging from 200.degree. to 350.degree. C. and pressures ranging from 100 to 300 bar in the presence of a heterogeneous catalyst, wherein the heterogeneous catalyst used is a zeolite of the type SSZ-37.
摘要翻译：制备通式I（I）的胺的方法，其中R 1，R 2，R 3，R 4，R 5，R 6表示氢，C 1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，C 3 -C 20环烷基，C 4 -C 20烷基环烷基，C 4 -C 20环烷基烷基，芳基，C 7 -C 20烷基芳基或C 7 -C 20芳烷基，R 1和R 2一起表示饱和或不饱和的C 3 -C 9亚烷基二
烯基，R 3或R 5表示C 21 -C 200烷基 C21 -C200烯基或它们一起形成C 2 -C 12亚烷基二酮，通过其中R3，R4，R5和R6具有上述含义的通式II（II）的烯烃与氨或在其中R1和R2具有上述含义的通式III（III）的伯或仲胺中，在200-350℃的温度和100-300巴的压力范围内，在异质的存在下催化剂，其中所用的非均相催化剂是SSZ-37型沸石。

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