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1. 发明专利

JP2011140439A Crystalline aluminosilicate: uzm-13, uzm-17, uzm-19 and uzm-25 有权
标题翻译：结晶铝氧化物：UZM-13，UZM-17，UZM-19和UZM-25
公开(公告)号：JP2011140439A
公开(公告)日：2011-07-21
申请号：JP2011056428
申请日：2011-03-15
申请人： Uop Llc , ユーオーピーエルエルシー
发明人： LEWIS GREGORY J , KNIGHT LISA M , MILLER MARK A , WILSON STEPHEN T
IPC分类号： C01B39/48 , B01J29/06 , B01J29/70 , C10G11/05
CPC分类号： B01J29/06 , B01J29/70 , C01B39/48
摘要： PROBLEM TO BE SOLVED: To provide a novel microporous zeolite UZM-25 and a manufacturing method thereof.
SOLUTION: A series of crystalline aluminosilicate compositions is prepared by using specific templates. These compositions have a layered structure and are identified as UZM-13, UZM-17 and UZM-19. Upon calcination at a temperature of 400 °C to 600 °C, these compositions form a microporous crystalline zeolite with a three dimensional framework which has been identified as UZM-25.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供新型微孔沸石UZM-25及其制造方法。解决方案：通过使用特定的模板制备一系列结晶硅铝酸盐组合物。这些组合物具有层状结构并且被鉴定为UZM-13，UZM-17和UZM-19。在400℃至600℃的温度下煅烧时，这些组合物形成具有三维框架的微孔结晶沸石，其被鉴定为UZM-25。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2012102014A Crystalline aluminosilicate zeolitic composition (uzm-15) 有权
标题翻译：水溶性铝酸锌组合物（UZM-15）
公开(公告)号：JP2012102014A
公开(公告)日：2012-05-31
申请号：JP2012009108
申请日：2012-01-19
申请人： Uop Llc , ユーオーピーエルエルシー
发明人： ROHDE LISA M , LEWIS GREGORY J , WILSON STEPHEN T , JAN DENG-YANG , PATTON R LYLE , KOSTER SUSAN C , MOSCOSO JAIME G , MILLER MARK A , GATTER MICHAEL G
IPC分类号： C01B39/48 , B01J29/70
摘要： PROBLEM TO BE SOLVED: To provide a new zeolite which is called UZM-15.SOLUTION: Aluminosilicate zeolite and a substitution form which is called UZM-15 are synthesized. These zeolites are prepared by using an organic ammonium cation which has at least one organic group having at least two carbon atoms, as a template. As an example of such a cation, there is diethyldimethylammonium cation. The template contains other organic ammonium cations as needed, alkali metal and alkaline earth metal. These UZM-15 materials are dealuminized by various processes, and UZM-15HS composition is formed. The both UZM-15 and UZM-15HS compositions are useful as a catalyst or a catalyst carrier in various processes such as conversion of cyclic hydrocarbon to non-cyclic hydrocarbon and olefin oligomerization.
摘要翻译：要解决的问题：提供称为UZM-15的新型沸石。解决方案：合成硅铝酸沸石和称为UZM-15的取代形式。这些沸石通过使用具有至少一个具有至少两个碳原子的有机基团的有机铵阳离子作为模板来制备。作为这样的阳离子的例子，有二乙基二甲基铵阳离子。该模板根据需要含有其他有机铵阳离子，碱金属和碱土金属。这些UZM-15材料通过各种工艺脱铝，形成UZM-15HS组成。 UZM-15和UZM-15HS组合物可用作各种方法中的催化剂或催化剂载体，例如将环烃转化成非环烃和烯烃低聚。版权所有（C）2012，JPO＆INPIT

3. 发明申请

WO2013096069A3 UZM-39 ALUMINOSILICATE ZEOLITE 审中-公开
标题翻译： UZM-39铝酸钠沸石
公开(公告)号：WO2013096069A3
公开(公告)日：2015-05-07
申请号：PCT/US2012069369
申请日：2012-12-13
申请人： UOP LLC
发明人： NICHOLAS CHRISTOPHER P , MILLER MARK A , BROACH ROBERT W , SINKLER WHARTON
IPC分类号： C01B39/48 , B01J20/18 , B01J29/06 , B01J29/80
CPC分类号： B01J43/00 , B01D15/08 , B01J20/18 , B01J29/70 , B01J29/80 , B01J29/86 , B01J29/87 , B01J29/88 , B01J35/002 , C01B39/023 , C01B39/46 , C01B39/48 , C07C2/66 , C07C2/76 , C07C7/13 , C07C2529/70 , C10G47/20
摘要： A new family of coherently grown composites of TUN and IMF zeotypes have been synthesized. These zeolites are represented by the empirical formula. NanMm k+TtAl1-xExSiyOz where "n" is the mole ratio of Na to (Al + E), M represents a metal or metals from zine, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, "m" is the mole ratio of M to (Al + E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to TNU-9 and IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations.
摘要翻译：已经合成了一系列连续生长的TUN和IMF染色体型复合物。这些沸石由经验公式表示。 NanMm k + TtAl1-xExSiyOz其中“n”是Na与（Al + E）的摩尔比，M表示来自ine，第1族，第2族，第3族和/或元素周期表的镧系元素的金属或金属， “m”是M与（Al + E）的摩尔比，“k”是金属或金属M的平均电荷，T是有机结构导向剂或试剂，E是骨架元素如镓。这些沸石类似于TNU-9和IM-5，但是其特征在于独特的组成和合成方法，并且具有用于进行各种烃转化方法和用于进行各种分离的分离性能的催化性能。

4. 发明申请

WO2013096072A3 LAYERED CONVERSION SYNTHESIS OF ZEOLITES 审中-公开
标题翻译： ZEOLITES的层状转化合成
公开(公告)号：WO2013096072A3
公开(公告)日：2015-04-23
申请号：PCT/US2012069395
申请日：2012-12-13
申请人： UOP LLC
发明人： NICHOLAS CHRISTOPHER P , MILLER MARK A
IPC分类号： C01B39/48 , B01J29/80
CPC分类号： B01J29/88 , B01J29/70 , B01J29/80 , B01J29/86 , B01J29/87 , B01J35/002 , C01B39/023 , C01B39/46 , C01B39/48
摘要： A new synthesis technique has been developed to prepare a family of coherently grown composites of at least two zeotypes. Examples of these composites are represented by the empirical formula. NanMm k+TtAl1-xExSiyOz where "n" is the mole ratio of Na to (Al + E), M represents at least one metal of zinc, Group 1, Group 2, Group 3 and the lanthanide series of the periodic table, and any combination thereof, "m" is the mole ratio of M to (Al + E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, "t" is the mole ratio of N from the organic structure directing agent or agents to (Al + E), and E is a framework element such as gallium. The synthesis technique is the Layered Conversion Synthesis technique.
摘要翻译：已经开发了一种新的合成技术来制备至少两种类型的相干生长复合材料的家族。这些复合材料的实例由经验公式表示。 NanMm k + TtAl1-xExSiyOz其中“n”是Na与（Al + E）的摩尔比，M表示锌，第1族，第2族，第3族和周期表的镧系元素中的至少一种金属，其任何组合，“m”是M与（Al + E）的摩尔比，“k”是金属或金属M的平均电荷，T是有机结构导向剂或试剂，“t” N从有机结构导向剂或试剂与（Al + E）的比例，E是诸如镓的骨架元素。合成技术是分层转化合成技术。

5. 发明申请

WO2008016974A2 UZM-22 ALUMINOSILICATE ZEOLITE, METHOD OF PREPARATION AND PROCESSES USING UZM-22 审中-公开
标题翻译： UZM-22铝酸钠沸石，使用UZM-22的制备方法和工艺
公开(公告)号：WO2008016974A2
公开(公告)日：2008-02-07
申请号：PCT/US2007074972
申请日：2007-08-01
申请人： UOP LLC , MILLER MARK A , MOSCOSO JAIME G , LEWIS GREGORY J
发明人： MILLER MARK A , MOSCOSO JAIME G , LEWIS GREGORY J
IPC分类号： B01J29/04 , C01B39/00
CPC分类号： B01J29/70 , C01B39/48 , C07C2/58 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G45/64 , C10G50/00 , C07C9/16
摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula (I), where M is an alkali, alkaline earth, or rare earth metal such as lithium and strontium, R is a singly charged organoammonium cation such as the choline cation and E is a framework element such as gallium. These zeolites are similar to ZSM-18 but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
摘要翻译：已经合成了一系列结晶硅铝酸盐沸石。这些沸石由经验式（I）表示，其中M是碱金属，碱土金属或稀土金属如锂和锶，R是单一带电的有机铵阳离子如胆碱阳离子，E是骨架元素作为镓。这些沸石类似于ZSM-18，但是其特征在于独特的x射线衍射图和组成，并具有用于进行各种烃转化方法的催化性能。

6. 发明申请

WO2014093110A3 UZM-44 ALUMINOSILICATE ZEOLITE 审中-公开
标题翻译： UZM-44铝硅酸盐沸石
公开(公告)号：WO2014093110A3
公开(公告)日：2014-08-07
申请号：PCT/US2013073224
申请日：2013-12-05
申请人： UOP LLC
发明人： MILLER MARK A , NICHOLAS CHRISTOPHER P , WILSON STEPHEN T
IPC分类号： C01B39/48 , B01J29/70
CPC分类号： C07C7/13 , B01J29/70 , C01B39/48 , C07C2/66 , C07C2/76 , C07C15/067 , C07C15/073 , C07C15/08 , C07C2529/70 , Y02P20/52
摘要： A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. NanMm k+TtAl1-xExSiyOz where "n" is the mole ratio of Na to (Al + E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, "m" is the mole ratio of M to (Al + E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations.
摘要翻译：已经合成了一种新的名为UZM-44的硅铝酸盐沸石家族。这些沸石由经验式表示。其中“n”是Na与（Al + E）的摩尔比，M表示来自锌，第1族，第2族，第3族和或周期表的镧系元素的金属或金属， “m”是M与（Al + E）的摩尔比，“k”是金属或金属M的平均电荷，T是有机结构定向剂或E，诸如镓的骨架元素。这些沸石类似于IM-5，但其特征在于独特的组成和合成程序，并且具有用于进行各种烃转化过程和用于进行各种分离的分离性质的催化性质。

7. 发明申请

WO2013096075A3 AROMATIC TRANSFORMATION USING UZM-39 ALUMINOSILICATE ZEOLITE 审中-公开
标题翻译：用UZM-39铝硅酸盐沸石进行芳香转化
公开(公告)号：WO2013096075A3
公开(公告)日：2013-08-22
申请号：PCT/US2012069408
申请日：2012-12-13
申请人： UOP LLC
发明人： NICHOLAS CHRISTOPHER P , MILLER MARK A , NEGIZ ANTOINE
IPC分类号： C07C15/00 , B01J29/70 , C07C2/66
CPC分类号： C07C2/66 , B01J29/70 , B01J35/002 , C07C2529/70 , C07C15/02
摘要： A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for aromatic transformation reactions. These zeolites are represented by the empirical formula. NanMm k+TtA11-xExSiyOz where "n" is the mole ratio of Na to (Al + E), M represents at least one metal, "m" is the mole ratio of M to (Al + E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, "t" is the mole ratio of N from the organic structure directing agent or agents to (Al + E), and E is a framework element such as gallium. The process involves contacting at least a first aromatic with the coherently grown composites of TUN and IMF zeotypes to produce at least a second aromatic.
摘要翻译：已经合成了一系列连贯生长的TUN和IMF原型的复合物，并显示它们是用于芳香族转化反应的有效催化剂。这些沸石由经验式表示。其中“n”是Na与（Al + E）的摩尔比，M表示至少一种金属，“m”是M与（Al + E）的摩尔比，“k”是一种或多种金属M，T的平均电荷是有机结构导向剂，“t”是N与有机结构导向剂或（Al + E）的摩尔比，E是骨架元素如镓。该方法涉及使至少第一种芳族化合物与TUN和IMF原型的相干生长的复合物接触以产生至少第二种芳族化合物。

8. 发明申请

WO2016089758A3 ORGANO-1-OXA-4-AZONIUM CYCLOHEXANE COMPOUNDS 审中-公开
标题翻译：有机基-1-氧杂-4-氮杂环戊烷化合物
公开(公告)号：WO2016089758A3
公开(公告)日：2016-09-01
申请号：PCT/US2015062971
申请日：2015-11-30
申请人： UOP LLC
发明人： NICHOLAS CHRISTOPHER P , MILLER MARK A , GALEY MELISSA M , YUHAS BENJAMIN D , PRABHAKAR SESH
IPC分类号： C07D265/30 , C07D265/34
CPC分类号： C07D295/037 , C07D295/023 , C07D295/027
摘要： Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.
摘要翻译：描述了新的1-氧杂-4-氮杂环己烷盐。这些化合物可以用作结构导向剂，并且它们克服了许多与OSDA合成和随后的沸石合成相关的典型问题。还描述了由各种原料合成1-氧杂-4-氮杂环己烷盐的方法。将取代的烃加入水中形成混合物，然后加入1-氧杂-4-氮杂环己烷衍生物。搅拌反应混合物直至得到含有1-氧杂-4-氮环己烷盐的溶液。

9. 发明申请

WO2012003321A3 UZM-7 ALUMINOSILICATE ZEOLITE, METHOD OF PREPARATION AND PROCESSES USING UZM-7 审中-公开
标题翻译： UZM-7铝酸锌沸石，使用UZM-7的制备方法和工艺
公开(公告)号：WO2012003321A3
公开(公告)日：2012-04-26
申请号：PCT/US2011042601
申请日：2011-06-30
申请人： UOP LLC , LEWIS GREGORY J , MILLER MARK A , KNIGHT LISA M
发明人： LEWIS GREGORY J , MILLER MARK A , KNIGHT LISA M
IPC分类号： C01B39/48 , B01J29/70 , C07C2/12 , C07C2/54 , C07C5/22
CPC分类号： C01B39/48 , B01J29/70 , B01J35/002 , B01J35/1019 , B01J37/10 , C07C2/12 , C07C2/58 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G35/095 , C10G47/16 , C10G73/00 , C10G2300/1044 , C10G2300/1059 , C10G2300/1096 , C10G2400/02 , C10G2400/30 , C07C15/02 , C07C9/16
摘要： A new family of crystalline aluminosilicate zeolites has been synthesized designated UZM-7. These zeolites are represented by the empirical formula. M m n+ R r p+ Al (1-x) E x Si y O z where M is an alkali, alkaline earth, or rare earth metal such as lithium, potassium and barium, R is an organoammonium cation such as the choline or the diethyldimethylammonium cation and E is a framework element such as gallium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
摘要翻译：已经合成了一系列结晶硅铝酸盐沸石，称为UZM-7。这些沸石由经验公式表示。 M m n + R r p + Al（1-x）E x Si y O z其中M是碱金属，碱土金属或稀土金属如锂，钾和钡，R是有机铵阳离子，如胆碱或二乙基二甲基铵阳离子，E是镓等骨架元素。这些沸石的特征在于独特的x射线衍射图和组成，并且具有用于进行各种烃转化方法的催化性能。

10. 发明申请

WO2006137900A3 UZM-12 AND UZM-12HS: CRYSTALLINE ALUMINOSILICATE ZEOLITIC COMPOSITIONS AND PROCESSES FOR PREPARING AND USING THE COMPOSITIONS 审中-公开
标题翻译： UZM-12和UZM-12HS：用于制备和使用组合物的结晶铝酸酯组合物和方法
公开(公告)号：WO2006137900A3
公开(公告)日：2007-07-12
申请号：PCT/US2005035559
申请日：2005-10-03
申请人： UOP LLC , MILLER MARK A , LEWIS GROGORY J , GISSELQUIST JANA L , MOSCOSO JAIME G , PATTON R LYLE
发明人： MILLER MARK A , LEWIS GROGORY J , GISSELQUIST JANA L , MOSCOSO JAIME G , PATTON R LYLE
IPC分类号： C01B39/30
CPC分类号： C01B39/48 , B01J29/50 , C01B39/305
摘要： A series of crystalline alumino-silicate zeolites identified as UZM-12 have been synthesized. These UZM-12 compositions have the ERI topology, a Si/Al >5.5 and can be prepared as nanocrystallites having an average particle size of 15 to 50 nanometers and a spheroidal morphology. The UZM-12 composition can be treated to remove at least a fraction of the framework aluminum atoms thereby providing zeolites with a Si/Al >5.75 and identified as UZM-12HS. Both the UZM-12 and UZM-12HS can catalyze various hydrocarbon conversion processes.
摘要翻译：已经合成了一系列标准为UZM-12的结晶铝硅酸盐沸石。这些UZM-12组合物具有ERI拓扑，Si / Al> 5.5，并且可以制备为具有15至50纳米的平均粒径和球形形态的纳米晶体。可以处理UZM-12组合物以除去至少一部分骨架铝原子，从而提供具有Si / Al> 5.75的沸石并鉴定为UZM-12HS。 UZM-12和UZM-12HS都可以催化各种烃转化过程。

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