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    • 1. 发明授权
    • 4-arryl-2-haloimidazole-5-carboxylic esters, the preparation and use
thereof
    • 4-芳基-2-卤代咪唑-5-羧酸酯的制备和应用
    • US5211737A
    • 1993-05-18
    • US666483
    • 1991-03-06
    • Ulrich WriedeGerhard HamprechtHermann KoehlerThomas KuekenhoehnerBruno WuerzerKarl-Otto Westphalen
    • Ulrich WriedeGerhard HamprechtHermann KoehlerThomas KuekenhoehnerBruno WuerzerKarl-Otto Westphalen
    • A01N25/32C07D233/90
    • A01N25/32C07D233/90
    • 4-Aryl-2-haloimidazole-5-carboxylic esters of the general formula Ia and Ib ##STR1## where R.sup.1 is C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl,R.sub.2 is C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl,Hal is chlorine or bromine,n is 0 to 3,x is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 -haloalkylthio, cyano, nitro, carbo-C.sub.1 -C.sub.4 -alkoxy, N,N-di-C.sub.1 -C.sub.4 -alkylcarbamoyl and/or halogen,processes for their manufacture, and their use in herbicidal agents as safeners in combination with at least one herbicidal active ingredient from the group consisting ofa) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives andb) cyclohexenone derivatives.
    • 其中R 1是C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6 - 炔基,R 2是(C 1 -C 6) - 烷基,C 3 -C 6 - 烯基或C 3 -C 6炔基的4-芳基-2-卤代咪唑-5-羧酸酯 C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6炔基,Hal为氯或溴,n为0至3,x为C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基, C 1 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基亚磺酰基,C 1 -C 4烷基磺酰基,C 1 -C 4卤代烷硫基,氰基,硝基,C 1 -C 4 - 烷氧基,N, C4-烷基氨基甲酰基和/或卤素,其制备方法和它们在除草剂中的用途作为安全剂与至少一种除草活性成分组合,所述除草活性成分包括a)2-(4-杂芳氧基) - 或2-(4 - 芳氧基) - 苯氧基乙酸或 - 丙酸衍生物,和b)环己烯酮衍生物。
    • 4. 发明授权
    • Pyridine derivatives and their use for controlling undesirable plant
growth
    • 吡啶衍生物及其用于控制​​不希望的植物生长的用途
    • US5262384A
    • 1993-11-16
    • US825793
    • 1992-01-21
    • Gerhard HamprechtNorbert GoetzBruno WuerzerKarl-Otto Westphalen
    • Gerhard HamprechtNorbert GoetzBruno WuerzerKarl-Otto Westphalen
    • A01N43/40A01N43/90C07D213/81C07D213/82C07D471/04C07D47/04
    • C07D213/81A01N43/40A01N43/90C07D213/82C07D471/04
    • Pyridine derivatives of the formulae ##STR1## where W, X, Y and Z are each C--R.sup.4, N or N.fwdarw.O, with the proviso that the ring contains only one heteroatom, and the substituents R.sup.1, R.sup.2 and R.sup.3 have the following meanings:R.sup.1 is alkoxy, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, or substituted or unsubstituted alkynyl,R.sup.2 is hydrogen,R.sup.3 is formyl, 4,5-dihydrooxazol-2-yl or --CO--A--R.sup.5 or --CO--NR.sup.6 R.sup.7,whereR.sup.4 is halogen, nitro, cyano, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, alkenyloxy, alkynyloxy, alkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, or is substituted or unsubstituted phenylA is oxygen or sulfur,R.sup.5 is hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, cycloalkyl, substituted or unsubstituted phenyl,one equivalent of a cation or the radical --N.dbd.CR.sup.8 R.sup.9 andR.sup.6 and R.sup.7 are hydrogen or alkyl or together denote a methylene chain having 4 or 5 members,their agriculturally utilizable salts, and their use for controlling unwanted plant growth.
    • 其中W,X,Y和Z各自为C-R 4,N或N-> O,条件是环仅含有一个杂原子,并且 取代基R 1,R 2和R 3具有以下含义:R 1是烷氧基,取代或未取代的烷基,取代或未取代的环烷基,取代或未取代的链烯基或取代或未取代的炔基,R 2是氢,R 3是甲酰基,4,5-二氢恶唑 -2-基或-CO-A-R5或-CO-NR6R7,其中R4是卤素,硝基,氰基,取代或未取代的烷基,取代或未取代的苄基,取代或未取代的环烷基,取代或未取代的烯基,取代或未取代的炔基 烷氧基,烷硫基,卤代烷氧基,卤代烷硫基,烯氧基,炔氧基,烷基亚磺酰基,烷基磺酰基,卤代烷基磺酰基,取代或未取代的苯氧基或苯硫基,取代或未取代的具有一个或两个选自t 由氧,硫和氮组成的组,或者是取代或未取代的苯基A是氧或硫,R5是氢,取代或未取代的烷基,取代或未取代的苄基,环烷基,取代或未取代的苯基,1当量的阳离子或 基团-N = CR 8 R 9和R 6和R 7是氢或烷基或一起表示具有4或5个成员的亚甲基链,它们的农业上可利用的盐,以及它们用于控制不想要的植物生长的用途。
    • 9. 发明授权
    • Preparation of thiazolo (2,3-b) zuinazolones
    • 噻唑(2,3-b)唑胺酮的制备
    • US5030727A
    • 1991-07-09
    • US508495
    • 1990-04-12
    • Gerhard HamprechtGuenther SeyboldNorbert MeyerBruno Wuerzer
    • Gerhard HamprechtGuenther SeyboldNorbert MeyerBruno Wuerzer
    • A01N43/90C07D277/32C07D513/04
    • C07D513/04A01N43/90
    • The process of manufacturing thiazolo-(2,3-b)-quinoazolones of the formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are defined in the disclosure, wherein either a) an anthranilamide derivative of the formula II ##STR2## where R.sup.5 and R.sup.6 are hydrogen or C.sub.1 -C.sub.4 -alkyl, is reacted with a thiazole derivative of the formula III ##STR3## where X is fluorine, chlorine, bormine, alkylsulfonyl or arylsulfonyl, or b) for certain radicals R.sup.4' from the group R.sup.4 - a thiazolo-(2,3-b)-quinazolone of the general formula IV ##STR4## is reacted with a nucleophile R.sup.4' -H, where R.sup.4' is alkoxy, alkylthio or unsubstituted or halogen-, alkyl-, haloalkyl-, nitro- or alkoxy-substituted phenoxy or thiophenyl, or an alkali metal, alkaline earth metal or ammonium salt of an alcohol.
    • 制备式I的噻唑并(2,3-b) - 喹唑啉酮的方法,其中R 1,R 2,R 3和R 4在本公开内容中定义,其中a)式II的邻氨基苯甲酰胺衍生物 其中R 5和R 6是氢或C 1 -C 4 - 烷基与式III的噻唑衍生物(III)反应,其中X是氟,氯,甲酚,烷基磺酰基或芳基磺酰基,或b )通式IV(IV)的噻唑并(2,3-b) - 喹唑酮的一些基团R4'与亲核试剂R4'-H反应,其中R4'是烷氧基, 烷硫基或未取代的或卤素,烷基 - ,卤代烷基 - ,硝基 - 或烷氧基取代的苯氧基或噻吩基,或醇的碱金属,碱土金属或铵盐。