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1. 发明授权

US07154740B2 Substituted poly(alkylenedioxythiophenes) as solid electrolytes in electrolytic capacitors 失效
标题翻译：在电解电容器中取代聚（亚烷基二氧噻吩）作为固体电解质
公开(公告)号：US07154740B2
公开(公告)日：2006-12-26
申请号：US10641560
申请日：2003-08-15
申请人： Udo Merker , Knud Reuter , Klaus Lerch
发明人： Udo Merker , Knud Reuter , Klaus Lerch
IPC分类号： H01G9/02 , H01G9/00
CPC分类号： H01G9/025 , C08G61/126 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： Described is an electrolytic capacitor that includes: (a) a layer of an oxidizable metal; (b) a layer of an oxide of the oxidixable metal; (c) a solid electrolyte; and (d) a plurality of contacts. The solid electrolyte includes a polythiophene having recurring units represented by the following formulas (I-a) and/or (I-b), Also described are processes for producing electrolytic capacitors, and conductive layers that include such polythiophenes.
摘要翻译：描述了一种电解电容器，其包括：（a）可氧化金属层; （b）可氧化金属的氧化物层; （c）固体电解质; 和（d）多个触点。固体电解质包括具有由下式（I-a）和/或（I-b）表示的重复单元的聚噻吩。还描述了生产电解电容器的方法，以及包括这种聚噻吩的导电层。

2. 发明授权

US08420671B2 Stabilised thiophene derivatives 失效
标题翻译：稳定的噻吩衍生物
公开(公告)号：US08420671B2
公开(公告)日：2013-04-16
申请号：US12894952
申请日：2010-09-30
申请人： Knud Reuter , Klaus Wussow , Udo Merker , Andreas Elschner
发明人： Knud Reuter , Klaus Wussow , Udo Merker , Andreas Elschner
IPC分类号： A61K31/4468
CPC分类号： C08K5/13 , C08G2261/3223 , C08K5/3435 , C08L65/00 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/43
摘要： The present invention relates to a stabilized monomer composition comprising at least 50 wt.-%, based on the total weight of the stabilized monomer composition, of a thiophene derivative monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, and 0.001 to 10 wt.-%, based on the total weight of the stabilized monomer composition, of a stabilizer. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method, the use of a stabilized monomer composition and to the use of a stabilizer.
摘要翻译：本发明涉及稳定的单体组合物，其包含基于稳定的单体组合物的总重量的至少50重量％的具有通式（I）的噻吩衍生物单体，其中R1和R2独立地为另一个，对于氢，对于任选被取代的C1-C20烷基或C1-C20-氧烷基，任选地被1至5个氧原子和/或硫原子间隔，或共同用于任选取代的C 1 -C 20 - 二氧亚烷基或C6-C20-二氧亚芳基，和基于稳定化单体组合物的总重量为0.001至10重量％的稳定剂。本发明还涉及一种用于制造电容器，通过该方法获得的电容器，使用稳定的单体组合物和使用稳定剂的方法。

3. 发明申请

US20110102970A1 MONOMERS OF SELECTED COLOUR NUMBERS AND CAPACITORS PREPARED THEREFROM 失效
标题翻译：选择的颜色编号和电容器的单体
公开(公告)号：US20110102970A1
公开(公告)日：2011-05-05
申请号：US12894976
申请日：2010-09-30
申请人： Udo Merker , Klaus Wussow , Knud Reuter , Andreas Elschner
发明人： Udo Merker , Klaus Wussow , Knud Reuter , Andreas Elschner
IPC分类号： H01G4/06 , C07D333/10 , C07D333/18 , C07D333/16 , C07D495/04 , H01G7/00
CPC分类号： H01G4/18 , C07D495/04 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/435
摘要： The present invention relates to a monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, wherein the monomer has a colour in a range of a Hazen colour number determined according to test method described herein of at least 20, to a Gardner colour number determined according to test method described herein of not more than 5. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method and to the use of a monomer.
摘要翻译：本发明涉及具有通式（I）的单体，其中R 1和R 2彼此独立地为氢，任选取代的C 1 -C 20 - 烷基或C 1 -C 20 - 烷氧基，任选地被 1至5个氧原子和/或硫原子，或共同用于任选取代的C 1 -C 20 - 二氧亚烷基或C 6 -C 20 - 二亚甲基，其中单体具有根据测试方法确定的哈岑色数范围内的颜色根据本文所述的测试方法确定的加德纳颜色数不超过5个。本发明还涉及制造电容器，通过该方法获得的电容器和使用的方法的单体。

4. 发明授权

US07341801B2 Polythiophenes having alkyleneoxythia thiophene units in electrolyte capacitors 失效
标题翻译：在电解质电容器中具有亚烷氧基硫噻吩单元的聚噻吩
公开(公告)号：US07341801B2
公开(公告)日：2008-03-11
申请号：US10889491
申请日：2004-07-12
申请人： Knud Reuter , Udo Merker , Friedrich Jonas
发明人： Knud Reuter , Udo Merker , Friedrich Jonas
IPC分类号： H01M4/00
CPC分类号： H01B1/127 , H01G9/025 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： Electrolyte capacitors containing certain polythiophenes are described. More particularly, the polythiophenes have backbones containing repeating units of the following general formula (I) and/or repeating units of the following general formula (II), wherein A is, for example, a C1-C5-alkylene radical, R is, for example, a C1-C18-alkyl radical, and x is an integer from 0 to 8. Also described are dispersions comprising such polythiophenes, and the use of such polythiophenes or dispersions thereof for producing conductive layers.
摘要翻译：描述了含有某些聚噻吩的电解电容器。更具体地说，聚噻吩具有含有以下通式（I）的重复单元和/或下列通式（II）的重复单元的骨架，其中A是例如C 1〜 C 5 - 亚烷基，R是例如C 1 -C 18 - 烷基，x是0的整数还描述了包含这种聚噻吩的分散体，以及这种聚噻吩或其分散体在制备导电层中的用途。

5. 发明申请

US20110128676A1 PROCESS FOR PRODUCING ELECTROLYTIC CAPACITORS HAVING A LOW LEAKAGE CURRENT 审中-公开
标题翻译：用于生产具有低漏电流的电解电容器的方法
公开(公告)号：US20110128676A1
公开(公告)日：2011-06-02
申请号：US12995467
申请日：2009-05-13
申请人： Hikmet Karabulut , Udo Merker , Knud Reuter , Gerd Passing
发明人： Hikmet Karabulut , Udo Merker , Knud Reuter , Gerd Passing
IPC分类号： H01G9/042 , H01G9/048
CPC分类号： H01G9/0029 , H01G9/04 , H01G9/052 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： Process for producing a capacitor anode based on at least one of a valve metal and a compound having properties comparable to a valve metal includes providing a pressing or cutting tool which is at least one of made of and coated with a pressing or cutting tool material comprising at least one of a metal carbide, an oxide, a boride, a nitride, a silicide, a carbonitride or alloys thereof, a ceramic material, a hardened steel, an alloy steel, and a capacitor anode material. Particles of the at least one of a valve metal and a compound having properties comparable to a valve metal are pressed or cut with the pressing or cutting tool so as to produce a porous electrode body and form the capacitor anode.
摘要翻译：基于阀金属和具有与阀金属相当的性质的化合物中的至少一种制造电容器阳极的方法包括提供压制或切割工具，所述压制或切削工具是由压制或切削工具材料制成并涂覆的至少一种，包括金属碳化物，氧化物，硼化物，氮化物，硅化物，碳氮化物或其合金中的至少一种，陶瓷材料，硬化钢，合金钢和电容器负极材料中的至少一种。使用压制或切割工具对具有与阀金属相当的性能的阀金属和化合物中的至少一种的颗粒进行压制或切割，以便产生多孔电极体并形成电容器阳极。

6. 发明申请

US20110102973A1 STABILISED THIOPHENE DERIVATIVES 失效
标题翻译：稳定的噻吩衍生物
公开(公告)号：US20110102973A1
公开(公告)日：2011-05-05
申请号：US12894952
申请日：2010-09-30
申请人： Knud Reuter , Klaus Wussow , Udo Merker , Andreas Elschner
发明人： Knud Reuter , Klaus Wussow , Udo Merker , Andreas Elschner
IPC分类号： H01G9/042 , C07D495/04 , H01G9/00 , H01G9/15
CPC分类号： C08K5/13 , C08G2261/3223 , C08K5/3435 , C08L65/00 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/43
摘要： The present invention relates to a stabilised monomer composition comprising at least 50 wt.-%, based on the total weight of the stabilised monomer composition, of a thiophene derivative monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, and 0.001 to 10 wt.-%, based on the total weight of the stabilised monomer composition, of a stabiliser. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method, the use of a stabilised monomer composition and to the use of a stabiliser.
摘要翻译：本发明涉及稳定的单体组合物，其包含基于稳定的单体组合物的总重量的至少50重量％的具有通式（I）的噻吩衍生物单体，其中R1和R2独立地为另一个，对于氢，对于任选被取代的C1-C20烷基或C1-C20-氧烷基，任选地被1至5个氧原子和/或硫原子间隔，或共同用于任选取代的C 1 -C 20 - 二氧亚烷基或C6-C20-二氧亚芳基，和基于稳定化单体组合物的总重量为0.001至10重量％的稳定剂。本发明还涉及一种用于制造电容器，通过该方法获得的电容器，使用稳定的单体组合物和使用稳定剂的方法。

7. 发明申请

US20090310285A1 PROCESS FOR PREPARING POLYTHIOPHENES 审中-公开
标题翻译：制备聚氧乙烯的方法
公开(公告)号：US20090310285A1
公开(公告)日：2009-12-17
申请号：US12441738
申请日：2007-09-19
申请人： Knud Reuter , Stephen Kirchmeyer , Udo Merker , Peter Wilfried Loevenich , Timo Meyer-Friedrichsen
发明人： Knud Reuter , Stephen Kirchmeyer , Udo Merker , Peter Wilfried Loevenich , Timo Meyer-Friedrichsen
IPC分类号： H01G9/025 , C08F4/32 , C08F2/04 , B05D5/12 , H01G9/02
CPC分类号： C08G61/126 , H01B1/127 , H01G9/0036 , H01G9/028
摘要： The invention relates to a process for preparing polythiophene dispersions or for in situ deposition of polythiophenes. The dispersion is prepared by oxidative polymerizing of a thiophene or thiophene derivative, wherein an oxidizing agent is used and is at least one organic peroxidic compound excluding diacyl peroxide. The invention also relates to the use of specific organic peroxides as oxidizing agents in the oxidative polymerization of thiophenes. The invention further relates to a process to process a conductive layer and the use of the conductive layer.
摘要翻译：本发明涉及一种制备聚噻吩分散体或用于原位沉积聚噻吩的方法。通过氧化聚合噻吩或噻吩衍生物制备分散体，其中使用氧化剂，并且是除二酰基过氧化物之外的至少一种有机过氧化合物。本发明还涉及在噻吩的氧化聚合中使用特定的有机过氧化物作为氧化剂。本发明还涉及一种处理导电层的方法和导电层的使用。

8. 发明授权

US08390988B2 Monomers of selected colour numbers and capacitors prepared therefrom 失效
标题翻译：所选颜色数字和由其制备的电容器的单体
公开(公告)号：US08390988B2
公开(公告)日：2013-03-05
申请号：US12894976
申请日：2010-09-30
申请人： Udo Merker , Klaus Wussow , Knud Reuter , Andreas Elschner
发明人： Udo Merker , Klaus Wussow , Knud Reuter , Andreas Elschner
IPC分类号： H01G9/00
CPC分类号： H01G4/18 , C07D495/04 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/435
摘要： The disclosure describes a monomer having the general formula (I): in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group. The monomer has a color in a range of a Hazen color number determined according to test method described herein of at least 20 to a Gardner color number determined according to test method described herein of not more than 5. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method and to the use of a monomer.
摘要翻译：本公开描述了具有通式（I）的单体：其中R 1和R 2彼此独立地表示氢，对于任选取代的C 1 -C 20 - 烷基或C 1 -C 20 - 烷氧基，任选地被1 至5个氧原子和/或硫原子，或共同用于任选取代的C 1 -C 20 - 二氧亚烷基或C 6 -C 20 - 二亚甲基。该单体具有根据根据本文所述的测试方法确定的至少20至根据本文所述测试方法确定的加德纳颜色数不超过5的哈根色数的颜色。本发明还涉及一种方法用于制造电容器，通过该方法获得的电容器和单体的使用。

9. 发明申请

US20050013094A1 Polythiophenes having alkyleneoxythia thiophene units in electrolyte capacitors 失效
标题翻译：在电解质电容器中具有亚烷氧基硫噻吩单元的聚噻吩
公开(公告)号：US20050013094A1
公开(公告)日：2005-01-20
申请号：US10889491
申请日：2004-07-12
申请人： Knud Reuter , Udo Merker , Friedrich Jonas
发明人： Knud Reuter , Udo Merker , Friedrich Jonas
IPC分类号： H01G9/028 , C08G75/00 , H01B1/06 , H01B1/12 , H01B13/00 , H01G9/00 , H01G9/025 , H01G9/04
CPC分类号： H01B1/127 , H01G9/025 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： Electrolyte capacitors containing certain polythiophenes are described. More particularly, the polythiophenes have backbones containing repeating units of the following general formula (I) and/or repeating units of the following general formula (II), wherein A is, for example, a C1-C5-alkylene radical, R is, for example, a C1-C18-alkyl radical, and x is an integer from 0 to 8. Also described are dispersions comprising such polythiophenes, and the use of such polythiophenes or dispersions thereof for producing conductive layers.
摘要翻译：描述了含有某些聚噻吩的电解电容器。更具体地，聚噻吩具有含有以下通式（I）的重复单元和/或下列通式（II）的重复单元的骨架，其中A是例如C 1 -C 5亚烷基，R 3，例如，C 1 -C 18烷基，x是0至8的整数。还描述了包含这种聚噻吩的分散体，以及这种聚噻吩或其分散体在制备导电层中的用途。

10. 发明授权

US10109427B2 Layer compositions with improved electrical parameters comprising PEDOT/PSS and a stabilizer 有权
公开(公告)号：US10109427B2
公开(公告)日：2018-10-23
申请号：US13877000
申请日：2011-09-30
申请人： Akio Ishikawa , Udo Merker , Klaus Wussow , Katrin Asteman
发明人： Akio Ishikawa , Udo Merker , Klaus Wussow , Katrin Asteman
IPC分类号： H01G9/00 , H01G9/025 , C08L65/00 , C09D5/24 , H01G9/028 , C09D165/00 , H01G11/48 , H01G11/56 , C08K5/13 , C08L25/18 , C08K5/132
摘要： The present invention relates to a process for the production of a layer composition (10) with an electrically conductive layer (11), comprising the process steps: a) provision of a substrate (12) with a substrate surface (13); b) formation of a polymer layer (14) comprising an electrically conductive polymer (15) on at least a part of the substrate surface (13); c) application of a liquid stabilizer phase, comprising a stabilizer and a liquid phase, to the polymer layer (14) from process step b), wherein the stabilizer phase comprises less than 0.2 wt. %, based on the stabilizer phase, of the electrically conductive polymer, wherein the stabilizer is an aromatic compound with at least two OH groups, and a layer composition (10) and uses thereof.

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