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1. 发明申请

WO2010132188A2 STAGED MEMBRANE SYSTEM FOR GAS, VAPOR, AND LIQUID SEPARATIONS 审中-公开
标题翻译：用于气体，蒸气和液体分离的分层膜系统
公开(公告)号：WO2010132188A2
公开(公告)日：2010-11-18
申请号：PCT/US2010/032144
申请日：2010-04-23
申请人： UOP LLC , ZHOU, Lubo , LIU, Chunqing , CABRERA, Carlos A. , COUGHLIN, Peter K.
发明人： ZHOU, Lubo , LIU, Chunqing , CABRERA, Carlos A. , COUGHLIN, Peter K.
IPC分类号： B01D65/00 , B01D61/00 , B01D71/00
CPC分类号： B01D53/228 , B01D67/0006 , B01D71/62 , B01D2256/16 , B01D2256/24 , B01D2257/504 , B01D2258/06 , B01D2323/30 , B01D2323/345 , Y02C10/10
摘要： The present invention involves the use of a multi-stage membrane system for gas, vapor, and liquid separations. In this multi-stage membrane system, high selectivity and high permeance or at least high selectivity polybenzoxazole membranes or cross-linked polybenzoxazole membranes are applied for a pre-membrane or both the pre-membrane and the secondary membrane. A primary membrane can be from conventional glassy polymers. This multi-stage membrane system can reduce inter-stage compression cost, increase product recovery and product purity for gas, vapor, and liquid separations. It can also save the cost compared to the system using all the high cost polybenzoxazole membranes or cross-linked polybenzoxazole membranes.
摘要翻译：本发明涉及使用多级膜系统进行气体，蒸汽和液体分离。在该多级膜系统中，对膜前或膜前和膜进行二次膜的预选择，高选择性和高渗透性或至少高选择性的聚苯并恶唑膜或交联聚苯并恶唑膜。初级膜可以来自常规玻璃状聚合物。这种多级膜系统可以降低气体，蒸汽和液体分离的阶段间压缩成本，提高产品回收率和产品纯度。与使用所有高成本聚苯并恶唑膜或交联聚苯并恶唑膜的系统相比，还可以节省成本。

2. 发明申请

WO2010110995A2 POLYMER MEMBRANES DERIVED FROM AROMATIC POLYIMIDE MEMBRANES 审中-公开
标题翻译：从芳族聚酰亚胺膜衍生的聚合物膜
公开(公告)号：WO2010110995A2
公开(公告)日：2010-09-30
申请号：PCT/US2010/025822
申请日：2010-03-02
申请人： UOP LLC , LIU, Chunqing , SERBAYEVA, Raisa , TANG, Man-Wing , ZHOU, Lubo , COUGHLIN, Peter K.
发明人： LIU, Chunqing , SERBAYEVA, Raisa , TANG, Man-Wing , ZHOU, Lubo , COUGHLIN, Peter K.
IPC分类号： B01D71/64 , C08J5/22
CPC分类号： B01D71/64 , B01D67/0088 , B01D2323/08 , B01D2323/30
摘要： The present invention discloses a new type of high performance polymer membranes derived from aromatic polyimide membranes and methods for making and using these membranes. The polymer membranes described in the present invention were derived from aromatic polyimide membranes by crosslinking followed by thermal treating. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The high performance polymer membranes showed significantly improved permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The high performance polymer membranes also showed significantly improved selectivity for gas separations compared to the thermal-treated but non-UV-crosslinked aromatic polyimide membranes. The high performance polymer membranes of the present invention are suitable for liquid, gas, and vapor separations, as well as for catalysis and fuel cell applications.
摘要翻译：本发明公开了一种衍生自芳族聚酰亚胺膜的新型高性能聚合物膜以及制造和使用这些膜的方法。本发明中描述的聚合物膜通过交联然后进行热处理从芳族聚酰亚胺膜得到。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，高性能聚合物膜显示出显着改善气体分离的渗透性。与热处理但非UV交联的芳族聚酰亚胺膜相比，高性能聚合物膜还显示出对气体分离的选择性显着提高。本发明的高性能聚合物膜适用于液体，气体和蒸汽分离，以及催化和燃料电池应用。

3. 发明申请

WO2010110994A2 POLYMER MEMBRANES PREPARED FROM AROMATIC POLYIMIDE MEMBRANES BY THERMAL TREATING AND UV CROSSLINKING 审中-公开
标题翻译：通过热处理和紫外线交联从芳族聚酰亚胺膜制备的聚合物膜
公开(公告)号：WO2010110994A2
公开(公告)日：2010-09-30
申请号：PCT/US2010/025820
申请日：2010-03-02
申请人： UOP LLC , LIU, Chunqing , COUGHLIN, Peter K. , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
发明人： LIU, Chunqing , COUGHLIN, Peter K. , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
IPC分类号： B01D71/64
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0093 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/16 , C08L79/08 , Y02C20/20
摘要： The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
摘要翻译：本发明公开了通过热处理和交联由芳族聚酰亚胺膜制备的新型高性能聚合物膜以及制造和使用这些膜的方法。聚合物膜由芳族聚酰亚胺膜通过在惰性气氛下热处理制备，然后优选通过使用UV辐射源进行交联。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，膜显示出气体分离的选择性和渗透性显着提高。膜可以制造成任何方便的几何形状，并且不仅适用于各种液体，气体和蒸汽分离，而且还可以用于其它应用，例如用于催化和燃料电池应用。

4. 发明申请

WO2011149724A2 TREATMENT OF NATURAL GAS FEEDS 审中-公开
标题翻译：天然气饲料的处理
公开(公告)号：WO2011149724A2
公开(公告)日：2011-12-01
申请号：PCT/US2011/036897
申请日：2011-05-18
申请人： UOP LLC , DUNNE, Stephen, R. (deceased) , ZHOU, Lubo , COUGHLIN, Peter, K.
发明人： DUNNE, Stephen, R. (deceased) , ZHOU, Lubo , COUGHLIN, Peter, K.
IPC分类号： B01D61/58 , B01D53/02 , B01D53/62 , C10L3/10
CPC分类号： B01D53/22 , B01D53/1443 , B01D53/1456 , B01D53/229 , B01D53/62 , B01D53/75 , B01D2252/20447 , B01D2252/20484 , B01D2252/20489 , B01D2253/108 , B01D2256/22 , B01D2256/245 , B01D2257/302 , B01D2257/304 , B01D2257/404 , B01D2257/504 , B01D2259/4566 , B01D2317/022 , C10L3/104 , Y02C10/04 , Y02C10/06 , Y02C10/08 , Y02C10/10
摘要： The present invention provides a process for treating a natural gas stream comprising sending a natural gas stream to at least one membrane unit to produce a permeate stream containing a higher concentration of carbon dioxide and a retentate stream containing a lower concentration of carbon dioxide. Then the retentate stream is sent to an adsorbent bed to remove carbon dioxide and other impurities to produce a natural gas product stream. The regeneration gas stream is sent through the molecular sieve adsorbent bed to desorb the carbon dioxide. In one process flow scheme, the regeneration stream is combined with the permeate stream from the membrane unit. Then the combined stream is sent to an absorbent column to remove carbon dioxide from the permeate stream to produce a second natural gas product stream. In the alternative flow scheme, a second membrane unit is used to improve efficiency.
摘要翻译：本发明提供了一种处理天然气流的方法，包括将天然气流送至至少一个膜单元以产生含有较高浓度二氧化碳的渗透物流和含有较低浓度二氧化碳的滞留物流。然后将滞留物流送入吸附床以除去二氧化碳和其它杂质以产生天然气产物流。再生气流通过分子筛吸附剂床排出以解吸二氧化碳。在一个工艺流程图中，再生流与来自膜单元的渗透物流组合。然后将合并的流送到吸收塔以从渗透物流中除去二氧化碳，以产生第二天然气产物流。在替代流程图中，使用第二膜单元来提高效率。

5. 发明申请

WO2010151451A3 POLYBENZOXAZOLE MEMBRANES PREPARED FROM AROMATIC POLYAMIDE MEMBRANES 审中-公开
公开(公告)号：WO2010151451A3
公开(公告)日：2010-12-29
申请号：PCT/US2010/038574
申请日：2010-06-15
申请人： UOP LLC , LIU, Chunqing , MINKOV, Raisa , FAHEEM, Syed, A. , TANG, Man-Wing , ZHOU, Lubo , BRICKER, Jeffery, C.
发明人： LIU, Chunqing , MINKOV, Raisa , FAHEEM, Syed, A. , TANG, Man-Wing , ZHOU, Lubo , BRICKER, Jeffery, C.
IPC分类号： B01D71/00 , B01D71/64 , B01D69/00 , C08J5/18
摘要： The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550°C under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. The polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.

6. 发明申请

WO2011037706A3 METHOD TO IMPROVE THE SELECTIVITY OF POLYBENZOXAZOLE MEMBRANES 审中-公开
标题翻译：提高聚苯并唑膜选择性的方法
公开(公告)号：WO2011037706A3
公开(公告)日：2011-03-31
申请号：PCT/US2010/045964
申请日：2010-08-19
申请人： UOP LLC , LIU, Chunqing , MINKOV, Raisa , TANG, Man-Wing , ZHOU, Lubo , BRICKER, Jeffery C.
发明人： LIU, Chunqing , MINKOV, Raisa , TANG, Man-Wing , ZHOU, Lubo , BRICKER, Jeffery C.
IPC分类号： B01D71/06 , B01D67/00 , B01D71/64 , C08G73/22
摘要： The present invention discloses a novel method to improve the selectivities of polybenzoxazole (PBO) membranes prepared from aromatic polyimide membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译：本发明公开了一种改进由芳族聚酰亚胺膜制备的用于气体，蒸气和液体分离的聚苯并恶唑（PBO）膜的选择性的新方法。通过热处理含有0.05-20重量％的聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。与不含聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物对CO 2 / CH 4和H 2 / CH 4分离的选择性显示出高达95％的改善。

7. 发明申请

WO2010110975A3 HIGH PERFORMANCE CROSS-LINKED POLYBENZOXAZOLE AND POLYBENZOTHIAZOLE POLYMER MEMBRANES 审中-公开
公开(公告)号：WO2010110975A3
公开(公告)日：2010-09-30
申请号：PCT/US2010/024855
申请日：2010-02-22
申请人： UOP LLC , LIU, Chunqing , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
发明人： LIU, Chunqing , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
IPC分类号： B01D71/64 , B01D67/00 , C08J5/22 , C08G73/22 , C08G75/32
摘要： In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., -OH or -SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.

8. 发明申请

WO2010110986A2 POLYBENZOXAZOLE POLYMER-BASED MIXED MATRIX MEMBRANES 审中-公开
标题翻译：聚苯并唑基聚合物混合基质膜
公开(公告)号：WO2010110986A2
公开(公告)日：2010-09-30
申请号：PCT/US2010/025391
申请日：2010-02-25
申请人： UOP LLC , LIU, Chunqing , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
发明人： LIU, Chunqing , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
IPC分类号： B01D71/00 , B01D69/00 , B01D67/00
CPC分类号： B01D71/62 , B01D67/0079 , B01D69/147
摘要： The present invention discloses new types of polybenzoxazole-based mixed matrix membranes and methods for making and using these membranes. The polybenzoxazole-based mixed matrix membranes are prepared by fabricating a polyimide-based mixed matrix membrane by dispersing molecular sieve particles in a continuous aromatic polyimide matrix with pendent hydroxyl groups ortho to the heterocyclic imide nitrogen; and then converting the polyimide-based mixed matrix membrane to a polybenzoxazole-based mixed matrix membrane by heating between 200 and 600C under inert atmosphere or vacuum. The polybenzoxazole-based mixed matrix membranes of the present invention can be fabricated into any convenient geometry such as flat sheet (or spiral wound), tube, hollow fiber, or thin film composite. These polybenzoxazole-based mixed matrix membranes exhibit high thermal stability, significantly higher selectivity than the neat polybenzoxazole polymer membranes, and much higher permeability than traditional mixed matrix membranes.
摘要翻译：本发明公开了新型的基于苯并恶唑的混合基质膜，以及制造和使用这些膜的方法。基于聚苯并恶唑的混合基质膜通过将分子筛颗粒分散在具有与杂环酰亚胺氮原子相邻的侧羟基的连续芳族聚酰亚胺基体中制备聚酰亚胺基混合基质膜来制备; 然后通过在惰性气氛或真空下在200℃至600℃之间加热将聚酰亚胺基混合基质膜转变成聚苯并恶唑类混合基质膜。本发明的基于聚苯并恶唑的混合基质膜可以制成任何方便的几何形状，例如平板（或螺旋缠绕），管，中空纤维或薄膜复合材料。这些基于聚苯并恶唑的混合基质膜具有高的热稳定性，比纯聚苯并恶唑聚合物膜显着更高的选择性，并且比传统的混合基质膜具有更高的渗透性。

9. 发明申请

WO2004067682A1 PRODUCTION OF LOW SULFUR GASOLINE 审中-公开
标题翻译：生产低硫汽油
公开(公告)号：WO2004067682A1
公开(公告)日：2004-08-12
申请号：PCT/US2003/001517
申请日：2003-01-17
申请人： UOP LLC , ZHOU, Lubo
发明人： ZHOU, Lubo
IPC分类号： C10G19/02
CPC分类号： C10G45/12 , C10G7/08 , C10G19/02 , C10G21/12 , C10G45/02 , C10G45/06 , C10G45/58 , C10G45/64 , C10G67/04 , C10G67/16
摘要： A process for desulfurizing a gasoline stream while continuing to maintain the octane rating of the blend stock. A gasoline stream containing sulfur compounds and olefins is introduced into a fractionation zone to produce a low boiling fraction containing mercaptan sulfur compounds and olefins, a mid boiling fraction containing thiophene and olefins, and a high boiling fraction containing sulfur compounds. The low boiling fraction containing mercaptan sulfur compounds is contacted with an aqueous alkaline solution to selectively remove mercaptan sulfur compounds. The mid boiling fraction containing thiophene is extracted to produce a raffinate stream containing olefins and having a reduced sulfur content relative to the mid boiling fraction and a hydrocarbonaceous stream rich in thiophene. The resulting hydrocarbonaceous stream rich in thiophene and the higher boiling fraction containing sulfur compounds is reacted in a hydrodesulfurization reaction zone to produce a hydrocarbonaceous stream having a reduced sulfur concentration.
摘要翻译：在继续保持共混料的辛烷值的同时对汽油流进行脱硫的方法。将含有硫化合物和烯烃的汽油流引入分馏区以产生含有硫醇硫化合物和烯烃的低沸点馏分，含有噻吩和烯烃的中沸腾馏分，以及含有硫化合物的高沸点馏分。含有硫醇硫化合物的低沸点馏分与碱性水溶液接触以选择性地除去硫醇硫化合物。提取含有噻吩的中沸点馏分以产生相对于中沸点馏分和富含噻吩的烃物流含有烯烃并具有降低的硫含量的萃余液流。所得到的含有噻吩的含烃物质和含有较高沸点馏分的硫化合物在加氢脱硫反应区中反应，生成具有降低的硫浓度的烃流。

10. 发明申请

WO2011016906A2 PROCESS FOR SIMULTANEOUS REMOVAL OF CARBON DIOXIDE AND SULFUR OXIDES FROM FLUE GAS 审中-公开
标题翻译：从烟气中同时去除二氧化碳和硫氧化物的方法
公开(公告)号：WO2011016906A2
公开(公告)日：2011-02-10
申请号：PCT/US2010/038765
申请日：2010-06-16
申请人： UOP LLC , ZHOU, Lubo , BELLVILLE, Dennis J. , ZBACNIK, Edward P.
发明人： ZHOU, Lubo , BELLVILLE, Dennis J. , ZBACNIK, Edward P.
IPC分类号： B01D53/78 , B01D53/34 , B01D53/50 , B01D53/62 , F23J15/02
CPC分类号： B01D53/1425 , B01D53/1456 , B01D53/501 , B01D53/62 , B01D2251/306 , B01D2251/606 , B01D2257/302 , B01D2257/504 , Y02A50/2342 , Y02C10/04 , Y02C10/06 , Y02E20/326
摘要： A process is provided for the simultaneous removal of carbon dioxide and sulfur oxides from a flue gas stream by a potassium carbonate solvent. As a part of the regeneration of the contaminated stream, a portion of that stream is removed and cooled to allow for filtration of potassium sulfate, the reaction product of the solvent and the sulfur oxides.
摘要翻译：提供了一种通过碳酸钾溶剂从烟道气流同时除去二氧化碳和硫氧化物的方法。作为污染物流再生的一部分，将该物流的一部分去除并冷却以允许过滤硫酸钾，溶剂和硫氧化物的反应产物。

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