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1. 发明申请

WO2011090877A3 AN AROMATIC ALKYLATING AGENT AND AN AROMATIC PRODUCTION APPARATUS 审中-公开
标题翻译：芳香碱性剂和芳香生产装置
公开(公告)号：WO2011090877A3
公开(公告)日：2011-11-24
申请号：PCT/US2011021092
申请日：2011-01-13
申请人： UOP LLC , NEGIZ ANTOINE , BOLDINGH EDWIN P , GAJDA GREGORY J , RENDE DEAN E , REKOSKE JAMES E , MACKOWIAK DAVID E , BARGER PAUL T , BOGDAN PAULA L
发明人： NEGIZ ANTOINE , BOLDINGH EDWIN P , GAJDA GREGORY J , RENDE DEAN E , REKOSKE JAMES E , MACKOWIAK DAVID E , BARGER PAUL T , BOGDAN PAULA L
IPC分类号： C10G45/58 , C07C2/66 , C07C15/02 , C10G35/00 , C10L1/04
CPC分类号： C07C2/76 , C07C15/06 , C07C15/08
摘要： One exemplary embodiment can be a process using an aromatic methylating agent. Generally, the process includes reacting an effective amount of the aromatic methylating agent having at least one of an alkane, a cycloalkane, an alkane radical, and a cycloalkane radical with one or more aromatic compounds. As such, at least one of the one or more aromatic compounds may be converted to one or more higher methyl substituted aromatic compounds to provide a product having a greater mole ratio of methyl to phenyl than a feed.
摘要翻译：一个示例性实施方案可以是使用芳族甲基化剂的方法。通常，该方法包括将有效量的具有烷烃，环烷烃，烷烃基和环烷烃基团中的至少一种的芳族甲基化试剂与一种或多种芳族化合物反应。因此，一种或多种芳族化合物中的至少一种可以转化为一种或多种高级甲基取代的芳族化合物，以提供与进料相比甲基与苯基摩尔比大的产物。

2. 发明申请

WO2005118136A3 CATALYST TREATMENT USEFUL FOR AROMATICS CONVERSION PROCESS 审中-公开
标题翻译：用于芳族转化过程的催化剂处理
公开(公告)号：WO2005118136A3
公开(公告)日：2006-02-16
申请号：PCT/US2005017600
申请日：2005-05-19
申请人： UOP LLC , BOLDINGH EDWIN P , NEGIZ ANTOINE , MAHER GREGORY F , BOGDAN PAULA L , RENDE DEAN E
发明人： BOLDINGH EDWIN P , NEGIZ ANTOINE , MAHER GREGORY F , BOGDAN PAULA L , RENDE DEAN E
IPC分类号： B01J21/12 , B01J23/36 , B01J29/06 , B01J29/076 , B01J29/26 , B01J29/48 , B01J29/78 , B01J37/20 , C07C5/27 , C10G45/64 , C07C4/12 , B01J21/00 , B01J21/08 , B01J21/14 , B01J27/02 , B01J29/00 , B01J29/18
CPC分类号： B01J37/18 , B01J21/12 , B01J23/36 , B01J29/061 , B01J29/076 , B01J29/26 , B01J29/48 , B01J29/7815 , B01J37/0009 , B01J37/0201 , B01J37/12 , B01J37/20 , B01J2229/42 , C07C5/2737 , C07C5/2775 , C10G45/64 , Y02P20/52 , C07C15/08
摘要： A process for preparing a transalkylation catalyst, the catalyst itself, and a transalkylation process for using the catalyst are herein disclosed. The catalyst comprises rhenium metal on a solid-acid support such as mordenite, which has been treated with a sulfur-based agent and/or a reducing agent under substantially dry reducing conditions including a temperature greater than 350°C. Such treatment reduces the amount of methane produced by metal hydrogenolysis in a transalkylation process wherein heavy aromatics like A9+ are reacted with toluene to produce xylenes. Reduced methane production relative to total light ends gas production results in lower hydrogen consumption and lower reactor exotherms.
摘要翻译：本文公开了制备烷基转移催化剂的方法，催化剂本身和用于使用催化剂的烷基转移方法。催化剂包括在固体酸性载体上的铼金属，例如丝光沸石，其已经在包括大于350℃的温度的基本上干燥的还原条件下用硫基试剂和/或还原剂处理。这种处理减少了在烷基转移过程中金属氢解产生的甲烷的量，其中诸如A9 +的重芳族化合物与甲苯反应生成二甲苯。降低甲烷生产相对于总轻馏分气体生产导致较低的氢消耗和较低的反应器放热。

3. 发明申请

WO2007037866A3 PROCESS FOR THE ISOMERIZATION OF XYLENES AND CATALYST THEREFOR 审中-公开
标题翻译：异氰酸酯和催化剂的异构化方法
公开(公告)号：WO2007037866A3
公开(公告)日：2007-12-06
申请号：PCT/US2006033140
申请日：2006-08-22
申请人： UOP LLC , BOGDAN PAULA L , WHITCHURCH PATRICK C , LARSON ROBERT B , REKOSKE JAMES E , TRUFANOV DIMITRI A
发明人： BOGDAN PAULA L , WHITCHURCH PATRICK C , LARSON ROBERT B , REKOSKE JAMES E , TRUFANOV DIMITRI A
IPC分类号： B01J29/06 , B01J29/068 , B01J29/83 , B01J29/84 , C07C4/12 , C07C4/18
CPC分类号： B01J29/44 , B01J27/16 , B01J29/068 , B01J29/405 , B01J37/0236 , B01J2229/20 , B01J2229/42 , C07C4/08 , C07C5/2737 , C07C5/2775 , Y02P20/52 , C07C15/02 , C07C15/08 , C07C15/04
摘要： Catalysts of certain combinations of platinum, tin, acidic molecular sieve and aluminum phosphate binder achieve the isomerization and dealkylation activities characteristic of platinum-containing catalysts yet enjoy the low net C 6 naphthenes make properties.
摘要翻译：铂，锡，酸性分子筛和磷酸铝粘合剂的某些组合的催化剂实现了含铂催化剂特征的异构化和脱烷基活性，但享有低的C 6 N 6环烷烃的性能。

4. 发明申请

WO2007032979A3 PROCESS FOR ISOMERIZING NON-EQUILIBRIUM XYLENE-CONTAINING FEED STREAMS 审中-公开
标题翻译：使不平衡的含二甲苯的进料流异构化的方法
公开(公告)号：WO2007032979A3
公开(公告)日：2007-05-24
申请号：PCT/US2006034725
申请日：2006-09-06
申请人： UOP LLC , BOGDAN PAULA L , REKOSKE JAMES E , LARSON ROBERT B , WHITCHURCH PATRICK C , BAUER JOHN E , QUICK MICHAEL H
发明人： BOGDAN PAULA L , REKOSKE JAMES E , LARSON ROBERT B , WHITCHURCH PATRICK C , BAUER JOHN E , QUICK MICHAEL H
IPC分类号： C07C5/22
CPC分类号： C07C5/2737 , C07C5/2775 , Y02P20/52 , C07C15/08
摘要： Reduced co-production of toluene and C 9 and higher aromatics such as trimethylbenzene, methylethylbenzene, and diethylbenzene is achieved in processes for the isomerization of xylenes to close to equilibrium using a layered catalyst having a thin outer layer of molecular sieve and hydrogenation metal component on a core, wherein at least 75 mass-% of the hydrogenation metal component is in the outer layer.
摘要翻译：在使用具有薄外层的层状催化剂使二甲苯异构化接近平衡的方法中，实现了甲苯和C 9和更高级芳族化合物如三甲苯，甲基乙苯和二乙苯的减少共生分子筛和氢化金属组分在芯上，其中至少75质量％的氢化金属组分在外层中。

5. 发明申请

WO2012170147A3 PROCESS FOR PRODUCING ONE OR MORE ALKYLATED AROMATICS 审中-公开
标题翻译：生产一种或多种碱性芳族化合物的方法
公开(公告)号：WO2012170147A3
公开(公告)日：2013-01-31
申请号：PCT/US2012037440
申请日：2012-05-11
申请人： UOP LLC , HAIZMANN ROBERT , LEONARD LAURA E , BOGDAN PAULA L
发明人： HAIZMANN ROBERT , LEONARD LAURA E , BOGDAN PAULA L
IPC分类号： C07C2/66 , C07C2/64 , C07C7/04 , C07C15/073
CPC分类号： C07C2/66 , C07C5/13 , C07C5/2791 , C07C5/367 , C07C6/123 , C07C6/126 , C07C7/12 , C07C7/14 , C07C2101/08 , C07C2101/14 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/08 , C07C2523/12 , C07C2523/14 , C07C2523/26 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/08 , C07C2529/18 , C07C2529/85 , C07C2601/08 , C07C2601/14 , C10G11/18 , C10G29/205 , C10G45/58 , C10G45/64 , C10G57/005 , C10G69/04 , C10G69/123 , C10G2300/4087 , Y02P30/464 , C07C15/08 , C07C13/10 , C07C13/18 , C07C15/04 , C07C15/073
摘要： One exemplary embodiment may be a process for producing one or more alkylated aromatics. Generally, the process includes providing a first stream including an effective amount of benzene for alkylating benzene from a fractionation zone, providing a second stream including an effective amount of ethene for alkylating benzene from a fluid catalytic cracking zone, providing at least a portion of the first and second streams to an alkylation zone; and passing at least a portion of an effluent including ethylbenzene from the alkylation zone downstream of a para-xylene separation zone.
摘要翻译：一个示例性实施方案可以是用于生产一种或多种烷基化芳族化合物的方法。通常，该方法包括提供包含有效量的苯的第一流，用于从分馏区烷基化苯，提供包含有效量的用于从流化催化裂化区烷基化苯的乙烯的第二料流，提供至少一部分第一和第二流到烷基化区; 并使来自包含乙苯的至少一部分流出物从对二甲苯分离区下游的烷基化区通过。

6. 发明申请

WO2011143031A3 MOLECULAR SIEVE, CATALYST, AND/OR A PROCESS RELATING THERETO 审中-公开
标题翻译：分子筛，催化剂，和/或与其相关的方法
公开(公告)号：WO2011143031A3
公开(公告)日：2012-04-19
申请号：PCT/US2011035160
申请日：2011-05-04
申请人： UOP LLC , WANG HUI , BOGDAN PAULA L , WILLIS RICHARD R
发明人： WANG HUI , BOGDAN PAULA L , WILLIS RICHARD R
IPC分类号： C07C4/18 , B01J29/40 , C07C15/02
CPC分类号： B01J35/1009 , B01J23/62 , B01J23/626 , B01J29/06 , B01J29/40 , B01J29/44 , B01J35/1019 , B01J37/0009 , B01J2229/42 , C01B39/40 , C01P2006/12 , C07C4/12 , C07C2529/40 , Y02P20/52 , C07C15/04
摘要： Disclosed herein is a process for dealkylating ethylbenzene, comprising: passing a stream comprising ethylbenzene over an effective amount of a catalyst, wherein the catalyst comprises (a) a molecular sieve comprising one or more crystals wherein the molecular sieve has an external surface area of no more than 20 m2/g; and (b) a binder.
摘要翻译：本文公开了一种使乙苯脱烷基化的方法，包括：使含有乙苯的物流通过有效量的催化剂，其中催化剂包含（a）包含一种或多种晶体的分子筛，其中分子筛的外表面积为超过20 m2 / g; 和（b）粘合剂。

7. 发明申请

WO2005065380A3 PROCESS AND CATALYST FOR C8 ALKYLAROMATIC ISOMERIZATION 审中-公开
标题翻译： C8烷基异构化的工艺和催化剂
公开(公告)号：WO2005065380A3
公开(公告)日：2005-11-24
申请号：PCT/US2004043952
申请日：2004-12-29
申请人： UOP LLC , LEON-ESCAMILLA E ALEJANDRO , BOGDAN PAULA L , BAUER JOHN E , MAHER GREGORY F , LARSON ROBERT B
发明人： LEON-ESCAMILLA E ALEJANDRO , BOGDAN PAULA L , BAUER JOHN E , MAHER GREGORY F , LARSON ROBERT B
IPC分类号： B01J23/42 , B01J29/74 , B01J37/00 , B01J37/20 , C07C5/22 , C07C5/27
CPC分类号： C07C5/2708 , B01J29/7469 , B01J37/0009 , B01J37/20 , B01J2229/20 , B01J2229/42 , C07C5/2775 , C07C2521/04 , C07C2521/08 , C07C2523/40 , C07C2523/42 , C07C2529/70 , Y02P20/52 , C07C15/08
摘要： A process for isomerizing ethylbenzene into xylenes such as para-xylene using a zeolitic catalyst system based on MTW-type zeolite is disclosed. Preferably the two metals are platinum and tin. The invention obtains a stable and improved yield of xylenes such as para-xylene without excess benzene production by dealkylation. The zeolitic silica-to-alumina ratio ranges from 20 to 45. Use of MTW substantially free of mordenite improves yields and integrated aromatics complex economics by reducing undesirable aromatic ring-loss reactions.
摘要翻译：公开了使用基于MTW型沸石的沸石催化剂体系将乙苯异构化为二甲苯（如对二甲苯）的方法。优选地，两种金属是铂和锡。本发明通过脱烷基化获得稳定且提高的二甲苯产率，如对二甲苯，而不产生过量的苯。沸石二氧化硅与氧化铝的比例范围为20至45.使用基本上不含丝光沸石的MTW通过减少不期望的芳族环损失反应来提高产率和综合芳族化合物复合经济性。

8. 发明专利

CA2583172A1 CATALYST TREATMENT USEFUL FOR AROMATICS CONVERSION PROCESS 未知
公开(公告)号：CA2583172A1
公开(公告)日：2005-12-15
申请号：CA2583172
申请日：2005-05-19
申请人： UOP LLC
发明人： RENDE DEAN E , BOGDAN PAULA L , MAHER GREGORY F , BOLDINGH EDWIN P , NEGIZ ANTOINE
IPC分类号： C07C4/12 , B01J21/00 , B01J21/08 , B01J21/12 , B01J21/14 , B01J23/36 , B01J27/02 , B01J29/00 , B01J29/06 , B01J29/076 , B01J29/18 , B01J29/26 , B01J29/48 , B01J29/78 , B01J37/20 , C07C5/27 , C10G45/64
摘要： A process for preparing a transalkylation catalyst, the catalyst itself, and a transalkylation process for using the catalyst are herein disclosed. The catalyst comprises rhenium metal on a solid-acid support such as mordenite, which has been treated with a sulfur-based agent. Such treatment reduces the amount of methane produced by metal hydrogenolysis in a transalkylation process wherein heavy aromatics like A9+ are reacted with toluene to produce xylenes. Reduced methane production relative to total light ends gas production results in lower hydrogen consumption and lower reactor exotherms.

9. 发明专利

ES2228675T3 VALORIZACION DE NAFTAS MEDIANTE LA COMBINACION DE AROMATIZACION Y FORMACION DE OLEFINAS. 未知
公开(公告)号：ES2228675T3
公开(公告)日：2005-04-16
申请号：ES01103917
申请日：2001-02-17
申请人： UOP LLC
发明人： BOGDAN PAULA L
IPC分类号： C10G59/02
摘要： Una combinación de procesos para valorizar selectivamente una materia prima de nafta, con el fin de obtener un producto rico en compuestos aromáticos que tiene un índice de octano mejorado, que comprende las etapas de: (a) alimentar la materia prima de nafta junto con hidrógeno libre a una zona de formación de olefinas, en la que las relaciones de hidrógeno a hidrocarburo relativas a la materia prima se encuentran dentro del intervalo de 0, 1 a 100, y poner en contacto la materia prima de nafta en la zona de formación de olefinas en presencia de hidrógeno libre con un catalizador de formación de olefinas no zeolítico no ácido, que comprende al menos un componente metálico del grupo del platino y un soporte no ácido considerablemente libre de material isoestructural con las zeolitas, en condiciones de formación de olefinas que comprenden una temperatura de alrededor de 350º a 650ºC, presión de alrededor de 100 kPa a 4 MPa y velocidad espacial horaria del líquido de alrededor de 0, 1 a 100 h-1, para deshidrogenar las parafinas sin deshidrociclación considerable y para producir una corriente intermedia que contiene olefinas; y, (b) convertir la corriente intermedia que contiene olefinas para producir compuestos aromáticos en una zona de aromatización mantenida en condiciones de aromatización que comprenden una temperatura de alrededor de 260 a 560ºC, presión de alrededor de 100 kPa a 4 MPa y velocidad espacial horaria del líquido de alrededor de 0, 5 a 40 h-1, en presencia de hidrógeno libre con un catalizador sólido de aromatización ácido que comprende un componente metálico del grupo del platino sobre un soporte y recuperar el producto rico en compuestos aromáticos.

10. 发明专利

CA2828762A1 SUBSTANTIALLY NON-POROUS SUBSTRATE SUPPORTED NOBLE METAL- AND LANTHANIDE-CONTAINING CATALYSTS 未知
公开(公告)号：CA2828762A1
公开(公告)日：2012-11-22
申请号：CA2828762
申请日：2012-05-09
申请人： UOP LLC
发明人： BOGDAN PAULA L , NEMETH VALERIA , BARE SIMON RUSSELL
IPC分类号： B01J37/02 , B01J23/10 , B01J23/44
摘要： Aspects of the invention relate to hydrogenation catalysts, and hydrogenation processes using these catalysts, having particular characteristics, in terms of the amount and type of metal hydrogenation component (or catalytic constituent), as well as the support or substrate. The catalyst compositions, comprising both a noble metal and a lanthanide element on a substantially non-porous substrate, provide advantageous performance characteristics, including conversion, selectivity, and activity stability, as demanded in industrial hydrogenation and selective hydrogenation applications.

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