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    • 6. 发明申请
    • HIGH CHARGE DENSITY METALLOPHOSPHATE MOLECULAR SIEVES
    • 高电荷密度金属磷酸盐分子筛
    • WO2017205041A1
    • 2017-11-30
    • PCT/US2017/031555
    • 2017-05-08
    • UOP LLC
    • LEWIS, Gregory J.MOSCOSO, Jaime G.KNIGHT, Lisa M.NICHOLAS, Christopher P.SEO, SeungwanLEE, JunghwanHONG, Suk Bong
    • B01J27/18B01J29/84B01J31/02C01B39/54C10G11/05C10G35/095
    • A new family of highly charged crystalline microporous metallophosphate molecular sieves has been synthesized. These metallophosphates are represented by the empirical formula of: Rp+rA+mM2+xEyPOz where A is an alkali metal cation, R is at least one quaternary organoammonium cation, M is a divalent metal such as zinc and E is a trivalent framework element such as aluminum or gallium. This family of high charge density metallophosphate materials are among the first metalloalumino(gallo)phosphate-type molecular sieves to be stabilized by combinations of alkali and quaternary organoammonium cations, enabling unique compositions. This family of high charge density metallophosphate molecular sieves has catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.
    • 已经合成了一族新的高电荷结晶微孔金属磷酸盐分子筛。 这些金属磷酸盐由经验式表示:Rp + rA + mM2 + xEyPOz其中A是碱金属阳离子,R是至少一个季铵有机铵阳离子,M是二价金属如锌,E是三价骨架元素,例如 如铝或镓。 这种高电荷密度金属磷酸盐材料家族是第一个通过碱金属和季铵有机铵阳离子组合稳定的金属铝(磷酸)型磷酸盐型分子筛,从而形成独特的组合物。 这类高电荷密度金属磷酸盐分子筛具有用于进行各种烃转化过程和用于分离至少一种组分的分离性质的催化性质。
    • 9. 发明申请
    • HIGH CHARGE DENSITY METALLOALUMINOPHOSPHOSILICATE MOLECULAR SIEVES MeAPSO-83
    • 高电荷密度金属铝氧磷酸硅分子筛MeAPSO-83
    • WO2017205112A1
    • 2017-11-30
    • PCT/US2017/032873
    • 2017-05-16
    • UOP LLC
    • LEWIS, Gregory J.
    • B01J27/182B01J29/85B01J31/02C01B39/54C10G11/05C10G35/095
    • A new family of crystalline microporous metalloalumino(gallo)phosphosilicates designated MeAPSO-83 has been synthesized. These metalloalumino(gallo)phosphosilicates are represented by the empirical formula of: R p+ rA + mM 2+ wExPSiyOz where A is an alkali metal such as potassium, R is an quaternary ammonium cation such as ethyltrimethylammonium, M is a divalent metal such as Zn and E is a trivalent framework element such as aluminum or gallium. This family of metalloalumino(gallo)phosphosilicate materials are stabilized by combinations of alkali and quaternary ammonium cations, enabling unique, high charge density compositions. The MeAPSO-83 family of materials have the BPH topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.
    • 合成了称为MeAPSO-83的新型结晶微孔金属铝(gallo)磷硅酸盐。 这些金属铝(羰基)磷硅酸盐由经验式表示:其中A是碱金属,例如 作为钾,R是季铵阳离子如乙基三甲基铵,M是二价金属如Zn,E是三价骨架元素如铝或镓。 这种金属铝(镓)磷硅酸盐材料系列通过碱金属和季铵阳离子的组合来稳定化,从而能够实现独特的高电荷密度组合物。 MeAPSO-83系列材料具有BPH拓扑结构,并具有催化性能,用于进行各种烃转化过程和分离性质,以分离至少一种组分。