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1. 发明申请

WO2011017183A3 UZM-29 FAMILY OF CRYSTALLINE ZEOLITIC COMPOSITIONS AND A METHOD OF PREPARING THE COMPOSITIONS 审中-公开
标题翻译： UZM-29结晶型沸石组合物及其组合物的制备方法
公开(公告)号：WO2011017183A3
公开(公告)日：2011-06-30
申请号：PCT/US2010043630
申请日：2010-07-29
申请人： UOP LLC , KOSTER SUSAN C , MOSCOSO JAIME G
发明人： KOSTER SUSAN C , MOSCOSO JAIME G
IPC分类号： C01B39/48 , B01J29/06 , C01B39/06 , C07C2/12 , C07C5/22
CPC分类号： B01J29/70 , B01J2229/37 , C01B39/06 , C01B39/48 , C07C1/20 , C07C5/2775 , C10G3/49 , C10G29/205 , C10G45/64 , C10G2400/20 , C07C11/02 , C07C9/10
摘要： This invention relates to a new family of crystalline microporous zeolite designated the UZM-29 family. These zeolites are represented by the empirical formula: Mm n+R+rAll-x ExSiyOz UZM-29 has the PHI structure type topology but is thermally stable up to a temperature of at least 350°C. The UZM-29 family of zeolite can be used in various hydrocarbon conversion processes such as, isomerization of butane.
摘要翻译：本发明涉及一种称为UZM-29族的结晶微孔沸石的新家族。这些沸石由经验式表示：Mm n + R + rAll-x ExSiyOz UZM-29具有PHI结构类型的拓扑结构，但在高达至少350℃的温度下是热稳定的。 UZM-29沸石家族可用于各种烃转化过程，如丁烷的异构化。

2. 发明申请

WO2009158244A3 NOVEL TRANSALKYLATION PROCESS 审中-公开
标题翻译：新型转移过程
公开(公告)号：WO2009158244A3
公开(公告)日：2010-03-25
申请号：PCT/US2009047584
申请日：2009-06-17
申请人： UOP LLC , BOLDINGH EDWIN P , GATTER MICHAEL G , KOSTER SUSAN C , LAFYATIS DAVID S , DEAK TERRENCE E , BAKER ERIC J , BROACH ROBERT W , JAN DENG-YANG , MOSCOSO JAIME G
发明人： BOLDINGH EDWIN P , GATTER MICHAEL G , KOSTER SUSAN C , LAFYATIS DAVID S , DEAK TERRENCE E , BAKER ERIC J , BROACH ROBERT W , JAN DENG-YANG , MOSCOSO JAIME G
IPC分类号： C10G45/46 , B01J29/06
CPC分类号： B01J29/80 , B01J29/26 , B01J29/48 , B01J29/70 , B01J29/72 , B01J29/78 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C07C6/126 , C07C2529/70 , C07C2529/78 , C07C2529/80 , Y02P20/52 , C07C15/08
摘要： This invention embodies a catalyst and a process for transalkylation of C7, C9, and C10 aromatics to obtain a high yield of xylenes. The catalyst comprises a novel UZM-14 catalytic material comprising globular aggregates of crystallites having a MOR framework type with a mean crystallite length parallel to the direction of the 12 ring channels of 60 nm or less and a mesopore volume of at least 0.10 cc/gram. The UZM-14 catalyst is particularly active and stable in a transalkylation process.
摘要翻译：本发明体现了C7，C9和C10芳族化合物的烷基转移催化剂和方法，以获得高产率的二甲苯。该催化剂包含一种新型的UZM-14催化材料，其包含具有MOR骨架型晶粒的球形聚集体，其平均晶体长度与12个环形通道的方向平行于60nm或更小，中孔体积至少为0.10cc / g 。 UZM-14催化剂在烷基转移过程中特别活跃和稳定。

3. 发明申请

WO2009158233A3 SELECTIVE CATALYST FOR AROMATICS CONVERSION 审中-公开
标题翻译： AROMATICS转换选择性催化剂
公开(公告)号：WO2009158233A3
公开(公告)日：2010-03-25
申请号：PCT/US2009047440
申请日：2009-06-16
申请人： UOP LLC , MOSCOSO JAIME G , BOLDINGH EDWIN P , GATTER MICHAEL G , KOSTER SUSAN C
发明人： MOSCOSO JAIME G , BOLDINGH EDWIN P , GATTER MICHAEL G , KOSTER SUSAN C
IPC分类号： C01B39/02 , B01J29/78
CPC分类号： B01J29/78 , B01J29/005 , B01J29/08 , B01J29/18 , B01J29/40 , B01J29/48 , B01J29/65 , B01J29/70 , B01J29/7023 , B01J29/7026 , B01J29/7034 , B01J29/7042 , B01J29/76 , B01J29/80 , B01J35/002 , B01J35/023 , B01J37/0072 , B01J37/20 , B01J2229/18 , B01J2229/20 , B01J2229/42 , C01B39/48 , C07C6/126 , C07C2529/70 , C07C2529/80 , Y02P20/52 , C07C15/08
摘要： The subject invention comprises a novel UZM-14 catalytic material comprising globular aggregates of crystallites having a MOR framework type with a mean crystallite length parallel to the direction of 12-ring channels of 60 nm or less and a mesopore volume of at least 0.10 cc/gram. Catalysts formed from the novel material are particularly effective for the transalkylation of aromatics.
摘要翻译：本发明包括一种新型的UZM-14催化材料，其包含具有MOR框架型晶粒的球形聚集体，其平均微晶长度平行于12个环通道的方向为60nm或更小，中孔体积为至少0.10cc / 公克。由新型材料形成的催化剂对于芳族化合物的烷基转移特别有效。

4. 发明申请

WO2012054546A3 PROCESSES FOR MAKING NANO ZEOLITES AND FOR RECOVERY OF NANO ZEOLITES FROM AN AQUEOUS SUSPENSION 审中-公开
标题翻译：制造纳米沸石和从水性悬浮液中回收纳米沸石的方法
公开(公告)号：WO2012054546A3
公开(公告)日：2012-07-19
申请号：PCT/US2011056796
申请日：2011-10-19
申请人： UOP LLC , MOSCOSO JAIME G
发明人： MOSCOSO JAIME G
IPC分类号： C01B39/02 , B04B1/00 , C01B39/20 , C01B39/38 , C01B39/46
CPC分类号： C01B39/082 , B01J29/70 , B01J29/84
摘要： Embodiments of a process for recovery of nano zeolites from an aqueous suspension are provided. The process comprises the steps of applying centrifugal force to the aqueous suspension to separate a supernatant phase from a solid phase that comprises the nano zeolites and residuals. The solid phase is contacted with a solution effective to dissolve or digest the residuals and to agglomerate the nano zeolites forming agglomerated nano zeolites. The solution is filtered to recover the agglomerated nano zeolites.
摘要翻译：提供了从水性悬浮液中回收纳米沸石的方法的实施方案。该方法包括以下步骤：将离心力施加到水悬浮液中，以将上清液相从包含纳米沸石和残余物的固相中分离出来。使固相与有效溶解或消化残余物的溶液接触，并使形成凝聚的纳米沸石的纳米沸石凝聚。将溶液过滤以回收附聚的纳米沸石。

5. 发明申请

WO2012128857A3 MICROPOROUS UZM-5 INORGANIC ZEOLITE MEMBRANES FOR GAS, VAPOR, AND LIQUID SEPARATIONS 审中-公开
标题翻译：用于气体，蒸气和液体分离的微波UZM-5无机沸石膜
公开(公告)号：WO2012128857A3
公开(公告)日：2012-10-26
申请号：PCT/US2012024401
申请日：2012-02-09
申请人： UOP LLC , LIU CHUNQING , MOSCOSO JAIME G , WILSON STEPHEN T
发明人： LIU CHUNQING , MOSCOSO JAIME G , WILSON STEPHEN T
IPC分类号： B01D71/02 , B01D69/02 , B01D69/12 , B01J20/16 , B01J20/18
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0048 , B01D67/0051 , B01D67/0088 , B01D69/10 , B01D2323/14 , B01J20/186 , B01J20/28007 , B01J20/28035 , B01J20/3057 , B01J20/3078 , B01J20/3085 , B01J20/3238 , B01J20/3272 , B82Y30/00
摘要： The present invention discloses microporous UZM-5 zeolite membranes, methods for making the same, and methods of separating gases, vapors, and liquids using the same. The small-pore microporous UZM-5 zeolite membrane is prepared by two different methods, including in-situ crystallization of one or more layers of UZM-5 zeolite crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of UZM-5 zeolite crystals on a seed layer of UZM-5 zeolite crystals supported on a porous membrane support. The membranes in the form of disks, tubes, or hollow fibers have superior thermal and chemical stability, good erosion resistance, high CO2 plasticization resistance, and significantly improved selectivity over polymer membranes for gas, vapor, and liquid separations.
摘要翻译：本发明公开了微孔UZM-5沸石膜，其制造方法，以及使用其分离气体，蒸汽和液体的方法。小孔微孔UZM-5沸石膜通过两种不同的方法制备，包括在多孔膜载体上的一层或多层UZM-5沸石晶体的原位结晶，以及通过原位结晶的接种方法在支撑在多孔膜载体上的UZM-5沸石晶种的种子层上连续的第二层UZM-5沸石晶体。圆盘，管或中空纤维形式的膜具有优异的热稳定性和化学稳定性，良好的抗侵蚀性，高的二氧化碳抗塑化性，并且对于气体，蒸汽和液体分离，在聚合物膜上显着提高了选择性。

6. 发明申请

WO2009158157A3 MIXED MATRIX MEMBRANES CONTAINING ION-EXCHANGED MOLECULAR SIEVES 审中-公开
标题翻译：含有离子交换分子筛的混合基质膜
公开(公告)号：WO2009158157A3
公开(公告)日：2010-04-29
申请号：PCT/US2009046071
申请日：2009-06-03
申请人： UOP LLC , LIU CHUNQING , MOSCOSO JAIME G , SERBAYEVA RAISA , WILSON STEPHEN T , LESCH DAVID A
发明人： LIU CHUNQING , MOSCOSO JAIME G , SERBAYEVA RAISA , WILSON STEPHEN T , LESCH DAVID A
IPC分类号： B01D71/00 , B01D69/00
CPC分类号： B01D71/028 , B01D67/0079 , B01D69/148 , B01D2323/21 , B01D2323/36 , B01D2325/16
摘要： The present invention discloses mixed matrix membranes (MMMs) comprising ion-exchanged molecular sieves such as UZM-5 zeolite ion-exchanged with Li+ cation (Li-UZM 5) and a continuous polymer matrix and methods for making and using these membranes. These MMMs, comprising ion-exchanged molecular sieves, in the form of symmetric dense films, asymmetric flat sheets, asymmetric hollow fibers, or thin-film composites, have exhibited simultaneously increased selectivity and permeability (or permeance) over polymer-only membranes and the mixed matrix membranes made from molecular sieves that have not been ion exchanged for gas separations. These MMMs are suitable for a variety of liquid, gas, and vapor separations such as desalination of water by reverse osmosis, deep desulfurization of gasoline and diesel fuels, ethanol/water separations, pervaporation dehydration of aqueous/organic mixtures, CO2/CH4, CO2/N2, H2/CH4, O2/N2, olefin/paraffin, iso/normal paraffins separations, and other light gas mixture separations.
摘要翻译：本发明公开了包含离子交换分子筛（例如与Li +阳离子（Li-UZM 5）离子交换的UZM-5沸石）和连续聚合物基质的混合基质膜（MMM）以及制备和使用这些膜的方法。这些包含离子交换分子筛，以对称致密膜，不对称平板，不对称中空纤维或薄膜复合材料形式的MMM已经显示出与聚合物膜相比增加的选择性和渗透性（或渗透性），并且由分子筛制成的未经离子交换进行气体分离的混合基质膜。这些MMM适用于各种液体，气体和蒸汽分离，如通过反渗透脱水，汽油和柴油燃料的深度脱硫，乙醇/水分离，水/有机混合物的渗透蒸发脱水，CO 2 / CH 4，CO 2 / N2，H2 / CH4，O2 / N2，烯烃/石蜡，异/正链烷烃分离和其他轻质气体混合物分离。

7. 发明申请

WO0181291A3 THE OXIDATION OF KETONES TO ESTERS USING A TIN SUBSTITUTED ZEOLITE BETA 审中-公开
标题翻译：使用TIN取代的ZEOLITE BETA进行酮的氧化
公开(公告)号：WO0181291A3
公开(公告)日：2002-01-24
申请号：PCT/US0112707
申请日：2001-04-19
申请人： UOP LLC , CANOS AVELINO CORMA , NEMETH LASZLO T , RENZ MICHAEL , MOSCOSO JAIME G
发明人： CANOS AVELINO CORMA , NEMETH LASZLO T , RENZ MICHAEL , MOSCOSO JAIME G
IPC分类号： B01J29/70 , B01J29/89 , C07B61/00 , C07C67/42 , C07D309/30 , C07D313/04 , C07D313/20 , C07D315/00
CPC分类号： C07D315/00 , C07D309/30
摘要： Applicants have developed a process for the oxidation of ketones to esters. The process involves contacting a ketone with hydrogen peroxide and a catalyst at oxidation conditions. The catalyst is a molecule sieve represented by the empirical formula: (MwSnxTiySi1-x-y-zGez)O2 where M is a trivalent metal such as aluminium or boron. These molecular sieves have a microporous three dimensional framework structure of at least SiO2 and SnO2 tetrahedral units, a crystallographically regular pore system and the characteristic x-ray diffraction pattern of zeolite beta.
摘要翻译：申请人已经开发了将酮氧化成酯的方法。该方法包括在氧化条件下使酮与过氧化氢和催化剂接触。催化剂是由经验式:( MwSn x Ti y Si 1-x-y-z Ge z）O 2表示的分子筛，其中M是三价金属如铝或硼。这些分子筛具有至少SiO 2和SnO 2四面体单元的微孔三维骨架结构，晶体学规则孔系统和β沸石的特征X射线衍射图。

8. 发明申请

WO2011123337A3 UZM-37 ALUMINOSILICATE ZEOLITE 审中-公开
标题翻译： UZM-37铝硅酸盐沸石
公开(公告)号：WO2011123337A3
公开(公告)日：2012-03-08
申请号：PCT/US2011029898
申请日：2011-03-25
申请人： UOP LLC , MOSCOSO JAIME G , JAN DENG-YANG
发明人： MOSCOSO JAIME G , JAN DENG-YANG
IPC分类号： C01B39/48 , B01J29/70 , C07C2/12 , C07C5/22
CPC分类号： C01B39/48 , C01B39/06
摘要： A new family of crystalline aluminosilicate zeolites and a method of preparing them is disclosed. These zeolites are represented by the empirical formula (I). where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
摘要翻译：公开了一种新型的结晶硅铝酸盐沸石及其制备方法。这些沸石由经验式（I）表示。其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如丙基三甲基铵阳离子，E是骨架元素如镓。这些沸石的特征在于独特的x射线衍射图案和组合物，并且具有用于进行各种烃转化方法的催化性能。

9. 发明申请

WO2011123344A2 AROMATIC ALKYLATION PROCESS USING UZM-37 ALUMINOSILICATE ZEOLITE 审中-公开
标题翻译：使用UZM-37铝酸钠沸石的芳香烷基化方法
公开(公告)号：WO2011123344A2
公开(公告)日：2011-10-06
申请号：PCT/US2011029924
申请日：2011-03-25
申请人： UOP LLC , JAN DENG-YANG , MOSCOSO JAIME G
发明人： JAN DENG-YANG , MOSCOSO JAIME G
CPC分类号： C07C2/66 , Y02P20/52 , C07C15/073 , C07C15/085 , C07C15/02
摘要： A process for the alkylation of aromatic hydrocarbons using acatalyst comprising a new family of crystalline aluminosilicate zeolites is disclosed. The zeolites are represented by the empirical formula (I). where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are characterized by unique x-ray diffraction patterns and compositions.
摘要翻译：公开了一种使用包含新型结晶硅铝酸盐沸石的催化剂烷基化芳族烃的方法。沸石由经验式（I）表示。其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如丙基三甲基铵阳离子，E是骨架元素如镓。这些沸石的特征在于独特的x射线衍射图和组成。

10. 发明申请

WO2010039431A3 UZM-35 ALUMINOSILICATE ZEOLITE, METHOD OF PREPARATION AND PROCESSES USING UZM-35 审中-公开
标题翻译： UZM-35铝酸钠沸石，使用UZM-35的制备方法和工艺
公开(公告)号：WO2010039431A3
公开(公告)日：2010-06-10
申请号：PCT/US2009057062
申请日：2009-09-16
申请人： UOP LLC , MOSCOSO JAIME G , JAN DENG-YANG
发明人： MOSCOSO JAIME G , JAN DENG-YANG
IPC分类号： C01B39/46 , B01J29/06 , C01B39/04
CPC分类号： C07F5/069 , B01J29/70 , C01B39/065 , C01B39/12 , C10G29/205 , C10G45/64 , C10G2300/1088 , Y10S208/02
摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mn+m R+r Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the choline cation and E is a framework element such as gallium. These zeolites are similar to MCM-68 but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
摘要翻译：已经合成了一系列结晶硅铝酸盐沸石。这些沸石由经验公式表示。 Mn + m R + r Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，如胆碱阳离子，E是骨架元素如镓。这些沸石类似于MCM-68，但是其特征在于独特的x射线衍射图和组成，并具有用于进行各种烃转化方法的催化性能。

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