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    • 4. 发明申请
    • DYE-SENSITIZED SOLAR CELL EMPLOYING ZINC OXIDE AGGREGATES GROWN IN THE PRESENCE OF LITHIUM
    • 在锂存在下使用氧化锌聚集体的染料敏化太阳能电池
    • WO2010017115A2
    • 2010-02-11
    • PCT/US2009/052531
    • 2009-08-03
    • UNIVERSITY OF WASHINGTONZHANG, QifengCAO, Guozhong
    • ZHANG, QifengCAO, Guozhong
    • H01L31/0224H01L31/042
    • H01G9/204C01P2002/60C01P2002/72C01P2002/84C01P2004/03C01P2004/50C09C1/02C09C1/043H01G9/2059Y02E10/542
    • The invention is a novel ZnO dye-sensitized solar cell and method of fabricating the same. In one embodiment, deliberately added lithium ions are used to mediate the growth of ZnO aggregates. The use of lithium provides ZnO aggregates that have advantageous microstructure, morphology, crystallinity, and operational characteristics. Employing lithium during aggregate synthesis results in a polydisperse collection of ZnO aggregates favorable for porosity and light scattering. The resulting nanocrystallites forming the aggregates have improved crystallinity and more favorable facets for dye molecule absorption. The lithium synthesis improves the surface stability of ZnO in acidic dyes. The procedures developed and disclosed herein also help ensure the formation of an aggregate film that has a high homogeneity of thickness, a high packing density, a high specific surface area, and good electrical contact between the film and the fluorine-doped tin oxide electrode and among the aggregate particles.
    • 本发明是一种新型ZnO染料敏化太阳能电池及其制造方法。 在一个实施方案中,故意添加的锂离子用于介导ZnO聚集体的生长。 使用锂提供具有有利的微结构,形态,结晶度和操作特性的ZnO聚集体。 在聚集体合成期间使用锂导致多分散的ZnO聚集物集合有利于孔隙率和光散射。 形成聚集体的所得纳米晶体具有改善的结晶度和更有利的用于染料分子吸收的方面。 锂合成提高了酸性染料中ZnO的表面稳定性。 本文开发和公开的程序还有助于确保形成具有高的厚度均匀性,高堆积密度,高比表面积和膜与氟掺杂氧化锡电极之间的良好电接触的聚集膜,和 在骨料颗粒之间。