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    • 1. 发明申请
    • BIODEGRADABLE POLYMER-BASED BIOCOMPOSITES WITH TAILORED PROPERTIES AND METHOD OF MAKING THOSE
    • 具有定性特性的可生物降解的基于聚合物的生物聚合物及其制备方法
    • WO2016138593A1
    • 2016-09-09
    • PCT/CA2016/050237
    • 2016-03-04
    • UNIVERSITY OF GUELPH
    • MOHANTY, Amar KumarMISRA, ManjusriZARRINBAKHSH, NimaMUTHURAJ, RajendranWANG, TaoRODRIGUEZ, ArturoVIVEKANANDHAN, Singaravelu
    • C08L101/16C08J3/20C08K11/00C08K3/00C08L101/06C08L67/00
    • C08J3/201C08J5/045C08J2300/16C08J2367/02C08J2367/04C08J2467/02C08J2467/04C08K3/013C08K5/0016C08K5/103C08K11/00C08K11/005C08L67/00C08L101/06C08L101/16C08L2201/06C08L67/04C08L67/02
    • A biodegradable composite including: (a) a polymeric matrix having a biodegradable polymer; (b) a filler; and (c) an anhydride grafted compatibilizer including one or more biodegradable polymers modified with an anhydride group. The composite may also include (d) polymer additives such as polymer chain extenders or plasticizers. An in situ method of manufacturing the biodegradable composite of the present invention, including the steps of: (a) melting one or more biodegradable polymers in the presence of a functional monomer and a free radical initiator to form a mixture; and (b) adding a filler and polymer additives to the mixture thereby manufacturing the biodegradable composite. A method of manufacturing a biodegradable polymer including (a) synthesizing a compatibilizer by (i) mixing a free radical initiator and a functional monomer, (ii) melting one or more biodegradable polymers to form a melt, and (iii) combining the product of step (i) and the melt of step (ii) thereby synthesizing the compatibilizer; and (b) mixing the compatibilizer of step (a), with a matrix of one or more biodegradable polymers and a filler and polymer additives, thereby manufacturing the biodegradable or compostable composite.
    • 一种可生物降解的复合材料,包括:(a)具有可生物降解的聚合物的聚合物基质; (b)填料; 和(c)包含用酸酐基改性的一种或多种可生物降解聚合物的酸酐接枝增容剂。 复合材料还可以包括(d)聚合物添加剂,例如聚合物增链剂或增塑剂。 本发明的生物可降解复合材料的原位制备方法,包括以下步骤:(a)在功能单体和自由基引发剂存在下熔融一种或多种可生物降解的聚合物以形成混合物; 和(b)向混合物中加入填料和聚合物添加剂,从而制造可生物降解的复合材料。 一种制造生物可降解聚合物的方法,包括(a)通过(i)混合自由基引发剂和官能单体合成增容剂,(ii)将一种或多种可生物降解的聚合物熔融以形成熔体,和(iii)将 步骤(i)和步骤(ii)的熔体,从而合成增容剂; 和(b)将步骤(a)的增容剂与一种或多种可生物降解聚合物的基质和填料和聚合物添加剂混合,从而制造可生物降解的或可堆肥的复合材料。