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    • 1. 发明申请
    • SYNTHESIS OF TRIDIMENSIONAL GRAPHENE OXIDE BASED MATERIALS
    • 三甲基氧化铁基材料的合成
    • WO2017017628A1
    • 2017-02-02
    • PCT/IB2016/054502
    • 2016-07-28
    • UNIVERSITÀ DEGLI STUDI DELL'AQUILACONSIGLIO NAZIONALE DELLE RICERCHE
    • IPPOLITI, RodolfoANGELUCCI, FrancescoARDINI, MatteoOTTAVIANO, LucaPERROZZI, FrancescoSANTUCCI, SandroMORANDI, VittorioORTOLANI, LucaPALERMO, Vincenzo
    • C01B31/04
    • C01B32/194C12N9/0006C12N11/14C12Y111/01015
    • The present invention relates to a three-dimensional structure made of graphene comprising at least two layers substantially constituted by graphene oxide therebetween one intermediate layer is interposed comprising protein rings or protein tubes of nanometric size as well as a process for implementing said structure. The present invention also relates to the use as adhesive, for implementing three-dimensional structures based upon hydrophilic materials, a protein capable of forming rings or tubes of nanometric dimensions having two surfaces with annular shape above and below a plane of the ring, not necessarily identical surfaces, at least partially hydrophobic and equipped with amino acids active from a redox point of view. Moreover, the present invention further relates to the manufacturing of 3D materials based upon graphene oxide functionalized with different metal species. The mineralisation of such materials is possible thanks to the engineering of the inner cavity of ring-like proteins with peptides equipped with amino acids capable of linking fixedly several metals.
    • 本发明涉及由石墨烯制成的三维结构,其包括基本上由氧化石墨烯构成的至少两层,其间插入包含蛋白质环或纳米尺寸的蛋白质管的中间层以及用于实施所述结构的方法。 本发明还涉及作为粘合剂的用途,用于实现基于亲水材料的三维结构,能够形成具有在环的平面上方和下方具有环形形状的具有环形形状的环的纳米尺寸的管的蛋白质,不一定 相同的表面,至少部分疏水并且配备有从氧化还原角度看活性的氨基酸。 此外,本发明还涉及基于用不同金属物质官能化的氧化石墨烯的3D材料的制造。 这种材料的矿化是可能的,这是由于具有装配有能够固定地连接几种金属的氨基酸的肽的环状蛋白质的内腔的工程化。