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1. 发明申请

WO2005056628A3 METHODS AND DEVICES COMPRISING SOLUBLE CONJUGATED POLYMERS 审中-公开
标题翻译：包含可溶性共轭聚合物的方法和装置
公开(公告)号：WO2005056628A3
公开(公告)日：2006-03-09
申请号：PCT/US2004030566
申请日：2004-09-17
申请人： UNIV CALIFORNIA , BAZAN GUILLERMO C , LIU BIN
发明人： BAZAN GUILLERMO C , LIU BIN
IPC分类号： C08G61/02 , C08G61/10 , C08G61/12 , C08G73/02 , C08G73/08 , H01B1/12 , B05D1/36 , B05D3/12 , B05D5/12
CPC分类号： H01L51/0003 , C08G61/02 , C08G61/10 , C08G61/123 , C08G61/126 , C08G73/02 , C08G73/08 , H01B1/127 , H01B1/128 , H01L51/0007 , H01L51/0036 , H01L51/0038 , H01L51/0039 , H01L51/0043 , H01L51/56 , H01S3/168 , Y10T428/31504
摘要： Methods, compositions and articles of manufacture involving soluble conjugated polymers are provided. The conjugated polymers have a sufficient density of polar substituents to render them soluble in a polar medium, for example water and/or methanol. The conjugated polymer may desirably comprise monomers which alter its conductivity properties. In some embodiments, the inventors have provided cationic conjugated polymers (CCPs) comprising both solubilizing groups and conductive groups, resulting in conductive conjugated polymers soluble in polar media. The different solubility properties of these polymers allow their deposition in solution in multilayer formats with other conjugated polymers. Also provided are articles of manufacture comprising multiple layers of conjugated polymers having differing solubility characteristics. Embodiments of the invention are described further herein.
摘要翻译：提供涉及可溶性共轭聚合物的方法，组合物和制品。共轭聚合物具有足够的极性取代基密度使其可溶于极性介质，例如水和/或甲醇。共轭聚合物可以理想地包括改变其导电性能的单体。在一些实施方案中，本发明人提供了包含增溶基团和导电基团的阳离子共轭聚合物（CCPs），导致可溶于极性介质的导电共轭聚合物。这些聚合物的不同的溶解性质使它们能够以其它共轭聚合物沉积在多层形式的溶液中。还提供了包含具有不同溶解度特性的多层共轭聚合物的制品。本文进一步描述本发明的实施例。

2. 发明申请

WO2005086617A3 CONFORMATIONALLY FLEXIBLE CATIONIC CONJUGATED POLYMERS 审中-公开
标题翻译：连续柔性阳离子聚合聚合物
公开(公告)号：WO2005086617A3
公开(公告)日：2006-02-23
申请号：PCT/US2004030605
申请日：2004-09-17
申请人： UNIV CALIFORNIA , BAZAN GUILLERMO C , LIU BIN
发明人： BAZAN GUILLERMO C , LIU BIN
IPC分类号： C08G61/02 , C08G61/10 , C08G61/12 , C08G73/02 , C08G73/08 , H01B1/12 , C08L35/06 , C08L53/00 , C08L71/02
CPC分类号： H01B1/122 , C08G61/02 , C08G61/10 , C08G61/123 , C08G61/126 , C08G73/02 , C08G73/08 , C40B40/04
摘要： Methods, compositions and articles of manufacture involving cationic conjugated conformationally flexible polymers are provided. A method for the synthesis of cationic water-soluble polymers with linkages along the polymer main chain structure which disrupt the ability of the polymers to form extended-rod structures is provided. Such polymers may serve in the fabrication of novel optoelectronic devices and in the development of highly efficient biosensors. The invention further relates to the application of these polymers in assay methods.
摘要翻译：提供涉及阳离子共轭构象柔性聚合物的方法，组合物和制品。提供了一种用于合成阳离子水溶性聚合物的方法，所述聚合物具有沿聚合物主链结构的连接，其破坏聚合物形成延伸棒结构的能力。这种聚合物可用于制造新的光电器件和开发高效生物传感器。本发明还涉及这些聚合物在测定方法中的应用。

3. 发明申请

WO2006074471A3 CATIONIC CONJUGATED POLYMERS SUITABLE FOR STRAND-SPECIFIC POLYNUCLEOTIDE DETECTION IN HOMOGENEOUS AND SOLID STATE ASSAYS 审中-公开
标题翻译：阳离子共轭聚合物适用于均匀和固态测定中特异性多核苷酸检测
公开(公告)号：WO2006074471A3
公开(公告)日：2006-11-02
申请号：PCT/US2006000882
申请日：2006-01-10
申请人： UNIV CALIFORNIA , BAZAN GUILLERMO C , LIU BIN
发明人： BAZAN GUILLERMO C , LIU BIN
IPC分类号： C08G61/10 , G01N21/64
CPC分类号： C08G61/02 , C08G61/122 , C08G61/123 , C12Q1/6818 , C12Q1/6837 , G01N21/6428 , G01N21/6452 , G01N2021/6419 , G01N2021/6439 , C12Q2563/131 , C12Q2537/119 , C12Q2525/107
摘要： The invention further relates to polycationic multichromophores, which may be conjugated polymers, and methods, articles and compositions employing them as described herein. In some aspects, the invention relates to methods, articles and compositions for the detection and analysis of biomolecules in a sample. Provided assays include those determining the presence of a target biomolecule in a sample or its relative amount, or the assays may be quantitative or semi-quantitative. The methods can be performed on a substrate. The methods can be performed in an array format on a substrate, which can be a sensor. In some embodiments, detection assays are provided employing sensor biomolecules that do not comprise a fluorophore that can exchange energy with the cationic multichromophore. In some aspects biological assays are provided in which energy is transferred between one or more of the multichromophore, a label on the target biomolecule, a label on the sensor biomolecule, and/or a fluorescent dye specific for a polynucleotide, in all permutations. The multichromophore may interact at least in part electrostatically with the sensor and/or the target, and an increase in energy transfer with the polymer may occur upon binding of the sensor and the target. Other variations of the inventions are described further herein.
摘要翻译：本发明进一步涉及聚阳离子多发色团，其可以是共轭聚合物，以及如本文所述使用它们的方法，制品和组合物。在一些方面，本发明涉及用于检测和分析样品中的生物分子的方法，物品和组合物。提供的分析包括那些确定样品中目标生物分子的存在或其相对量，或者分析可以是定量或半定量的。该方法可以在基底上进行。这些方法可以在衬底上以阵列格式执行，衬底可以是传感器。在一些实施方案中，使用不包含可以与阳离子多发色团交换能量的荧光团的传感器生物分子提供检测测定。在一些方面中，提供了生物测定法，其中能量在一个或多个多发色团，目标生物分子上的标记，传感器生物分子上的标记和/或多核苷酸特异性荧光染料之间转移，全部置换。多发色团可以至少部分地与传感器和/或目标静电相互作用，并且在传感器和目标结合时可以发生与聚合物的能量传递的增加。本发明的其他变型在此进一步描述。

4. 发明申请

WO2006083932A3 METHODS AND COMPOSITIONS FOR AGGREGANT DETECTION 审中-公开
标题翻译：用于聚集检测的方法和组合物
公开(公告)号：WO2006083932A3
公开(公告)日：2006-11-23
申请号：PCT/US2006003498
申请日：2006-01-31
申请人： UNIV , BAZAN GUILLERMO C , LIU BIN
发明人： BAZAN GUILLERMO C , LIU BIN
IPC分类号： G01N33/542 , C12Q1/68
CPC分类号： G01N21/6486 , C08G61/02 , C08G61/123 , C12Q1/6818 , C12Q1/6825 , G01N33/542 , G01N33/54373 , Y10T436/143333 , C12Q2565/113 , C12Q2563/173 , C12Q2565/101
摘要： This invention relates to an aggregation sensor useful for the detection and analysis of aggregants in a sample, and methods, articles and compositions relating to such a sensor. The sensor comprises first and second optically active units, where energy may be transferred from an excited state of the first optically active unit to the second optically active unit. The second optically active unit is present in a lesser amount, but its relative concentration is increased upon aggregation, increasing its absorption of energy from the first optically active units. This increase in energy transfer can be detected in variety of formats to produce an aggregation sensing system for various aggregants, including for quantitation. Other variations of the inventions are described further herein.
摘要翻译：本发明涉及可用于检测和分析样品中的聚集体的聚集传感器，以及与这种传感器相关的方法，制品和组合物。传感器包括第一和第二光学有源单元，其中能量可以从第一光学活性单元的激发状态转移到第二光学活性单元。第二光学活性单元以较小的量存在，但是其聚集时其相对浓度增加，从而增加其从第一光学活性单元的能量吸收。可以以各种格式检测能量转移的这种增加，以产生用于各种聚合物的聚集感测系统，包括用于定量。本文进一步描述了本发明的其它变型。

5. 发明申请

WO2012174561A3 REGIOREGULAR PYRIDAL[2,1,3]THIADIAZOLE pi-CONJUGATED COPOLYMERS FOR ORGANIC SEMICONDUCTORS 审中-公开
标题翻译：有机半导体[2,1,3]噻唑啉π共轭共聚物
公开(公告)号：WO2012174561A3
公开(公告)日：2013-06-20
申请号：PCT/US2012043004
申请日：2012-06-18
申请人： UNIV CALIFORNIA , BAZAN GUILLERMO C , YING LEI , HSU BEN B Y , WEN WEN , TSENG HSIN-RONG
发明人： BAZAN GUILLERMO C , YING LEI , HSU BEN B Y , WEN WEN , TSENG HSIN-RONG , WELCH GREGORY C
IPC分类号： C08G61/12 , C08G73/06 , H01L31/00
CPC分类号： H01L51/0036 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/148 , C08G2261/1646 , C08G2261/212 , C08G2261/3241 , C08G2261/3246 , C08G2261/344 , C08G2261/414 , C08G2261/91 , C08G2261/92 , H01L51/0043 , H01L51/0094 , H01L51/0533 , H01L51/0545 , Y02E10/549
摘要： A method of regioselectively preparing a pyridine-containing compound is provided. In particular embodiments, the method includes reacting halogen-functionalized pyridal[2,1,3]thiadiazole with organotin-functionalized cyclopenta[2,1-b:3,4-b'] 'dithiophene or organotin-functionalized indaceno[1,2-b:5,6-b']dithiophene. Also provided is a method of preparing a polymer. The method includes regioselectively preparing a monomer that includes a pyridal[2,1,3]thiadiazole unit; and reacting the monomer to produce a polymer that includes a regioregular conjugated backbone section, wherein the section includes a repeat unit containing the pyridal[2,1,3]thiadiazole unit. A polymer that includes a regioregular conjugated backbone section, and electronic devices that include the polymer, are also provided.
摘要翻译：提供了一种区域选择性制备含吡啶化合物的方法。在具体实施方案中，该方法包括使卤素官能化的吡啶并[2,1,3]噻二唑与有机锡官能化的环戊二烯并[2,1-b：3,4-b']二噻吩或有机锡官能化的茚并不是[1,2 -b：5,6-b']二。还提供了制备聚合物的方法。该方法包括区域选择性制备包含吡啶并[2,1,3]噻二唑单元的单体; 并使所述单体反应以制备包含区域结构共轭主链部分的聚合物，其中所述部分包括含有所述吡啶并[2,1,3]噻二唑单元的重复单元。还提供了包括区域性共轭主链部分的聚合物和包括聚合物的电子器件。

6. 发明申请

WO2009151825A2 TRANSITION METAL INITIATORS SUPPORTED BY KETONE DIIMINE LIGANDS FOR THE HOMOPOLYMERIZATION OF OLEFINS AND THE COPOLYMERIZATION OF OLEFINS WITH POLAR COMONOMERS 审中-公开
标题翻译：由KETONE DIIMINE配体支持的过渡金属反应器用于烯烃的共聚合和烯烃与极性共聚物的共聚合
公开(公告)号：WO2009151825A2
公开(公告)日：2009-12-17
申请号：PCT/US2009042877
申请日：2009-05-05
申请人： UNIV CALIFORNIA , AZOULAY JASON D , SCHNEIDER YANIKA , BAZAN GUILLERMO C
发明人： AZOULAY JASON D , SCHNEIDER YANIKA , BAZAN GUILLERMO C
IPC分类号： C08F4/80 , C07F15/00 , C08F4/42
CPC分类号： C07F15/045 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/02 , C08F210/16 , C08F2500/01 , C08F2500/03 , C08F220/14 , C08F2500/04 , C08F210/14 , C08F4/7006
摘要： Metal-ligand combination initiators are provided which yield organometallic complexes capable of the polymerization of olefins to high molecular weight polymers. Additionally, these initiators also enable the copolymerization of olefins with functionalized comonomers. These organometallic complexes comprise of a late transition metal with a neutral chelating Iigand that contains a Lewis basic functionality in conjugation with an electronically delocalized conduit extending from the metal to the functionality. This structural feature results in a highly active complex, which generates high molecular weight polymers with unique microstructures. Under particular conditions, the organometallic complexes provide for the living polymerization of monomers and comonomers.
摘要翻译：提供了金属 - 配体组合引发剂，其产生能够将烯烃聚合成高分子量聚合物的有机金属络合物。此外，这些引发剂还使烯烃与官能化共聚单体共聚。这些有机金属络合物包含具有中性螯合配体的后过渡金属，其含有与从金属延伸至官能团的电离离域导管共轭的路易斯碱性官能团。这种结构特征导致高活性复合物，其产生具有独特微结构的高分子量聚合物。在特定条件下，有机金属配合物提供单体和共聚单体的活性聚合。

7. 发明申请

WO2008045122A3 HYBRID POLYMER LIGHT-EMITTING DEVICES 审中-公开
标题翻译：混合聚合物发光器件
公开(公告)号：WO2008045122A3
公开(公告)日：2008-08-14
申请号：PCT/US2007001475
申请日：2007-01-18
申请人： UNIV CALIFORNIA , BAZAN GUILLERMO C , SHAO YAN , HEEGER ALAN J
发明人： BAZAN GUILLERMO C , SHAO YAN , HEEGER ALAN J
IPC分类号： H01J63/04 , C08K5/34 , C08L101/00 , H05B33/00
CPC分类号： H01L51/5032 , C08K5/19 , C08K5/42 , H01L51/0038
摘要： Mixtures and light-emitting devices that incorporate such mixtures are disclosed in which a soluble phenyl-substituted poly(para-phenylene vinylene) (PPV) copolymer ("superyellow") is used as the host light-emitting polymer and methyltrioctylammonium trifluoromethanesulfonate, an ionic liquid, is used to introduce a dilute concentration of mobile ions into the emitting polymer layer. These mixtures and devices incorporating them are able to combine some of the characteristics of polymer light emitting diodes (PLEDs) and polymer light-emitting electrochemical cells (PLECs).
摘要翻译：公开了掺入这种混合物的混合物和发光装置，其中使用可溶性苯基取代的聚（对亚苯基亚乙烯基）（PPV）共聚物（“超级”）作为主体发光聚合物和甲基三辛基三氟甲磺酸铵，液体，用于将稀释浓度的可移动离子引入发光聚合物层。这些混合物和结合它们的装置能够结合聚合物发光二极管（PLED）和聚合物发光电化学电池（PLEC）的一些特性。

8. 发明申请

WO2008066933A2 ENHANCING PERFORMANCE CHARACTERISTICS OF ORGANIC SEMICONDUCTING FILMS BY IMPROVED SOLUTION PROCESSING 审中-公开
标题翻译：改进溶液处理提高有机半导体薄膜的性能
公开(公告)号：WO2008066933A2
公开(公告)日：2008-06-05
申请号：PCT/US2007024792
申请日：2007-12-03
申请人： UNIV CALIFORNIA , BAZAN GUILLERMO C , HEEGER ALAN J , MOSES DANIEL , PEET JEFFREY
发明人： BAZAN GUILLERMO C , HEEGER ALAN J , MOSES DANIEL , PEET JEFFREY
IPC分类号： H01L51/44 , H01L51/46
CPC分类号： H01L51/005 , B82Y10/00 , H01L31/0256 , H01L51/0007 , H01L51/0028 , H01L51/0036 , H01L51/0047 , H01L51/4253 , Y02E10/549
摘要： Improved processing methods for enhanced properties of conjugated polymer films are disclosed, as well as the enhanced conjugated polymer films produced thereby. Addition of low molecular weight alkyl-containing molecules to solutions used to form conjugated polymer films leads to improved photoconductivity and improvements in other electronic properties. The enhanced conjugated polymer films can be used in a variety of electronic devices, such as solar cells and photodiodes.
摘要翻译：公开了用于增强共轭聚合物膜性能的改进处理方法，以及由此制得的增强共轭聚合物膜。向用于形成共轭聚合物膜的溶液中添加低分子量含烷基的分子导致改善的光电导性和其他电子性能的改善。增强共轭聚合物膜可用于各种电子器件，如太阳能电池和光电二极管。

9. 发明申请

WO2010090751A3 METHODS AND MATERIALS FOR THE DETECTION OF MELAMINE 审中-公开
标题翻译：检测三聚氰胺的方法和材料
公开(公告)号：WO2010090751A3
公开(公告)日：2010-12-16
申请号：PCT/US2010000323
申请日：2010-02-05
申请人： UNIV CALIFORNIA , LI NA , WEI FANG , LI HUAPING , BAZAN GUILLERMO C
发明人： LI NA , WEI FANG , LI HUAPING , BAZAN GUILLERMO C
IPC分类号： G01N31/22 , G01N21/78 , G01N31/02 , G01N33/04
CPC分类号： G01N31/22 , B82Y15/00 , G01N21/554 , G01N21/78 , G01N21/82 , Y10S977/773 , Y10S977/81 , Y10S977/921 , Y10T436/147777
摘要： Methods and materials for the detection of melamine in test samples such as foodstuffs are described. Embodiments of the invention comprise combining a test sample suspected of containing melamine with a particle that produces a colorimetric and/or turbidimetric signal that is dependent upon the concentration of melamine in the test sample. In certain embodiments of the invention, the particles and test sample are combined together with a chemical compound selected to induce the aggregation melamine in a manner that amplifies the colorimetric and/or turbidimetric signal of the assay. In some embodiments of the invention, the aggregation inducing agent is not physically coupled to the particles used in the assays. In other embodiments of the invention, the aggregation inducing agent is physically coupled to the particles used in these assays.
摘要翻译：描述了检测样品如食品中三聚氰胺的方法和材料。本发明的实施方案包括将怀疑含有三聚氰胺的测试样品与产生取决于测试样品中三聚氰胺浓度的比色和/或浊度信号的粒子组合。在本发明的某些实施方案中，将颗粒和测试样品与选定的化学化合物组合在一起，以放大测定的比色和/或浊度信号的方式诱导聚集的三聚氰胺。在本发明的一些实施方案中，聚集诱导剂不物理偶联到测定中使用的颗粒。在本发明的其他实施方案中，聚集诱导剂与这些测定中使用的颗粒物理偶联。

10. 发明申请

WO2008033246A8 ZWITTERIONIC GROUP VIII TRANSITION METAL INITIATORS SUPPORTED BY OLEFIN LIGANDS 审中-公开
标题翻译：由OleFIN LiganDS支持的第八组过渡金属开关
公开(公告)号：WO2008033246A8
公开(公告)日：2009-08-13
申请号：PCT/US2007019364
申请日：2007-09-05
申请人： UNIV CALIFORNIA , BAZAN GUILLERMO C , CHEN YAOFENG
发明人： BAZAN GUILLERMO C , CHEN YAOFENG
IPC分类号： C07F9/00 , B01J31/22 , C07F15/00 , C08F4/70 , C08F4/82
CPC分类号： C07F15/04 , C08F10/00 , C08F110/02 , C08F110/06 , C08F2500/03 , C08F4/7022
摘要： A zwitterionic Group VIII transition metal complex containing the simple and relatively small 3-(arylimino)-but-1-en-2-olato ligand that catalyzes the formation of polypropylene and high molecular weight polyethylene. A novel feature of this catalyst is that the active species is stabilized by a chelated olefin adduct. The present invention also provides methods of polymerizing olefin monomers using zwitterionic catalysts, particularly polypropylene and high molecular weight polyethylene.
摘要翻译：含有简单且相对较小的3-（芳基亚氨基） - 丁-1-烯-2-醇配体的两性离子第VIII族过渡金属络合物，其催化聚丙烯和高分子量聚乙烯的形成。该催化剂的一个新特征是活性物质被螯合烯烃加合物稳定。本发明还提供使用两性离子催化剂，特别是聚丙烯和高分子量聚乙烯聚合烯烃单体的方法。

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