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    • 5. 发明申请
    • THICKENED AQUEOUS DETERGENT LIQUID
    • 稠化的水性洗剂液体
    • WO2014082955A1
    • 2014-06-05
    • PCT/EP2013/074596
    • 2013-11-25
    • UNILEVER PLCUNILEVER N.V.CONOPCO, INC., D/B/A UNILEVER
    • JARVIS, Adam, PeterLIMER, Adam, JohnRYAN, Philip, MichaelTHOMAS, Matthew, Rhys
    • C11D3/37C11D1/02
    • C11D3/3765C11D1/02C11D1/22C11D3/3746
    • A thickened aqueous detergent liquid comprising: (i) at least 5 wt% of a surfactant system comprising anionic surfactant, (ii) at least 0.2 wt% of a thickening system comprising a linear copolymer formed by the addition polymerisation of: (A) 0.1 to 5 wt% of a first monomer consisting of an ethylenically unsaturated diacid of formula (I): HOOC-CR 1 =CR 2 -COOH (I) or an unsaturated cyclic anhydride precursor of such an ethylenically unsaturated diacid, the anhydride having formula (II), where R 1 and R 2 are individually selected from H, C 1 -C 3 alkyl, phenyl, chlorine and bromine; (B) 15 to 60 wt% of a second ethylenically unsaturated monoacidic monomer consisting of (meth)acrylic acid; (C) 30 to 70 wt% of a third ethylenically unsaturated monomer consisting of C 1 -C 8 alkyl ester of (meth)acrylic acid; (D) 1 to 25 wt%, of a fourth ethylenically unsaturated monomer, consisting of surfmer of formula (III), wherein each R 3 and R 4 are each independently selected from H, methyl, -C(=O)OH, or -C(=O)OR 5 ; R 5 is a C 1 -C 30 alkyl; T is -CH 2 C(=O)O-, -C(=O)O-, -O-, -CH 2 O-, -NHC(=O)NH-, -C(=O)NH-, -Ar-(CE 2 ) z -NHC(=O)O-, -Ar-(CE 2 ) z -NHC(=O)NH-, or CH 2 CH 2 NHC(=O)- Ar is divalent aryl; E is H or methyl; z is 0 or 1; k is an integer in the range of 0 to 30; and m is 0 or 1; with the proviso that when k is 0, m is 0, and when k is in the range of 1 to 30; m is 1; (R 6 O) n is polyoxyalkylene, which is a homopolymer, a random copolymer, or a block copolymer of C2-C4-oxyalkylene units, wherein R 6 is C 2 H 4 , C 3 H 6 , C 4 H 8 , or a mixture thereof, and n is an integer in the range of 5 to 250;Y is -R 6 O-, -R 6 -, -C(=O)-, -C(=O)NH-, =R 6 NHC(=O)NH-, or -C(=O)NHC(=O)-; and R 7 is substituted or unsubstituted alkyl selected from the group consisting of C 8 -C 40 linear alkyl, C 8 -C 40 branched alkyl, C 8 -C 40 carbocyclic alkyl, C 2 -C 40 alkyl-substituted, phenyl, aryl-substituted C 2 -C 40 alkyl, and C 8 C 80 complex ester; wherein the R 7 alkyl group optionally comprises one or more substituents selected from the group consisting of hydroxy, alkoxy, and halogen.
    • 增稠的含水洗涤剂液体包括:(i)至少5重量%的包含阴离子表面活性剂的表面活性剂体系,(ii)至少0.2重量%的增稠体系,其包含通过以下加成聚合形成的线性共聚物:(A)0.1 至5重量%的由式(I)的烯属不饱和二酸组成的第一单体:HOOC-CR1 = CR2-COOH(I)或这种烯属不饱和二酸的不饱和环酸酐前体,具有式(II)的酸酐, 其中R 1和R 2分别选自H,C 1 -C 3烷基,苯基,氯和溴; (B)15〜60重量%的由(甲基)丙烯酸组成的第二烯属不饱和单酸单体; (C)30〜70重量%的由(甲基)丙烯酸的C1-C8烷基酯组成的第三烯属不饱和单体; (D)1至25重量%的第四烯属不饱和单体,由式(III)的冲浪剂组成,其中每个R 3和R 4各自独立地选自H,甲基,-C(= O)OH或-C (= O)OR 5; R5是C1-C30烷基; T是-CH 2 C(= O)O-,-C(= O)O-,-O-,-CH 2 O-,-NHC(= O)NH-,-C(= O)NH-, CE2)z-NHC(= O)O-,-Ar-(CE2)z-NHC(= O)NH-或CH 2 CH 2 NHC(= O) E为H或甲基; z为0或1; k为0〜30的整数, m为0或1; 条件是当k为0时,m为0,当k为1〜30的范围时, m为1; (R6O)n为聚氧化烯,其为C2-C4-氧化烯单元的均聚物,无规共聚物或嵌段共聚物,其中R6为C2H4,C3H6,C4H8或其混合物,n为整数 (= O)NH-,= R6NHC(= O)NH-或-C(= O)NHC(= = O) - ; 并且R 7是选自C 8 -C 40直链烷基,C 8 -C 40支链烷基,C 8 -C 40碳环烷基,C 2 -C 40烷基取代的苯基,芳基取代的C 2 -C 40烷基和C 8 C 8的取代或未取代的烷基 复合酯; 其中所述R 7烷基任选地包含一个或多个选自羟基,烷氧基和卤素的取代基。
    • 6. 发明申请
    • POLYMER STRUCTURED AQUEOUS DETERGENT COMPOSITIONS
    • 聚合物结构的水性洗涤剂组合物
    • WO2014082874A1
    • 2014-06-05
    • PCT/EP2013/073935
    • 2013-11-15
    • UNILEVER PLCUNILEVER N.V.CONOPCO, INC., D/B/A UNILEVER
    • JARVIS, Adam, PeterLIMER, Adam, JohnRYAN, Philip, MichaelTHOMAS, Matthew, Rhys
    • C11D1/02C11D3/37
    • C11D3/3765C11D1/02C11D1/22C11D3/3715C11D3/3723C11D3/505C11D17/0013
    • An aqueous polymer structured detergent liquid composition comprising: (i) a surfactant system comprising surfactant and alkaline material present as surfactant salts and/or as free base, (ii) optionally, 0.01 wt% or more suspended particles, (iii) optionally, 3 wt% or more polymer that reduces the composition viscosity at 20 s -1 , and (iv) at least 0.05 wt% of a suspending system comprising copolymer formed by the addition polymerisation of: (A) 0.1 to 5 wt% of a first monomer consisting of an ethylenically unsaturated diacid of formula (I): HOOC-CR 1 =CR 2 -COOH or an unsaturated cyclic anhydride precursor of such an ethylenically unsaturated diacid, the anhydride having formula (II) where R 1 and R 2 are individually selected from H, C 1 -C 3 alkyl, phenyl, chlorine and bromine; (B) 15 to 60 wt% of a second ethylenically unsaturated monoacidic monomer consisting of (meth)acrylic acid; (C) 30 to 70 wt% of a third ethylenically unsaturated monomer consisting of C 1 -C 8 alkyl ester of (meth)acrylic acid; (D) 1 to 25 wt%, of a fourth ethylenically unsaturated monomer, consisting of surfmer of formula (III) wherein each R 3 and R 4 are each independently selected from H, methyl, -C(=O)OH, or -C(=O)OR 5 ; R 5 is a C 1 -C 30 alkyl; T is -CH2C(=O)O-, -C(=O)O-, -O-, -CH 2 O-, -NHC(=O)NH-, -C(=O)NH-, -Ar-(CE 2 ) 2 -NHC(=O)O-, -Ar-(CE 2 ) 2 -NHC(=O)NH-, or -CH 2 CH 2 NHC(=O)-; Ar is divalent aryl; E is H or methyl; z is 0 or 1; k is an integer in the range of 0 to 30; and m is 0 or 1; with the proviso that when k is 0, m is 0, and when k is in the range of 1 to 30; m is 1; (R 6 O) n is polyoxyalkylene, which is a homopolymer, a random copolymer, or a block copolymer of C 2 -C 4 -oxyalkylene units, wherein R 6 is C 2 H 4 , C 3 H 6 , C 4 H 8 , or a mixture thereof, and n is an integer in the range of 5 to 250;Y is -R 6 O-, -R 6 -, -C(=O)-, -C(=O)NH-, =R 6 NHC(=O)NH-, or -C(=O)NHC(=O)-; and R 7 is substituted or unsubstituted alkyl selected from the group consisting of C 8 -C 40 linear alkyl, C 8 -C 40 branched alkyl, C 8 -C 40 carbocyclic alkyl, C 2 -C 40 alkyl-substituted, phenyl, aryl-substituted C 2 - C 40 alkyl, and C 8 -C 80 complex ester; wherein the R 7 alkyl group optionally comprises one or more substituents selected from the group consisting of hydroxy, alkoxy, and halogen; and (E) 0.005 to 5 wt%, of a cross linking agent, for introducing branching and controlling molecular weight, the cross linking monomer comprising polyfunctional units carrying multiple reactive functionalisation groups selected from the group consisting of vinyl, allyl and functional mixtures thereof.
    • 一种含水聚合物结构洗涤剂液体组合物,其包含:(i)包含作为表面活性剂盐和/或游离碱存在的表面活性剂和碱性物质的表面活性剂体系,(ii)任选的0.01重量%或更多的悬浮颗粒,(iii)任选地3 wt%或更多的聚合物,其降低20s-1时的组成粘度,和(iv)至少0.05wt%的包含通过加成聚合形成的共聚物的悬浮体系的至少0.05wt%:(A)0.1至5wt%的第一单体 由式(I)的烯键式不饱和二酸组成:HOOC-CR1 = CR2-COOH或这种烯键式不饱和二酸的不饱和环状酸酐前体,其中R1和R2分别选自H,C1 -C3烷基,苯基,氯和溴; (B)15〜60重量%的由(甲基)丙烯酸组成的第二烯属不饱和单酸单体; (C)30〜70重量%的由(甲基)丙烯酸的C1-C8烷基酯组成的第三烯属不饱和单体; (D)1至25重量%的第四烯键式不饱和单体,由式(III)的冲浪剂组成,其中每个R 3和R 4各自独立地选自H,甲基,-C(= O)OH或-C( = O)OR 5; R5是C1-C30烷基; T是-CH 2 C(= O)O-,-C(= O)O-,-O-,-CH 2 O-,-NHC(= O)NH-,-C(= O)NH-, CE2)2-NHC(= O)O-,-Ar-(CE2)2 -NHC(= O)NH-或-CH2CH2NHC(= O) - ; Ar是二价芳基; E为H或甲基; z为0或1; k为0〜30的整数, m为0或1; 条件是当k为0时,m为0,当k为1〜30的范围时, m为1; (R6O)n为聚氧化烯,其为C2-C4-氧化烯单元的均聚物,无规共聚物或嵌段共聚物,其中R6为C2H4,C3H6,C4H8或其混合物,n为整数 (= O)NH-,= R6NHC(= O)NH-或-C(= O)NHC(= = O) - ; 并且R 7是选自C 8 -C 40直链烷基,C 8 -C 40支链烷基,C 8 -C 40碳环烷基,C 2 -C 40烷基取代的苯基,芳基取代的C 2 -C 40烷基和C 8 -C80复合酯; 其中所述R 7烷基任选地包含一个或多个选自羟基,烷氧基和卤素的取代基; 和(E)0.005-5重量%的用于引入支化和控制分子量的交联剂,所述交联单体包含多官能单元,其携带选自乙烯基,烯丙基和其功能性混合物的多个反应性官能化基团。
    • 8. 发明申请
    • COMPOSITION
    • WO2018210700A1
    • 2018-11-22
    • PCT/EP2018/062260
    • 2018-05-11
    • UNILEVER PLCUNILEVER N.V.CONOPCO, INC., D/B/A UNILEVER
    • JARVIS, Adam, PeterROGERS, Susanne, HenningTHOMAS, Matthew, RhysWILLS, Peter, William
    • C11D3/37
    • An aqueous detergent liquid composition comprising: (i) a surfactant system comprising anionic surfactant, and (ii) at least 0.05 wt % of a polymer formed from the polymerisation of monomers consisting of monomer (A1): R 1 C=CR 2 R 3 (A1) And optionally monomer (A2): R 4 C=CR 5 R 6 (A2) R 1 and R 2 are each independently selected from H, methyl, -C(=O)OH, or -C(=O)OR 7 , wherein R 7 is a C 1 -C 30 alkyl; R 3 is T 1 -[CH 2 ] k -[O] p -[R 8 O] q -Y 1 -R 9 T 1 is -CH 2 C(=O)O-, -C(=O)O-, -O-, -CH 2 O-, -NHC(=O)NH-, -C(=O)NH-, -Ar-(CE 2 ) x -NHC(=O)O-, -Ar-(CE 2 ) x -NHC(=O)NH-, or -CH 2 CH 2 NHC(=O)-; Ar is divalent aryl; E is H or methyl; x is 0 or 1; k is an integer in the range of 0 to 30; and p is 0 or 1; optionally with the proviso that when k is 0, p is 0, and when k is in the range of 1 to 30; p is 1; (R 8 O) q is polyoxyalkylene, which is a homopolymer, a random copolymer, or a block copolymer of C 2 -C 4 -oxyalkylene units, wherein R 8 is C 2 H 4 , C 3 H 6 , C 4 H 8 , or a mixture thereof, and n is an integer in the range of 5 to 250; Y 1 is -R 8 O-, -R 8 H-, -C(=O)-, -C(=O)NH-, =R 8 NHC(=O)NH-, or - C(=O)NHC(=O)-; and R 9 is substituted or unsubstituted alkyl selected from the group consisting of C 8 -C 40 linear alkyl, C 8 -C 40 branched alkyl, C 8 -C 40 carbocyclic alkyl, C 2 -C 40 alkyl-substituted, phenyl, aryl-substituted C 2 -C 40 alkyl, and C 8 -C 80 complex ester; wherein the R 11 alkyl group optionally comprises one or more substituents selected from the group consisting of hydroxy, alkoxy, and halogen; R 4 and R 5 are independently H or C 1-4 alkyl, preferably H or methyl; R 6 is -C(O)-OR 10 , where R 10 is H or C 1-4 alkyl, preferably H or methyl, more preferably H; and wherein the degree of polymerisation of polymer (ii) is 30 or more.