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1. 发明申请

WO2006018257A3 PLATINUM/RUTHENIUM CATALYST FOR DIRECT METHANOL FUEL CELLS 审中-公开
标题翻译：用于直接甲醇燃料电池的铂/钌催化剂
公开(公告)号：WO2006018257A3
公开(公告)日：2007-04-19
申请号：PCT/EP2005008827
申请日：2005-08-13
申请人： UMICORE AG & CO KG , LOPEZ MARCO , BIBERBACH PETER
发明人： LOPEZ MARCO , BIBERBACH PETER
IPC分类号： H01M4/92 , B01J23/40 , B01J37/03
CPC分类号： H01M4/921
摘要： A carbon- supported PtRu anode catalyst for direct methanol fuel cells (DMFC) which has a platinum/ruthenium content in the range from 80 to 98 wt.%, preferably in the range from 85 to 98 wt.%, particularly preferably in the range from 85 to 95 wt.% (based on the total weight of the catalyst), on a carbon-based electrically conductive support material and has a mean particle size of less than 3 nm. The catalyst is prepared using a carbon black support material having a specific surface area (measured by the BET method) in the range from 1000 to 2000 m 2 /g by means of a reduction process using chemical reducing agents with addition of organic acids. Electrodes and membrane -electrode units containing the catalyst according to the invention having a high precious metal loading have an elctrode layer thickness of less than 80 urn at a PtRu loading per unit area of the elctrode of from 6 to 12 mg of PtRu/ cm 2 and lead to improved electric power in direct methanol fuel cells.
摘要翻译：用于直接甲醇燃料电池（DMFC）的碳负载PtRu阳极催化剂，其具有在80至98重量％范围内的铂/钌含量，优选在85至98重量％的范围内，特别优选在该范围内 85重量％至95重量％（基于催化剂的总重量），在碳基导电载体材料上，并且具有小于3nm的平均粒度。使用具有比表面积（通过BET法测量）在1000-2000m 2 / g范围内的碳黑载体材料通过使用化学还原剂的还原方法制备催化剂加入有机酸。含有贵金属负载量高的本发明催化剂的电极和膜 - 电极单元，在每单位面积电极PtRu负载量为6〜12mg PtRu / cm 2时，电极层厚度小于80um， SUP> 2 ，导致直接甲醇燃料电池的功率提高。

2. 发明专利

JP2009114545A Platinum and platinum alloy powders with high surface areas and low chlorine content, and processes for preparing these powders 审中-公开
标题翻译：具有高表面积和低氯含量的白金和铂合金粉及其制备这些粉末的方法
公开(公告)号：JP2009114545A
公开(公告)日：2009-05-28
申请号：JP2009001123
申请日：2009-01-06
申请人： Umicore Ag & Co Kg , ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフトUmicore AG & Co.KG
发明人： BIBERBACH PETER
IPC分类号： B01J23/42 , B22F1/00 , B01J23/46 , B01J35/10 , B22F9/24 , C22B11/02 , C22C5/04 , H01M4/86 , H01M4/88 , H01M4/90 , H01M4/92 , H01M8/10
CPC分类号： H01M4/92 , B22F9/24 , B22F2998/00 , C22B11/02 , H01M4/8605 , H01M8/1004 , Y02P70/56 , B22F1/0018
摘要： PROBLEM TO BE SOLVED: To provide a process for preparing a platinum or platinum alloy powder for forming a metal powder having a finely and uniformly divided particle size, a large surface area and a low chlorine content and also to provide a platinum or platinum alloy powder prepared by the process. SOLUTION: The process comprises: a step of forming a melt which contains a low-melting mixture of alkali-metal nitrate, a chlorine-free platinum compound and a chlorine-free compound of alloying elements; a step of heating the melt up to a reaction temperature at which the platinum compound and the compound of the alloying elements are thermally decomposed to give an oxide; a step of cooling the melt; and a step where the melt is dissolved in water and the resulting oxide or mixed oxides are converted into a powder of platinum or platinum alloy by successive reduction. The powder of platinum or platinum alloy includes a powder having a BET specific surface area larger than 40 m 2 /g and a chlorine content lower than 100 ppm. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种制备铂或铂合金粉末的方法，所述铂或铂合金粉末用于形成精细且均匀分散的粒度，大的表面积和低氯含量的金属粉末，并且还提供铂或铂铂合金粉末通过该方法制备。解决方案：该方法包括：形成含有碱金属硝酸盐，无氯铂化合物和合金元素的无氯化合物的低熔点混合物的熔体的步骤; 将熔融物加热到铂化合物和合金元素的化合物被热分解以产生氧化物的反应温度的步骤; 冷却熔体的步骤; 以及将熔体溶解在水中并通过连续还原将所得氧化物或混合氧化物转化为铂或铂合金粉末的步骤。铂或铂合金粉末包括BET比表面积大于40m 2 / SP / g，氯含量低于100ppm的粉末。版权所有（C）2009，JPO＆INPIT

3. 发明专利

JP2007289960A Noble metal-containing supported catalyst and process for its preparation 有权
标题翻译：含金属的载体催化剂及其制备方法
公开(公告)号：JP2007289960A
公开(公告)日：2007-11-08
申请号：JP2007164424
申请日：2007-06-21
申请人： Umicore Ag & Co Kg , ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフトUmicore AG & Co.KG
发明人： RUTH KARSTEN , BIBERBACH PETER , STARZ KARL ANTON
IPC分类号： B01D53/86 , B01J23/652 , B01J21/18 , B01J23/38 , B01J23/42 , B01J23/46 , B01J23/54 , B01J23/56 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/02 , B01J37/08 , B01J37/34 , H01M4/86 , H01M4/88 , H01M4/90 , H01M4/92 , H01M4/96 , H01M8/10
CPC分类号： B82Y30/00 , B01J21/18 , B01J23/38 , B01J23/54 , B01J23/6522 , B01J35/0013 , B01J35/002 , B01J35/0033 , B01J35/0053 , B01J35/006 , B01J37/08 , H01M4/90 , H01M4/9075 , H01M4/9083 , H01M4/92 , H01M4/921 , H01M4/925 , H01M4/926
摘要： PROBLEM TO BE SOLVED: To provide a process for preparation of a noble metal-containing supported catalyst having high crystallinity or sufficiently developed alloy structure. SOLUTION: The invention provides a noble metal-containing supported catalyst which contains one or more of the noble metals from the group Au, Ag, Pt, Pd, Rh, Ru, Ir, Os or alloys thereof in the form of noble metal particles deposited on a powdered support material. The noble metal particles have a relative crystallinity, determined by X-ray diffraction, of more than 2 and an average particle size between 2 and 10 nm. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种制备具有高结晶度或足够开发的合金结构的含贵金属负载型催化剂的方法。解决方案：本发明提供一种含贵金属的负载型催化剂，其含有Au，Ag，Pt，Pd，Rh，Ru，Ir，Os族中的一种或多种贵金属或其贵金属的贵金属沉积在粉状载体材料上的金属颗粒。贵金属颗粒具有通过X射线衍射确定的相对结晶度大于2且平均粒度在2和10nm之间。版权所有（C）2008，JPO＆INPIT

4. 发明专利

CA2446692C PROCESS AND APPARATUS FOR THE THERMAL TREATMENT OF PULVERULENT SUBSTANCES 未知
公开(公告)号：CA2446692C
公开(公告)日：2012-06-19
申请号：CA2446692
申请日：2002-04-17
申请人： UMICORE AG & CO KG
发明人： AUER EMMANUEL , BIBERBACH PETER , GROSS MICHAEL , GUTSCH ANDREAS , PRIDOHL MARKUS , RUTH KARSTEN , STAAB EDWIN
IPC分类号： B01J37/08 , B01J6/00 , B01J8/00 , B01J8/12 , B01J19/00 , B01J19/12 , B01J19/14 , B01J23/00 , B01J37/34
摘要： Process and apparatus for the thermal treatment of pulverulent substances, in which the pulverulent substance is dispersed in a carrier gas and is passed in a continuous manner through a heated reactor where it is thermally treated and is then quenched by a cooling medium and is collected in a gas-solids separating unit.

5. 发明专利

AT377096T 未知
公开(公告)号：AT377096T
公开(公告)日：2007-11-15
申请号：AT01120859
申请日：2001-08-30
申请人： UMICORE AG & CO KG
发明人： BIBERBACH PETER
IPC分类号： C22B11/00 , B22F9/16 , C22B11/02 , H01M4/92 , H01M8/00

6. 发明专利

AT314141T 未知
公开(公告)号：AT314141T
公开(公告)日：2006-01-15
申请号：AT02011370
申请日：2002-05-23
申请人： UMICORE AG & CO KG
发明人： RUTH KARSTEN DR , BIBERBACH PETER , STARZ KARL-ANTON DR , MCINTOSH RALPH
IPC分类号： B01J23/46 , B01J23/40 , B01J23/42 , B01J37/03 , H01M4/86 , H01M4/88 , H01M4/92 , H01M8/10
摘要： Solutions of hexachloroplatinic acid and ruthenium chloride are added to a support material suspension. pH of the suspension is increased to 6.5-10 by adding an alkaline solution to precipitate sparingly soluble noble metal compounds. Organic carboxylic acid(s) and/or their salts are added to the suspension, and precipitated noble metal compounds are reduced to form a supported platinum-ruthenium catalyst. A support material is suspended in water to form a suspension. The suspension is heated at most up to solution boiling point. Solutions of hexachloroplatinic acid and ruthenium chloride are added to suspension while maintaining the same temperature and stirring. pH of the suspension is increased to 6.5-10 by adding an alkaline solution to precipitate hexachloroplatinic acid and ruthenium chloride in form of sparingly soluble noble metal compounds. Organic carboxylic acid(s) and/or their salts are added to the suspension, and precipitated noble metal compounds are reduced by adding reducing agents to form a supported platinum-ruthenium catalyst on a powdered support material. The catalyst is washed and dried. Independent claims are included for the following: (1) preparation of an unsupported platinum-ruthenium catalyst which involves heating solution comprising hexachloroplatinic acid and ruthenium chloride to a maximum of solutions boiling point. pH of the solution is increased to 6.5-10 by adding an alkaline solution to precipitate hexachloroplatinic acid and ruthenium chloride in form of sparingly soluble noble metal compounds, adding organic carboxylic acid(s) and/or their salts, reducing precipitated noble metal compounds by adding reducing agents to form the catalyst, washing and drying; (2) supported platinum-ruthenium catalyst; (3) unsupported platinum-ruthenium catalyst; (4) a membrane electrode assembly for fuel cells comprising the catalyst; and (5) method for using the catalyst in polymer electrolyte membrane or direct methanol fuel cells.

7. 发明专利

CA2543256C PRECIOUS METAL OXIDE CATALYST FOR WATER ELECTROLYSIS 未知
公开(公告)号：CA2543256C
公开(公告)日：2010-06-29
申请号：CA2543256
申请日：2004-10-29
申请人： UMICORE AG & CO KG
发明人： LOPEZ MARCO , SCHLEUNUNG ANDREAS , BIBERBACH PETER
IPC分类号： B01J23/46 , B01J35/10 , B01J37/03 , C02F1/461 , C25B9/23 , H01M4/88 , H01M4/90 , H01M4/92 , H01M8/10 , H01M8/18
摘要： The invention is directed to iridium oxide based catalysts for use as anode catalysts in PEM water electrolysis. The claimed composite catalyst materials comprise iridium oxide (IrO2) and optionally ruthenium oxide (RuO2) in combination with a high surface area inorganic oxide (for example TiO2, A12O3, ZrO2 and mixtures thereof). The inorganic oxide has a BET surface area in the range of 50 to 400 m2/g, a water solubility of lower than 0,15 g/l and is present in a quantity of less than 20 wt.% based on the total weight of the catalyst. The claimed catalyst materials are characterised by a low oxygen overvoltage and long lifetime in water electrolysis. The catalysts are used in electrodes, catalyst-coated membranes and membrane-electrode-assemblies for PEM electrolyzers as well as in regenerative fuel cells (RFC), sensors, and other electrochemical devices.

8. 发明专利

AT442901T 未知
公开(公告)号：AT442901T
公开(公告)日：2009-10-15
申请号：AT04791049
申请日：2004-10-29
申请人： UMICORE AG & CO KG
发明人： LOPEZ MARCO , SCHLEUNUNG ANDREAS , BIBERBACH PETER
IPC分类号： B01J23/46 , B01J35/10 , B01J37/03 , C02F1/461 , C25B9/23 , H01M4/88 , H01M4/90 , H01M4/92 , H01M8/10 , H01M8/18
摘要： The invention is directed to iridium oxide based catalysts for use as anode catalysts in PEM water electrolysis. The claimed composite catalyst materials comprise iridium oxide (IrO2) and optionally ruthenium oxide (RuO2) in combination with a high surface area inorganic oxide (for example TiO2, Al2O3, ZrO2 and mixtures thereof). The inorganic oxide has a BET surface area in the range of 50 to 400 m2/g, a water solubility of lower than 0.15 g/l and is present in a quantity of less than 20 wt. % based on the total weight of the catalyst. The claimed catalyst materials are characterized by a low oxygen overvoltage and long lifetime in water electrolysis. The catalysts are used in electrodes, catalyst-coated membranes and membrane-electrode-assemblies for PEM electrolyzers as well as in regenerative fuel cells (RFC), sensors, and other electrochemical devices.

9. 发明专利

DE60205061T2 未知
公开(公告)号：DE60205061T2
公开(公告)日：2006-04-20
申请号：DE60205061
申请日：2002-05-06
申请人： UMICORE AG & CO KG
发明人： RUTH KARSTEN , BIBERBACH PETER , STARZ KARL ANTON
IPC分类号： B01D53/86 , B01J23/38 , B01J21/18 , B01J23/42 , B01J23/46 , B01J23/54 , B01J23/56 , B01J23/652 , B01J23/89 , B01J35/00 , B01J35/02 , B01J35/04 , B01J35/10 , B01J37/02 , B01J37/08 , H01M4/86 , H01M4/88 , H01M4/90 , H01M4/92 , H01M4/96 , H01M8/10
摘要： An exhaust gas catalytic surface has a powdered substrate bearing a noble metal (gold, silver, platinum, palladium, rhodium, ruthenium, iridium or osmium) or an alloy containing one or more of these metals. The noble metal crystals deposited upon the substrate have especially a relative radiological crystallinity of more than 2 and a median particle size between 2 and 10 nm. Preferred Features: The relative radiological crystallinity is greater than 5. The substrate material contains carbon and is based on soot, graphite, active carbon, and fibre-formed graphite nano-tubes. The substrate material is an oxidized material based on aluminum oxide, aluminum silicate, zeolite, titanium oxide, zircon oxide, rare dioxides, or mixtures of these. The noble metals also incorporate alloys from the group titanium, zirconium, carbon, chromium, manganese, iron, cobalt, nickel, copper or zinc. The catalyst has platinum on soot of at least 40 m/g in a concentration of 5-80 wt.%, w.r.t the total weight of the substrate material and platinum. An Independent claim is also included for the production of a fuel cell catalyst.

10. 发明专利

DE602004023231D1 未知
公开(公告)号：DE602004023231D1
公开(公告)日：2009-10-29
申请号：DE602004023231
申请日：2004-10-29
申请人： UMICORE AG & CO KG
发明人： LOPEZ MARCO , SCHLEUNUNG ANDREAS , BIBERBACH PETER
IPC分类号： B01J23/46 , B01J35/10 , B01J37/03 , C02F1/461 , C25B9/23 , H01M4/88 , H01M4/90 , H01M4/92 , H01M8/10 , H01M8/18
摘要： The invention is directed to iridium oxide based catalysts for use as anode catalysts in PEM water electrolysis. The claimed composite catalyst materials comprise iridium oxide (IrO2) and optionally ruthenium oxide (RuO2) in combination with a high surface area inorganic oxide (for example TiO2, Al2O3, ZrO2 and mixtures thereof). The inorganic oxide has a BET surface area in the range of 50 to 400 m2/g, a water solubility of lower than 0.15 g/l and is present in a quantity of less than 20 wt. % based on the total weight of the catalyst. The claimed catalyst materials are characterized by a low oxygen overvoltage and long lifetime in water electrolysis. The catalysts are used in electrodes, catalyst-coated membranes and membrane-electrode-assemblies for PEM electrolyzers as well as in regenerative fuel cells (RFC), sensors, and other electrochemical devices.

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