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1. 发明申请

US20080287627A1 Perfluoroelastomer compositions and methods of preparing same 有权
标题翻译：全氟弹性体组合物及其制备方法
公开(公告)号：US20080287627A1
公开(公告)日：2008-11-20
申请号：US12148014
申请日：2008-04-16
申请人： Tsuyoshi Noguchi , Jiazhong Luo , Tatsuya Morikawa , Hirokazu Komori , Takafumi Yamato , Meiten Koh
发明人： Tsuyoshi Noguchi , Jiazhong Luo , Tatsuya Morikawa , Hirokazu Komori , Takafumi Yamato , Meiten Koh
IPC分类号： C08F16/24
CPC分类号： C08L27/18 , C08K5/18 , C08L2205/02 , Y10T428/3154 , C08L2666/04
摘要： The present invention includes crosslinked perfluoroelastomeric compositions and molded articles formed from a cross-linkable perfluoroelastomeric composition having a first curable perfluoropolymer having a cure site monomer and a second perfluoropolymer having a cure site monomer. The molar ratio of the tetrafluoroethylene monomer to perfluoroalkylvinyl ether in one perfluoropolymer is about 0 to 100 to about 65 to 35 in the perfluoropolymer. The molar ratio of the tetrafluoroethylene monomer to the perfluoroalkylvinyl ether monomer in the second polymer is about 65:35 to about 95:5 in the second perfluoropolymer. The composition further includes a curative. One fluorine-containing elastomer composition herein, having a short crosslinking time, has perfluoroelastomers (A) having a tetrafluoroethylene unit, a perfluoralkylvinyl ether unit (a) and a monomer unit (b) having at least one kind selected from the group consisting of a nitrile group, a carboxyl group and an alkoxycarbonyl group, wherein the composition has two or more kinds of perfluoroelastomers (A) having differing contents of perfluoroalkylvinyl ether unit (a).
摘要翻译：本发明包括交联的全氟弹性体组合物和由可交联的全氟弹性体组合物形成的模塑制品，其具有具有固化部位单体的第一可固化全氟聚合物和具有固化部位单体的第二全氟聚合物。全氟聚合物中四氟乙烯单体与全氟烷基乙烯基醚的摩尔比在全氟聚合物中为约0至约100至约65至35。第二聚合物中四氟乙烯单体与全氟烷基乙烯基醚单体的摩尔比在第二全氟聚合物中为约65:35至约95:5。组合物还包括治疗剂。具有交联时间短的一种含氟弹性体组合物具有全氟弹性体（A），其具有四氟乙烯单元，全氟烷基乙烯基醚单元（a）和单体单元（b），所述单体单元具有选自以下的至少一种：腈基，羧基和烷氧基羰基，其中所述组合物具有两种或更多种具有不同全氟烷基乙烯基醚单元（a）含量的全氟弹性体（A）。

2. 发明授权

US08367776B2 Perfluoroelastomer compositions and methods of preparing same 有权
公开(公告)号：US08367776B2
公开(公告)日：2013-02-05
申请号：US12148014
申请日：2008-04-16
申请人： Tsuyoshi Noguchi , Jiazhong Luo , Tatsuya Morikawa , Hirokazu Komori , Takafumi Yamato , Meiten Koh
发明人： Tsuyoshi Noguchi , Jiazhong Luo , Tatsuya Morikawa , Hirokazu Komori , Takafumi Yamato , Meiten Koh
IPC分类号： C08F214/26
CPC分类号： C08L27/18 , C08K5/18 , C08L2205/02 , Y10T428/3154 , C08L2666/04
摘要： The present invention includes crosslinked perfluoroelastomeric compositions and molded articles formed from a cross-linkable perfluoroelastomeric composition having a first curable perfluoropolymer having a cure site monomer and a second perfluoropolymer having a cure site monomer. The molar ratio of the tetrafluoroethylene monomer to perfluoroalkylvinyl ether in one perfluoropolymer is about 0 to 100 to about 65 to 35 in the perfluoropolymer. The molar ratio of the tetrafluoroethylene monomer to the perfluoroalkylvinyl ether monomer in the second polymer is about 65:35 to about 95:5 in the second perfluoropolymer. The composition further includes a curative. One fluorine-containing elastomer composition herein, having a short crosslinking time, has perfluoroelastomers (A) having a tetrafluoroethylene unit, a perfluoralkylvinyl ether unit (a) and a monomer unit (b) having at least one kind selected from the group consisting of a nitrile group, a carboxyl group and an alkoxycarbonyl group, wherein the composition has two or more kinds of perfluoroelastomers (A) having differing contents of perfluoroalkylvinyl ether unit (a).

3. 发明授权

US09068069B2 Perfluoroelastomer compositions and methods of preparing same 有权
标题翻译：全氟弹性体组合物及其制备方法
公开(公告)号：US09068069B2
公开(公告)日：2015-06-30
申请号：US12969463
申请日：2010-12-15
申请人： Tsuyoshi Noguchi , Jiazhong Luo , Tatsuya Morikawa , Hirokazu Komori , Takafumi Yamato , Meiten Koh
发明人： Tsuyoshi Noguchi , Jiazhong Luo , Tatsuya Morikawa , Hirokazu Komori , Takafumi Yamato , Meiten Koh
IPC分类号： C08L27/18 , C08K5/18
CPC分类号： C08L27/18 , C08K5/18 , C08L2205/02 , Y10T428/3154 , C08L2666/04
摘要： The present invention includes crosslinked perfluoroelastomeric compositions and molded articles formed from a cross-linkable perfluoroelastomeric composition having a first curable perfluoropolymer having a cure site monomer and a second perfluoropolymer having a cure site monomer. The molar ratio of the tetrafluoroethylene monomer to perfluoroalkylvinyl ether in one perfluoropolymer is about 0 to 100 to about 65 to 35 in the perfluoropolymer. The molar ratio of the tetrafluoroethylene monomer to the perfluoroalkylvinyl ether monomer in the second polymer is about 65:35 to about 95:5 in the second perfluoropolymer. The composition further includes a curative. One fluorine-containing elastomer composition herein, having a short crosslinking time, has perfluoroelastomers (A) having a tetrafluoroethylene unit, a perfluoralkylvinyl ether unit (a) and a monomer unit (b) having at least one kind selected from the group consisting of a nitrile group, a carboxyl group and an alkoxycarbonyl group, wherein the composition has two or more kinds of perfluoroelastomers (A) having differing contents of perfluoroalkylvinyl ether unit (a).
摘要翻译：本发明包括交联的全氟弹性体组合物和由可交联的全氟弹性体组合物形成的模塑制品，其具有具有固化部位单体的第一可固化全氟聚合物和具有固化部位单体的第二全氟聚合物。全氟聚合物中四氟乙烯单体与全氟烷基乙烯基醚的摩尔比在全氟聚合物中为约0至约100至约65至35。第二聚合物中四氟乙烯单体与全氟烷基乙烯基醚单体的摩尔比在第二全氟聚合物中为约65:35至约95:5。组合物还包括治疗剂。具有交联时间短的一种含氟弹性体组合物具有全氟弹性体（A），其具有四氟乙烯单元，全氟烷基乙烯基醚单元（a）和单体单元（b），所述单体单元具有选自以下的至少一种：腈基，羧基和烷氧基羰基，其中所述组合物具有两种或更多种具有不同全氟烷基乙烯基醚单元（a）含量的全氟弹性体（A）。

4. 发明申请

US20110086229A1 PERFLUOROELASTOMER COMPOSITIONS AND METHODS OF PREPARING SAME 有权
标题翻译：全氟聚合物组合物及其制备方法
公开(公告)号：US20110086229A1
公开(公告)日：2011-04-14
申请号：US12969463
申请日：2010-12-15
申请人： Tsuyoshi Noguchi , Jiazhong Luo , Tatsuya Morikawa , Hirokazu Komori , Takafumi Yamato , Meiten Koh
发明人： Tsuyoshi Noguchi , Jiazhong Luo , Tatsuya Morikawa , Hirokazu Komori , Takafumi Yamato , Meiten Koh
IPC分类号： C08L27/22 , C08L27/18 , B32B15/08
CPC分类号： C08L27/18 , C08K5/18 , C08L2205/02 , Y10T428/3154 , C08L2666/04
摘要： The present invention includes crosslinked perfluoroelastomeric compositions and molded articles formed from a cross-linkable perfluoroelastomeric composition having a first curable perfluoropolymer having a cure site monomer and a second perfluoropolymer having a cure site monomer. The molar ratio of the tetrafluoroethylene monomer to perfluoroalkylvinyl ether in one perfluoropolymer is about 0 to 100 to about 65 to 35 in the perfluoropolymer. The molar ratio of the tetrafluoroethylene monomer to the perfluoroalkylvinyl ether monomer in the second polymer is about 65:35 to about 95:5 in the second perfluoropolymer. The composition further includes a curative. One fluorine-containing elastomer composition herein, having a short crosslinking time, has perfluoroelastomers (A) having a tetrafluoroethylene unit, a perfluoralkylvinyl ether unit (a) and a monomer unit (b) having at least one kind selected from the group consisting of a nitrile group, a carboxyl group and an alkoxycarbonyl group, wherein the composition has two or more kinds of perfluoroelastomers (A) having differing contents of perfluoroalkylvinyl ether unit (a).
摘要翻译：本发明包括交联的全氟弹性体组合物和由可交联的全氟弹性体组合物形成的模塑制品，其具有具有固化部位单体的第一可固化全氟聚合物和具有固化部位单体的第二全氟聚合物。全氟聚合物中四氟乙烯单体与全氟烷基乙烯基醚的摩尔比在全氟聚合物中为约0至约100至约65至35。第二聚合物中四氟乙烯单体与全氟烷基乙烯基醚单体的摩尔比在第二全氟聚合物中为约65:35至约95:5。组合物还包括治疗剂。具有交联时间短的一种含氟弹性体组合物具有全氟弹性体（A），其具有四氟乙烯单元，全氟烷基乙烯基醚单元（a）和单体单元（b），所述单体单元具有选自以下的至少一种：腈基，羧基和烷氧基羰基，其中所述组合物具有两种或更多种具有不同全氟烷基乙烯基醚单元（a）含量的全氟弹性体（A）。

5. 发明申请

US20100151254A1 Perfluoroelastomer Compositions Including Barium Titanate Fillers 审中-公开
标题翻译：包括钛酸钡填料的全氟弹性体组合物
公开(公告)号：US20100151254A1
公开(公告)日：2010-06-17
申请号：US12635640
申请日：2009-12-10
申请人： Jiazhong Luo , Tsuyoshi Noguchi
发明人： Jiazhong Luo , Tsuyoshi Noguchi
IPC分类号： C08K3/22 , B32B15/08 , F16J15/10
CPC分类号： F16J15/102 , Y10T428/31544
摘要： Provided herein is a fluorine-containing elastomer composition having a first curable perfluoropolymer comprising tetrafluoroethylene, at least one perfluoroalkylvinyl ether and at least one cure site monomer having a functional group to permit crosslinking of the perfluoropolymer; and barium titanate.
摘要翻译：本发明提供一种含氟弹性体组合物，其具有包含四氟乙烯，至少一种全氟烷基乙烯基醚和至少一种具有官能团的固化部位单体的第一可固化全氟聚合物，以使全氟聚合物交联; 和钛酸钡。

6. 发明授权

US08632699B2 Fugitive viscosity and stability modifiers for carbon nanotube compositions 失效
标题翻译：用于碳纳米管组合物的挥发性粘度和稳定性改性剂
公开(公告)号：US08632699B2
公开(公告)日：2014-01-21
申请号：US11547903
申请日：2005-04-07
申请人： Paul J. Glatkowski , Joseph W. Piche , C. Michael Trottier , Philip Wallis , David J. Arthur , Jiazhong Luo
发明人： Paul J. Glatkowski , Joseph W. Piche , C. Michael Trottier , Philip Wallis , David J. Arthur , Jiazhong Luo
IPC分类号： H01B1/24 , H01B1/18
CPC分类号： B82Y30/00 , B82Y10/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/28 , H01B1/24 , H01L51/0007 , H01L51/0048
摘要： The invention is directed to carbon nanotube-containing compositions that have increased viscosity and stability. In particular, the invention is directed to methods for manufacturing carbon nanotube films and layers that provide superior electrical properties.
摘要翻译：本发明涉及具有增加的粘度和稳定性的含碳纳米管的组合物。特别地，本发明涉及制造提供优异电性能的碳纳米管膜和层的方法。

7. 发明申请

US20050266162A1 Carbon nanotube stripping solutions and methods 审中-公开
标题翻译：碳纳米管剥离溶液及方法
公开(公告)号：US20050266162A1
公开(公告)日：2005-12-01
申请号：US11079012
申请日：2005-03-14
申请人： Jiazhong Luo , Philip Wallis , David Arthur , Paul Glatkowski
发明人： Jiazhong Luo , Philip Wallis , David Arthur , Paul Glatkowski
IPC分类号： B05D1/12 , C01B31/02 , C09D9/00 , H01B1/24
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C09D9/005 , H01B1/24
摘要： The invention is directed to compositions and methods for forming conductive patterned coatings of carbon nanotubes. Patterns are electrically conductive coatings/films made by exploiting self patterning nanostructures composed of electrically conductive materials. The resulting layer is suitable for conducting electricity in applications where a transparent electrode is required. Typical applications include, but are not limited to; LC displays, touch screens, EMI shielding windows, and architectural windows. Films may be highly transparent. In one embodiment, carbon nanotubes are applied to an insulating substrate to form an electrically conductive network of nanotubes with controlled porosity in the network. The open area between the networks of nanotubes, increases the optical transparency in the visible spectrum while the continuous nanotube phase provides electrical conductivity across the entire surface or patterned area. Through the controlled application of this self assembled network of nanotubes by means of printing or spraying, patterned areas can be formed to function as electrodes in devices. The use of printing technology to form these electrodes obviates the need for more expensive process such as vacuum deposition and photolithography typically employed today during the formation of ITO coatings.
摘要翻译：本发明涉及用于形成碳纳米管的导电图案化涂层的组合物和方法。图案是通过利用由导电材料构成的自组装纳米结构制成的导电涂层/薄膜。所得的层适用于在需要透明电极的应用中导电。典型应用包括但不限于： LC显示屏，触摸屏，EMI屏蔽窗和建筑窗口。电影可能非常透明。在一个实施例中，将碳纳米管施加到绝缘基板上以形成网络中具有受控多孔性的纳米管的导电网络。纳米管网络之间的开放区域增加了可见光谱中的光学透明度，而连续的纳米管相位提供整个表面或图案区域的导电性。通过这种通过印刷或喷涂的纳米管自组装网络的受控应用，可以形成图案化的区域以用作器件中的电极。使用印刷技术形成这些电极消除了在ITO涂层形成期间通常使用的更昂贵的工艺，例如真空沉积和光刻的需要。

8. 发明申请

US20050003217A1 Fluid resistant silicone encapsulant 失效
标题翻译：耐流体硅胶密封胶
公开(公告)号：US20050003217A1
公开(公告)日：2005-01-06
申请号：US10901699
申请日：2004-07-29
申请人： Elizabeth Walker , Jiazhong Luo , Rose Schultz , Katharine Pearce
发明人： Elizabeth Walker , Jiazhong Luo , Rose Schultz , Katharine Pearce
IPC分类号： G01L19/06 , C08G77/50 , C08K5/5435 , C08L83/04 , C08L83/05 , C08L83/08 , C08L83/14 , B32B9/04
CPC分类号： C08G77/50 , C08G77/12 , C08G77/20 , C08G77/70 , C08K5/5435 , C08L83/04 , C08L83/08 , C08L83/14 , H01L23/296 , H01L2924/0002 , Y10T428/31663 , C08L83/00 , H01L2924/00
摘要： A cross-linkable and cross-linked organosilicon polymer which is prepared from a mixture of a reactive polysiloxane resin having both reactive carbon-carbon double bonds and silicone-hydrogen groups, characterized by alternating structures of polycyclic polyene residue and cyclic (or tetrahedral) polysiloxane residue, and either vinyl terminated fluorine-containing polysiloxane or vinyl terminated phenyl-substituted siloxane. In an alternative embodiment, the polymer comprises a mixture of vinyl terminated phenyl-substituted polysiloxane and vinyl functional fluorosilicone elastomer with the cross-linkable and cross linked organosilicon polymer.
摘要翻译：由具有反应性碳 - 碳双键和硅氢基团的反应性聚硅氧烷树脂的混合物制备的可交联和交联的有机硅聚合物，其特征在于多环多烯残基和环（或四面体）聚硅氧烷的交替结构残基和乙烯基封端的含氟聚硅氧烷或乙烯基封端的苯基取代的硅氧烷。在替代实施方案中，聚合物包含乙烯基封端的苯基取代的聚硅氧烷和乙烯基官能的氟硅氧烷弹性体与可交联和交联的有机硅聚合物的混合物。

9. 发明授权

US6087432A Particle engineering for toughened polyimide-matrix composites 失效
标题翻译：增韧聚酰亚胺基复合材料的粒子工程
公开(公告)号：US6087432A
公开(公告)日：2000-07-11
申请号：US126823
申请日：1998-07-31
申请人： John J. Lannutti , Robert R. Seghi , Jiazhong Luo
发明人： John J. Lannutti , Robert R. Seghi , Jiazhong Luo
IPC分类号： C08K3/34
CPC分类号： C08K3/34
摘要： The material of the present invention is a filled polymeric material, the material comprising, or consisting essentially of, a thermosetting polymeric material formed from the at least one monomer; the thermosetting polymeric containing a nano-porous inorganic gel material, the inorganic gel material having a sufficient degree of porosity for the monomer(s) such that the inorganic gel material is capable of bonding to the thermosetting polymeric material during polymerization. The present invention also includes an method for the production of such filled polymeric materials.
摘要翻译：本发明的材料是填充的聚合物材料，该材料包含或基本上由至少一种单体形成的热固性聚合物材料; 含有纳米多孔无机凝胶材料的热固性聚合物，所述无机凝胶材料对于单体具有足够的孔隙度，使得无机凝胶材料能够在聚合过程中与热固性聚合材料结合。本发明还包括用于生产这种填充的聚合物材料的方法。

10. 发明授权

US07378040B2 Method of forming fluoropolymer binders for carbon nanotube-based transparent conductive coatings 失效
标题翻译：形成碳纳米管基透明导电涂层的氟聚合物粘合剂的方法
公开(公告)号：US07378040B2
公开(公告)日：2008-05-27
申请号：US11201275
申请日：2005-08-11
申请人： Jiazhong Luo , David J. Arthur , Paul J. Glatkowski
发明人： Jiazhong Luo , David J. Arthur , Paul J. Glatkowski
IPC分类号： H01B1/00
CPC分类号： H01B1/24 , B82Y10/00 , C08J7/045 , C08J2367/02 , C08J2427/12 , Y10T156/10
摘要： This invention relates to flexible, transparent and conductive coatings and films formed using carbon nanotubes (CNT) and, in particular, single wall CNT, with polymer binders. Preferably, coatings and films are formed from CNT applied to transparent substrates forming one or multiple conductive layers at nanometer level of thickness. Polymer binders are applied to the CNT network coating having an open structure to provide protection through infiltration, and may comprise a basecoat, a topcoat, or a combination thereof, providing enhanced optical transparency, conductivity, moisture resistance, thermal resistance, abrasion resistance and interfacial adhesion. Polymers may be thermoplastics, thermosets, insulative, conductive or a combination thereof. A fluoropolymer containing binder is applied onto a CNT-based transparent conductive coating at nanometer level of thickness on a clear substrate. The fluoropolymers or blend can be either semi-crystalline or amorphous. This binder coating and the resulting products can be used for display and electronic applications.
摘要翻译：本发明涉及使用碳纳米管（CNT），特别是单壁CNT与聚合物粘合剂形成的柔性，透明和导电的涂层和膜。优选地，涂层和膜由施加到形成纳米级厚度的一个或多个导电层的透明基板上的CNT形成。将聚合物粘合剂施加到具有开放结构的CNT网络涂层以通过渗透提供保护，并且可以包括底漆，面漆或其组合，提供增强的光学透明度，导电性，耐湿性，耐热性，耐磨性和界面附着力。聚合物可以是热塑性塑料，热固性材料，绝缘，导电或其组合。将含氟聚合物的粘合剂以纳米级的透明基材涂覆在CNT-基透明导电涂层上。含氟聚合物或共混物可以是半结晶或无定形的。该粘合剂涂层和所得产品可用于显示和电子应用。

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