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    • 3. 发明授权
    • Rod-shaped or tubular amorphous Zr alloy made by die casting and method
for manufacturing said amorphous Zr alloy
    • 通过压铸制成的棒状或管状无定形Zr合金以及制造所述无定形Zr合金的方法
    • US5803996A
    • 1998-09-08
    • US651668
    • 1996-05-21
    • Akihisa InoueTsuyoshi MasumotoTao ZhangYoshiyuki Shinohara
    • Akihisa InoueTsuyoshi MasumotoTao ZhangYoshiyuki Shinohara
    • C22C16/00B81C99/00C22C45/10C22F1/18
    • C22C45/10
    • An alloy material 4 received in a melting hearth 1 is melted by high-density energy supplied from a heat source 5. The molten alloy is transferred to a forced-cooled die 3 having a cavity 2 defining the profile of a product, and quenched to an amorphous state. The alloy has the composition represented by the general formula of Zr.sub.100-a-b-c A.sub.a B.sub.b C.sub.c (wherein the mark A represents one or more elements selected from Ti, Hf, Al and Ga, the mark B represents one or more elements selected from Fe, Co, Ni and Cu, the mark C represents one or more elements selected from Pd, Pt, Au and Ag, and the marks a-c represent the atomic ratios of respective elements A-C under the conditions of a=5-20, b=15-45, c.ltoreq.10 and a+b+c=30-70. The differential temperature region .DELTA.T (=T.sub.x -T.sub.g) in the supercooled liquid phase of the Zr alloy represented by the difference between the crystallization point T.sub.x and the glass transition point T.sub.g, is preferably 100 K or more. The obtained amorphous alloy has a rod-shaped or tubular profile having a large cross section and being excellent in plastic workability.
    • 容纳在熔化炉床1中的合金材料4由从热源5供给的高密度能量熔化。熔融合金被转移到具有限定产品轮廓的空腔2的强制冷却模具3中, 无定形状态。 该合金具有由通式Zr100-ab-cAaBbCc表示的组成(其中,标记A表示选自Ti,Hf,Al和Ga中的一种或多种元素,标记B表示选自Fe,Co, Ni和Cu,标记C表示选自Pd,Pt,Au和Ag中的一种或多种元素,标记ac表示在a = 5-20,b = 15-45的条件下各元素AC的原子比, c + = 10-70,a + b + c = 30-70,Zr合金过冷液相中的温差区域DELTA T(= Tx-Tg)由结晶点Tx和玻璃化转变温度 点Tg优选为100K以上,得到的非晶合金具有截面积大,塑性加工性优异的棒状或管状。
    • 4. 发明授权
    • Rod-shaped or tubular amorphous Zr alloy made by die casting and method
for manufacturing said amorphous Zr alloy
    • 通过压铸制成的棒状或管状无定形Zr合金以及制造所述无定形Zr合金的方法
    • US5980652A
    • 1999-11-09
    • US28008
    • 1998-02-23
    • Akihisa InoueTsuyoshi MasumotoTao ZhangYoshiyuki Shinohara
    • Akihisa InoueTsuyoshi MasumotoTao ZhangYoshiyuki Shinohara
    • C22C45/10C22C16/00
    • C22C45/10
    • An alloy material 4 received in a melting hearth 1 is melted by high-density energy supplied from a heat source 5. The molten alloy is transferred to a forced-cooled die 3 having a cavity 2 defining the profile of a product, and quenched to an amorphous state. The alloy has the composition represented by the general formula of Zr.sub.100-a-b-c A.sub.a B.sub.b C.sub.c, wherein the mark A represents one or more elements selected from Ti, Hf, Al and Ga, the mark B represents one or more elements selected from Fe, Co, Ni and Cu, the mark C represents one or more elements selected from Pd, Pt, Au and Ag, and the marks a-c represent the atomic ratios of respective elements A-C under the conditions of a=5-20, b=15-45, c.ltoreq.10 and a+b+c=30-70. The differential temperature region .DELTA.T (=T.sub.x -T.sub.g) in the supercooled liquid phase of the Zr alloy represented by the difference between the crystallization point T.sub.x and the glass transition point T.sub.g is preferably 100 K or more. The obtained amorphous alloy has a rod-shaped or tubular profile having a large cross section and being excellent in plastic workability.
    • 容纳在熔化炉床1中的合金材料4由从热源5供给的高密度能量熔化。熔融合金被转移到具有限定产品轮廓的空腔2的强制冷却模具3中, 无定形状态。 该合金具有由通式Zr100-ab-cAaBbCc表示的组成,其中标记A表示选自Ti,Hf,Al和Ga中的一种或多种元素,标记B表示选自Fe,Co, Ni和Cu,标记C表示选自Pd,Pt,Au和Ag中的一种或多种元素,标记ac表示在a = 5-20,b = 15-45的条件下各元素AC的原子比, c
    • 5. 发明授权
    • High strength and high rigidity aluminum-based alloy
    • 高强度高刚性铝基合金
    • US06017403A
    • 2000-01-25
    • US601949
    • 1996-02-15
    • Tsuyoshi MasumotoAkihisa InoueYuma Horio
    • Tsuyoshi MasumotoAkihisa InoueYuma Horio
    • C22C21/00
    • C22C21/00
    • An aluminum-based alloy having the general formula Al.sub.x L.sub.y M.sub.z (wherein L is Mn or Cr; M is Ni, Co, and/or Cu; and x, y, and z, representing a composition ratio in atomic percentages, satisfy the relationships x+y+z=100, 75.ltoreq.x.ltoreq.95, 2.ltoreq.y.ltoreq.15, and 0.5.ltoreq.z.ltoreq.10) having a metallographic structure comprising a quasi-crystalline phase possesses high strength and high rigidity. In order to enhance the ductility and toughness of the aluminum-based alloy, the atomic percentage of M may be further limited to 0.5.ltoreq.z.ltoreq.4, and more preferably to 0.5.ltoreq.z.ltoreq.3. The aluminum-based alloy is useful as a structural material for aircraft, vehicles and ships, and for engine parts; as material for sashes, roofing materials, and exterior materials for use in construction; or as materials for use in marine equipment, nuclear reactors, and the like.
    • 具有通式AlxLyMz(其中L是Mn或Cr; M是Ni,Co和/或Cu;和表示原子百分比的组成比的x,y和z)的铝基合金满足关系x + 具有包含准结晶相的金相组织的y + z = 100,75,或者= x,y = x,z = 100,75
    • 10. 发明授权
    • Sacrificial electrode material for corrosion prevention
    • 用于防腐的牺牲电极材料
    • US5423969A
    • 1995-06-13
    • US217009
    • 1994-03-23
    • Tsuyoshi MasumotoAkihisa InoueTakashi SakumaToshisuke Shibata
    • Tsuyoshi MasumotoAkihisa InoueTakashi SakumaToshisuke Shibata
    • C22C23/00C22C45/00C23F13/00C23F13/14C25B11/04
    • C23F13/14
    • The present invention provides a sacrificial electrode material which consists of a single phase amorphous structure or a structure consisting of an amorphous phase and a crystalline solid solution phase and provides electrochemical corrosion protection to metallic articles exposed to an aqueous electrolytic solution. The electrode material is prepared by rapidly quenching a magnesium-based alloy material from the liquid phase or vapor phase thereof, the magnesium-based alloy material consisting the general formula: Mg.sub.bal X1.sub.a X2.sub.b or Mg.sub.bal X1.sub.a, wherein X1 is at least one element selected from the group consisting of Al, Zn, Ga, Ca and In; X2 is at least one element selected from the group consisting of Mm (misch metal), Y and rare earth metal elements; a and b are, in atomic percentages, 5.0.ltoreq.a.ltoreq.35.0 and 3.0.ltoreq.b.ltoreq.25.0, respectively. The magnesium-based alloy material may further contain one or more transition metal elements in their total contents not exceeding 1.0 atomic %.
    • 本发明提供一种牺牲电极材料,其由单相无定形结构或由非晶相和结晶固溶体相组成的结构组成,并且对暴露于水性电解液的金属制品提供电化学腐蚀保护。 通过从其液相或气相快速淬火镁基合金材料制备电极材料,镁基合金材料由以下通式组成:MgbalX1aX2b或MgbalX1a,其中X1是选自以下的至少一种元素: 的Al,Zn,Ga,Ca和In; X2是选自由Mm(混合稀土金属),Y和稀土金属元素组成的组中的至少一种元素; a和b分别为原子百分比为5.0