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    • 6. 发明申请
    • Plasma-Assisted Deposition Method and System for Carrying Out the Same
    • 等离子辅助沉积方法及其执行系统
    • US20070259131A1
    • 2007-11-08
    • US11660649
    • 2006-08-25
    • Yasuo KobayashiKenichi NishizawaTakatoshi KameshimaRyuichiro IsakiManabu Shinriki
    • Yasuo KobayashiKenichi NishizawaTakatoshi KameshimaRyuichiro IsakiManabu Shinriki
    • H01L21/314H01L21/31H01L21/768
    • H01L21/0212C23C16/26C23C16/4402H01L21/02274H01L21/3127
    • A fluorine-containing carbon film excellent in heat stability is formed by using C5F8 gas having a moisture content of 60×10−9 volume ratio or below. A purifier 2 packed with particles having hydrophilic or reducing surface layers is placed in a gas supply line connecting a process gas source 1 for supplying C5F8 gas and a film deposition unit 3 for depositing a fluorine-containing carbon film on a substrate by using a plasma produced by ionizing C5F8 gas. C5F8 gas is passed through the purifier 2 to remove moisture from the C5F8 gas. The C5F8 gas supplied to the film deposition unit 3 to deposit a fluorine-containing carbon film has a moisture content on the order of 20×10−9 volume ratio. A fluorine-containing carbon film thus deposited contains a very small amount of moisture. Consequently, desorption of fluorine due to moisture contained in the fluorine-containing carbon film when the fluorine-containing carbon film is heated by a subsequent heating process is not likely to occur and the fluorine-containing carbon film has high heat stability.
    • 通过使用水分含量为60×10 -9体积比的C 5 N 5 S 8气体形成热稳定性优异的含氟碳膜 或以下。 填充有具有亲水性或还原性表面层的颗粒的净化器2放置在连接用于供应C 5 C 8气体的处理气体源1和膜沉积物的气体供应管线 单元3,用于通过使用通过电离C 5 C 8气体产生的等离子体在基板上沉积含氟碳膜。 气体通过净化器2以从C 5 C 8气体中除去水分。 供给到成膜单元3以沉积含氟碳膜的C 5 C 8 N 8气体的水分含量为20×10 -9 / SUP>体积比。 这样沉积的含氟碳膜含有非常少量的水分。 因此,通过随后的加热工序加热含氟碳膜时,由于含氟碳膜所含的水分的氟解吸不易发生,含氟碳膜的热稳定性高。